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Utah State University

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2015

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Articles 31 - 60 of 140

Full-Text Articles in Physical Sciences and Mathematics

A Coordinated Study Of 1-H Mesoscale Gravity Waves Propagating From Logan To Boulder With Crrl Na Doppler Lidars And Temperature Mapper, Xian Liu, Cao Chen, Wentao Huang, John A. Smith, Xinzhao Chu, Tao Yuan, Pierre-Dominique Pautet, Michael J. Taylor, Jie Gong, Chihoko Y. Cullens Oct 2015

A Coordinated Study Of 1-H Mesoscale Gravity Waves Propagating From Logan To Boulder With Crrl Na Doppler Lidars And Temperature Mapper, Xian Liu, Cao Chen, Wentao Huang, John A. Smith, Xinzhao Chu, Tao Yuan, Pierre-Dominique Pautet, Michael J. Taylor, Jie Gong, Chihoko Y. Cullens

Publications

We present the first coordinated study using two lidars at two separate locations to characterize a 1 h mesoscale gravity wave event in the mesopause region. The simultaneous observations were made with the Student Training and Atmospheric Research (STAR) Na Doppler lidar at Boulder, CO, and the Utah State University Na Doppler lidar and temperature mapper at Logan, UT, on 27 November 2013. The high precision possessed by the STAR lidar enabled these waves to be detected in vertical wind. The mean wave amplitudes are ~0.44 m/s in vertical wind and ~1% in relative temperature at altitudes of 82–107 km. …

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Comparing Experimental Apples And Oranges With Quantile-Quantile Plots, Allen Andersen, Jr Dennison Oct 2015

Comparing Experimental Apples And Oranges With Quantile-Quantile Plots, Allen Andersen, Jr Dennison

Presentations

An important question often encountered in experimental physics is, are two observables related or not? Quantile-quantile (q-q) analysis compares the cumulative distributions of two observations (or one set of observations and a theoretical curve) in a way that is both visually apparent and statistically quantifiable. If the two observables follow the same distribution, the q-q plot will be linear; if they are identical the plot will have unity slope. Deviations from a linear q-q plot indicate that the two observables do not follow the same distribution. We show that the q-q analysis method is applicable to a wide range of …

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The Space Survivability Test Chamber, Katie Gamaunt, Heather Tippets, Alex Souvall, Ben Russon, Jr Dennison Oct 2015

The Space Survivability Test Chamber, Katie Gamaunt, Heather Tippets, Alex Souvall, Ben Russon, Jr Dennison

Posters

The Space Survivability Test chamber is a new ground-based research instrument being used for accelerated testing of environment-induced modifications of diverse samples. The chamber simulates space environment conditions, including neutral gas atmospheres and vacuum (<10-5 Pa) environments, temperature (~100 K to >450 K), ionizing radiation, electron fluxes (<10 eV to ~2½ MeV), and vacuum ultraviolet through mid-infrared photon fluxes. This versatile test chamber is well-suited for cost-effective testing of complete systems up to the size (< 20 cm dia.) of a 1U CubeSat, smaller components or electronics, and individual material samples. Multiple in-flux or in-situ space survivability and radiation exposure tests can be performed simultaneously, as well as extensive before and after ex-situ tests. Currently the chamber is performing a series of radiation experiments using a Sr90 beta radiation source which approximately mimics the geostationary high energy electron spectra at ~4-10X accelerated …

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Density Of State Models Of Steady-State Temperature Dependent Radiation Induced Conductivity, Jodie Corbridge Gillespie, Jr Dennison Oct 2015

Density Of State Models Of Steady-State Temperature Dependent Radiation Induced Conductivity, Jodie Corbridge Gillespie, Jr Dennison

Posters

Radiation induced conductivity (RIC) occurs when incident radiation deposits energy and excites electrons into the conduction band of insulators. The magnitude of the enhanced conductivity is dependent on a number of factors including temperature and the spatial- and energy-dependence and occupation of the material’s distribution of localized trap states within the band gap—or density of states (DOS). Expressions are developed for steady-state RIC over an extended temperature range, based on DOS models for highly disordered insulating materials. A general discussion of the DOS of disordered materials can be given using two simple distributions: one that monotonically decreases below the band …

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Properties Of Spacecraft Materials Exposed To Ionizing Radiation, Alex Souvall, Gregory Wilson, Katie Gamaunt, Ben Russon, Heather Tippets, Jr Dennison Oct 2015

Properties Of Spacecraft Materials Exposed To Ionizing Radiation, Alex Souvall, Gregory Wilson, Katie Gamaunt, Ben Russon, Heather Tippets, Jr Dennison

Posters

The effects of ionizing radiation damage on the various properties of spacecraft materials resulting from exposure in the Space Survivability Testing chamber (SST) are being studied with both ex situ and in situ tests. The SST is a ground based test facility designed to mimic low earth orbit (LEO), and geosynchronous orbit to test potential environmental-induced modifications to small satellites , and materials. Tests described here expose spacecraft materials to a Sr90 ionizing beta radiation source at room temperature and in high vacuum. Ex situ optical transmission/reflectivity measurements glass samples will monitor optical darkening. Properties of polymeric samples will …

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Multi-Scale Environmental Filters And Niche Partitioning Govern The Distributions Of Riparian Vegetation Guilds, Nate Hough-Snee, Brian G. Laub, David M. Merritt, Arin Lexine Long, Lloyd L. Nackley, Brett B. Roper, Joseph Michael Wheaton Oct 2015

Multi-Scale Environmental Filters And Niche Partitioning Govern The Distributions Of Riparian Vegetation Guilds, Nate Hough-Snee, Brian G. Laub, David M. Merritt, Arin Lexine Long, Lloyd L. Nackley, Brett B. Roper, Joseph Michael Wheaton

Watershed Sciences Faculty Publications

Across landscapes, riparian plant communities assemble under varying levels of disturbance, environmental stress, and resource availability, leading to the development of distinct riparian life-history guilds over evolutionary timescales. Identifying the environmental filters that exert selective pressures on specific riparian vegetation guilds is a critical step in setting baseline expectations for how riparian vegetation may respond to environmental conditions anticipated under future global change scenarios. In this study, we ask: (1) What riparian plant guilds exist across the interior Columbia and upper Missouri River basins? (2) What environmental filters shape riparian guild distributions? (3) How does resource partitioning among guilds influence …

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Dependence Of Electrostatic Field Strength On Voltage Ramp Rates For Spacecraft Material, Krysta Moser, Allen Andersen, Jr Dennison Oct 2015

Dependence Of Electrostatic Field Strength On Voltage Ramp Rates For Spacecraft Material, Krysta Moser, Allen Andersen, Jr Dennison

Posters

Previous tests done by the USU Materials Physics Group (MPG) using our electrostatic discharge (ESD) custom vacuum chamber have found that, for the polymeric materials polyimide and low density polyethylene (LDPE), the electrostatic field strength at breakdown depends on the voltage ramp rate applied across the materials. At ramp rates an order of magnitude lower than the maximum recommended rate of 500 V/s, the breakdown electrostatic field strength was also found to be significantly lower. The data from these tests were compared to a microscopic mean field theory for dielectric breakdown in highly disordered insulating materials. We present new ramp …

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Measurement Of Effects Of Long Term Ionizing Radiation On High Efficiency Solar Arrays, Ben Russon, Heather Tippets, Gregory Wilson, Katie Gamaunt, Alex Souvall, Jr Dennison Oct 2015

Measurement Of Effects Of Long Term Ionizing Radiation On High Efficiency Solar Arrays, Ben Russon, Heather Tippets, Gregory Wilson, Katie Gamaunt, Alex Souvall, Jr Dennison

Posters

Degradation of power output efficiency for high-efficiency multilayer solar arrays due to ionizing radiation is measured using the Space Survivability Test chamber. Exposure to ionizing radiation disrupts the crystalline structure and can reduce solar array power output to the point that it no longer provides adequate output capacity. This can be a significant concern, particularly in the harsh environment of space where radiation dose rate is significantly higher and replacing components is often impossible. Ionizing radiation is simulated in a controlled environment to allow measurement and characterization of the power output of solar arrays, using a 100 mCi encapsulated Sr90 …

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Predictive Formula For Electron Range Over A Large Span Of Energies, Anne C. Starley, Gregory Wilson, Lisa Montierth Phillipps, Jr Dennison Oct 2015

Predictive Formula For Electron Range Over A Large Span Of Energies, Anne C. Starley, Gregory Wilson, Lisa Montierth Phillipps, Jr Dennison

Posters

A model has been developed to predict the approximate penetration depth into diverse classes of materials for a broad range of energetic incident electrons (<10 eV to >10 MeV, with better than 20% accuracy). The penetration depth—or range—of a material describes the maximum distance electrons can travel through a material, before losing all of its incident kinetic energy. This model leads to a predictive formula that estimates the penetration depth for materials without the need for supporting data, but rather using only basic material properties and a single fitting parameter (Nv, described as the effective number of valence electrons). Nv …

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Enhanced Electron Yield Measurements Of Extremely Low-Conductivity High Yield Dielectrics, Justin Christensen, Jr Dennison Oct 2015

Enhanced Electron Yield Measurements Of Extremely Low-Conductivity High Yield Dielectrics, Justin Christensen, Jr Dennison

Presentations

An important question often encountered in experimental physics is, are two observables related or not? Quantile-quantile (q-q) analysis compares the cumulative distributions of two observations (or one set of observations and a theoretical curve) in a way that is both visually apparent and statistically quantifiable. If the two observables follow the same distribution, the q-q plot will be linear; if they are identical the plot will have unity slope. Deviations from a linear q-q plot indicate that the two observables do not follow the same distribution. We show that the q-q analysis method is applicable to a wide range of …

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Using Life History Trade-Offs To Understand Core-Transient Structuring Of A Small Mammal Community, Sarah R. Supp, David N. Koons, S.K. Morgan Ernest Oct 2015

Using Life History Trade-Offs To Understand Core-Transient Structuring Of A Small Mammal Community, Sarah R. Supp, David N. Koons, S.K. Morgan Ernest

Wildland Resources Faculty Publications

An emerging conceptual framework suggests that communities are composed of two main groups of species through time: core species that are temporally persistent, and transient species that are temporally intermittent. Core and transient species have been shown to differ in spatiotemporal turnover, diversity patterns, and importantly, survival strategies targeted at local versus regional habitat use. While the core-transient framework has typically been a site-specific designation for species, we suggest that if core and transient species have local versus regional survival strategies across sites, and consistently differ in population-level spatial structure and gene flow, they may also typically exhibit different life-history …

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Momentum Flux Estimates Accompanying Multiscale Gravity Waves Over Mount Cook, New Zealand, On 13 July 2014 During The Deepwave Campaign, K. Bossert, D. C. Fritts, B. P. Williams, Michael J. Taylor, B. Kaifler, A. Dornbrack, I. M. Reid, D. J. Murphy, A. J. Spargo, A. D. Mackinnon, Pierre-Dominique Pautet Sep 2015

Momentum Flux Estimates Accompanying Multiscale Gravity Waves Over Mount Cook, New Zealand, On 13 July 2014 During The Deepwave Campaign, K. Bossert, D. C. Fritts, B. P. Williams, Michael J. Taylor, B. Kaifler, A. Dornbrack, I. M. Reid, D. J. Murphy, A. J. Spargo, A. D. Mackinnon, Pierre-Dominique Pautet

All Physics Faculty Publications

Observations performed with a Rayleigh lidar and an Advanced Mesosphere Temperature Mapper aboard the National Science Foundation/National Center for Atmospheric Research Gulfstream V research aircraft on 13 July 2014 during the Deep Propagating Gravity Wave Experiment (DEEPWAVE) measurement program revealed a large-amplitude, multiscale gravity wave (GW) environment extending from ~20 to 90 km on flight tracks over Mount Cook, New Zealand. Data from four successive flight tracks are employed here to assess the characteristics and variability of the larger- and smaller-scale GWs, including their spatial scales, amplitudes, phase speeds, and momentum fluxes. On each flight, a large-scale mountain wave (MW) …

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Interactions Between Thiourea And Imines. Prelude To Catalysis, Vincent De Paul Nzuwah-Nziko, Steve Scheiner Sep 2015

Interactions Between Thiourea And Imines. Prelude To Catalysis, Vincent De Paul Nzuwah-Nziko, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The interaction between thiourea and a series of imines was examined via high-level ab initio calculations. For each imine, there is a set of stable complexes that represent minima on the potential energy surface. One type is characterized by a pair of symmetric NH···N hydrogen bonds (HBs), with both NH groups of thiourea approaching the imine N from above and below its molecular plane. Another geometry category combines a linear NH···N with a CH···S HB. A third, which is less stable, has the S approaching the imine’s CH2 group, and a stacking arrangement is present in the fourth. Interaction energies …

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Momentum Flux Estimates Accompanying Multi-Scale Gravity Waves Over Mt. Cook, New Zealand On 13 July 2014 During The Deepwave Campaign, Katrina Bossert, David C. Fritts, Pierre-Dominique Pautet, Bifford P. Williams, Michael J. Taylor, Bernd Kaifler, Andrea Dornbrack, Iain M. Reid, Damian J. Murphy, Andrew J. Spargo, Andrew D. Mackinnon Sep 2015

Momentum Flux Estimates Accompanying Multi-Scale Gravity Waves Over Mt. Cook, New Zealand On 13 July 2014 During The Deepwave Campaign, Katrina Bossert, David C. Fritts, Pierre-Dominique Pautet, Bifford P. Williams, Michael J. Taylor, Bernd Kaifler, Andrea Dornbrack, Iain M. Reid, Damian J. Murphy, Andrew J. Spargo, Andrew D. Mackinnon

Publications

Observations performed with a Rayleigh lidar and an Advanced Mesosphere Temperature Mapper aboard the National Science Foundation/National Center for Atmospheric Research Gulfstream V research aircraft on 13 July 2014 during the Deep Propagating Gravity Wave Experiment (DEEPWAVE) measurement program revealed a large-amplitude, multiscale gravity wave (GW) environment extending from ~20 to 90 km on flight tracks over Mount Cook, New Zealand. Data from four successive flight tracks are employed here to assess the characteristics and variability of the larger- and smaller-scale GWs, including their spatial scales, amplitudes, phase speeds, and momentum fluxes. On each flight, a large-scale mountain wave (MW) …

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Dependence Of Electrostatic Field Strength On Voltage Ramp Rates For Spacecraft Materials, Krysta Moser, Allen Andersen, Jr Dennison Sep 2015

Dependence Of Electrostatic Field Strength On Voltage Ramp Rates For Spacecraft Materials, Krysta Moser, Allen Andersen, Jr Dennison

Presentations

Previous tests done by the USU Materials Physics Group (MPG) using our electrostatic discharge (ESD) custom vacuum chamber have found that, for the polymeric materials polyimide and low density polyethylene (LDPE), the electrostatic field strength at breakdown depends on the voltage ramp rate applied across the materials. At ramp rates an order of magnitude lower than the maximum recommended rate of 500 V/s, the breakdown electrostatic field strength was also found to be significantly lower. The data from these tests were compared to a microscopic mean field theory for dielectric breakdown in highly disordered insulating materials. We present new ramp …

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Magnetic Meridional Winds In The Thermosphere Obtained From Global Assimilation Of Ionospheric Measurements (Gaim) Model, Levan Lomidze, Ludger Scherliess, Robert W. Schunk Sep 2015

Magnetic Meridional Winds In The Thermosphere Obtained From Global Assimilation Of Ionospheric Measurements (Gaim) Model, Levan Lomidze, Ludger Scherliess, Robert W. Schunk

All Physics Faculty Publications

Thermospheric neutral winds play an important part in the dynamics of ionospheric plasma and represent one of the key inputs for ionospheric physics-based models. Yet wind measurements are scarce and generally lack global coverage and continuity. To help mitigate this shortcoming, a data assimilation model was used to estimate neutral winds in the low- and middle-latitude thermosphere. Seasonal global maps of NmF2 andhmF2 were generated from Constellation Observing System for Meteorology, Ionosphere, and Climate radio occultation measurements for geomagnetically quiet and low solar flux conditions. The maps were assimilated into the Utah State University Global Assimilation of …

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Pre-Breakdown Arcing As A Proxy For Dc Dielectric Breakdown Testing Of Polymeric Insulators, Allen Andersen, Jr Dennison Sep 2015

Pre-Breakdown Arcing As A Proxy For Dc Dielectric Breakdown Testing Of Polymeric Insulators, Allen Andersen, Jr Dennison

Journal Articles

Pre-breakdown arcing is proposed as a key indicator of DC breakdown properties of polymeric dielectric materials. Voltage step-up tests were performed for films of low-density polyethylene (LDPE) at ramp rates significantly lower than is common in most studies, allowing for the observation of both breakdown and transient pre-breakdown current spikes. The distributions of the breakdowns versus applied field were compared with the more frequent pre-breakdown arcs. A strong correlation was observed for LDPE between the distribution of breakdowns in step-up tests and the distribution of pre-breakdown arcing. Pre-breakdown arcing distributions are much easier to obtain than breakdown distributions and may …

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Mountain Pine Beetles Use Volatile Cues To Locate Host Limber Pine And Avoid Non-Host Great Basin Bristlecone Pine, Curtis A. Gray, Justin B. Runyon, Michael J. Jenkins, Andrew D. Giunta Sep 2015

Mountain Pine Beetles Use Volatile Cues To Locate Host Limber Pine And Avoid Non-Host Great Basin Bristlecone Pine, Curtis A. Gray, Justin B. Runyon, Michael J. Jenkins, Andrew D. Giunta

Wildland Resources Faculty Publications

The tree-killing mountain pine beetle (Dendroctonus ponderosae Hopkins) is an important disturbance agent of western North American forests and recent outbreaks have affected tens of millions of hectares of trees. Most western North American pines (Pinus spp.) are hosts and are successfully attacked by mountain pine beetles whereas a handful of pine species are not suitable hosts and are rarely attacked. How pioneering females locate host trees is not well understood, with prevailing theory involving random landings and/or visual cues. Here we show that female mountain pine beetles orient toward volatile organic compounds (VOCs) from host limber pine (Pinus flexilis …

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Added Value From 576 Years Of Tree-Ring Records In The Prediction Of The Great Salt Lake Level, Robert R. Gillies, Oi-Yu Chung, Shih-Yu (Simon) Wang, R. Justin Derose, Yan Sun Sep 2015

Added Value From 576 Years Of Tree-Ring Records In The Prediction Of The Great Salt Lake Level, Robert R. Gillies, Oi-Yu Chung, Shih-Yu (Simon) Wang, R. Justin Derose, Yan Sun

Wasatch Dendroclimatology Research

Predicting lake level fluctuations of the Great Salt Lake (GSL) in Utah – the largest terminal salt-water lake in the Western Hemisphere – is critical from many perspectives. The GSL integrates both climate and hydrological variations within the region and is particularly sensitive to low-frequency climate cycles. Since most hydroclimate variable records cover less than a century, forecasting the predominant yet under-represented decadal variability of the GSL level with such relatively short instrumental records poses a challenge. To overcome data limitations, this study assesses two options: (1) developing a model using the observational GSL elevation record of 137 years to …

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Bear Lake Limnology & Nutrient Limnology, Wayne A. Wurtsbaugh Sep 2015

Bear Lake Limnology & Nutrient Limnology, Wayne A. Wurtsbaugh

Watershed Sciences Faculty Publications

No abstract provided.

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Dissection Of The Factors Affecting Formation Of A Ch∙∙∙O H-Bond. A Case Study, Steve Scheiner Aug 2015

Dissection Of The Factors Affecting Formation Of A Ch∙∙∙O H-Bond. A Case Study, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

Quantum calculations are used to examine how various constituent components of a large molecule contribute to the formation of an internal CH∙∙∙O H-bond. Such a bond is present in the interaction between two amide units, connected together by a series of functional groups. Each group is removed one at a time, so as to monitor the effect of each upon the H-bond, and thereby learn the bare essentials that are necessary for its formation, as well as how its presence affects the overall molecular structure. Also studied is the perturbation caused by change in the length of the aliphatic chain …

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Characterizing Demographicparameters Across Environmental Gradients: A Case Study With Ontario Moose, Garrett M. Street, Tal Avgar, Arthur R. Rodgers, John M. Fryxell Aug 2015

Characterizing Demographicparameters Across Environmental Gradients: A Case Study With Ontario Moose, Garrett M. Street, Tal Avgar, Arthur R. Rodgers, John M. Fryxell

Wildland Resources Faculty Publications

Population-level demographic characteristics as estimated by standard logistic growth models (i.e., carrying capacity and intrinsic growth rate) should vary with changes in habitat quality and availability of resources. However, few published studies have tested this hypothesis by comparing population growth rates across broad bioclimatic gradients, and fewer still the carrying capacities of those populations. We used time series data on moose (Alces alces) population densities based on aerial census and hunter harvest data for 34 management units across Ontario to estimate local carrying capacities and intrinsic growth rates. These population parameters were then regressed against associated habitat covariates for each …

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Is Atmospheric Phosphorus Pollution Altering Global Alpine Lake Stoichiometry?, Janice Brahney, Natalie Mahowald, Daniel S. Ward, Ashley P. Ballantyne, Jason C. Neff Aug 2015

Is Atmospheric Phosphorus Pollution Altering Global Alpine Lake Stoichiometry?, Janice Brahney, Natalie Mahowald, Daniel S. Ward, Ashley P. Ballantyne, Jason C. Neff

Watershed Sciences Faculty Publications

Anthropogenic activities have significantly altered atmospheric chemistry and changed the global mobility of key macronutrients. Here we show that contemporary global patterns in nitrogen (N) and phosphorus (P) emissions drive large hemispheric variation in precipitation chemistry. These global patterns of nutrient emission and deposition (N:P) are in turn closely reflected in the water chemistry of naturally oligotrophic lakes (r2 = 0.81, p < 0.0001). Observed increases in anthropogenic N deposition play a role in nutrient concentrations (r2 = 0.20, p < 0.05); however, atmospheric deposition of P appears to be major contributor to this pattern (r2 = 0.65, p < 0.0001). Atmospheric simulations indicate a global increase in P deposition by 1.4 times the preindustrial rate largely due to increased dust and biomass burning emissions. Although changes in the mass flux of global P deposition are smaller than for N, the impacts on primary productivity may be greater because, on average, one unit of increased P deposition has 16 times the influence of one unit of N deposition. These stoichiometric considerations, combined with the evidence presented here, suggest that increases in P deposition may be a major driver of alpine Lake trophic status, particularly in the Southern Hemisphere. These results underscore the need for the broader scientific community to consider the impact of atmospheric phosphorus deposition on the water quality of naturally oligotrophic lakes.

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Small Satellite Verification And Assessment Test Facility With Space Environments Effects Ground-Testing Capabilities, Eric Stromberg, Crystal Frazier, Lisa Montierth Phillipps, Alex Souvall, Jr Dennison, James S. Dyer Aug 2015

Small Satellite Verification And Assessment Test Facility With Space Environments Effects Ground-Testing Capabilities, Eric Stromberg, Crystal Frazier, Lisa Montierth Phillipps, Alex Souvall, Jr Dennison, James S. Dyer

Presentations

The Utah State University Space Dynamics Laboratory (SDL) and Materials Physics Group (MPG) have developed an extensive versatile and cost-effective pre-launch test capability for verification and assessment of small satellites, system components, and spacecraft materials. The facilities can perform environmental testing, component characterization, system level hardware in-the-loop testing, and qualification testing to ensure that each element is functional, reliable, and working per its design. Unique capabilities of SDL’s Nano-Satellite Operation Verification and Assessment (NOVA) test facility include: (i) mass and moment of inertia testing using a high resolution mass measurement table to determine the center of gravity and an inverted …

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Comparison Of Ch∙∙O, Sh∙∙O, Chalcogen, And Tetrel Bonds Formed By Neutral And Cationic Sulfur-Containing Compounds, Steve Scheiner Aug 2015

Comparison Of Ch∙∙O, Sh∙∙O, Chalcogen, And Tetrel Bonds Formed By Neutral And Cationic Sulfur-Containing Compounds, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The ability of neutral and charged S-compounds to form different sorts of noncovalent bonds is examined by ab initio calculations. Neutrals are represented by CH3SH and fluoro substituted FSCH3; cations are (CH3)3S+, CH3SH2+, and FHSCH3+. Each is paired with N-methylacetamide (NMA) whose O atom serves as common electron donor. Charged species engage in much stronger noncovalent bonds than do the neutral molecules, by as much as an order of magnitude. The strongest noncovalent bond for any system is a O∙∙SF chalcogen bond wherein the O lies directly opposite a S-F covalent bond, amounting to as much as 39 kcal/mol. Second …

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Materials At The Atomic Scale: A Key To Exploring The Vast Reaches Of Space, Jr Dennison Aug 2015

Materials At The Atomic Scale: A Key To Exploring The Vast Reaches Of Space, Jr Dennison

Presentations

A critical technology to master for any interplanetary probe is mitigation of risks from spacecraft charging and electrostatic discharge, which cause the majority of environmentally-induced “anomalies.” Understanding how charge is acquired through interaction with space fluxes of electrons, ions and photons; how temperature, dose and fields affect redistributed of charge within spacecraft materials; and what triggers electrostatic arcs all require the study of how charged particles interact with the structure of materials on an atomic scale. This seminar presents an overview of the dynamic properties of materials underlying spacecraft charging, how the material’s structure affects these properties, which properties are …

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Riparian Vegetation, Colorado River, And Climate: Five Decades Of Spatiotemporal Dynamics In The Grand Canyon With River Regulation, Joel B. Sankey, Barbara Ralston, Paul E. Grams, John C. Schmidt, Laura E. Cagney Aug 2015

Riparian Vegetation, Colorado River, And Climate: Five Decades Of Spatiotemporal Dynamics In The Grand Canyon With River Regulation, Joel B. Sankey, Barbara Ralston, Paul E. Grams, John C. Schmidt, Laura E. Cagney

Watershed Sciences Faculty Publications

Documentation of the interacting effects of river regulation and climate on riparian vegetation has typically been limited to small segments of rivers or focused on individual plant species. We examine spatiotemporal variability in riparian vegetation for the Colorado River in Grand Canyon relative to river regulation and climate, over the five decades since completion of the upstream Glen Canyon Dam in 1963. Long-term changes along this highly modified, large segment of the river provide insights for management of similar riparian ecosystems around the world. We analyze vegetation extent based on maps and imagery from eight dates between 1965 and 2009, …

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Competitive Halide Binding By Halogen Versus Hydrogen Bonding: Bis-Triazole Pyridinium, Binod Nepal, Steve Scheiner Jul 2015

Competitive Halide Binding By Halogen Versus Hydrogen Bonding: Bis-Triazole Pyridinium, Binod Nepal, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

The binding of F-, Cl-, Br-, and I- anions by bis‐triazole‐pyridine (BTP) was examined by quantum chemical calculations. There is one H atom on each of the two triazole rings that chelate the halide via H bonds. These H atoms were replaced by halogens Cl, Br, and I, thus substituting H bonds by halogen bonds. I substitution strongly enhances the binding; Br has a smaller effect, and Cl weakens the interaction. The strength of the interaction is sensitive to the overall charge on the BTP, rising as the binding agent becomes singly and then doubly positively charged. The strongest preference …

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A Structurally-Tunable 3-Hydroxyflavone Motif For Visible Light-Induced Carbon Monoxide-Releasing Molecules (Corms), Stacey N. Anderson, Jason M. Richards, Hector J. Esquer, Abby D. Benninghoff, Atta M. Arif, Lisa M. Berreau Jul 2015

A Structurally-Tunable 3-Hydroxyflavone Motif For Visible Light-Induced Carbon Monoxide-Releasing Molecules (Corms), Stacey N. Anderson, Jason M. Richards, Hector J. Esquer, Abby D. Benninghoff, Atta M. Arif, Lisa M. Berreau

Chemistry and Biochemistry Faculty Publications

Molecules that can be used to deliver a controlled amount of carbon monoxide (CO) have the potential to facilitate investigations into the roles of this gaseous molecule in biology and advance therapeutic treatments. This has led to the development of light-induced CO-releasing molecules (photoCORMs). A goal in this field of research is the development of molecules that exhibit a combination of controlled CO release, favorable biological properties (e.g., low toxicity and trackability in cells), and structural tunability to affect CO release. Herein, we report a new biologically-inspired organic photoCORM motif that exhibits several features that are desirable in a next-generation …

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Regioselectivity Of The Interaction Of Temozolomide With Borane And Boron Trifluoride, Okuma Emile Kasende, Jules Tshishimbi Muya, Steve Scheiner Jul 2015

Regioselectivity Of The Interaction Of Temozolomide With Borane And Boron Trifluoride, Okuma Emile Kasende, Jules Tshishimbi Muya, Steve Scheiner

Chemistry and Biochemistry Faculty Publications

MP2 and B3LYP calculations are used to predict the most favorable site of temozolomide toward BH3 and BF3 which are classical Lewis acids. Binding energies, charge transfers, and bond length perturbations of the temozolomide in various complexes indicate that the N12 atom is the preferred attack site for BH3, while BF3 prefers the O17 atom. The interactions are quite strong, as much as 100 kJ/mol for BH3 and more than 60 kJ/mol for BF3. The molecular electrostatic potential surrounding temozolomide is most negative around the O atoms, which is unable to explain the energetic order of binding of the Lewis …

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