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Full-Text Articles in Physical Sciences and Mathematics

Tracking The Fate Of A High Concentration Groundwater Nitrate Plume Through A Fringing Marsh: A Combined Groundwater Tracer And In Situ Isotope Enrichment Study, Cr Tobias, Sa Macko, Iris C. Anderson, Elizabeth A. Canuel, Jw Harvey Dec 2001

Tracking The Fate Of A High Concentration Groundwater Nitrate Plume Through A Fringing Marsh: A Combined Groundwater Tracer And In Situ Isotope Enrichment Study, Cr Tobias, Sa Macko, Iris C. Anderson, Elizabeth A. Canuel, Jw Harvey

VIMS Articles

A groundwater plume enriched in (15)NO(3)(-) was created upgradient of a mesohaline salt marsh. By measuring the changes in concentration and isotopic enrichment of NO(3)(-), N(2)O, N(2), NH(4)(+), and particulate organic nitrogen (PON) during plume transport through the marsh, in situ rates of dissimilatory nitrate reduction to ammonium (DNRA) and denitrification (DNF) were estimated, as well as N storage in the reduced N pools. For groundwater discharge within the top 10 cm of marsh, NO(3)(-) removal was 90% complete within the 50 cm of marsh nearest the upland border. The peak NO(3)(-) loss rate from the plume ranged from 208 …


Sources And Cycling Of Dissolved And Particulate Organic Radiocarbon In The Northwest Atlantic Continental Margin, Je Bauer, Erm Druffel, Dm Wolgast, S Griffin Aug 2001

Sources And Cycling Of Dissolved And Particulate Organic Radiocarbon In The Northwest Atlantic Continental Margin, Je Bauer, Erm Druffel, Dm Wolgast, S Griffin

VIMS Articles

Continental shelves and slopes are productive and dynamic ocean margin systems that also regulate the fluxes of terrestrial, riverine, and estuarine materials between the continents and oceans. In order to evaluate the ages, potential sources, and transformations of organic matter in an ocean margin system, we measured the radiocarbon (Delta (14)C and delta (13)C distributions of total dissolved organic carbon (DOC), suspended particulate organic carbon (POC), and dissolved inorganic carbon (DIC) in waters of the Middle Atlantic Bight (MAB) continental shelf and slope in April-May 1994. The Delta (14)C of DOC was greatest (as high as -39 parts per thousand) …


Quantifying Groundwater Discharge Through Fringing Wetlands To Estuaries: Seasonal Variability, Methods Comparison, And Implications For Wetland-Estuary Exchange, Cr Tobias, Jw Harvey, Iris C. Anderson May 2001

Quantifying Groundwater Discharge Through Fringing Wetlands To Estuaries: Seasonal Variability, Methods Comparison, And Implications For Wetland-Estuary Exchange, Cr Tobias, Jw Harvey, Iris C. Anderson

VIMS Articles

Because groundwater discharge along coastal shorelines is often concentrated in zones inhabited by fringing wetlands, accurately estimating discharge is essential for understanding its effect on the function and maintenance of these ecosystems. Most previous estimates of groundwater discharge to coastal wetlands have been temporally limited and have used only a single approach to estimate discharge. Furthermore, groundwater input has not been considered as a major mechanism controlling pore-water flushing. We estimated seasonally varying groundwater discharge into a fringing estuarine wetland using three independent methods (Darcy's Law, salt balance, and Br- tracer). Seasonal patterns of discharge predicted by both Darcy's Law …


Persistent Organic Pollutant Transport And Fate: Assessment By Molecular Tracers, Padma T. Venkatraman Jan 2001

Persistent Organic Pollutant Transport And Fate: Assessment By Molecular Tracers, Padma T. Venkatraman

Dissertations, Theses, and Masters Projects

Persistent organic pollutants (POPs) such as the organochlorine pesticide hexachlorocyclohexane (HCH) may undergo atmospheric transport and accumulate in regions remote from the source. It is important to develop techniques to help apportion source and identify transport or transformation processes to which HCHs and other mobile POPs may be subjected. Molecular tracers such as compound specific stable isotope and enantiomer ratios (ERs) may prove valuable in studying POP fate and transport. The objective of this study was to further develop the use of these two novel geochemical tools to evaluate the sources, transport and environmental fate of POPs, in the context …