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Articles 31 - 60 of 71

Full-Text Articles in Physical Sciences and Mathematics

Interactions Between Macroalgae And The Sediment Microbial Community: Nutrient Cycling Within Shallow Coastal Bays, Amber Kay Hardison Jan 2009

Interactions Between Macroalgae And The Sediment Microbial Community: Nutrient Cycling Within Shallow Coastal Bays, Amber Kay Hardison

Dissertations, Theses, and Masters Projects

Ephemeral macroalgal blooms are considered a symptom of eutrophication in shallow coastal lagoons, but their influence on nutrient cycling dynamics in these systems is not fully understood. From 2006-2008, I conducted a series of experiments to determine the influence of living and senescent macroalgae on sediment carbon (C) and nitrogen (N) cycling in coastal lagoons along the Delmarva Peninsula, USA. In particular, I focused on how macroalgae affect the microbial community at the sediment-water interface of shallow subtidal sediments because this complex consortium of autotrophic (e.g. benthic microalgae, BMA) and heterotrophic (e.g. bacteria) organisms plays a critical role in nutrient …


Multi-System Analysis Of Nitrogen Use By Phytoplankton And Heterotrophic Bacteria, Paul B. Bradley Jan 2009

Multi-System Analysis Of Nitrogen Use By Phytoplankton And Heterotrophic Bacteria, Paul B. Bradley

Dissertations, Theses, and Masters Projects

Traditional measurements of phytoplankton N uptake have been confounded by bacterial retention on filters used in 15N uptake studies, and such methodological obstacles have limited our understanding of phytoplankton-bacterial interactions regarding N cycling. In this research, uptake of various inorganic and organic N substrates by phytoplankton and bacteria was measured in several marine ecosystems using two distinct approaches: size fractionation into phytoplankton and bacterial size classes, and flow cytometric (FCM) sorting of autotrophic cells. Comprehensive assessments of N uptake dynamics were conducted in Chesapeake Bay, the Mid-Atlantic Bight, and Raunefjord, Norway, with supplementary data collected from the York River, Virginia …


Community Dynamics In Submersed Aquatic Vegetation: Intermediate Consumers As Mediators Of Environmental Change, James G. Douglass Jan 2008

Community Dynamics In Submersed Aquatic Vegetation: Intermediate Consumers As Mediators Of Environmental Change, James G. Douglass

Dissertations, Theses, and Masters Projects

Natural ecosystems are strongly affected by changes in resource supply (bottom-up forces) and by changes in upper trophic levels (top-down forces). The extent to which these processes impact a system depends largely on the responses of organisms at middle trophic levels. In seagrass beds, a group of mid-level consumers known as mesograzers form a critical link in the chain of impact, connecting seagrass and epiphytic algae with predatory fishes and crustaceans. I observed dramatic seasonal and interannual changes in mesograzer abundance and species composition in eelgrass (Zostera marina) beds of lower Chesapeake Bay, Virginia, and endeavored to explain the top-down …


Technical Note: Molecular Characterization Of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, As Wosniak, Je Bauer, Rl Sleighter, Rm Dickhut, Pg Hatcher Jan 2008

Technical Note: Molecular Characterization Of Aerosol-Derived Water Soluble Organic Carbon Using Ultrahigh Resolution Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, As Wosniak, Je Bauer, Rl Sleighter, Rm Dickhut, Pg Hatcher

VIMS Articles

Despite the acknowledged relevance of aerosol-derived water-soluble organic carbon (WSOC) to climate and biogeochemical cycling, characterization of aerosol WSOC has been limited. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) was utilized in this study to provide detailed molecular level characterization of the hi(,h molecular weight (HMW; m/z>223) component of aerosol-derived WSOC collected from rural sites in Virginia and New York, USA. More than 3000 peaks were detected by ESI FT-ICR MS within a m/z range of 223-600 for each sample. Approximately 86% (Virginia) and 78% (New York) of these peaks were assigned molecular formulas …


Biogeochemistry And Phytoplankton Dynamics In The Ross Sea, Antarctica, Amy Rebecca Shields Jan 2007

Biogeochemistry And Phytoplankton Dynamics In The Ross Sea, Antarctica, Amy Rebecca Shields

Dissertations, Theses, and Masters Projects

The Ross Sea, Antarctica seasonal phytoplankton bloom is one of the largest in the Southern Ocean. This project focuses on the biological pump, which removes carbon from the surface ocean to the deep ocean through the settling of particulate organic matter, the advection of dissolved organic carbon, and active flux due to vertical migration of zooplankton. The objective of this study was to focus on three interrelated components of the biological pump including sedimentation, photosynthetic rates and grazing. The study was conducted in coordination with the Interannual Variability in the Antarctic-Ross Sea program, which covered the time period between 2001--2005. …


Dissolved And Particulate Organic Matter Source-Age Characterization In The Upper And Lower Chesapeake Bay: A Combined Isotope And Biochemical Approach, An Loh, Je Bauer, Ea Canuel May 2006

Dissolved And Particulate Organic Matter Source-Age Characterization In The Upper And Lower Chesapeake Bay: A Combined Isotope And Biochemical Approach, An Loh, Je Bauer, Ea Canuel

VIMS Articles

In order to characterize the sources and ages of organic matter contributing to river and estuarine outflow waters, the present study investigated Delta C-14 and delta C-13 signatures of the major operationally defined biochemical classes of ultrafiltered dissolved organic matter (UDOM) in conjunction with lipid biomarker and elemental compositions of UDOM and suspended particulate organic matter (POM) in the Chesapeake Bay. Freshwater (Susquehanna River) UDOM was dominated by a molecularly uncharacterized (MUC) fraction, followed by total carbohydrate (TCHO), total hydrolysable amino acid (THAA) and total lipid (TLE) components. In contrast, UDOM at the bay mouth (salinity similar to 22-24) was …


Bioreactivity Of Estuarine Dissolved Organic Matter: A Combined Geochemical And Microbiological Approach, Sl Mccallister, Je Bauer, Elizabeth A. Canuel Jan 2006

Bioreactivity Of Estuarine Dissolved Organic Matter: A Combined Geochemical And Microbiological Approach, Sl Mccallister, Je Bauer, Elizabeth A. Canuel

VIMS Articles

An integrated multidisciplinary study utilizing geochemical and microbial ecological approaches was conducted to characterize the origins, chemical nature, and quantities of dissolved and particulate organic matter (OM) utilized by heterotrophic bacteria in a temperate estuary. C: N, stable isotope (delta C-13), and lipid biomarker analyses revealed differences in the inferred reactivity of autochthonous versus allochthonous OM sources. Isotopic comparison of OM size fractions and bacterial nucleic acids suggests that high-molecular-weight dissolved OM (DOM) is consistently linked to bacterial biomass synthesis along the estuarine salinity gradient. Polyunsaturated fatty acids (as percent of total fatty acids, FA) were a reliable predictor of …


Sediment Biogeochemistry Of Northern Cascadia Margin Shallow Gas Hydrate Systems, John W. Pohlman Jan 2006

Sediment Biogeochemistry Of Northern Cascadia Margin Shallow Gas Hydrate Systems, John W. Pohlman

Dissertations, Theses, and Masters Projects

Methane contained in gas hydrate is a significant component of the global organic carbon inventory. Describing the methane sources supporting these systems and the mechanisms that control the distribution of methane in marine sediments are critical elements in evaluating the resource potential, climate change implications and geologic hazards associated with gas hydrate. The northern Cascadia margin (offshore Vancouver Island, Canada) is a convergent margin with gas hydrate-bearing cold seeps composed of both thermogenic (Barkley Canyon) and microbial (Bullseye vent) gas sources. Gas hydrate and sediment cores were collected from each of these settings to examine the sources that sustain the …


Effects Of Sunlight On Decomposition Of Estuarine Dissolved Organic C, N And P And Bacterial Metabolism, Sl Mccallister, Je Bauer, J Kelly, Hw Ducklow Jul 2005

Effects Of Sunlight On Decomposition Of Estuarine Dissolved Organic C, N And P And Bacterial Metabolism, Sl Mccallister, Je Bauer, J Kelly, Hw Ducklow

VIMS Articles

The effects of natural sunlight and microbial decomposition on DOC, DON, and DOP were investigated along the salinity gradient of a temperate coastal plain estuary. The impact of sunlight-irradiated DOM on bacterial properties (bacterial abundance, production, bacterial growth efficiency [BGE]) was also followed. Surface-water light levels resulted in no detectable abiotic production of NH4+ or PO43- or loss of DOC. Bacterial decomposition of DOC was enhanced by 27 to 200 % in irradiated relative to dark treatments. There was, however, no corresponding enhancement in DON and DOP remineralization. Significant differences in bacterial decomposition of light-exposed DOC were frequently observed following …


Input Of Particulate Organic And Dissolved Inorganic Carbon From The Amazon To The Atlantic Ocean, Erm Druffel, Je Bauer, S Griffin Mar 2005

Input Of Particulate Organic And Dissolved Inorganic Carbon From The Amazon To The Atlantic Ocean, Erm Druffel, Je Bauer, S Griffin

VIMS Articles

We report concentrations and isotope measurements (radiocarbon and stable carbon) of dissolved inorganic carbon (DIC) and suspended particulate organic carbon (POC) in waters collected from the mouth of the Amazon River and the North Brazil Current. Samples were collected in November 1991, when the Amazon hydrograph was at its annual minimum and the North Brazil Current had retroflected into the equatorial North Atlantic. The DIC D 14 C results revealed postbomb carbon in river and ocean waters, with slightly higher values at the river mouth. The low DIC delta(13)C signature of the river end-member (-11%) demonstrates that about half of …


Iron And Carbon Limitation Of Prokaryotic Growth In The Ocean, Jacques L. Oliver Jan 2005

Iron And Carbon Limitation Of Prokaryotic Growth In The Ocean, Jacques L. Oliver

Dissertations, Theses, and Masters Projects

Studies were undertaken to examine the roles of iron and carbon in modulating prokaryotic growth in the ocean. The context of the first study was an open-open iron fertilization experiment in the high nutrient, low chlorophyll (HNLC) regime in the Southern Ocean. The context of the second study was the oligotrophic, iron-replete, and organic carbon-limited northwest Sargasso Sea. Experimental sea water cultures were amended with an iron chelator, desferrioxamine B (DFOB), and other nutrients to examine the effects of iron and carbon limitation on growth. In the first study prokaryotic abundance, carbon production, and growth rate increased in response to …


Bacterial Utilization Of Transient Plankton-Derived Dissolved Organic Carbon And Nitrogen Inputs In Surface Ocean Waters, J Cherrier, Je Bauer May 2004

Bacterial Utilization Of Transient Plankton-Derived Dissolved Organic Carbon And Nitrogen Inputs In Surface Ocean Waters, J Cherrier, Je Bauer

VIMS Articles

The majority of bacterial growth and respiration in the upper ocean is thought to result from coupling between microheterotrophic populations and the reactive soluble components of planktonic primary and secondary production. However, we know little about the potential turnover of these components and the concomitant growth of bacteria under conditions of intermittent or transient inputs of natural dissolved organic matter (DOM) compared to quasi-steady state, low DOM conditions. The present study evaluated the short-term (similar to3 d) rates and net extents of utilization (as measured losses) of selected constituents of plankton-derived DOM (DOMPD) by indigenous bacterioplankton populations in eastern North …


High Rates Of Ammonium Recycling Drive Phytoplankton Productivity In The Offshore Mississippi River Plume, B Wawrik, Jh Paul, Da Bronk, Et Al Apr 2004

High Rates Of Ammonium Recycling Drive Phytoplankton Productivity In The Offshore Mississippi River Plume, B Wawrik, Jh Paul, Da Bronk, Et Al

VIMS Articles

As part of an integrated study of the regulation of carbon fixation in the offshore Mississippi River plume, we measured the rates of N-15-labeled ammonium and nitrate uptake in the surface plume waters from offshore to nearshore along the plume axis towards the Mississippi Delta. Concentrations of nitrate in the plume ranged from 0.19 to 2.5 muM with the highest concentrations primarily in the shoreward stations, while ammonium ranged from 0.17 to 0.44 muM, showing little spatial variability. Rates of ammonium uptake ranged from 16.5 to 260 nM h(-1), and showed a strong trend of increasing values from offshore towards …


Benthic Algae Control Sediment-Water Column Fluxes Of Organic And Inorganic Nitrogen Compounds In A Temperate Lagoon, Ac Tyler, Kj Mcglathery, Iris C. Anderson Oct 2003

Benthic Algae Control Sediment-Water Column Fluxes Of Organic And Inorganic Nitrogen Compounds In A Temperate Lagoon, Ac Tyler, Kj Mcglathery, Iris C. Anderson

VIMS Articles

Coastal lagoons are a common land-margin feature worldwide and function as an important filter for nutrients entering from the watershed. The shallow nature of lagoons leads to dominance by benthic autotrophs, which can regulate benthic-pelagic coupling. Here we demonstrate that both microalgae and macroalgae are important in controlling dissolved inorganic as well as organic nitrogen (DIN and DON) fluxes between the sediments and the water column. Fluxes of nitrogen (NH4+, NO3-, DON, urea, and dissolved free and combined amino acids [DFAA, DCAA]) and O-2 were measured from October 1998 through August 1999 in sediment cores collected from Hog Island Bay, …


Penetration Of Anthropogenic Carbon Into Organic Particles Of The Deep Ocean, Erm Druffel, Je Bauer, S Griffin, J Hwang Jul 2003

Penetration Of Anthropogenic Carbon Into Organic Particles Of The Deep Ocean, Erm Druffel, Je Bauer, S Griffin, J Hwang

VIMS Articles

] In the late 1980s, bomb C-14 was present in suspended particulate organic carbon (POC) from the North Central Pacific (NCP) and Sargasso Sea ( SS) throughout most of the water column, demonstrating that deep POC had exchanged with atmospheric CO2 in the past 30 years. Upon reoccupation of these sites in 1999 and 2000, respectively, we observed that the delta(13)C values of suspended POC were lower than those measured a decade earlier. This demonstrates that anthropogenic CO2 from fossil fuel and biomass burning has penetrated a major organic matter pool in the deep ocean. Delta(14)C measured in the suspended …


Microbial Dynamics And Biogeochemistry In The North Pacific Subtropical Gyre, Matthew J. Church Jan 2003

Microbial Dynamics And Biogeochemistry In The North Pacific Subtropical Gyre, Matthew J. Church

Dissertations, Theses, and Masters Projects

The research presented in this dissertation describes the influence of planktonic bacterial growth on upper ocean organic matter dynamics in the North Pacific Subtropical Gyre (NPSG). Examination of the temporal dynamics in dissolved organic matter (DOM) was coupled with investigations that targeted the influence of heterotrophic bacterial production (HBP) on organic matter fluxes in the NPSG. Nine cruises to the Hawaii Ocean Time-series field site Station ALOHA revealed that HBP accounted for a large flux of organic carbon in the upper ocean of the NPSG. HBP was significantly enhanced by sunlight, with photoenhancement of HBP accounting for 3.2 mol C …


Transport Of Dissolved Inorganic Carbon From A Tidal Freshwater Marsh To The York River Estuary, Sc Neubauer, Iris C. Anderson Jan 2003

Transport Of Dissolved Inorganic Carbon From A Tidal Freshwater Marsh To The York River Estuary, Sc Neubauer, Iris C. Anderson

VIMS Articles

The cycling of dissolved inorganic carbon (DIC) and the role of tidal marshes in estuarine DIC dynamics were studied in a Virginia tidal freshwater marsh and adjacent estuary. DIC was measured over diurnal cycles in different seasons in a marsh tidal creek and at the junction of the creek with the adjacent Pamunkey River. In the creek, DIC concentrations around high tide were controlled by the same processes affecting whole-estuary DIC gradients. Near low tide, DIC concentrations were 1.5-5-fold enriched relative to high tide concentrations, indicating an input of DIC from the marsh. Similar patterns (although dampened in magnitude) were …


Availability Of Humic Nitrogen To Phytoplankton, Jason Holt See Jan 2003

Availability Of Humic Nitrogen To Phytoplankton, Jason Holt See

Dissertations, Theses, and Masters Projects

The chemical, physical, and biological factors affecting the bioavailability of humic nitrogen (N) to coastal phytoplankton were examined. Historically, humic substances have largely been considered biologically refractory, and humic-N is though to be unavailable biologically without prior oxidation via photochemical cleavage or remineralization by bacteria. This is due in part to the high aromaticity and low N content of humic substances. This dissertation investigates whether these assumptions are valid, and whether humic substances may be a more important source of N to the coastal phytoplankton community than previously believed. The research consisted of four main parts. First, changes in the …


Stable Carbon And Nitrogen Isotope Composition Of Aquatic And Terrestrial Plants Of The San Francisco Bay Estuarine System, Je Cloern, Elizabeth A. Canuel, D Harris May 2002

Stable Carbon And Nitrogen Isotope Composition Of Aquatic And Terrestrial Plants Of The San Francisco Bay Estuarine System, Je Cloern, Elizabeth A. Canuel, D Harris

VIMS Articles

We report measurements of seasonal variability in the C-N stable isotope ratios of plants collected across the habitat mosaic of San Francisco Bay, its marshes, and its tributary river system. Analyses of 868 plant samples were binned into 10 groups (e.g., terrestrial riparian, freshwater phytoplankton, salt marsh) to determine whether C-N isotopes can be used as biomarkers for tracing the origins of organic matter in this river-marsh-estuary complex. Variability of delta(130)C and delta(15)N was high (similar to5-10parts per thousand) within each plant group, and we identified three modes of variability: (1) between species and their microhabitats, (2) over annual cycles …


Fate Of Organic Compounds Associated With Extractable And Bound Phases Of Estuarine Sediments Deposited Under Varying Depositional Regimes, Krisa Murray Arzayus Jan 2002

Fate Of Organic Compounds Associated With Extractable And Bound Phases Of Estuarine Sediments Deposited Under Varying Depositional Regimes, Krisa Murray Arzayus

Dissertations, Theses, and Masters Projects

Surficial sediments and sediment cores were collected from two distinct depositional regimes of the York River subestuary of Chesapeake Bay to document seasonal inputs, spatial variability, and longer-term (>40 years) fate of total organic carbon (TOC), lipid biomarker compounds and polycyclic aromatic hydrocarbons (PAHs). These regimes included biological mixing in the lower York and episodic mixing at the mid river site. Compounds were selected to represent a range of chemical reactivities, biological and anthropogenic sources, and modes of entry to the environment. The depositional environments were characterized with a suite of analytical tools: x-radiographs, Eh, 210Pb and 137Cs, total …


Organic Matter Cycling In The York River Estuary, Virginia: An Analysis Of Potential Sources And Sinks, Leigh Mccallister Jan 2002

Organic Matter Cycling In The York River Estuary, Virginia: An Analysis Of Potential Sources And Sinks, Leigh Mccallister

Dissertations, Theses, and Masters Projects

A study of the organic matter (OM) sources and biogeochemical and physicochemical sinks was undertaken in the York River estuary, Virginia. The reactivity of dissolved organic carbon (DOC) was enhanced from ∼25--68% by the combined effects of exposure to natural sunlight and bacterial decomposition. In contrast, sunlight exposure decreased the bioreactivity of DOC in the higher salinity lower York by a factor of five. The combined effects of photochemical and bacterial processing were found to modify both the bioavailability and metabolic fate of OM (e.g. respiration vs. biomass). Stable isotopic (delta13C, delta15N) and radiocarbon (Delta14C) values of bacterial nucleic acids …


Supplemental Data: Effects Of Physical Mixing On The Attenuation Of Polycyclic Aromatic Hydrocarbons In Estuarine Sediments., Krisa M. Arzayus, Rebecca M. Dickhut, Elizabeth A. Canuel Jan 2002

Supplemental Data: Effects Of Physical Mixing On The Attenuation Of Polycyclic Aromatic Hydrocarbons In Estuarine Sediments., Krisa M. Arzayus, Rebecca M. Dickhut, Elizabeth A. Canuel

Reports

To examine the role of physical disturbance on the long-term preservation of polycyclic aromatic hydrocarbons (PAHs) in sediments, cores were collected from two sites removed from point sources of PAHs and representing contrasting seabed mixing regimes. Although SPAH concentrations in sediments over the past 50 years were not significantly different between the two sites, several PAH isomer ratios were significantly different (p


Tracking The Fate Of A High Concentration Groundwater Nitrate Plume Through A Fringing Marsh: A Combined Groundwater Tracer And In Situ Isotope Enrichment Study, Cr Tobias, Sa Macko, Iris C. Anderson, Elizabeth A. Canuel, Jw Harvey Dec 2001

Tracking The Fate Of A High Concentration Groundwater Nitrate Plume Through A Fringing Marsh: A Combined Groundwater Tracer And In Situ Isotope Enrichment Study, Cr Tobias, Sa Macko, Iris C. Anderson, Elizabeth A. Canuel, Jw Harvey

VIMS Articles

A groundwater plume enriched in (15)NO(3)(-) was created upgradient of a mesohaline salt marsh. By measuring the changes in concentration and isotopic enrichment of NO(3)(-), N(2)O, N(2), NH(4)(+), and particulate organic nitrogen (PON) during plume transport through the marsh, in situ rates of dissimilatory nitrate reduction to ammonium (DNRA) and denitrification (DNF) were estimated, as well as N storage in the reduced N pools. For groundwater discharge within the top 10 cm of marsh, NO(3)(-) removal was 90% complete within the 50 cm of marsh nearest the upland border. The peak NO(3)(-) loss rate from the plume ranged from 208 …


Sources And Cycling Of Dissolved And Particulate Organic Radiocarbon In The Northwest Atlantic Continental Margin, Je Bauer, Erm Druffel, Dm Wolgast, S Griffin Aug 2001

Sources And Cycling Of Dissolved And Particulate Organic Radiocarbon In The Northwest Atlantic Continental Margin, Je Bauer, Erm Druffel, Dm Wolgast, S Griffin

VIMS Articles

Continental shelves and slopes are productive and dynamic ocean margin systems that also regulate the fluxes of terrestrial, riverine, and estuarine materials between the continents and oceans. In order to evaluate the ages, potential sources, and transformations of organic matter in an ocean margin system, we measured the radiocarbon (Delta (14)C and delta (13)C distributions of total dissolved organic carbon (DOC), suspended particulate organic carbon (POC), and dissolved inorganic carbon (DIC) in waters of the Middle Atlantic Bight (MAB) continental shelf and slope in April-May 1994. The Delta (14)C of DOC was greatest (as high as -39 parts per thousand) …


Quantifying Groundwater Discharge Through Fringing Wetlands To Estuaries: Seasonal Variability, Methods Comparison, And Implications For Wetland-Estuary Exchange, Cr Tobias, Jw Harvey, Iris C. Anderson May 2001

Quantifying Groundwater Discharge Through Fringing Wetlands To Estuaries: Seasonal Variability, Methods Comparison, And Implications For Wetland-Estuary Exchange, Cr Tobias, Jw Harvey, Iris C. Anderson

VIMS Articles

Because groundwater discharge along coastal shorelines is often concentrated in zones inhabited by fringing wetlands, accurately estimating discharge is essential for understanding its effect on the function and maintenance of these ecosystems. Most previous estimates of groundwater discharge to coastal wetlands have been temporally limited and have used only a single approach to estimate discharge. Furthermore, groundwater input has not been considered as a major mechanism controlling pore-water flushing. We estimated seasonally varying groundwater discharge into a fringing estuarine wetland using three independent methods (Darcy's Law, salt balance, and Br- tracer). Seasonal patterns of discharge predicted by both Darcy's Law …


Persistent Organic Pollutant Transport And Fate: Assessment By Molecular Tracers, Padma T. Venkatraman Jan 2001

Persistent Organic Pollutant Transport And Fate: Assessment By Molecular Tracers, Padma T. Venkatraman

Dissertations, Theses, and Masters Projects

Persistent organic pollutants (POPs) such as the organochlorine pesticide hexachlorocyclohexane (HCH) may undergo atmospheric transport and accumulate in regions remote from the source. It is important to develop techniques to help apportion source and identify transport or transformation processes to which HCHs and other mobile POPs may be subjected. Molecular tracers such as compound specific stable isotope and enantiomer ratios (ERs) may prove valuable in studying POP fate and transport. The objective of this study was to further develop the use of these two novel geochemical tools to evaluate the sources, transport and environmental fate of POPs, in the context …


Modeling Distinct Vertical Biogeochemical Structure Of The Black Sea: Dynamical Coupling Of The Oxic, Suboxic, And Anoxic Layers, T Oguz, Hw Ducklow, P Malanotte-Rizzoli Nov 2000

Modeling Distinct Vertical Biogeochemical Structure Of The Black Sea: Dynamical Coupling Of The Oxic, Suboxic, And Anoxic Layers, T Oguz, Hw Ducklow, P Malanotte-Rizzoli

VIMS Articles

A one-dimensional, vertically resolved, physical-biogeochemical model is used to provide a unified representation of the dynamically coupled oxic-suboxic-anoxic system for the interior Black Sea. The model relates the annual cycle of plankton production in the form of a series of successive phytoplankton, mesozooplankton, and higher consumer blooms to organic matter generation and to the remineralization-ammonification-nitrification-dentrification chain of the nitrogen cycle as well as to anaerobic sulfide oxidation in the suboxic-anoxic interface zone. The simulations indicate that oxygen consumption during remineralixation and nitrification, together with a lack of ventilation of subsurface waters due to the presence of strong stratification, are the …


Radiocarbon Distributions In Southern Ocean Dissolved And Particulate Organic Matter, Erm Druffel, Je Bauer May 2000

Radiocarbon Distributions In Southern Ocean Dissolved And Particulate Organic Matter, Erm Druffel, Je Bauer

VIMS Articles

Dissolved organic carbon (DOC) is the largest actively exchanging pool of organic carbon in the ocean, yet its sources and sinks are not well constrained. The average C-14 ages of DOC in the deep N. Atlantic and N. Pacific Oceans are 4,000 [Bauer et al., 1992; Druffel et al., 1992] and 6,000 years [Williams and Druffel, 1987], respectively, and represent the beginning and end of the deep ocean conveyor [Broecker, 1991]. Here we report that the deep Southern Ocean DOC has a C-14 age (5,600 y) much closer to that of the deep N. Pacific, but its concentration in seawater …


A Stable Isotopic Study To Determine Carbon And Nitrogen Cycling In A Disturbed Southern Californian Forest Ecosystem, S Korontzi, Sa Macko, Iris C. Anderson Mar 2000

A Stable Isotopic Study To Determine Carbon And Nitrogen Cycling In A Disturbed Southern Californian Forest Ecosystem, S Korontzi, Sa Macko, Iris C. Anderson

VIMS Articles

This study utilized isotope analyses to contrast nitrogen and carbon dynamics at four sites located along an air pollution gradient in the San Bernardino National Forest in southern California. Natural N-15 and C-13 abundances along with nutritional and edaphic properties were determined in soil, litter, and vegetation samples. Mean bulk nitrogen delta(15)N values of soil and vegetation at Camp Paivika (CP), the most polluted site, were at least 1.7 parts per thousand more enriched than the other, less polluted sites. Mean soil delta(15)NH(4)(+) was also significantly enriched in N-15 at CP compared to Barton Flats (BF), the least polluted site, …


Organic Matter Composition Of Sediments And The History Of Eutrophication And Anoxia In The Mesohaline Chesapeake Bay, Andrew R. Zimmerman Jan 2000

Organic Matter Composition Of Sediments And The History Of Eutrophication And Anoxia In The Mesohaline Chesapeake Bay, Andrew R. Zimmerman

Dissertations, Theses, and Masters Projects

To evaluate the effects of anthropogenic alteration of the Chesapeake Bay (CB) watershed since European settlement, the historical progression of eutrophication and anoxia in the mesohaline region of CB was reconstructed. Lipid biomarker and carbon and nitrogen stable isotopic and elemental composition of CB surficial sediments were examined seasonally in order to identify the present sources of organic matter to CB sediments and the processes controlling their distribution. Temporal variability in surficial sediment composition could be linked to seasonal changes in phytoplankton community composition and biomass while spatial variation was dominated by the delivery of alloclithonous versus autochthonous sources of …