Physical Sciences and Mathematics Commons^™

Non-Adiabatic Quantum Dynamics Of The Ultracold Li+Lina→ Li2+Na Chemical Reaction, B. K. Kendrick, M. Li, H. Li, S. Kotochigova, J. F.E. Croft, Balakrishnan Naduvalath

Chemistry and Biochemistry Faculty Research

We report non-adiabatic dynamics of the Li+LiNa→Li2+Na chemical reaction at cold and ultracold temperatures employing accurate ab initio electronic potential energy surfaces in a quantum dynamics formulation employing a diabatic representation. Results are compared against those from a single adiabatic ground state potential energy surface and a universal model based on the long-range interaction potential. We discuss signatures of non-universal behavior in the total rate coefficients as well as strong non-adiabatic effects in the state-to-state rotationally resolved rate coefficients.

Neogene Retroarc Foreland Basin Evolution, Sediment Provenance, And Magmatism In Response To Flat Slab Subduction, Western Argentina, Tomas N. Capaldi, Brian K. Horton, N. Ryan Mckenzie, Chelsea Mackaman-Lofland, Daniel F. Stockli, Gustavo Ortiz, Patricia Alvarado

Geoscience Faculty Research

Understanding the effects of flat slab subduction on mountain building, arc magmatism, and basin evolution is fundamental to convergent‐margin tectonics, with implications for potential feedbacks among geodynamic, magmatic, and surface processes. New stratigraphic and geochronological constraints on Cenozoic sedimentation and magmatism in the southern Central Andes of Argentina (31°S) reveal shifts in volcanism, foreland/hinterland basin development, sediment accumulation, and provenance as the retroarc region was structurally partitioned during slab flattening. Detrital zircon U‐Pb age distributions from the western (Calingasta basin), central (Talacasto and Albarracín basins), and eastern (Bermejo foreland basin) segments of the retroarc basin system preserve syndepositional volcanism and …

A Mildly Relativistic Outflow From The Energentic, Fast-Rising Blue Optical Transient Css161010 In A Dwarf Galaxy, Deanne L. Coppejans, R. Margutti, G. Terreran, A. J. Nayana, E. R. Coughlin, T. Laskar, K. D. Alexander, M. Bietenholz, D. Caprioli, P. Chandra, M. R. Drout, D. Frederiks, C. Frohmaier, K. H. Hurley, C. S. Kochanek, M. Macleod, A. Meisner, P. E. Nugent, A. Ridnaia, D. J. Sand, D. Svinkin, C. Ward, S. Yang, A. Baldeschi, I. V. Chilingarian, Y. Dong, C. Esquivia, W. Fong, C. Guidorzi, P. Lundqvist, D. Milisavljevic

Physics & Astronomy Faculty Research

We present X-ray and radio observations of the Fast Blue Optical Transient CRTS-CSS161010 J045834−081803 (CSS161010 hereafter) at t = 69–531 days. CSS161010 shows luminous X-ray (L x ~ 5 × 1039 erg s−1) and radio (L ν ~ 1029 erg s−1 Hz−1) emission. The radio emission peaked at ~100 days post-transient explosion and rapidly decayed. We interpret these observations in the context of synchrotron emission from an expanding blast wave. CSS161010 launched a mildly relativistic outflow with velocity Γβc ≥ 0.55c at ~100 days. This is faster than the non-relativistic AT 2018cow (Γβc ~ 0.1c) and closer to ZTF18abvkwla (Γβc …

Thermotropic Liquid-Crystalline And Light-Emitting Properties Of Bis(4-Aalkoxyphenyl) Viologen Bis(Triflimide) Salts, Pradip K. Bhowmik, Muhammed Kareem M. Al-Karawi, Shane T. Killarney, Erenz J. Dizon, Anthony Chang, Jongin Kim, Si L. Chen, Ronald Carlo G. Principe, Andy Ho, Haesook Han

Chemistry and Biochemistry Faculty Research

A series of bis(4-alkoxyphenyl) viologen bis(triflimide) salts with alkoxy chains of different lengths were synthesized by the metathesis reaction of respective bis(4-alkoxyphenyl) viologen dichloride salts, which were in turn prepared from the reaction of Zincke salt with the corresponding 4-n-alkoxyanilines, with lithium triflimide in methanol. Their chemical structures were characterized by 1H and 13C nuclear magnetic resonance spectra and elemental analysis. Their thermotropic liquid-crystalline (LC) properties were examined by differential scanning calorimetry, polarizing optical microscopy, and variable temperature X-ray diffraction. Salts with short length alkoxy chains had crystal-to-liquid transitions. Salts of intermediate length alkoxy chains showed both crystal-to-smectic A (SmA) …

The Planetary Luminosity Problem: " Missing Planets" And The Observational Consequences Of Episodi Accretion, Sean D. Brittain, Joan R. Najita, Ruobing Dong, Zhaohuan Zhu

Physics & Astronomy Faculty Research

The high occurrence rates of spiral arms and large central clearings in protoplanetary disks, if interpreted as signposts of giant planets, indicate that gas giants commonly form as companions to young stars (Myr) at orbital separations of 10–300 au. However, attempts to directly image this giant planet population as companions to more mature stars (>10 Myr) have yielded few successes. This discrepancy could be explained if most giant planets form by "cold start," i.e., by radiating away much of their formation energy as they assemble their mass, rendering them faint enough to elude detection at later times. In that …

Computational Study Of The Time Relaxation Model With High Order Deconvolution Operator, Jeffrey Belding, Monika Neda, Fran Pahlevani

Mathematical Sciences Faculty Research

This paper presents a computational investigation for a time relaxation regularization of Navier–Stokes equations known as Time Relaxation Model, TRM, and its corresponding sensitivity equations. The model generates a regularization based on both filtering and deconvolution. We discretize the equations of TRM and the corresponding sensitivity equations using finite element in space and Crank–Nicolson in time. The step problem and the shear layer roll-up benchmark is used to computationally test the performance of TRM across different orders of deconvolution operator as well as the sensitivity of the shear layer computations of the model with respect to the variation of time …

A Note On Eulerian Numbers And Toeplitz Matrices, Tian-Xiao He, Peter J.-S. Shiue

Mathematical Sciences Faculty Research

This note presents a new formula of Eulerian numbers derived from Toeplitz matrices via Riordan array approach.

A Fast Radio Burst Discovered In Fast Drift Scan Survey, Weiwei Zhu, Di Li, Rui Luo, Chenchen Miao, Bing Zhang, Laura Spitler, Duncan Lorimer, Michael Kramer, David Champion, Youling Yue, Andrew Cameron, Marilyn Cruces, Ran Duan, Yi Feng, Jun Han, George Hobbs, Chenhui Niu, Jiarui Niu, Zhichen Pan, Lei Qian, Dai Shi, Ningyu Tang, Pei Wang, Hongfeng Wang, Mao Yuan, Lei Zhang, Xinxin Zhang, Shuyun Cao, Li Feng, Hengqian Gan, Long Gao

Physics & Astronomy Faculty Research

We report the discovery of a highly dispersed fast radio burst (FRB), FRB 181123, from an analysis of ~1500 hr of drift scan survey data taken using the Five-hundred-meter Aperture Spherical radio Telescope (FAST). The pulse has three distinct emission components, which vary with frequency across our 1.0–1.5 GHz observing band. We measure the peak flux density to be... (See full abstract in article).

Assessing The Potential For Greater Solar Development In West Texas, Usa, Dale D. Devitt, M. H. Young, J. P. Pierre

Life Sciences Faculty Research

As population and economies continue to grow on a global scale, so too does the demand for energy. To improve reliability and independence of energy supplies, the U.S. and many other countries are seeking internally-sourced renewable energy; solar is one such renewable-energy source that meets these criteria. However, all energy sources exert some environmental impacts. In the case of solar, direct impacts stem mostly from alteration of land needed to host infrastructure. Understanding the environmental upside and downside potential of solar energy systems allows a more comprehensive, side-by-side comparison with different energy sources. In this article, we focus on the …

Evidence For Sodium-Rich Alkaline Water In The Tagish Lake Parent Body And Implications For Amino Acid Synthesis And Racemization, Lee F. White, Kimberly T. Tait, Brian Langelier, Elizabeth A. Lymer, Ana Černok, Tanya V. Kizovski, Chi Ma, Oliver Tschauner, Richard I. Nicklin

Geoscience Faculty Research

Understanding the timing and mechanisms of amino acid synthesis and racemization on asteroidal parent bodies is key to demonstrating how amino acids evolved to be mostly left-handed in living organisms on Earth. It has been postulated that racemization can occur rapidly dependent on several factors, including the pH of the aqueous solution. Here, we conduct nanoscale geochemical analysis of a framboidal magnetite grain within the Tagish Lake carbonaceous chondrite to demonstrate that the interlocking crystal arrangement formed within a sodium-rich, alkaline fluid environment. Notably, we report on the discovery of Na-enriched subgrain boundaries and nanometer-scale Ca and Mg layers surrounding …

Water On Mars—A Literature Review, Mohammad Nazari-Sharabian, Mohammad Aghababei, Moses Karakouzian, Mehrdad Karami

Civil and Environmental Engineering and Construction Faculty Research

To assess Mars’ potential for both harboring life and providing useable resources for future human exploration, it is of paramount importance to comprehend the water situation on the planet. Therefore, studies have been conducted to determine any evidence of past or present water existence on Mars. While the presence of abundant water on Mars very early in its history is widely accepted, on its modern form, only a fraction of this water can be found, as either ice or locked into the structure of Mars’ plentiful water-rich materials. Water on the planet is evaluated through various evidence such as rocks …

College Of Engineering Senior Design Competition Spring 2020, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge. The senior design competition helps focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects on …

Recent Advances In Computational Mathematics And Applications, Eric Machorro, Jichun Li, Monika Neda, Pengtao Sun, Hongtao Yang

Mathematical Sciences Faculty Research

No abstract provided.

Dust Condensation In Evolving Discs And The Composition Of Planetary Building Blocks, Min Li, Shichun Huang, Michail I. Petaev, Zhaohuan Zhu, Jason H. Steffen

Physics & Astronomy Faculty Research

Partial condensation of dust from the Solar nebula is likely responsible for the diverse chemical compositions of chondrites and rocky planets/planetesimals in the inner Solar system. We present a forward physical–chemical model of a protoplanetary disc to predict the chemical compositions of planetary building blocks that may form from such a disc. Our model includes the physical evolution of the disc and the condensation, partial advection, and decoupling of the dust within it. The chemical composition of the condensate changes with time and radius. We compare the results of two dust condensation models: one where an element condenses when the …

The Equifax Hack Revisited And Repurposed, Hal Berghel

Civil and Environmental Engineering and Construction Faculty Research

Reports on the recent indictments against Chinese hackers regarding Equifax.

Accurate Confidence Intervals For Risk Difference In Meta-Analysis With Rare Events, Tao Jiang, Baixin Cao, Guogen Shan

Environmental & Occupational Health Faculty Publications

Background: Meta-analysis provides a useful statistical tool to effectively estimate treatment effect from multiple studies. When the outcome is binary and it is rare (e.g., safety data in clinical trials), the traditionally used methods may have unsatisfactory performance. Methods: We propose using importance sampling to compute confidence intervals for risk difference in meta-analysis with rare events. The proposed intervals are not exact, but they often have the coverage probabilities close to the nominal level. We compare the proposed accurate intervals with the existing intervals from the fixed- or random-effects models and the interval by Tian et al. (2009). Results: We …

Swift Spectroscopy Of The Accretion Disk Wind In The Black Hole Gro J1655-40, M. Balakrishnan, J. M. Miller, N. Trueba, M. Reynolds, J. Raymond, Daniel Proga, A. C. Fabian, T. Kallman, J. Kaastra

Physics & Astronomy Faculty Research

Chandra obtained two High Energy Transmission Grating spectra of the stellar-mass black hole GRO J1655−40 during its 2005 outburst, revealing a rich and complex disk wind. Soon after its launch, the Neil Gehrels Swift Observatory began monitoring the same outburst. Some X-ray Telescope (XRT) observations were obtained in a mode that makes it impossible to remove strong Mn calibration lines, so the Fe Kα line region in the spectra was previously neglected. However, these lines enable a precise calibration of the energy scale, facilitating studies of the absorption-dominated disk wind and its velocity shifts. Here we present fits to 15 …

Alma 0.88 Mm Survey Of Disks Around Planetary-Mass Companions, Ya-Lin Wu, Brendan P. Bowler, Patrick D. Sheehan, Sean M. Andrews, Gregory J. Herczeg, Adam L. Kraus, Luca Ricci, David J. Wilner, Zhaohuan Zhu

Physics & Astronomy Faculty Research

Characterizing the physical properties and compositions of circumplanetary disks can provide important insights into the formation of giant planets and satellites. We report Atacama Large Millimeter/submillimeter Array 0.88 mm (Band 7) continuum observations of six planetary-mass (10–20 M Jup) companions: CT Cha b, 1RXS 1609 b, ROXs 12 b, ROXs 42B b, DH Tau b, and FU Tau b. No continuum sources are detected at the locations of the companions down to 3σ limits of 120–210 μJy. Given these nondetections, it is not clear whether disks around planetary-mass companions indeed follow the disk-flux–host-mass trend in the stellar regime. The faint …

Arc‐Type Magmatism Due To Continental‐Edge Plowing Through Ancient Subduction‐Enriched Mantle, Douwe J.J. Van Hinsbergen, Wim Spakman, Hugo De Boorder, Michiel Van Dongen, Simon M. Jowitt, Paul R.D. Mason

Geoscience Faculty Research

The puzzling... (See article for full abstract).

Analysis Of Cryptotephra At Whitney Mesa Nature Preserve, Henderson, Nevada, Alex Newsom

Calvert Undergraduate Research Awards

Advanced Undergraduate Winner

Cryptotephra (small volcanic shards ranging 20-80 microns in size) were discovered within Unit X of the Las Vegas Formation at Whitney Mesa Nature Preserve, Henderson, Nevada. Cryptotephra are deposited soon after a volcanic eruption and can be used as a dating tool to create narrow time constraints for surrounding sediments. Cryptotephra have many applications but are mainly useful as a dating tool. Their study has important implications for the understanding of the timing of palaeoclimatological and paleoenvironmental events as well as for archaeological studies to date important events in human history.

The Whitney Mesa cryptotephra were correlated …

Insight On Thermal Stability Of Magnetite Magnetosomes: Implications For The Fossil Record And Biotechnology, Jefferson Cypriano, Mounib Bahri, Kassioge Dembele, Walid Baaziz, Pedro Leao, Dennis A. Bazylinski, Fernanda Abreu, Ovidiu Ersen, Marcos Farina, Jacques Werckmann

Life Sciences Faculty Research

Magnetosomes are intracellular magnetic nanocrystals composed of magnetite (Fe3O4) or greigite (Fe3S4), enveloped by a lipid bilayer membrane, produced by magnetotactic bacteria. Because of the stability of these structures in certain environments after cell death and lysis, magnetosome magnetite crystals contribute to the magnetization of sediments as well as providing a fossil record of ancient microbial ecosystems. The persistence or changes of the chemical and magnetic features of magnetosomes under certain conditions in different environments are important factors in biotechnology and paleomagnetism. Here we evaluated the thermal stability of magnetosomes in a temperature range between 150 and 500 °C subjected …

On-Chip Terahertz Modulation And Emission With Integrated Graphene Junctions, Joshua O. Island, Peter Kissin, Jacob Schalch, Xiaomeng Cui, Sheikh Rubaiat Ui Haque, Alex Potts, Takashi Taniguchi, Kanji Watanabe, Richard D. Averitt, Andrea F. Young

Physics & Astronomy Faculty Research

The efficient modulation and control of ultrafast signals on-chip is of central importance in terahertz (THz) communications and a promis- ing route toward sub-diffraction limit THz spectroscopy. Two-dimensional (2D) materials may provide a platform for these endeavors. We explore this potential, integrating high-quality graphene p–n junctions within two types of planar transmission line circuits to modulate and emit picosecond pulses. In a coplanar strip line geometry, we demonstrate the electrical modulation of THz signal transmission by 95%. In a Goubau waveguide geometry, we achieve complete gate-tunable control over THz emission from a photoexcited graphene junction. These studies inform the development …

Vibration Overtone Hyperpolarizability Measured For H2, Rachel M. Ellis, David P. Shelton

Physics & Astronomy Faculty Research

The second hyperpolarizability (γ) of the H2 molecule was measured by gas-phase electric field induced second harmonic generation at the frequencies of the one-photon resonance for the 3–0 Q(J) overtone transitions (v, J = 0, J → 3, J for J = 0, 1, 2, and 3). The magnitude of the resonant contribution to γ was measured with 2% accuracy using the previously determined non-resonant γ for calibration. Pressure broadening and frequency shift for the transitions were also measured. A theoretical expression for the resonant vibrational γ contribution in terms of transition polarizabilities is compared to the observations. The measured …

Structure-Strength Relations Of Distinct Mon Phases From First-Principles Calculations, Cheng Lu, Changfeng Chen

Physics & Astronomy Faculty Research

Molybdenum mononitrides (MoN) exhibit superior strength and hardness among the large class of transition-metal light-element compounds, but the underlying atomistic mechanisms for their outstanding mechanical properties and the variations of those properties among various MoN phases adopting different crystal structures remain largely unexplored and require further investigation. Here we report first-principles calculations that examine the stress-strain relations of these materials, and systematically compare results under pure and indentation shear deformations. In particular, we examine the distinct bonding structures and the associated mechanical properties in four different crystal phases of MoN that have been experimentally synthesized and stabilized under various physical …

Indentation-Strain Stiffening In Tungsten Nitrides: Mechanisms And Implications, Cheng Lu, Changfeng Chen

Physics & Astronomy Faculty Research

We report on a systematic computational study of ideal strengths, i.e., the lowest stresses needed to destabilize a perfect crystal under a variety of loading conditions for six stable and metastable tungsten nitrides identified by advanced crystal structure search algorithms. We employ first-principles calculations to determine stress-strain relations and examine the corresponding atomistic bonding changes for a microscopic understanding of the structural deformation modes. The obtained results show that, in stark contrast to many previously studied transition-metal borides, carbides, and also most nitrides, the tungsten nitrides exhibit surprisingly broad and common patterns of strain-stiffening effects under indentation strains. These extraordinary …

Global 3d Radiation Magnetohydrodynamic Simulations For Fu Ori's Accretion Disc And Observational Signatures Of Magnetic Fields, Zhaohuan Zhu, Yan-Fei Jiang, James M. Stone

Physics & Astronomy Faculty Research

FU Ori is the prototype of FU Orionis systems that are outbursting protoplanetary discs. Magnetic fields in FU Ori’s accretion discs have previously been detected using spectropolarimetry observations for Zeeman effects. We carry out global radiation ideal MHD simulations to study FU Ori’s inner accretion disc. We find that (1) when the disc is threaded by vertical magnetic fields, most accretion occurs in the magnetically dominated atmosphere at z ∼ R, similar to the ‘surface accretion’ mechanism in previous locally isothermal MHD simulations. (2) A moderate disc wind is launched in the vertical field simulations with a terminal speed of …

Superconductivity In Compression-Shear Deformed Diamond, Chang Liu, Xianqi Song, Quan Li, Yanming Ma, Changfeng Chen

Physics & Astronomy Faculty Research

Diamond is a prototypical ultrawide band gap semiconductor, but turns into a superconductor with a critical temperature Tc≈4 K near 3% boron doping [E. A. Ekimov et al., Nature (London) 428, 542 (2004)]. Here we unveil a surprising new route to superconductivity in undoped diamond by compression-shear deformation that induces increasing metallization and lattice softening with rising strain, producing phonon mediated Tc up to 2.4–12.4 K for a wide range of Coulomb pseudopotential μ∗=0.15–0.05. This finding raises intriguing prospects of generating robust superconductivity in strained diamond crystal, showcasing a distinct and hitherto little explored approach to driving materials into superconducting …

The Breakup Of A Helium Cluster After Removing Attractive Interaction Among A Significant Number Of Atoms In The Cluster, Tao Pang

Physics & Astronomy Faculty Research

The breakup of a quantum liquid droplet is examined through a 4He cluster by removing the attractive tail in the interaction between some of the atoms in the system with the diffusion quantum Monte Carlo simulation. The ground-state energy, kinetic energy, cluster size, and density profile of the cluster are evaluated against the percentage of the atoms without the attractive tail. The condition for the cluster to lose its ability to form a quantum liquid droplet at zero temperature is found and analyzed. The cluster is no longer able to form a quantum liquid droplet when about two-thirds of pairs …

Techno-Economic Analysis Of Electrocoagulation On Water Reclamation And Bacterial/Viral Indicator Reductions Of A High-Strength Organic Wastewater—Anaerobic Digestion Effluent, Sibel Uludag-Demirer, Nathan Olson, Rebecca Ives, Jean Pierre Nshimyimana, Cory A. Rusinek, Joan B. Rose, Wei Liao

Chemistry and Biochemistry Faculty Research

This study investigated the use of iron and aluminum and their combinations as electrodes to determine the technically sound and economically feasible electrochemical approach for the treatment of anaerobic digestion effluent. The results indicated that the use of iron as anode and cathode is the most suitable solution among different electrode combinations. The reduction of turbidity, total chemical oxygen demand, total phosphorus, total coliforms, Escherichia coli, Enterococci, and phages in the reclaimed water were 99%, 91%, 100%, 1.5 log, 1.7 log, 1.0 log, and 2.0 log, respectively. The economic assessment further concluded that the average treatment cost is $3 per …

Correlation Coefficients For A Study With Repeated Measures, Guogen Shan, Hua Zhang, Tao Jiang

Environmental & Occupational Health Faculty Publications

Repeated measures are increasingly collected in a study to investigate the trajectory of measures over time. One of the first research questions is to determine the correlation between two measures. The following five methods for correlation calculation are compared: (1) Pearson correlation; (2) correlation of subject means; (3) partial correlation for subject effect; (4) partial correlation for visit effect; and (5) a mixed model approach. Pearson correlation coefficient is traditionally used in a cross-sectional study. Pearson correlation is close to the correlations computed from mixed-effects models that consider the correlation structure, but Pearson correlation may not be theoretically appropriate in …