Nuclear Engineering Commons^™

Modeling Of Laser-Produced Plasma Plumes: Expansion, Chemistry, And Thin-Film Deposition, Edmund Tsiri Semaha, Edmund Tsiri Semaha

Theses and Dissertations

Abstract

Laser-assisted material processing involves coupled plasma expansion, chemical reactions, and particle transport that govern the quality of thin-film deposition. This dissertation presents a comprehensive computational investigation of these processes using the OpenFOAM framework. First, the performance of the twoPhaseEulerFoam (tPEF), rhoCentralFoam (rCF), and sonicFoam (sF) solvers is evaluated for modeling laser-produced plasma plume expansion under atmospheric conditions, demonstrating that tPEF accurately captures shock-wave propagation, hydrodynamic behavior, and multispecies interactions. Building on this validation, the reactingFoam (rF) solver is employed to investigate the chemistry of aluminum plasma expanding into an air environment (Al–N₂–O₂). The model incorporates appropriate thermodynamic, transport, and …

Multiphysics Modeling Of Material Response To High-Intensity X-Ray And Laser Pulses: Heating, Ablation, And Plasma Expansion, Youssef Abouhussien

Theses and Dissertations

This dissertation presents a computational framework to investigate material response under high-intensity X-ray fluxes produced by an exo-atmospheric nuclear detonation and laser-material irradiations, with a focus on heating, ablation, and plasma expansion phenomena relevant to satellite vulnerability and high-energy-density environments. A hybrid Monte Carlo and Two-Temperature Model (MC-TTM) was developed to simulate X-ray and laser energy deposition and thermal relaxation in metals and semiconductors across a range of X-ray and laser pulse durations from femtoseconds to nanoseconds. Results demonstrate distinct thermal behavior between materials, with ablation thresholds and phase transitions captured in good agreement with experimental data.

In parallel, a …

Hafnium Oxide-Based Nanoheterostructures For Catalytic Radiosensitization And Enhanced X-Ray Radiotherapy, Marlen Dariela Calix Quezada

Theses and Dissertations

Orthovoltage X-ray beams are attractive for surface and intra-operative radiotherapy. Yet, their clinical utility is constrained by rapid attenuation and the limited dose that can be delivered without harming healthy tissue. High-Z hafnium oxide (HfO₂) nanoparticles can boost local energy deposition through the photoelectric effect, while catalytic surface defects accelerate water radiolysis. Harnessing both mechanisms in a single nano-heterostructure could enable potent radiosensitization at diagnostic-range energies.

This thesis develops and evaluates HfO₂-based nanoheterostructures, both bare and Au-decorated, as catalytic radiosensitizers.

Two types of HfO₂ were evaluated, one was synthesized following a specific route and the …

Advanced Air Preheater Sealing Systems For Enhanced Efficiency And Reliability In Thermal Power Plants, Pavan Kumar Ravulaparthy

Theses and Dissertations

Global electricity generation still relies heavily on thermal power plants, which consume vast amounts of fuel and emit significant amounts of carbon dioxide. A major but often overlooked source of inefficiency in these plants lies within the rotary regenerative air preheater (RAPH), a critical heat-exchange component where air leakage can exceed 20% in aging units. This leakage increases fuel consumption, parasitic fan power, and CO₂ emissions, while degrading boiler reliability.

This research introduces advanced adaptive sealing systems designed to mitigate these losses by dynamically compensating for rotor eccentricity, thermal distortion, and wear under harsh operating conditions. Brush seals, composed of …

Laser Ablation-Induced Corrosion Resistance For Molten Salt Equipment Materials Evaluated Utilizing Electrochemical And Spectroscopic Analysis, Peggy Milota

Theses and Dissertations

Advanced reactors and used nuclear fuel separation (i.e. pyroprocessing technology) utilize high temperature salt as a thermal storage medium as well as an ionic solution for electrochemical processes. The use of these aggressive molten chloride and fluoride mediums requires specific materials or additional system alterations to extend the lifetime and structural integrity of equipment due to corrosion. Some materials, in the presence of inherently impure salt, will corrode and form oxide films in a specific formation that decreases corrosion rate by electrochemically and physically preventing elemental movement to the material surface. This is referred to as a passivation layer. However, …

Applying X-Ray Fluorescence With Monte Carlo Methods For Analysis Of Surface Defects On Coated Zr4, James Tyler Cahill

Theses and Dissertations

Chromium-coated Zircaloy-4 cladding represents a novel solution for creating nuclear cladding that has passive safety features. This and related developments aimed at improving nuclear safety are broadly categorized as accident-tolerant fuel and cladding. However, implementing this material presents practical challenges such as the vulnerability that cladding has to surface damage such as fretting wear. This research aims to determine if the pre-existing technique of X-ray fluorescence analysis is applicable for detecting these defects on the surface of the cladding. This was done by developing Monte Carlo N-Particle Transport models of a handheld device, the XL-5, alongside experimental measurements using this …

Modeling Of Macroscopic Melt Splashing On Beryllium First Wall Panels Of Fusion Tokamaks Under Off-Normal Events, Cheng Zhang

Theses and Dissertations

Beryllium (Be) is a material which is used as a plasma facing component in tokamak reactors due to its unique properties of high thermal conductivity, low density, and high strength. However, under extreme conditions of high temperature and pressure, Be can melt on the surface of armor tiles and molten droplets can be ejected into the reactor chamber leading to disruption of fusion plasma. The variations of pressure, mass density, velocity, and temperature of Be vapor on the surface of melt layer as well as magnetic field strength and direction can influence the splashing of Be melt and their effects …

Modeling The Radiation Shielding Effectiveness Of Hafnium Diboride Reinforced Epoxy Composites Using Mcnp, Randolph Snook

Theses and Dissertations

This thesis uses MCNP simulations to evaluate the performance of a radiation shielding material consisting of Hafnium Diboride (HfB₂) powder in an epoxy matrix. Comparing the results to previously measured data against both gamma and neutron sources, suitability for other applications can be confirmed. The model simulated the epoxy material with different weight percentages of HfB₂ and thicknesses. It was compared to other shielding materials such as pure epoxy and 5% Borated High Density Polyethylene (HDPE-B). The HfB₂-epoxy composite was tested against a wide energy range gamma spectrum from a ¹⁵²Eu source, and neutrons …

Openfoam Computational Fluid Dynamic Modeling Of Plasma Expansion Into Vacuum, Robert B. Padgett

Theses and Dissertations

Nuclear weapons, and their effects, have been heavily studied with decades of data and information to create simulations and quantify the risks of their use. However, in the modern day, nuclear strikes pose new risks to precision electronics, power systems, and vital infrastructure. As such, simulations of nuclear weapon use are required due to nuclear weapon testing being prohibited. These simulations can incorporate testing practices, such as laboratory lasers, and computer simulation technology, such as OpenFOAM Computational Fluid Dynamics (CFD). The use of OpenFOAM CFD allows testing in an area that has never been tested with nuclear weapons before, specifically …

Fluid Flow And Thermal Performance Investigation Of Twisted Elliptical Tubes For Use In High Prandtl Number Systems, Connor F. Donlan

Theses and Dissertations

The development of clean energy systems is paramount to reducing mankind's climate impact. These clean energy systems include solar, wind, and nuclear power where nuclear power shows a reduced lifetime carbon dioxide footprint per kilowatt hour compared to other sources [102]. Advanced nuclear reactors, fusion energy systems, and concentrated solar power designers are looking at using molten salt heat transfer fluids and improved heat exchanger design to increase power production and efficiency of clean energy systems. The improving heat transfer within the main heat transfer components within advanced nuclear reactors will enable increased efficiencies and power production.

Heat transfer improvements …

Incorporation Of Poly(Tfema) In Perovskite Thin Films Using A Supercritical Fluid, Kasey Handy, Gary C. Tepper

Mechanical and Nuclear Engineering Publications

A new process is reported for the incorporation of a fluoropolymer into a solid perovskite film. Poly(trifluoroethyl methacrylate) [CH₂C(CH₃)(CO₂CH₂CF₃)]_n was delivered to methylammonium lead iodide (CH₃NH₃PbI₃) perovskite films by crystallizing the film in supercritical carbon dioxide/ethanol containing the dissolved fluoropolymer. The surface was characterized before and after fluoropolymer exposure using scanning electron microscopy, Raman spectroscopy, and contact angle measurements. The results indicate that the fluoropolymer was incorporated into the perovskite film during the supercritical fluid crystallization process. The incorporation of a hydrophobic fluoropolymer …

Radiation Shielding Effectiveness Of Hafnium Diboride (Hfb2) Reinforced Epoxy Composites For Enhanced Radiation Protection And Safety, Furkan Erdogan

Theses and Dissertations

This thesis investigates the radiation shielding effectiveness of hafnium diboride (HfB2) reinforced epoxy composites, with the aim of enhancing radiation protection and safety in various applications. The study focuses on the development and characterization of HfB2-epoxy composites with varying weight percentages of HfB2 nanoparticles, as well as on the evaluation of their shielding effectiveness against gamma rays and thermal neutrons. The radiation shielding performance of the composites is assessed using gamma-ray spectroscopy and neutron counting, and the neutron attenuation efficacy is compared with that of 5% borated high-dense polyethylene. The results indicate that the HfB2-epoxy composites exhibit promising radiation shielding …

Analysis Of Non-Conventional Radiological Terrorism, James N. Padgett

Theses and Dissertations

Nuclear terrorism has been a risk since the dawn of the first atomic bomb. Though state sponsored nuclear weapons development is of concern for countries, non-state sponsored terrorism with radiological material can be of even greater concern. This stems from the fact that the material is under less stringent or no safeguards and can readily change hands between different terrorist groups or innocent civilians may accidently come into contact with the material.

Within this paper an analysis of previous accidents using orphan radiological sources, malicious use of orphan radiological sources, and how these sources could be used by terrorists is …

Modeling Pa-233 Generation In Thorium-Fueled Reactors For Safeguards, Victoria Davis

Theses and Dissertations

Thorium has been researched for many decades as a possible alternative to uranium nuclear fuel. Thorium can be implemented in many different reactor designs including pressurized water reactors (PWRs), pressurized heavy water reactors (PHWRs), and molten salt reactors (MSRs). Its abundance in the earth, decreased long-lived transuranic waste, and claims that there are fewer proliferation concerns contribute to the attractiveness of using thorium as alternative nuclear fuel. However, possible proliferation pathways have been noted and must be investigated, particularly the potential diversion of ²³³Pa which can then decay to ²³³U – special fissionable material that should be under …

Molten Salt Technologies For Advanced Nuclear Fuel Cycles And Molten Salt Reactors, Dimitris Killinger

Theses and Dissertations

This dissertation provides five topics—an assessment of different monitoring and analytical techniques often cited in the literature for molten salt systems and designs for nuclear engineering applications. First, we explored commonly used materials for quasi-reference electrodes in molten chloride salts. Second, the limitations of the electrochemical analysis known as cyclic voltammetry due to the concentration of uranium(III) present were being investigated. Third, we provided an experimental assessment on the development of a spectroelectrochemical cell for interrogating various spectroelectrochemical techniques, namely chronoabsorptometry and chronofluorometry, and their limitations due to the presence of uranium(III) ions. Fourth, a study on the corrosion resistance …

Accident Tolerant Fuels Claddings And The Evolution Of Their Surface Characteristics Under Critical Heat Flux, Rajnikant V. Umretiya

Theses and Dissertations

Enhanced Accident Tolerant Fuels (ATFs) systems for light water reactors require higher temperature oxidation resistance in steam environments than the current UO₂ – zirconium fuel system. Investigating the ATF materials’ surface properties is needed as they have evidenced to affect the Critical Heat Flux (CHF), which is an important parameter of the thermal-hydraulic performance required to provide safety margins. In this dissertation, the surface properties of FeCrAl alloys (APMT and C26M), Zircaloy-2, Zircaloy-4, and Cr-coating on Zircaloy-4 substrates produced by Physical Vapor Deposition (PVD) and Cold Spray (CS) were investigated according to their chemistry, topography, and wettability. The static …

Equations Of State For Warm Dense Carbon From Quantum Espresso, Derek J. Schauss

Theses and Dissertations

Warm dense plasma is the matter that exists, roughly, in the range of 10,000 to 10,000,000 Kelvin and has solid-like densities, typically between 0.1 and 10 grams per centimeter. Warm dense fluids like hydrogen, helium, and carbon are believed to make up the interiors of many planets, white dwarfs, and other stars in our universe. The existence of warm dense matter (WDM) on Earth, however, is very rare, as it can only be created with high-energy sources like a nuclear explosion. In such an event, theoretical and computational models that accurately predict the response of certain materials are thus very …

Surface Characterization Of Accident Tolerant Fuel Claddings Candidates After Prolonged Exposure To Steam Oxidation, Connor F. Donlan

Theses and Dissertations

Accident Tolerant Fuel Claddings are designed to improve fuel performance and safety in abnormal reactor conditions. The development of these cladding materials has become a top priority for the nuclear community, with incidents such as the Three Mile Island accident and the Fukashima Dai-chi accident. The development of these claddings has resulted in 2 subsections: coating current claddings or replacing cladding materials with new materials. The claddings studied in this thesis are a Zircaloy-4 cladding coated with chromium through physical vapor deposition, Zircaloy-4, and a FeCrAl alloy, C26M. This thesis assessed the surface chemistry, roughness, and wettability after extended exposure …

Elastic Foundations As Heterogeneous Adventitial Boundary Condition For The Assessment Of Aortic Wall And Peri-Aortic Stiffness From Dense-Mri Data Using Inverse Fem Approach, Johane H. Bracamonte, John S. Wilson, Joao S. Soares

Graduate Research Posters

Background: The establishment of in vivo, patient-specific, and regionally resolved techniques to quantify aortic properties is key for improving risk assessment in clinical practice and scientific understanding of cardiovascular growth and remodeling. Many in vivo studies quantify vascular stiffness using Pulse Wave Velocity. This method provides an averaged measure of stiffness for the entire aorta, ignoring variations in wall stiffness and boundary conditions. Previous studies using Displacement Encoding with Stimulated Echoes Magnetic Resonance Imaging (DENSE-MRI) suggested that the infrarenal abdominal aorta (IAA) deforms heterogeneously throughout the cardiac cycle.

Method: Herein, we hypothesize that the aortic wall strain heterogeneity is driven …

Evaluating The Effectiveness Of Aerospace Materials, Vehicle Shape And Astronaut Position At Lowering The Whole Body Effective Dose Equivalent In Deep Space, Daniel K. Bond

Theses and Dissertations

As future crewed, deep space missions are being planned, it is important to assess how spacecraft design can be used to minimize radiation exposure. Collectively with shielding material, vehicle shape and astronaut position must be used to protect astronauts from the two primary sources of space radiation: Galactic Cosmic Rays (GCR) and Solar Particle Events (SPE). GCRs, which are composed of low intensity, highly energetic, and fully ionized stable and meta-stable isotopes, are considered a chronic source of radiation risk to the astronauts. SPEs, which originate from solar coronal mass ejections, are composed mostly of high intensity protons that can …

Perfusion Cell Seeding And Expansion In Dual Mechanical Stimulation Bioreactor For In Vitro Tissue Development, Sarah Saunders, Sam Coles, Joao S. Soares

Graduate Research Posters

BACKGROUND: Engineered tissues are an exciting potential source of small diameter vascular grafts due to limited supply and patency of available alternatives. Engineered tissue vascular grafts (ETVGs) will provide physiological function that resembles native arteries and maintain the required mechanical properties as they integrate with host tissue. Mechanical stimulation during incubation encourages proper cell alignment and increases extracellular matrix deposition. The enhanced organization of the engineered tissue leads to improved compliance over synthetic alternatives without sacrificing strength and may lead to better integration in vivo.

METHODS: We have developed a bioreactor that mechanically trains grafts during incubation. To test the …

Development Of Near-Real Time Material Detection And Analysis By Coupling Electrochemical & Optical Spectroscopy Methods For Molten Salt Systems, Hunter Andrews

Theses and Dissertations

For both pyroprocessing and molten salt reactors (MSRs), it is desirable from a process control and nuclear safeguards perspective to monitor the species in the molten salts for material accountancy. Many traditional monitoring techniques, even simple salt sample retrieval, are time exhaustive or rendered useless for these systems due to the high thermal loads, high radiation zones, and corrosive nature of molten salts. Therefore, the main motivation for this work is the need for an online monitoring system for a molten salt system that is robust enough to handle the extreme environment yet deliver quantifiable salt concentrations. The intent of …

Reducing Material Attractiveness Utilizing Pu-238 And U-232, Cody Lloyd

Theses and Dissertations

Decreasing the material attractiveness of uranium and plutonium materials is crucial to nuclear nonproliferation. The International Atomic Energy Agency (IAEA) implements safeguards across the world on a limited budget. Not only does decreasing material attractiveness reduce the possibility of proliferation, but also may lighten the financial burden on the IAEA if safeguards can be reduced. Two particular isotopes that have negative material attractiveness traits are ²³⁸Pu and ²³²U. Without isotopic separation technology, these isotopes cannot be removed from plutonium and uranium materials respectively. Both ²³⁸Pu and ²³²U produce large quantities of heat by alpha decay. High …

Dose Deposition And Electrostatic Charging Of Kapton Films Irradiated With Electrons, Youssef Abouhussien, Gennady Miloshevsky

Graduate Research Posters

Kapton films are widely utilized in harsh radiation environments where radiation resistant insulating materials are required. For space applications, Kapton polymers are used on satellites as substrates for solar arrays and outer layers of thermal systems. Kapton is also used in nuclear power plants as wire insulation. Kapton materials can be exposed in nuclear reactors to a reactive chemical environment in addition to severe radiation. It is of utmost important to understand how Kapton materials behave under high irradiation conditions and mitigate radiation damage effects. High-energy electrons can deposit ionizing dose and electric charge deeply inside Kapton materials. The charge …

Jxb Force Effects On Beryllium Melt Splashing In Fusion Devices, Cheng Zhang, Gennady Miloshevsky

Graduate Research Posters

Instability and disruption of high-temperature plasma in fusion devices may result in the edge-localized modes (ELMs) and lead to melting of plasma facing components (PFCs) causing their damage. Beryllium (Be) is used as a first wall for PFCs due to its low density, high strength, and high thermal conductivity. However, melting of Be on the surface of first wall is of a great concern as splashing of a molten Be layer will result in the plasma contamination and termination of fusion reaction. Therefore, it is important to understand the physics mechanisms characterizing the splashing of Be from a pool under …

Spatio-Temporal Evolution Of Warm Dense Plasmas: Molecular Dynamics Modeling, Harrison Wenzel, Gennady Miloshevsky

Graduate Research Posters

SPATIO-TEMPORAL EVOLUTION OF WARM DENSE PLASMAS: MOLECULAR

DYNAMICS MODELING Cole Wenzel and Gennady Miloshevsky

Virginia Commonwealth University, Department of Mechanical and Nuclear Engineering, 401

West Main St, Richmond, VA 23284-3015

The exo-atmospheric detonation of nuclear device would be of great impact on the material integrity of orbiting satellites. The spectral energy distribution of high intensity X-ray flux, ~10 28 -10 35 photons/(cm 2 ∙s), originating from a nuclear blast is described by the Planck's blackbody function with the temperature from 0.1 keV to 10 keV. Particular damage would occur to the multi-layered, solar cell panels of satellites. However, the X-ray …

Compositional Analysis Of Cerium And Cesium In Rapid Setting Cement As An Immobilization Agent For Nuclear Waste, Riyadh M. Motny

Theses and Dissertations

A feasibility of rapid setting cement (RSC) as an agent of immobilization for certain elements such as fission products or radioactive materials was explored. Cerium (Ce) and cesium (Cs) have been selected as a surrogate for U and/or Pu and fission products, respectively, in this study in three phases. In Phase I, RSC was evaluated for physical properties (e.g., porosity, density, pH values, etc.) using two groups methods—the cement powder at different concentrations of Ce (2 – 10 wt%) with deionized water (DIW) and artificial seawater (ASW). The results showed that the final setting time and compressive strength of RSC …

Electrochemical Separation Of Multivalent Species On A Liquid Bismuth Cathode In Licl-Kcl Eutectic For Used Nuclear Fuel Reprocessing, Michael Woods

Theses and Dissertations

The presence of group I/II fission products (Cs-137, Sr-90, and Ba-137) within molten salt nuclear processes degrades operational efficiencies by contributing to increased radiation levels in the case of material handling processes or to loss of criticality in the case of a reactor. While methods such as zone freezing and ion exchange have been proven for the separation of these fission products in LiCl-KCl salts, they require extra equipment and processing steps. Addition of a liquid metal electrode to molten salt media, such as the electrorefiner of a pyroprocessing scheme or the salt cleaning stage of a molten salt fast …

Au@Tio2 Nanocomposites Synthesized By X-Ray Radiolysis As Potential Radiosensitizers, Maria C. Molina Higgins

Theses and Dissertations

Radiosensitization is a novel targeted therapy strategy where chemical compounds are being explored to enhance the sensitivity of the tissue to the effects of ionizing radiation. Among the different radiosensitizers alternatives, nanomaterials have shown promising results by enhancing tumor injury through the production of free radicals and reactive oxygen species (ROS). In this work, Gold-supported titania (Au@TiO₂) nanocomposites were synthesized through an innovative strategy using X-ray irradiation, and their potential as radiosensitizers was investigated. Radiosensitization of Au@TiO₂ nanocomposites was assessed by monitoring the decomposition of Methylene Blue (MB) under X-ray irradiation in the presence of the nanomaterial. …

Innovative Fuel Design To Improve Proliferation Management, Taylor C. Britt

Theses and Dissertations

This research uses an existing innovative fuel design (IFD) that has intrinsic safety features and enhanced economics over the current uranium dioxide (UO₂) light water fuel design and evaluates promising methods to improve the waste management and proliferation resistance of the IFD by doping the fresh fuel with select actinides.The most robust approach for proliferation resistance is to denature these materials by adding a uranium or plutonium isotope that hampers the usability of the materials in weapons. The proposed modifications to the IFD use this approach through elevated fractions of ²³⁸Pu. ²³⁸Pu generates large quantities of …