Physical Sciences and Mathematics Commons^™

The Photophysical Studies Of Transition Metal Polyimines Encapsulated In Metal Organic Frameworks (Mof’S), Jacob M. Mayers

USF Tampa Graduate Theses and Dissertations

Light harvesting systems provide a platform that converts solar energy into other forms of energy. One of the most common examples of photon capturing and conversion into chemical energy is observed in photosynthetic organisms in both Eurkaroyic and Prokaryotic domains. Nature provides a model for successful light harvesting platforms which includes the compartmentalization of antenna complexes that contain separated donor and acceptor pairs that participate in efficient electron transfer processes. In order to mimic such systems, crystalline porous materials that exhibits regular cavities and pore dimensions provides an excellent starting place. Metal organic frameworks (MOFs) are a class of porous …

A System Architecture For Water Distribution Networks, Noha Abdel-Mottaleb

USF Tampa Graduate Theses and Dissertations

This dissertation examines structure-function relationships of water distribution networks (WDNs), with focus on improving the decision-making process for water utilities. WDNs are lifeline infrastructure systems, necessary for the functioning of cities. Yet water utilities around the world struggle with emerging challenges that include but are not limited to aging infrastructure components, limited budgets, increased interdependencies between infrastructure systems, increased rates of urbanization, and increasing extreme weather conditions. This is why enhancing the performance of WDNs is a priority for water utilities around the world. This research begins to delineate a system architecture for WDNs and evaluates the use of various …

Investigation Of Immobilized Enzymes In Confined Environment Of Mesoporous Host Matrices, Xiaoliang Wang

USF Tampa Graduate Theses and Dissertations

Enzyme immobilization in metal-organic frameworks (MOFs) as a promising strategy, is attracting the interest of scientists from different disciplines with the expansion of MOF’s development. Different from other traditional host materials, their unique strengths of high surface areas, large yet adjustable pore sizes, functionalizable pore walls, and diverse architectures make MOFs an ideal platform to investigate hosted enzymes, which is critical to the industrial and commercial process. In addition to the protective function of MOFs, the extensive roles of MOFs in the enzyme immobilization are being well-explored by making full use of their remarkable properties like well-defined structure, high porosity, …

Modeling The Ambient Conditions Of A Manufacturing Environment Using Computational Fluid Dynamics (Cfd), Yang Liu

USF Tampa Graduate Theses and Dissertations

As manufacturing equipment evolve to higher speed and require high precision operations, the impact of environmental changes on machine accuracy becomes critical. Due to thermal expansion, the structure of the machine can change when ambient temperature varies. When the airflow in the laboratory changes, this also alters the operator's thermal comfort. Either the change in machine structure or operator comfort can ultimately affect machine accuracy. The manufacturing industry is currently using heating, ventilation, and air-conditioning (HVAC) systems to regulate the temperature of the working environment. However, since conventional HVAC systems determine whether to activate the HVAC system by collecting the …

Effects Of Nitrate On Arsenic Mobilization During Aquifer Storage And Recovery, Hania Hawasli

USF Tampa Graduate Theses and Dissertations

Aquifer storage and recovery technology is used to sustain water resources and to prevent saltwater intrusion. The injected water can come from various resources, including treated wastewater. In pilot ASR studies in the Tampa Bay region, researchers found high As concentrations in the recovered water from the oxidation of the arsenopyrite that is embedded in the aquifers. The presence of dissolved O2 in the injected water is a major factor in the arsenopyrite oxidation during ASR, however the effects of NO3- on the arsenopyrite has not been studied yet. This is an important knowledge gap because injected water may contain …

Texturing In Bi2Te3 Alloy Thermoelectric Materials: An Applied Physics Investigation, Oluwagbemiga P. Ojo

USF Tampa Graduate Theses and Dissertations

Thermoelectric devices provide the means for direct conversion between heat and electricity. The device conversion efficiency, or performance, is directly related to the thermoelectric figure of merit, ZT, of the working materials. Bismuth telluride alloys are the materials currently in use in most thermoelectric devices for near room temperature solid-state refrigeration and power conversion applications. The vast majority of publications in the literature on thermoelectricity report on investigations towards developing new materials with enhanced thermoelectric properties, however Bi₂Te₃ alloys have been used in thermoelectric devices for decades.

In this thesis, an investigation of crystallographic texturing on large …

Constructing Frameworks For Task-Optimized Visualizations, Ghulam Jilani Abdul Rahim Quadri

USF Tampa Graduate Theses and Dissertations

Visualization is crucial in today’s data-driven world to augment and enhance human understanding and decision-making. Effective visualizations must support accuracy in visual task performance and expressive data communication. Effective visualization design depends on the visual channels used, chart types, or visual tasks. However, design choices and visual judgment are co-related, and effectiveness is not one-dimensional, leading to a significant need to understand the intersection of these factors to create optimized visualizations. Hence, constructing frameworks that consider both design decisions and the task being performed enables optimizing visualization design to maximize efficacy. This dissertation describes experiments, techniques, and user studies to …

Fiber-Based Supercapacitor For Wearable Electronics, Rohit Lallansingh Yadav

USF Tampa Graduate Theses and Dissertations

Supercapacitors are significant devices that are used for energy storage and also have the capability of delivering energy at a faster rate than batteries. The increase in the significance of portable and wearable electronic equipment giving rise to pace in the development of flexible supercapacitor and flexible electrodes in recent years. A fiber-based supercapacitor (FSCs) is one of the most significant devices which have even helped us give pace knowing the properties of supercapacitor. These FSCs are said to have excellent electrochemical properties and flexibility. This did make function it in different forms of individual fibers or integrated textiles which …

Preparation And Characterization Of Single Layer Conducting Polymer Electrochromic And Touchchromic Devices, Sharan Kumar Indrakar

USF Tampa Graduate Theses and Dissertations

Electrochromic devices (ECDs) have triggered great interest because of their potential applicability in energy-efficient buildings and low power display systems, including reflective type smart windows/mirrors and wearable-flexible devices. In the past decades, electrochromic technologies with different device structures and materials have been proposed. The idea of employing a simple device structure with a durable, cost effective electrolyte is crucial to designing and manufacturing high-performance ECDs. With this idea in mind, this thesis describes the various efforts to develop a simple ECD comprising of a composite single active layer gel electrolyte, sandwiched between two transparent conducting electrodes, lasting over 10,000 cycles …

Automated Wound Segmentation And Dimension Measurement Using Rgb-D Image, Chih-Yun Pai

USF Tampa Graduate Theses and Dissertations

Accurate pressure ulcer (PrU) measurement is critical in assessing the effectiveness of PrU treatment. The traditional measurement process is manual, subjective, and requires frequent contact with the wound. The manual measurement relies on human observation which makes the measurement inconsistent, and the frequent contact with the wound increases risk of contamination or infection. The purpose of this research was to develop an automatic Pressure Ulcer Monitoring System (PrUMS) using a depth camera to provide automated, non-contact wound measurement. In this dissertation, 1) a wound segmentation with traditional machine learning method, which combines the color classification using K-Nearest Neighbors and the …

Data-Driven Studies On Social Networks: Privacy And Simulation, Yasanka Sameera Horawalavithana

USF Tampa Graduate Theses and Dissertations

Social media datasets are fundamental to understanding a variety of phenomena, such as epidemics, adoption of behavior, crowd management, and political uprisings. At the same time, many such datasets capturing computer-mediated social interactions are recorded nowadays by individual researchers or by organizations. However, while the need for real social graphs and the supply of such datasets are well established, the flow of data from data owners to researchers is significantly hampered by privacy risks: even when humans’ identities are removed, or data is anonymized to some extent, studies have proven repeatedly that re-identifying anonymized user identities (i.e., de-anonymization) is doable …

Adaptive Network Slicing In Fog Ran For Iot With Heterogeneous Latency And Computing Requirements: A Deep Reinforcement Learning Approach, Almuthanna Nassar

USF Tampa Graduate Theses and Dissertations

In view of the recent advances in Internet of Things (IoT) devices and the emerging new breed of smart city applications and intelligent vehicular systems driven by artificial intelligence, fog radio access network (F-RAN) has been recently introduced for the next generation wireless communications. The capability of F-RAN has emerged to overcome the latency limitations of cloud-RAN (C-RAN) and assure the quality-of-service (QoS) requirements of the ultra-reliable-low-latency-communication (URLLC) for IoT applications. To this end, fog nodes (FNs) are equipped with computing, signal processing and storage capabilities to extend the inherent operations and services of the cloud to the edge. However, …

Sensible/Latent Hybrid Thermal Energy Storage For The Supercritical Carbon Dioxide Brayton Cycle, Kelly Osterman

USF Tampa Graduate Theses and Dissertations

Mitigating the effects of climate change will require rapid deployment of a carbon-free electricity system that includes all available forms of zero-carbon energy. Both renewables and nuclear show great promise, but both come with drawbacks. Power production from wind and solar is limited to times when their respective resources are available, while nuclear is limited in its ability to adjust its output according to the ever-varying demand for electricity. Additionally, the systems must be affordable. One way to reduce the cost of thermal power plants (concentrated solar power and nuclear) is to use new power cycles, such as the supercritical …

An Automated Framework For Connected Speech Evaluation Of Neurodegenerative Disease: A Case Study In Parkinson's Disease, Sai Bharadwaj Appakaya

USF Tampa Graduate Theses and Dissertations

Neurodegenerative diseases affect millions of people around the world. The progressive degeneration worsens the symptoms, heavily impacting the quality of life of the patients as well as the caregivers. Speech production is one of the physiological processes affected by neurodegenerative diseases like Alzheimer’s disease, amyotrophic lateral sclerosis (ALS) and Parkinson’s disease (PD). Speech is the most basic form of communication, and the effect of neurodegeneration degrades speech production, thereby reducing social interaction and mental well-being. PD is the second most common neurodegenerative disease affecting speech production in 90% of the diagnosed individuals. Speech analysis methods for PD in clinical methods …

Efficient Hardware Constructions For Error Detection Of Post-Quantum Cryptographic Schemes, Alvaro Cintas Canto

USF Tampa Graduate Theses and Dissertations

Quantum computers are presumed to be able to break nearly all public-key encryption algorithms used today. The National Institute of Standards and Technology (NIST) started the process of soliciting and standardizing one or more quantum computer resistant public-key cryptographic algorithms in late 2017. It is estimated that the current and last phase of the standardization process will last till 2022-2024. Among those candidates, code-based and multivariate-based cryptography are a promising solution for thwarting attacks based on quantum computers. Nevertheless, although code-based and multivariate-based cryptography, e.g., McEliece, Niederreiter, and Luov cryptosystems, have good error correction capabilities, research has shown their hardware …

Strategies In Botnet Detection And Privacy Preserving Machine Learning, Di Zhuang

USF Tampa Graduate Theses and Dissertations

Peer-to-peer (P2P) botnets have become one of the major threats in network security for serving as the infrastructure that responsible for various of cyber-crimes. Though a few existing work claimed to detect traditional botnets effectively, the problem of detecting P2P botnets involves more challenges. In this dissertation, we present two P2P botnet detection systems, PeerHunter and Enhanced PeerHunter. PeerHunter starts from a P2P hosts detection component. Then, it uses mutual contacts as the main feature to cluster bots into communities. Finally, it uses community behavior analysis to detect potential botnet communities and further identify bot candidates. Enhanced PeerHunter is an …

Fabrication And Characterization Methods Of Self-Cleaning Coatings For Solar Panels Application, Mohammed Khaleel M Alhussain

USF Tampa Graduate Theses and Dissertations

Transparent self-cleaning coatings with superhydrophobic and superhydrophilic behavior are of great interest in a wide range of industrial applications such as automotive, solar panels, windows, and optical devices. Each has its uses, properties, and characteristics. For the use of these coatings on solar panels, certain features are important in maintaining the efficiency of the panels in different weather conditions and reducing the operation and maintenance cost, such as self-cleaning, high transparency, antifouling, anti-fogging, and anti-icing. Herein, we have investigated the fabrication of self-cleaning coatings using two simple methods and ways to improve their characteristics. In the first method, a hydrophobic …

An Investigation Of Cross-Links On Crystallization And Degradation In A Novel, Photocross-Linkable Poly (Lactic Acid) System, Nicholas Baksh

USF Tampa Graduate Theses and Dissertations

Polymeric molecular structure consists of repeating units bonded together. Mechanicalproperties can be altered without affecting chemical makeup by altering the number of these units. Small molecules can be introduced and/or polymers can be modified to form bonds between molecular chains. Cross-linking, as this is called, also introduces mechanical variation with minimal effects on chemical composition. Lastly, polymer chains reorient themselves in response to intermolecular forces. This temperature dependent response is known as crystallization. Although chemistry is unaltered, mechanical properties can depend highly on the percent of the sample that is crystallized.

Cross-linking is known to enhance the mechanical properties of …

Conversion From Metal Oxide To Mof Thin Films As A Platform Of Chemical Sensing, Meng Chen

USF Tampa Graduate Theses and Dissertations

Chemical sensor is working as a widely used device which can be applied to the detection of specific chemicals that are existing in the environment especially in gas phase. The detection of combustible and toxic chemicals can be extremely important in the field of both industrial and civil activities. The chemical sensor is commonly operating by utilizing a chemical or physical interaction between the specific chemical compound and the sensing functional unit, to obtain an electronic signal caused by the property change and realize the chemical detection. Traditional chemical gas sensors such as catalytic gas sensor, thermal conductivity gas sensor, …

The Utilization Of Shared Energy Storage In Energy Systems: Design, Modeling And Optimization, Rui Dai

USF Tampa Graduate Theses and Dissertations

Energy storage (ES) plays a significant role in modern smart grids and energy systems. With the advances of ES technologies, efficiently applying ES to energy systems has become the bottleneck for achieving the benefits of ES. The traditional approach of utilizing ES is the so-called distributed framework in which there is a separate ES for each individual user. Due to the inherent limits in the distributed framework such as cost inefficiency and space limitations, many studies have promoted to utilize a shared ES in energy systems to further exploit the potentials of ES. However, current studies always focus on maximizing …

Coral Reef Restoration In The Tropical West Atlantic Amid The Covid-19 Pandemic, Linden Cheek

USF Tampa Graduate Theses and Dissertations

Climate change is increasing threats to coasts, both from storm surge and sea level rise. Healthy coral reefs provide reduction in storm surges, wave energy, coastal flooding and everyday erosion, and are found across a variety of spatial scales. Given the state of coral reefs worldwide, active Coral Reef Restoration (CRR) in emerging as a necessary component of coastal protection. CRR can be classified as a nature-based solutions (NbS) for coastal protection that also provides a multitude of ecosystem-based services to both humans and other life. Nearly all literature on coral restoration efforts assume a steady-state of human-ecological interactions, but …

Laser-Induced Modifications In Two-Dimensional Materials, Tariq Afaneh

USF Tampa Graduate Theses and Dissertations

Atomically thin two-dimensional (2D) materials have attracted a growing interest in the lastdecade from the fundamental point of view as well as their potential applications in functional devices. Due to their high surface-to-volume ratio, the physical properties of 2D materials are very sensitive to the environmental factor such as surrounding media and illumination conditions (e.g. light-mater interaction). In the first part of this dissertation I will present recent advances in developing laser-assisted methods to tune the physical properties of 2D transition metal dichalcogenides (TMDs). We demonstrate laser-assisted chemical modification ultrathin TMDs, locally replacing selenium by sulfur atoms. The photo-conversion process …

Sustainable Non-Noble Metal Based Catalysts For High Performance Oxygen Electrocatalysis, Swetha Ramani

USF Tampa Graduate Theses and Dissertations

Current energy crisis has dramatically shifted the focus of technological advancements towards clean and renewable forms of energy. Continued dependence and utilization of fossil fuels has created global awareness on harmful greenhouse gas emissions and climate change. A need for sustainable technology has gained a lot of significance in the recent years. This has led to the development of devices and technologies that rely on environmentally friendly electrochemical conversion and storage of energy. One such advancement that generates electrical energy from chemical reactions is known as fuel cell technology. While fuel cells have demonstrated potential in replacing the conventional technologies …

Control Of A Human Arm Robotic Unit Using Augmented Reality And Optimized Kinematics, Carlo Canezo

USF Tampa Graduate Theses and Dissertations

There are more than 350000 amputees in the US who suffer loss of functionality in their daily living activities, and roughly 100000 of them are upper arm amputees. Many of these amputees use prostheses to compensate part of their lost arm function, including power prostheses. Research on 6-7 degree of freedom powered prostheses is still relatively new, and most commercially available powered prostheses are typically limited to 1 to 3 degrees of freedom. Due to the myriad of possible options for various powered protheses from different manufacturers, each configuration is governed by a distinct control scheme typically specific to the …

Detecting Symptoms Of Chronic Obstructive Pulmonary Disease And Congestive Heart Failure Via Cough And Wheezing Sounds Using Smart-Phones And Machine Learning, Anthony Windmon

USF Tampa Graduate Theses and Dissertations

Chronic Obstructive Pulmonary Disease (COPD) and Congestive Heart Failure (CHF) are progressive disorders, and major health concerns among today’s aging population. COPD causes a large mucus buildup in the lungs, leading to chronic cough and difficulty to breathe. CHF causes fluid buildup in the lower lungs due to the failing heart, causing cough and difficulty to breath. People who are clinically diagnosed with COPD or CHF are expected to regularly monitor their symptoms and follow complex medical recommendations in an effort to prevent exacerbation. In this dissertation, we elaborate upon three different machine learning based techniques that we developed for …

Black Lives Matter In Engineering, Too! An Environmental Justice Approach Towards Equitable Decision-Making For Stormwater Management In African American Communities, Maya Elizabeth Carrasquillo

USF Tampa Graduate Theses and Dissertations

The United States and the world have recently been challenged with the disparate effects of COVID-19 and the continual killings of unarmed Black men and women across the nation. A history of anti-black racism has led to systemic structures of inequity that thread throughout institutions and communities across the nation. This environmental engineering research comes at a time when understanding how to effectively engage in, and with Black communities is at the forefront of discourse in academia, utilities and private sector.

In 2018 the Brookings Institute published a report on workforce in the water sector demonstrating the lack of diversity …

Distributed Control Of Multiagent Systems Under Heterogeneity, Selahattin Burak Sarsilmaz

USF Tampa Graduate Theses and Dissertations

The overarching objective of this work is to propose solutions to quite a few distributed control problems arising from networks of heterogeneous agents or the heterogeneous nature of multiagent systems. Each problem with its solutions is concisely summarized below.

We consider the cooperative output regulation problem of heterogeneous linear multiagent systems over fixed directed communication graphs. The purpose of this problem is to design a distributed control law such that the overall closed-loop stability is ensured and the tracking error of each agent converges to zero asymptotically for a class of reference inputs and disturbances generated by a so-called exosystem. …

Machine Learning For The Internet Of Things: Applications, Implementation, And Security, Vishalini Laguduva Ramnath

USF Tampa Graduate Theses and Dissertations

Artificial intelligence and ubiquitous sensor systems have seen tremendous advances in recent times, resulting in groundbreaking impact across domains such as healthcare, entertainment, and transportation through a collective ecosystem called the Internet of Things. The advent of 5G and improved wireless networks will further accelerate the research and development of tools in deep learning, sensor systems, and computing platforms by providing improved network latency and bandwidth. While tremendous progress has been made in the Internet of Things, current work has largely focused on building robust applications that leverage the data collected through ubiquitous sensor nodes to provide actionable rules and …

Socio-Technical Transitions In The Water Sector: Emerging Boundaries For Utility Resilience In Barbados, Wainella N. Isaacs

USF Tampa Graduate Theses and Dissertations

Resilience is gaining popularity in the water sector where it described as contributing to reduced vulnerability to water-related risks and hazards including climate change. Unfortunately, literature in this area, contributed mainly from North America and Europe, is fragmented with a concentration on engineering resilience in water supply infrastructure. The absence of any scholarship on resilience for a small island nation, coupled with the absence of sociological contributors to building resilience in this sector motivated this research.

The goal of this research was to understand and evaluate how resilience is characterized and operationalized in the Barbados water and wastewater infrastructure system, …

Relational Joins On Gpus For In-Memory Database Query Processing, Ran Rui

USF Tampa Graduate Theses and Dissertations

Relational join processing is one of the core functionalities in database management systems. Implementing join algorithms on parallel platforms, especially modern GPUs, has gain a lot of momentum in the past decade. This dissertation addresses the following issues on GPU join algorithms. First, we present empirical evaluations of a state-of-the-art work on GPU-based join processing. Since 2008, the compute capabilities of GPUs have increased following a pace faster than that of the multi-core CPUs. We run a comprehensive set of experiments to study how join operations can benefit from such rapid expansion of GPU capabilities. We also present improved GPU …