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2022

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Articles 151 - 169 of 169

Full-Text Articles in Nanoscience and Nanotechnology

Type Iii And Iv Deformation Twins In Minerals And Metals, John P. Hirth, Greg Hirth, Jian Wang Jan 2022

Type Iii And Iv Deformation Twins In Minerals And Metals, John P. Hirth, Greg Hirth, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Type IV twins are defined and shown to exist in triclinic crystal systems, as well as in some monoclinic and trigonal systems. Here, we focus on Pericline twins in triclinic plagioclase as an example. Type IV twins are associated with the irrationality of one of the twinning elements that is rational for a type II twin. The formation of type IV twins is accomplished through the shear on a K2 plane produced by the motion of twinning disconnections on a K1 plane, followed by rotational partitioning. The same systems where type IV twins are present also have type III twins …


Emissivity Prediction Of Functionalized Surfaces Using Artificial Intelligence, Greg Acosta, Andrew Reicks, Miguel Moreno, Alireza Borjali, Craig Zuhlke, Mohammad Ghashami Jan 2022

Emissivity Prediction Of Functionalized Surfaces Using Artificial Intelligence, Greg Acosta, Andrew Reicks, Miguel Moreno, Alireza Borjali, Craig Zuhlke, Mohammad Ghashami

Department of Mechanical and Materials Engineering: Faculty Publications

Tuning surface emissivity has been of great interest in thermal radiation applications, such as thermophotovoltaics and passive radiative cooling. As a low-cost and scalable technique for manufacturing surfaces with desired emissivities, femtosecond laser surface processing (FLSP) has recently drawn enormous attention. Despite the versatility offered by FLSP, there is a knowledge gap in accurately predicting the outcome emissivity prior to fabrication. In this work, we demonstrate the immense advantage of employing artificial intelligence (AI) techniques to predict the emissivity of complex surfaces. For this aim, we used FLSP to fabricate 116 different aluminum samples. A comprehensive dataset was established by …


Construction Of A Peridynamic Model For Viscous Flow, Jiangming Zhao, Adam Larios, Florin Bobaru Ph.D. Jan 2022

Construction Of A Peridynamic Model For Viscous Flow, Jiangming Zhao, Adam Larios, Florin Bobaru Ph.D.

Department of Mechanical and Materials Engineering: Faculty Publications

We derive the Eulerian formulation for a peridynamic (PD) model of Newtonian viscous flow starting from fundamental principles: conservation of mass and momentum. This formulation is different from models for viscous flow that utilize the so-called “peridynamic differential operator” with the classical Navier- Stokes equations. We show that the classical continuity equation is a limiting case of the PD one, assuming certain smoothness conditions. The PD model for viscous flow is calibrated to the classical Navier-Stokes equations by enforcing linear consistency for the viscous stress term. Couette and Poiseuille flows, and incompressible fluid flow past a regular lattice of cylinders …


Ultrathin Coding Metasurface For Underwater Wave Focusing, Branching And Self-Bending Generation With One Single Actuator, Lixie Song, Zhong Chen, Mehrdad Negahban, Lei Liang, Zheng Li, Zheng Wu Jan 2022

Ultrathin Coding Metasurface For Underwater Wave Focusing, Branching And Self-Bending Generation With One Single Actuator, Lixie Song, Zhong Chen, Mehrdad Negahban, Lei Liang, Zheng Li, Zheng Wu

Department of Mechanical and Materials Engineering: Faculty Publications

A novel metasurface is proposed that aims to generate underwater acoustic waves with various functions by only one actuator. Each metasurface unit consists of an air cavity sandwiched on one side by a vibration plate and connecting rubber supports. By properly selecting the ratio of the plate to unit lengths, a phase shift of π can be attained to constitute a binary coding metasurface. Three demonstrations, including focusing, branching and self-bending waves, are chosen to validate the functionality of the design. The design is also shown to work over a wide frequency range through changing the ratio. In addition, the …


Machine Learning Assisted Metamaterial‑Based Reconfigurable Antenna For Low‑Cost Portable Electronic Devices, Shobhit K. Patel, Jaymit Surve, Vijay Katkar, Juveriya Parmar Jan 2022

Machine Learning Assisted Metamaterial‑Based Reconfigurable Antenna For Low‑Cost Portable Electronic Devices, Shobhit K. Patel, Jaymit Surve, Vijay Katkar, Juveriya Parmar

Department of Mechanical and Materials Engineering: Faculty Publications

Antenna design has evolved from bulkier to small portable designs but there is a need for smarter antenna design using machine learning algorithms that can meet today’s high growing demand for smart and fast devices. Here in this research, main focus is on developing smart antenna design using machine learning applicable in 5G mobile applications and portable Wi-Fi, Wi-MAX, and WLAN applications. Our design is based on the metamaterial concept where the patch is truncated and etched with a split ring resonator (SRR). The high gain requirement is met by adding metamaterial superstrates having thin wires (TW) and SRRs. The …


Symmetric Or Asymmetric Glide Resistance To Twinning Disconnection?, Mingyu Gong, Houyu Ma, Kunming Yang, Yue Liu, Jian-Feng Nie, Jian Wang Jan 2022

Symmetric Or Asymmetric Glide Resistance To Twinning Disconnection?, Mingyu Gong, Houyu Ma, Kunming Yang, Yue Liu, Jian-Feng Nie, Jian Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Successive gliding of twinning disconnections (TDs) creates three-dimensional twins in parent crystal and accommodates shear deformation. It is generally recognized that TD is subject to the same Peierls stress as it glides forward or backward because of its dislocation character and the twofold rotation symmetry of the twin plane. Based on atomistic simulations, we demonstrate that the glide of TDs may be subject to a symmetric or asymmetric resistance corresponding to step character, symmetric resistance for A/A type steps but asymmetric resistance for A/B type steps, where A and B represent crystallographic planes in twin and matrix. Furthermore, we experimentally …


Recent Advances In Biosensors For Detection Of Covid-19 And Other Viruses, Shobhit K. Patel, Jaymit Surve, Juveriya Parmar, Kawsar Ahmed, Francis M. Bui, Fahad Ahmed Al-Zahrani Jan 2022

Recent Advances In Biosensors For Detection Of Covid-19 And Other Viruses, Shobhit K. Patel, Jaymit Surve, Juveriya Parmar, Kawsar Ahmed, Francis M. Bui, Fahad Ahmed Al-Zahrani

Department of Mechanical and Materials Engineering: Faculty Publications

This century has introduced very deadly, dangerous, and infectious diseases to humankind such as the influenza virus, Ebola virus, Zika virus, and the most infectious SARS-CoV-2 commonly known as COVID-19 and have caused epidemics and pandemics across the globe. For some of these diseases, proper medications, and vaccinations are missing and the early detection of these viruses will be critical to saving the patients. And even the vaccines are available for COVID-19, the new variants of COVID-19 such as Delta, and Omicron are spreading at large. The available virus detection techniques take a long time, are costly, and complex and …


A Robot-Assisted Acoustofluidic End Effector, Jan Durrer, Prajwal Agrawal, Ali Ozgul, Stephen C.F. Neuhauss, Nitesh Nama, Daniel Ahmed Jan 2022

A Robot-Assisted Acoustofluidic End Effector, Jan Durrer, Prajwal Agrawal, Ali Ozgul, Stephen C.F. Neuhauss, Nitesh Nama, Daniel Ahmed

Department of Mechanical and Materials Engineering: Faculty Publications

Liquid manipulation is the foundation of most laboratory processes. For macroscale liquid handling, both do-it-yourself and commercial robotic systems are available; however, for microscale, reagents are expensive and sample preparation is difficult. Over the last decade, lab-on-a-chip (LOC) systems have come to serve for microscale liquid manipulation; however, lacking automation andmulti-functionality. Despite their potential synergies, each has grown separately and no suitable interface yet exists to link macro-level robotics with micro-level LOC or microfluidic devices. Here, we present a robot-assisted acoustofluidic end effector (RAEE) system, comprising a robotic arm and an acoustofluidic end effector, that combines robotics and microfluidic functionalities.We …


A New Spinel High-Entropy Oxides Nanoparticles (Feconimnzn)3o4 As Anode Materials For Lithium-Ion Batteries, Maha Nur Aida Jan 2022

A New Spinel High-Entropy Oxides Nanoparticles (Feconimnzn)3o4 As Anode Materials For Lithium-Ion Batteries, Maha Nur Aida

Chulalongkorn University Theses and Dissertations (Chula ETD)

A novel (FeCoNiMnZn)3O4 HEO as an anode in lithium-ion batteries (LIBs) was developed for the first time. High-entropy oxide (HEO) of (FeCoNiMnZn)3O4 was synthesized using a hydrothermal technique to control size and crystallinity. We also synthesized oxides of each element (Fe, Co, Ni, Mn, Zn) from HEO composition under similar condition for comparison. The samples were then analyzed using XRD, SEM, TEM, EDS elemental mapping, surface area analysis, ICP-OES, and XPS. Cyclic voltammetry, galvanostatic charge-discharge, electrochemical impedance spectroscopy, and associated coulombic efficiencies were also used to study the electrochemical performance of (FeCoNiMnZn)3O4. Three samples with different preparation conditions, HEO-3, HEO-6, …


An Archimedes' Screw For Light, Emanuele Galiffi, Paloma A. Huidobro, J. B. Pendry Jan 2022

An Archimedes' Screw For Light, Emanuele Galiffi, Paloma A. Huidobro, J. B. Pendry

Advanced Science Research Center

An Archimedes’ Screw captures water, feeding energy into it by lifting it to a higher level. We introduce the first instance of an optical Archimedes’ Screw, and demonstrate how this system is capable of capturing light, dragging it and amplifying it. We unveil new exact analytic solutions to Maxwell’s Equations for a wide family of chiral space-time media, and show their potential to achieve chirally selective amplification within widely tunable parity-time-broken phases. Our work, which may be readily implemented via pump-probe experiments with circularly polarized beams, opens a new direction in the physics of time-varying media by merging the rising …


Corrosion Protection Mechanisms Of Trivalent Chromium Based Passivations On Γ-Znni Coated Al6061-T6 Alloy, Kevin Foster Jan 2022

Corrosion Protection Mechanisms Of Trivalent Chromium Based Passivations On Γ-Znni Coated Al6061-T6 Alloy, Kevin Foster

Doctoral Dissertations

“The role of cobalt in trivalent chromium passivations (TCPs) to improve corrosion resistance of γ-ZnNi coated steel and aluminum is based on its effect on hexavalent chromium content in the passive layer. Investigations of both a cobalt-containing and cobalt-free TCP on SAE 1008 steel indicated that both passivations protect well for up to 1000 hours in neutral salt spray exposure (SSE). A repetition on Al 6061-T6 alloy indicated that TCP performed much better than cobalt-free TCP implicating the underlying substrate. Optical and electron micrographs indicated physical changes such as crack thickness, crack density, passivation porosity, and passivation thickness existed between …


High-Pressure Study Of Hybrid Organic-Inorganic Perovskites And Double Perovskites, Ardimas - Jan 2022

High-Pressure Study Of Hybrid Organic-Inorganic Perovskites And Double Perovskites, Ardimas -

Chulalongkorn University Theses and Dissertations (Chula ETD)

Hybrid and double perovskite have been of great attraction for optoelectronic devices. However, exploring a feasible method to enhance their optical abilities remains a considerable challenge. Here, the researcher reports the pressure-induced phase transition as an effective way to modify optoelectronic properties. The researcher successfully synthesized the hybrid perovskite (MAPbI3) and the double perovskite (Cs2TiBr6) by the inverse temperature crystallization (ITC) and solution method, respectively. the researcher studied the pressure dependence phase transition and photoluminescence (PL) by placing the sample into diamond anvil cells (DACs) through Raman spectroscopy. The first principles method was used to support the idea. The researcher …


Improving Quality Of Cvd Graphene Grown On The Copper Foil By Physical Polishing Electropolishing And Thermal Annealing Pretreatment Processes, Methawut Sirisom Jan 2022

Improving Quality Of Cvd Graphene Grown On The Copper Foil By Physical Polishing Electropolishing And Thermal Annealing Pretreatment Processes, Methawut Sirisom

Chulalongkorn University Theses and Dissertations (Chula ETD)

This study optimized the pretreatment processes (physical polishing (PP), electropolishing (EP), and thermal annealing) for high-quality graphene growth on thin copper (Cu) foils. PP using Brasso solvent was applied to smoothen the substrate surface, followed by EP with H3PO4 to reduce rolling lines and surface contamination. The EP process involved different H3PO4 concentrations (30-60%) and etching times (60-120 seconds). After thermal annealing at 860-940 ºC, graphene growth was performed using direct-liquid-injection chemical-vapor deposition with cyclohexane (C6H12) as the carbon precursor and nitrogen as the carrier gas. The optimized conditions involved PP and EP with 45% H3PO4 concentration and 90 seconds …


Biopolymer Nanocomposites For Food And Healthcare Applications, Tatiya Siripongpreda Jan 2022

Biopolymer Nanocomposites For Food And Healthcare Applications, Tatiya Siripongpreda

Chulalongkorn University Theses and Dissertations (Chula ETD)

This dissertation focuses on development of biopolymers by integrating nanomaterials to improve the properties of pristine polymers for enhancing the performances of chemical sensors and laser desorption/ionization mass spectroscopy (LDI-MS) applied for food quality control health monitoring and biomedical applications. The dissertation is divided into 4 parts: the first part, polylactic acid and cellulose were used for dual detection platform of biogenic amines for food spoilage indication. Highly porous PLA film is fabricated by adding nanosized calcium carbonate resulted in high sensing element entrapment. On another side of platform, pristine cellulose is modified with graphene oxide and exploited a substrate …


Branched Chain Amino Acid Strain State Monitoring With Raman Spectroscopy And Plasmonic Bowtie Nanoantenna Devices For Early Disease Detection, Caroline A. Campbell Jan 2022

Branched Chain Amino Acid Strain State Monitoring With Raman Spectroscopy And Plasmonic Bowtie Nanoantenna Devices For Early Disease Detection, Caroline A. Campbell

Theses and Dissertations

This work centers on the development and the down-selection of nano-manufactured devices to be used in conjunction with Raman spectroscopy for probing a branched chain amino acid. The nano-manufactured devices integrate plasmonic nanoantennas for the purpose of amplifying molecular fingerprints, which are otherwise difficult to detect, through Surface Enhanced Raman Spectroscopy (SERS). Plasmonic nanostructures can be utilized for a variety of biomedical and biochemical applications to detect the characteristic fingerprint provided by Raman Spectroscopy. The nano-manufactured devices create an electric field that amplifies minute perturbations and raises the signal above background noise. This may provide a deeper understanding of signal …


Computational Framework Of Magnetized Mgo–Ni/Water-Based Stagnation Nanoflow Past An Elastic Stretching Surface: Application In Solar Energy Coatings, M, M. Bhatti, O. A. Bég, Sara Abdelsalam Jan 2022

Computational Framework Of Magnetized Mgo–Ni/Water-Based Stagnation Nanoflow Past An Elastic Stretching Surface: Application In Solar Energy Coatings, M, M. Bhatti, O. A. Bég, Sara Abdelsalam

Basic Science Engineering

In this article, motivated by novel nanofluid solar energy coating systems, a mathematical model of hybrid magnesium oxide (MgO) and nickel (Ni) nanofluid magnetohydrodynamic (MHD) stagnation point flow impinging on a porous elastic stretching surface in a porous medium is developed. The hybrid nanofluid is electrically conducted, and a magnetic Reynolds number is sufficiently large enough to invoke an induced magnetic field. A Darcy model is adopted for the isotropic, homogenous porous medium. The boundary conditions account for the impacts of the velocity slip and thermal slip. Heat generation (source)/absorption (sink) and also viscous dissipation effects are included. The mathematical …


Molecular Modeling Of High-Performance Thermoset Polymer Matrix Composites For Aerospace Applications, Prathamesh P. Deshpande Jan 2022

Molecular Modeling Of High-Performance Thermoset Polymer Matrix Composites For Aerospace Applications, Prathamesh P. Deshpande

Dissertations, Master's Theses and Master's Reports

The global efforts from major space agencies to transport humans to Mars will require a novel lightweight and ultra-high strength material for the spacecraft structure. Three decades of research with the carbon nanotubes (CNTs) have proved that the material can be an ideal candidate for the composite reinforcement if certain shortcomings are overcome. Also, the rapid development of the polymer resin industry has introduced a wide range of high-performance resins that show high compatibility with the graphitic surface of the CNTs. This research explores the computational design of these materials and evaluates their efficacy as the next generation of aerospace …


Molecular Modeling Of High-Performance Polymers, Sagar Umesh Patil Jan 2022

Molecular Modeling Of High-Performance Polymers, Sagar Umesh Patil

Dissertations, Master's Theses and Master's Reports

High-performance polymers are extensively used in the aerospace and aeronautics industries due to their low density, high specific strength, and high specific stiffness. These properties along with better infiltration with reinforcements [carbon nanotubes (CNTs), glass, etc.] capability make them an excellent candidate to fabricate Polymer Matrix Composites (PMCs) tailored for specific applications. The applications range from products used daily to deep space exploration. These materials are subjected to varying temperatures and pressures during fabrication and in service. Therefore, the evolution of their intrinsic properties needs to be studied and their ability to sustain extreme environmental conditions in outer space needs …


Phase-Changing Nanodroplets As Nanotheranostic Platform For Combination Cancer Therapy, Catalina-Paula Spatarelu Jan 2022

Phase-Changing Nanodroplets As Nanotheranostic Platform For Combination Cancer Therapy, Catalina-Paula Spatarelu

Dartmouth College Ph.D Dissertations

Cancer is a cluster of diseases, and 1.8 million Americans are newly diagnosed each year. Treatment issues such as drug instability, the occurrence of severe side effects, as well as resistance make the need for solutions to improve conventional methods, like chemotherapy, apparent. Nano-sized drug-delivery platforms, particles loaded with therapeutic molecules that escape the immune system clearance and accumulate at the tumor site, were proposed as one of these solutions. Despite the expansion of the field, several aspects still need to be addressed: inconsistent delivery of the drugs, inability of measuring the effective dose being delivered to the tumor, lack …