Nuclear Engineering Commons^™

Impact Of The Synthesis Process On Structure Properties For Afci Fuel Candidates, Kenneth Czerwinski

Fuels Campaign (TRP)

The research objectives are:

• To explore a low-temperature fluoride route to synthesize actinide nitrides. • To characterize actinide nitrides structurally and thermally.

• To use high resolution TEM techniques to explore the microstructure of the radioactive samples.

Solution-Based Synthesis Of Nitride Fuels, Kenneth Czerwinski, Tyler A. Sullens

Fuels Campaign (TRP)

One of the original synthetic routes devised for the synthesis of U (III)N involved the entire reaction taking place in liquid ammonia. Several experimental reactions were conducted in an attempt to synthesize the UI₃(NH₃)_x and U(NH₂)₃(NH₃)_x precursors of U(III) N. Each attempt involved cleaning of the uranium metal to remove the oxide coating of the metal reagent with 3 washes of concentrated nitric acid, each followed by a rinse with liquid ammonia. Success of this cleaning procedure was varied, with a majority of cleaned metal oxidizing rapidly once …

Implementation Of Uncertainty Propagation In Triton/Keno, Charlotta Sanders, Denis Beller

Reactor Campaign (TRP)

Monte Carlo methods are beginning to be used for three dimensional fuel depletion analyses to compute various quantities of interest, including isotopic compositions of used nuclear fuel. The TRITON control module, available in the SCALE 5.1 code system, can perform three-dimensional (3-D) depletion calculations using either the KENO V.a or KENO-VI Monte Carlo transport codes, as well as the two-dimensional (2-D) NEWT discrete ordinates code. To overcome problems such as spatially nonuniform neutron flux and non-uniform statistical uncertainties in computed reaction rates and to improve the fidelity of calculations using Monte Carlo methods, uncertainty propagation is needed for depletion calculations.

Development Of Integrated Process Simulation System Model For Spent Fuel Treatment Facility Design, Yitung Chen, Sean Hsieh

Separations Campaign (TRP)

The major objectives will lead to the creation of a framework that combines all the strengths of AMUSE’s complicated calculations, well-established commercial system process package, and ISOPro’s flexible parameter optimization modules. Development of the process simulation code can be done using the solvent extraction process at Argonne National Laboratory in collaboration with the research team from the Mechanical Engineering Department at UNLV.

Research accomplishments:

• Completed final version of the ISOPro User Manual associated with summarized ISOPro source codes.

• Redesigned and completed use case and design class diagrams (DCD) of the ISOPro package using ArgoUML.

• Improved ISOPro system …

Nevada Risk Assessment/Management Program – Phase 2 (Nramp2): Quarterly Progress Report July 1, 2007 Through September 30, 2007, Klaus J. Stetzenbach

Nevada Risk Assessment/Management Program

Work conducted in this 4th quarter consisted of 3 major activities:

• Continue the receipt and reconciliation of Area 5 Radioactive Waste Management Site (RWMS) inventory data.

• Receive, review, install, calibrate, and run the Goldsim Area 5 Performance Assessment (PA) Model, and review the supporting parameters and assumptions in the 93-document reference set as a tool for regulatory compliance and closure assessment.

• Identify, review, and compare the interpretation of pertinent regulatory guidelines and orders by DOE sites in compliance for PA, Compliance Assessment (CA), and closure activities - as they may relate to the Nevada Test Site (NTS) …

High Temperature Heat Exchanger Project: Quarterly Progress Report July 1, 2007 Through September 30, 2007, Anthony Hechanova

Publications (NSTD)

• Ceramatec Sulfuric Acid Decomposer. The numerical model of a SiC ceramic coupon with two layers of microchannels was developed. Calculations of the factor of safety and probability of failure for the case of a straight channel were performed. Results for a pressure of 7.5 MPa were performed. The thermal and mechanical stress analyses of the Ceramatec HTHX and decomposer were completed.

• Bayonet Heat Exchanger. The thermal and mechanical stress analyses of the bayonet type HTHX and decomposer (Sandia design) were completed. Temperature profiles obtained from thermocouples measured from the Sandia experiments have been applied to the whole packed …

Implementation Of Uncertainty Propagation In Triton/Keno: To Support The Global Nuclear Energy Partnership, Charlotta Sanders, Denis Beller

Reactor Campaign (TRP)

Monte Carlo methods are beginning to be used for three-dimensional fuel depletion analyses to compute various quantities of interest, including isotopic compositions of used fuel.1 The TRITON control module, available in the SCALE 5.1 code system, can perform three dimensional (3-D) depletion calculations using either the KENO V.a or KENO-VI Monte Carlo transport codes, as well as the two-dimensional (2- D) NEWT discrete ordinates code. For typical reactor systems, the neutron flux is not spatially uniform. For Monte Carlo simulations, this results in non-uniform statistical uncertainties in the computed reaction rates. For spatial regions where the flux is low, e.g., …

Monaco/Mavric Evaluation For Facility Shielding And Dose Rate Analysis: To Support The Global Nuclear Energy Partnership, Charlotta Sanders, Denis Beller

Reactor Campaign (TRP)

Monte Carlo methods are used to compute fluxes or dose rates over large areas using mesh tallies. For problems that demand that the uncertainty in each mesh cell be less than some set maximum, computation time is controlled by the cell with the largest uncertainty. This issue becomes quite troublesome in deep-penetration problems, and advanced variance reduction techniques are required to obtain reasonable uncertainties over large areas.

In this project the MAVRIC sequence will be evaluated along with the Monte Carlo engine Monaco to investigate its effectiveness and usefulness in facility shielding and dose rate analyses. A previously MCNP-evaluated cask …

Gnep Quarterly Input – Unlv July 1 Through September 30, 2007, Harry Reid Center For Environmental Studies. Nuclear Science And Technology Division

Transmutation Research Program Reports (TRP)

Quarterly report highlighting research projects, activities and objectives of the Transmutation Research Program at the Nuclear Science & Technology Division, Harry Reid Research Center.

The University of Nevada, Las Vegas supports the Global Nuclear Energy Partnership (GNEP) through research and development of technologies for economic and environmentally sound refinement of spent nuclear fuel. The UNLV program has four components: infrastructure, international collaboration, student-based research, and management and program support.

Unlv Research Foundation High Temperature Heat Exchanger Development: 9/08, Anthony Hechanova

Publications (NSTD)

Barriers addressed:

Nuclear Hydrogen Initiative R&D Plan – Material performance and component design and testing for the intermediate heat exchanger and high-temperature thermochemical water splitting (H₂SO₄ decomposition and HI decomposition). Improved materials for High Temperature Electrolysis.

Nevada Risk Assessment/Management Program (Nramp) – Phase 2: Quarterly Progress Report April 1, 2007 Through June 30, 2007, Klaus J. Stetzenbach

Nevada Risk Assessment/Management Program

Work conducted this quarter consisted of continuing the detailed data and information acquisition; review of the received document contents, and interpretation of significance in light of previous DOE documents. Much of the effort was devoted to reconciling inconsistencies and contradictions in both the primary data bases and in and among the DOE published documents. These review and reconciliation efforts included regular telephone and e-mail correspondence, as well as in-person discussions with DOE NVO personnel at the April DOE Generator Conference in Las Vegas. Reconciliation efforts continued with frequent (daily) exchanges on the inventory data sets, and the engineering descriptions of …

High Temperature Heat Exchanger Project: Quarterly Progress Report April 1, 2007 Through June 30, 2007, Anthony Hechanova

Publications (NSTD)

• Ceramatec Sulfuric Acid Decomposer. Modeling with different reacting flow channel configurations (ribbed-surface channels, hexagonal channels, and diamond-shaped channels) was performed. The probability of failure for the one channel geometry with different reacting flow channel configurations was calculated to be zero in the three principal directions for all of the cases.

• Bayonet Heat Exchanger. The Matlab code for calculating the probability of failure using a two-dimensional axisymmetric model of the bayonet decomposer was developed. The probability of failure was calculated for the inner and outer SiC walls, and the intermediate quartz wall of the decomposer and found to be …

Afci Quarterly Input – Unlv April 1 Through June 30, 2007, Harry Reid Center For Environmental Studies. Nuclear Science And Technology Division

Transmutation Research Program Reports (TRP)

Quarterly report highlighting research projects, activities and objectives of the Transmutation Research Program at the Nuclear Science & Technology Division, Harry Reid Research Center.

The University of Nevada, Las Vegas supports the AFCI through research and development of technologies for economic and environmentally sound refinement of spent nuclear fuel. The UNLV program has four components: infrastructure, international collaboration, student-based research, and management and program support.

Nevada Risk Assessment/Management Program (Nramp) – Phase 2: Quarterly Progress Report January 1, 2007 Through March 31, 2007, Klaus J. Stetzenbach

Nevada Risk Assessment/Management Program

Work conducted in this second quarter consisted of continuing the detailed data and information acquisition; review of the received document contents, and interpretation of significance in light of previous DOE documents. This included telephone and in-person discussions with DOE NVO personnel at the March Waste Management Symposia in Tucson. As a result of these discussions and review of the supporting data and methodologies, a more specific listing of activities was developed, and DOE provided a confirmatory note to HRC in March.

Much of the review of the received information does indicate significant changes in data, methodologies, and baseline assumptions over …

High Temperature Heat Exchanger Project: Quarterly Progress Report January 1, 2007 Through March 31, 2007, Anthony Hechanova

Publications (NSTD)

• The variation of sulfur dioxide production (throughput) of the baseline design of the Ceramatec sulfuric acid decomposer with total mass flow rate of reacting flow has been calculated. According to the calculations, the sulfur dioxide production increases as the total mass flow rate of reacting flow increases regardless of the fact that decomposition percentage of sulfuric trioxide decreases. A parametric study of the baseline design of the Ceramatec sulfuric acid decomposer was performed.

• The thermal performance using various channel geometries for the decomposer was studied. The baseline design (straight channels) has 89.5% thermal efficiency while the thermal efficiency …

Afci Quarterly Input – Unlv January 1 Through March 31, 2007, Harry Reid Center For Environmental Studies. Nuclear Science And Technology Division

Transmutation Research Program Reports (TRP)

Quarterly report highlighting research projects, activities and objectives of the Transmutation Research Program at the Nuclear Science & Technology Division, Harry Reid Research Center.

The University of Nevada, Las Vegas supports the AFCI through research and development of technologies for economic and environmentally sound refinement of spent nuclear fuel. The UNLV program has four components: infrastructure, international collaboration, student-based research, and management and program support.

Condition Reporting And Resolution, J. M. Pesek, S. A. Wade

Publications (YM)

This procedure facilitates a safety conscious work environment by providing a mechanism for employees to make management aware of existing and potential conditions. This procedure establishes the responsibilities and process to be used to ensure that conditions related to, but not limited to, the environment, safety, health, waste isolation, operations, security, or quality of items and services associated with Office of Civilian Radioactive Waste Management (OCRWM) work activities are promptly identified, controlled, evaluated, and corrected as soon as practical. This procedure describes the process flow, controls, interfaces, and requirements for condition identification and resolution. This includes adverse conditions as well …

Nevada Risk Assessment/Management Program (Nramp) – Phase 2: Quarterly Progress Report, Oct. 1, 2006- Dec. 31, 2006, Klaus J. Stetzenbach

Nevada Risk Assessment/Management Program

Work conducted in this initial period consisted of work start-up (technical, administrative, contractual), and interviewing/site visits with DOE NVO staff (and support contractors) and HRC staff to quickly ascertain current technical activities and priorities as related to the scope of this task.

Since much of the technical work scope builds on previous technical work, it was considered critical to determine the changes (programmatic, technical, and regulatory) that have occurred over the past several years that directly relate to the scope. It was also equally important to determine the technical and programmatic priorities that have been established in the interim.

High Temperature Heat Exchanger Project: Quarterly Progress Report October 1, 2006 Through December 31, 2006, Anthony Hechanova

Publications (NSTD)

Modifications to the single-channel models of the Ceramatec heat exchanger and decomposer concept for hexagonal flow channels under two values of layer-overlapping (50% and 100%) and for diamond-shaped flow channels were completed.

The finite element calculations of the “Ball on Three Ball Test” for ceramic material for the purpose of selecting the appropriate specimen thickness for future experimental testing was performed for plate thicknesses ranging from 2 to 8 mm.

A finite element model of the “Ball on Three Ball Test” was also studied for discs having micro-channels.

Environmental Effects On Corrosion Properties Of Alloy 22, Mano Misra, L. G. Mcmillion

Publications (YM)

Subtask 1: Experimental Determination of Parameters for the General Corrosion Model Subtask 2: Corrosion Under Dust Deposits Containing Hygroscopic Salts Subtask 3: Heated Electrode Approach for the Study of Corrosion Under Aggressive Conditions Subtask 4: Effect of Hydrogen Permeation on the Stability of the Passive Film of Alloy 22

Phase Stability And Segregation In Alloy 22 Base Metal And Weldments, Jeffrey Lacombe, G. L. Mcmillon

Publications (YM)

Subtask 1: Microstructural Characterization of Phase Stability and Variability in Alloy 22. Develop an improved understanding of Alloy 22 and the extent to which compositional and microstructural variations are present in otherwise “nominal” as-procured material. Subtask 2: Electrochemical Methods to Detect Susceptibility of Alloy 22 to Localized Corrosion. Study the influence that compositional and microstructural variations have on the corrosion performance of Alloy 22.

Thermal Transient Flow Rate Sensor For High Temperature Liquid Metal Cooled Nuclear Reactor, Yingtao Jiang, Jian Ma, Rohit Reddy Saddi

Mechanical Engineering Faculty Research

In nuclear power plants and accelerator driven system (ADS) for nuclear waste treatment, it is important to monitor the coolant flow rate in the reactor core and pipe-line. In such a strong irradiation, high pressure and temperature environment, no accurate local flow measurement technique is readily available. Electromagnetic (EM) flow meter is popular in low temperature application as it is a non-intrusive technology. However, additional voltage will be produced due to temperature, flow, pressure, the chemical properties of the liquid metal and surface condition of the steel walls. In addition, the non-definite wetting behavior of liquid lead-bismuth to the electrically …

Decoupling And Disturbance Rejection Control For Target Circulation, Jian Ma, Joon S. Lee, Woosoon Yim

Reactor Campaign (TRP)

In 1998, the Institute of Physics and Power Engineering (IPPE) and Experimental and Development Organization “Gidropress” in Russia, began the design and construction of a prototype lead-bismuth eutectic (LBE) accelerator target, the Target Complex 1 (TC-1), under the International Science and Technology Center (ISTC) project #559 (“Pilot Flow Lead-Bismuth Target of 1 MW Power for Accelerator Driven Systems”) in support of the international efforts to develop accelerator-driven spallation systems for nuclear transmutation and other applications.

During the thermal and engineering test of the TC-1 in 2005 at UNLV, it was observed that the existing control algorithm led to a very …

Modeling And Design Algorithms For Electromagnetic Pumps, Daniel P. Cook

Reactor Campaign (TRP)

Electromagnetic (EM) induction pumps are used in a number of nuclear energy related applications, such as circulation of molten lead-bismuth eutectic alloys in neutron targets, and circulation of liquid sodium metal in Gen IV Sodium-cooled Fast Reactors (SFR). Because EM pumps have no moving parts which can fail, they are considerably more reliable than conventional mechanical pumps for molten metal usage, and thus EM pumps are favored over mechanical pumps even though their pumping efficiency is lower and their initial cost is higher when compared to mechanical pumps of similar flow rates.

The research objectives of this task are:

• A …

Thermal Transient Flow Rate Sensor For High Temperature Liquid Metal Cooled Nuclear Reactor, Yingtao Jiang

Reactor Campaign (TRP)

In nuclear power plants and accelerator driven system (ADS) for nuclear waste treatment, it is important to monitor the coolant flow rate in the reactor core and pipe-line. In such a strong irradiation, high pressure and temperature environment, no accurate local flow measurement technique is readily available. Electromagnetic (EM) flow meter is popular in low temperature application as it is a non-intrusive technology. However, additional voltage will be produced due to temperature, flow, pressure, the chemical properties of the liquid metal and surface condition of the steel walls. In addition, the non-definite wetting behavior of liquid lead-bismuth to the electrically …

University Of Nevada, Las Vegas Transmutation Research Program Annual Report Academic Year 2006-2007, Anthony Hechanova, Rebecca Arbour

Transmutation Research Program Reports (TRP)

It is my pleasure to present the UNLV Transmutation Research Program’s sixth annual report that highlights the academic year 2006-2007. Supporting this document are the many technical reports and theses that have been generated over the past five years.

In the sixth year of our program, we continued to see growth in the Radiochemistry Ph.D. program with a total of 13 students in the third year of the program (we anticipated eight in the program proposal). Since our inception, the program has sponsored to their conclusion 42 M.S. and 4 Ph.D. degrees. The program supported 39 graduate students, 17 undergraduates, …

Combined Radiation Detection Methods For Assay Of Higher Actinides In Separation Processes, Denis Beller, Warnick Kernan

Safeguards Campaign (TRP)

The ultimate objective of this project is to develop technology to detect and accurately measure quantities of higher actinides in processing systems without taking frequent samples. These systems include used fuel receipt, separations batches, and pipelines. A variety of measurements may be combined to calculate flow rates of actinide elements with a to-be-determined precision. Nuclear and decay characteristics of materials during processing will be acquired, conceptual designs of monitoring systems will be developed, radiation transport studies will be conducted to develop an understanding of operational regimes, and experiments will be performed to confirm performance. Radiation transport and scoping studies will …

Use Of Positron Annihilation Spectroscopy For Stress-Strain Measurements, Ajit K. Roy

Transmutation Sciences Materials (TRP)

During the past academic year, this project was focused on the characterization of residual stress in welded specimens consisting of austenitic and martensitic stainless steels using an activation technique based on the Positron Annihilation Spectroscopic (PAS) method. The extent of residual stress was expressed in terms of three line-shape parameters (S-, W- and T-). Further, efforts were made to characterize linear lattice defects such as dislocations in the vicinity of Fusion-Line (FL), Heat-Affected- Zone (HAZ), and the base material of the welded specimens using Transmission Electron Microscopy (TEM). The metallurgical microstructures at these three regions have also been evaluated by …

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry Morphology, And Surface Preparation, John Farley, Allen L. Johnson, Dale L. Perry

Transmutation Sciences Materials (TRP)

Advanced nuclear processes and facilities (e.g., transmutation of nuclear waste, fast reactors, and spallation neutron sources) impose special demands on materials, which must withstand high temperatures, high radiation fields, and chemical corrosion. Proposed schemes for transmuting nuclear waste require a nonmoderating coolant such as lead-bismuth eutectic (LBE). While LBE corrodes most steels, small amounts of oxygen in the LBE greatly reduces the corrosion rate, and could ideally re-grow a damaged oxide layer in-situ. The protective oxide layer would thus be self-healing. However, the fundamental understanding of the role of oxygen and passivating oxide layers is presently incomplete.

During the present …

Effect Of Silicon Content On The Corrosion Resistance And Radiation- Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems, Ajit K. Roy

Transmutation Sciences Materials (TRP)

This task is focused on the evaluation of the effects of silicon content on both the corrosion behavior and radiation-induced embrittlement of martensitic stainless steels having compositions similar to that of modified 9Cr-1Mo steel, also known as T91 grade steel. T91 grade steel was selected to be a candidate structural material to contain molten lead-bismuth eutectic (LBE), which can act both as a target material and a coolant during the spallation process. The operating temperature during this process may range from 420-550 °C. Thus, moderate tensile strength of the containment material (T91) is a major requirement.

The beneficial effects of …