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2021

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Articles 91 - 120 of 184

Full-Text Articles in Nanoscience and Nanotechnology

Electrochemical Surface-Enhanced Raman Spectroscopic Studies On Nickel Ultramicroelectrode, Li-Wen Wu, Wei Wang, Yi-Fan Huang Apr 2021

Electrochemical Surface-Enhanced Raman Spectroscopic Studies On Nickel Ultramicroelectrode, Li-Wen Wu, Wei Wang, Yi-Fan Huang

Journal of Electrochemistry

Nickel (Ni) electrodes are widely used in electrochemical researches. Understanding electrochemical processes on Ni electrodes through in-situ characterization of adsorbed species on their surfaces is helpful for rational optimization and application of Ni electrochemistry. Microelectrochemical surface-enhanced Raman spectroscopy (μEC-SERS) combines the mass transfer feature of ultramicroelectrode with high-sensitivity characterizations of molecular structures, which is a powerful method for studying Ni electrochemistry on polarization and non-equilibrium conditions. The key point of performing μEC-SERS is to make a SERS-active Ni ultramicroelectrode.
Here, we demonstrate a method of preparing a SERS-active Ni ultramicroelectrode through electrochemical deposition of several atomic layers of …

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Improving Accuracy Of Unmanned Aerial System Thermal Infrared Remote Sensing For Use In Energy Balance Models In Agriculture Applications, Mitchell S. Maguire, C.M.U. Neale, Wayne E. Woldt Apr 2021

Improving Accuracy Of Unmanned Aerial System Thermal Infrared Remote Sensing For Use In Energy Balance Models In Agriculture Applications, Mitchell S. Maguire, C.M.U. Neale, Wayne E. Woldt

Department of Mechanical and Materials Engineering: Faculty Publications

Unmanned aerial system (UAS) remote sensing has rapidly expanded in recent years, leading to the development of several multispectral and thermal infrared sensors suitable for UAS integration. Remotely sensed thermal infrared imagery has been used to detect crop water stress and manage irrigation by leveraging the increased thermal signatures of water stressed plants. Thermal infrared cameras suitable for UAS remote sensing are often uncooled microbolometers. This type of thermal camera is subject to inaccuracies not typically present in cooled thermal cameras. In addition, atmospheric interference also may present inaccuracies in measuring surface temperature. In this study, a UAS with integrated …

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Funtionalization Of Morphologically Different Nanoclays For Enhanced Mechanical Properties, Malachi Kent Apr 2021

Funtionalization Of Morphologically Different Nanoclays For Enhanced Mechanical Properties, Malachi Kent

Honors College Theses

Nanoclays are microscopic clays that are comprised of layered nanoparticle aluminosilicates that are naturally arranged in several morphologies. Halloysite nanotubes (HNT) are hollow, double-layered tubes, bentonite (BNT) clays are trapezoidal platelets, and nanosilica or silica dioxide (SiO2) are spherical. These nanoclays were chosen for sustainable purposes as they are naturally derived and for economical purposes because of their cheap commercial availability. In this study, the nanoclays are functionalized with an epoxy organosilane group through reflux conditions at 120 °C for 24 hours. The pristine and functionalized nanoclays were extensively characterized with infrared radiation (IR) spectroscopy, scanning electron microscope …

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Investigation Of Coo Ato For Solar Cells And Infrared Sheaths, Manopriya Devisetty Subramanyam Apr 2021

Investigation Of Coo Ato For Solar Cells And Infrared Sheaths, Manopriya Devisetty Subramanyam

USF Tampa Graduate Theses and Dissertations

Solar as an energy source is expected to grow fastest from now to 2050. Increasing the efficiency is usually achieved by increasing the short circuit current density (JSC) and/or the fill factor. Improving the efficiency of solar cells will be an ongoing effort.Structurally solar technologies can be classified into two types, wafer-based and thin-film-based. Wafer solar cells have been used in this study. The anti-reflective layer on top of solar cells has been fabricated by a process called electrospinning to tune the solar cells' top surface with the desired thickness and dimensions of the nanofibers. The nanofibers' dimensions, shape, and …

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Nanopore Guided Regional Assembly, Eleni Adam, Desh Ranjan, Harold Riethman Apr 2021

Nanopore Guided Regional Assembly, Eleni Adam, Desh Ranjan, Harold Riethman

College of Sciences Posters

The telomeres are the “caps” of the chromosomes and their vital role is to protect them. Possible telomere dysfunction caused by telomere rearrangements can be fatal for the cell and result in age-related diseases, including cancer. The telomeres and subtelomeres are regions that are hard to investigate. The current technology cannot provide their complete sequence, instead the DNA is given in multiple pieces. Current methods of assembling the pieces of these regions are not accurate enough due to the region’s high variability and complex repeated patterns. We propose a hybrid assembly method, the NPGREAT, which utilizes two of the latest …

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Six-Sigma Quality Management Of Additive Manufacturing, Hui Yang, Prahalad Rao, Timothy Simpson, Yan Lu, Paul Witherell, Abdalla R. Nassar, Edward Reutzel, Soundar Kumara Apr 2021

Six-Sigma Quality Management Of Additive Manufacturing, Hui Yang, Prahalad Rao, Timothy Simpson, Yan Lu, Paul Witherell, Abdalla R. Nassar, Edward Reutzel, Soundar Kumara

Department of Mechanical and Materials Engineering: Faculty Publications

Quality is a key determinant in deploying new processes, products, or services and influences the adoption of emerging manufacturing technologies. The advent of additive manufacturing (AM) as a manufacturing process has the potential to revolutionize a host of enterprise-related functions from production to the supply chain. The unprecedented level of design flexibility and expanded functionality offered by AM, coupled with greatly reduced lead times, can potentially pave the way for mass customization. However, widespread application of AM is currently hampered by technical challenges in process repeatability and quality management. The breakthrough effect of six sigma (6S) has been demonstrated in …

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Piezo-Tribo Dual Effect Hybrid Nanogenerators For Health Monitoring, Sk Md Ali Zaker Shawon, Andrew Xu Sun, Valeria Suarez Vega, Brishty Deb Chowdhury, Phong Tran, Zaida D. Carballo, Jim Aica Tolentino, Jianzhi Li, Muhammad Sufian Rafaqut, Mohammed Jasim Uddin Apr 2021

Piezo-Tribo Dual Effect Hybrid Nanogenerators For Health Monitoring, Sk Md Ali Zaker Shawon, Andrew Xu Sun, Valeria Suarez Vega, Brishty Deb Chowdhury, Phong Tran, Zaida D. Carballo, Jim Aica Tolentino, Jianzhi Li, Muhammad Sufian Rafaqut, Mohammed Jasim Uddin

Electrical and Computer Engineering Faculty Publications

Over the years, nanogenerators for health monitoring have become more and more attractive as they provide a cost-effective and continuous way to successfully measure vital signs, physiological status, and environmental changes in/around a person. Using such sensors can positively affect the way healthcare workers diagnose and prevent life-threatening conditions. Recently, the dual piezo-tribological effect of hybrid nanogenerators (HBNGs) have become a subject of investigation, as they can provide a substantial amount of data, which is significant for healthcare. However, real-life exploitation of these HBNGs in health monitoring is still marginal. This review covers piezo-tribo dual-effect HBNGs that are used as …

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Anisotropic Scaffolds For Peripheral Nerve And Spinal Cord Regeneration, Wen Xue, Wen Shi, Yunfan Kong, Mitchell Kuss, Bin Duan Apr 2021

Anisotropic Scaffolds For Peripheral Nerve And Spinal Cord Regeneration, Wen Xue, Wen Shi, Yunfan Kong, Mitchell Kuss, Bin Duan

Department of Mechanical and Materials Engineering: Faculty Publications

The treatment of long-gap (>10 mm) peripheral nerve injury (PNI) and spinal cord injury (SCI) remains a continuous challenge due to limited native tissue regeneration capabilities. The current clinical strategy of using autografts for PNI suffers from a source shortage, while the pharmacological treatment for SCI presents dissatisfactory results. Tissue engineering, as an alternative, is a promising approach for regenerating peripheral nerves and spinal cords. Through providing a beneficial environment, a scaffold is the primary element in tissue engineering. In particular, scaffolds with anisotropic structures resembling the native extracellular matrix (ECM) can effectively guide neural outgrowth and reconnection. In …

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Polymer Based Triboelectric Nanogenerator For Cost‐Effective Green Energy Generation And Implementation Of Surface‐Charge Engineering, Diana Lopez, Aminur Rashid Chowdhury, Abu Masa Abdullah, Muhtasim Ul Karim Sadaf, Isaac Martinez, Brishty Deb Chowdhury, Serena Danti, Christopher J. Ellison, Karen Lozano, Mohammed Jasim Uddin Mar 2021

Polymer Based Triboelectric Nanogenerator For Cost‐Effective Green Energy Generation And Implementation Of Surface‐Charge Engineering, Diana Lopez, Aminur Rashid Chowdhury, Abu Masa Abdullah, Muhtasim Ul Karim Sadaf, Isaac Martinez, Brishty Deb Chowdhury, Serena Danti, Christopher J. Ellison, Karen Lozano, Mohammed Jasim Uddin

School of Integrative Biological & Chemical Sciences (Formerly Dept. of Chemistry)

Performance of triboelectric nanogenerators for harvesting mechanical energy from the ambient environment has been limited by structural complexity, cost-effectiveness, and mechanical weakness of materials. Herein, a cost-effective vertical contact separation mode triboelectric nanogenerator using polyethylene (PE) and polycarbonate (PC) in a regular digital versatile disc is reported. This cost-effective nanogenerator with simplified structures is able to generate an open-circuit voltage of 215.3 V and short-circuit current of 80 μA. The effects of the distance of impact and the air gap between the triboelectric layers have also been tested from 3 to 9 cm, and 0.25 to 1 cm, respectively. It …

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Modulation Of Mechanical Stress Mitigates Anti-Dsg3 Antibody-Induced Dissociation Of Cell–Cell Adhesion, Xiaowei Jin, Jordan Rosenbohm, Eunju Kim, Amir Monemian Monemianesfahani, Kristina Seiffert-Sinha, James K. Wahl Iii, Jung Yul Lim, Animesh A. Sinha, Ruiguo Yang Mar 2021

Modulation Of Mechanical Stress Mitigates Anti-Dsg3 Antibody-Induced Dissociation Of Cell–Cell Adhesion, Xiaowei Jin, Jordan Rosenbohm, Eunju Kim, Amir Monemian Monemianesfahani, Kristina Seiffert-Sinha, James K. Wahl Iii, Jung Yul Lim, Animesh A. Sinha, Ruiguo Yang

Department of Mechanical and Materials Engineering: Faculty Publications

It is becoming increasingly clear that mechanical stress in adhesive junctions plays a significant role in dictating the fate of cell–cell attachment under physiological conditions. Targeted disruption of cell–cell junctions leads to multiple pathological conditions, among them the life-threatening autoimmune blistering disease pemphigus vulgaris (PV). The dissociation of cell–cell junctions by autoantibodies is the hallmark of PV, however, the detailed mechanisms that result in tissue destruction remain unclear. Thus far, research and therapy in PV have focused primarily on immune mechanisms upstream of autoantibody binding, while the biophysical aspects of the cell– cell dissociation process leading to acantholysis are less …

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Modulation Of Mechanical Stress Mitigates Anti-Dsg3 Antibody-Induced Dissociation Of Cell–Cell Adhesion, Xiaowei Jin, Jordan Rosenbohm, Eunju Kim, Amir Monemian Esfahani, Kristina Seiffert-Sinha, James K. Wahl Iii, Jung Yul Lim, Animesh A. Sinha, Ruiguo Yang Mar 2021

Modulation Of Mechanical Stress Mitigates Anti-Dsg3 Antibody-Induced Dissociation Of Cell–Cell Adhesion, Xiaowei Jin, Jordan Rosenbohm, Eunju Kim, Amir Monemian Esfahani, Kristina Seiffert-Sinha, James K. Wahl Iii, Jung Yul Lim, Animesh A. Sinha, Ruiguo Yang

Department of Mechanical and Materials Engineering: Faculty Publications

It is becoming increasingly clear that mechanical stress in adhesive junctions plays a significant role in dictating the fate of cell–cell attachment under physiological conditions. Targeted disruption of cell–cell junctions leads to multiple pathological conditions, among them the life-threatening autoimmune blistering disease pemphigus vulgaris (PV). The dissociation of cell–cell junctions by autoantibodies is the hallmark of PV, however, the detailed mechanisms that result in tissue destruction remain unclear. Thus far, research and therapy in PV have focused primarily on immune mechanisms upstream of autoantibody binding, while the biophysical aspects of the cell– cell dissociation process leading to acantholysis are less …

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Solid State Synthesis And Characterization Of Apatite Based Ceramic Waste Form For The Immobilization Of Radioactive Iodine, Md Imdadul Islam Mar 2021

Solid State Synthesis And Characterization Of Apatite Based Ceramic Waste Form For The Immobilization Of Radioactive Iodine, Md Imdadul Islam

LSU Doctoral Dissertations

The growing demand for nuclear power in the United States and worldwide is accountable for addressing the major concern of radioactive waste, involving the technical challenges of maintaining the nuclear fuel cycle and immobilizing high-level wastes for safe disposal in geological storage. The appropriate selection of waste forms for spent nuclear fuel such as fission products and radionuclides can be effective means for a feasible and sustainable nuclear fuel cycle. But highly volatile radionuclides such as iodine (129) are of specific concern due to its extraordinary long half-life (15.7 million years). Due to its poor solubility and high volatility at …

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Investigating The Novel Role Of Dextromethorphan In Mitigating Oxidative Stress Induced Changes In Retinal Pigment Epithelial Cells (Rpe), Zeinab A. Mohamed Mar 2021

Investigating The Novel Role Of Dextromethorphan In Mitigating Oxidative Stress Induced Changes In Retinal Pigment Epithelial Cells (Rpe), Zeinab A. Mohamed

USF Tampa Graduate Theses and Dissertations

Oxidative stress contributes to the degeneration of retinal pigment epithelial (RPE) cells and photoreceptors that lead to the dry form of age-related macular degeneration. Activation of N-Methyl-D-aspartate (NMDA) receptors contributes to the increase of free radicals that induce oxidative stress-induced changes. Our study investigates if Dextromethorphan, an NMDA receptor antagonist, reverses oxidative stress-induced changes in RPE. We used Paraquat and H2O2 as oxidative stress-inducing agents to induce oxidative damage in human ARPE-19 cells. To illustrate the change in cell viability and measure the apoptosis of ARPE-19 cells from oxidative damage, we performed MTT assay and Annexin V-DAPI flow cytometry analysis. …

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A Systematic Multiscale Investigation Of Nanoparticle-Assisted Co2 Enhanced Oil Recovery (Eor) Process For Shale Oil Reservoirs, Dayo A. Afekare Mar 2021

A Systematic Multiscale Investigation Of Nanoparticle-Assisted Co2 Enhanced Oil Recovery (Eor) Process For Shale Oil Reservoirs, Dayo A. Afekare

LSU Doctoral Dissertations

Shale oil reservoirs are prolific on the short term due to hydraulic fracturing and horizontal drilling but experience significant production decline, leading to poor ultimate recovery and leaving billions of barrels of oil buried in the ground. In this study, a systematic multi-scale investigation of an enhanced oil recovery (EOR) process using relatively inexpensive silicon dioxide nanoparticles and carbon dioxide for shale oil reservoirs was conducted. Using the Tuscaloosa Marine Shale (TMS) as a case study, aqueous dispersions of nanosilica in conjunction with CO2 were investigated at nano-to-core scales. At the nanoscale, atomic force microscope was used to investigate …

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Formulation And Characterization Of Raloxifene Nanostructured Lipid Carries For Permeability Enhancement Applications, Anju Sharma Mar 2021

Formulation And Characterization Of Raloxifene Nanostructured Lipid Carries For Permeability Enhancement Applications, Anju Sharma

USF Tampa Graduate Theses and Dissertations

Raloxifene (RLX), a BCS class-II drug is a selective estrogen receptor modulator (SERM)having estrogenic effect on bone and antiestrogenic effect on endometrium and breast respectively. Low solubility, high permeability, high metabolism and low bioavailability are the characteristics of raloxifene. It is used to prevent and treat in women and those on It is also used to reduce the risk of in those at high risk. Although 60% is absorbed orally, raloxifene shows extremely poor bioavailability (2%) owing to its low solubility and an extensive (>90%) intestinal/hepatic first-pass metabolism. Hence it becomes important to increase the solubility of raloxifene in …

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Wavefront-Selective Fano Resonant Metasurfaces, Adam C. Overvig, Andrea Alù Mar 2021

Wavefront-Selective Fano Resonant Metasurfaces, Adam C. Overvig, Andrea Alù

Advanced Science Research Center

Fano resonances are conventionally understood as sharp spectral features with selectivity in the momentum-frequency domain, implying that they can be excited only by plane waves with specific frequencies and incident angles. We demonstrate that Fano resonances can be made generally selective in the space-frequency domain. They can be tailored to resonate only when excited by a frequency, polarization, and wavefront of choice. This generalization reveals that Fano systems are characterized by eigenwaves that scatter to their time-reversed image upon reflection. Although in conventional Fano systems this trivially occurs for normally incident plane waves, we show that, in general, the selected …

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Nanocellulose Sheets From Oil Palm Empty Fruit Bunches Treated With Naoh Solution, Farah Fahma, Faiza Ayu Lestari, Ika Amalia Kartika, Nurmalisa Lisdayana, Evi Savitri Iriani Mar 2021

Nanocellulose Sheets From Oil Palm Empty Fruit Bunches Treated With Naoh Solution, Farah Fahma, Faiza Ayu Lestari, Ika Amalia Kartika, Nurmalisa Lisdayana, Evi Savitri Iriani

Karbala International Journal of Modern Science

The objective of this study is to produce nanocellulose sheets from oil palm empty fruit bunches (OPEFBs). Nanocellulose sheets from OPEFBs were prepared through the dewatering process using vacuum filtration. Subsequently, the produced sheets were treated with NaOH solution to improve the mechanical stability of their structure, causing them to be firm in water. The water absorption of nanocellulose sheet increased with increasing NaOH concentrations up to 20 wt%, increasing tensile strength, and Young’s modulus, but decreased when they were treated with 30 wt%. The diameter shrinkage of nanocellulose sheets was directly proportional to the NaOH concentration and soaking time. …

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Mechanical Characteristics Of Cement Paste In The Presence Of Carbon Nanotubes And Silica Oxide Nanoparticles: An Experimental Study, Moses Karakouzian, Visar Farhangi, Marzieh R. Farani, Alireza Joshaghani, Mehdi Zadehmohamad, Mohammad Ahmadzadeh Mar 2021

Mechanical Characteristics Of Cement Paste In The Presence Of Carbon Nanotubes And Silica Oxide Nanoparticles: An Experimental Study, Moses Karakouzian, Visar Farhangi, Marzieh R. Farani, Alireza Joshaghani, Mehdi Zadehmohamad, Mohammad Ahmadzadeh

Civil and Environmental Engineering and Construction Faculty Research

Considering the remarkable characteristics of nanomaterials, previous research studies investigated the effects of incorporating different types of these materials on improving the concrete properties. However, further studies are required to evaluate the complementary hybridization and synergistic influence of nanomaterials. In this research, the combined effect of adding nano silica particles (NS) and multi-walled carbon nanotubes (MWCNT) on enhancing both the compressive and flexural strengths of the cement paste was investigated. Moreover, the morphology of the interface between cement paste and aggregates was studied by scanning electron microscopy (SEM). The mixtures were prepared using three different portions of MWCNT and NS. …

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Plasmonic Photocatalysis For Gas-Phase Degradation Of Total Volatile Organic Compounds: Theory, Experimentation, And Catalyst Stability, Amaury P. Betancourt Iii Mar 2021

Plasmonic Photocatalysis For Gas-Phase Degradation Of Total Volatile Organic Compounds: Theory, Experimentation, And Catalyst Stability, Amaury P. Betancourt Iii

USF Tampa Graduate Theses and Dissertations

Plasmonic nanomaterials have become a strong contender for improving the efficiency of photocatalytic degradation of air pollutants. This study demonstrates an easy and scalable fabrication method, employing electron beam evaporation and rapid thermal annealing, for producing plasmonic photocatalysts. Samples were made by either coating silver on, or layering silica-protected (i.e., silica-coated) or unprotected (i.e., uncoated) silver beneath, the photocatalyst (either zinc oxide or titanium dioxide). Stability and catalytic performance for gas-phase toluene degradation was assessed by monitoring total volatile organic compound (TVOC) concentration versus ultraviolet-A (UV-A) illumination time in a recirculating batch reactor (plate-type flow-through). Samples were characterized using a …

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Common Pool Resource Management: Assessing Water Resources Planning For Hydrologically Connected Surface And Groundwater Systems, Francisco Munoz-Arriola, Tarik Abdel-Monem, A. Amaranto Mar 2021

Common Pool Resource Management: Assessing Water Resources Planning For Hydrologically Connected Surface And Groundwater Systems, Francisco Munoz-Arriola, Tarik Abdel-Monem, A. Amaranto

Department of Mechanical and Materials Engineering: Faculty Publications

Common pool resource (CPR) management has the potential to overcome the collective action dilemma, defined as the tendency for individual users to exploit natural resources and contribute to a tragedy of the commons. Design principles associated with effective CPR management help to ensure that arrangements work to the mutual benefit of water users. This study contributes to current research on CPR management by examining the process of implementing integrated management planning through the lens of CPR design principles. Integrated management plans facilitate the management of a complex common pool resource, ground and surface water resources having a hydrological connection. Water …

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Part-Scale Thermal Simulation Of Laser Powder Bed Fusion Using Graph Theory: Effect Of Thermal History On Porosity, Microstructure Evolution, And Recoater Crash, Reza Yavari, Ziyad Smoqi, Alex Riensche, Ben Bevans, Humaun Kobir, Heimdall Mendoza, Hyeyun Song, Kevin Cole, Prahalada Rao Mar 2021

Part-Scale Thermal Simulation Of Laser Powder Bed Fusion Using Graph Theory: Effect Of Thermal History On Porosity, Microstructure Evolution, And Recoater Crash, Reza Yavari, Ziyad Smoqi, Alex Riensche, Ben Bevans, Humaun Kobir, Heimdall Mendoza, Hyeyun Song, Kevin Cole, Prahalada Rao

Department of Mechanical and Materials Engineering: Faculty Publications

Flaw formation in laser powder bed fusion (LPBF) is influenced by the spatiotemporal temperature distribution – thermal history – of the part during the process. Therefore, to prevent flaw formation there is a need for fast and accurate models that can predict the thermal history as a function of the part shape and processing parameters. In previous work, a thermal modeling approach based on graph theory was used to predict the thermal history in LPBF parts in less-than 20% of the time required by finite element-based models with error within 10% of experimental measurements. The present work transitions toward the …

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Error Reduction For The Determination Of Transverse Moduli Of Single-Strand Carbon Fibers Via Atomic Force Microscopy, Joshua D. Frey Mar 2021

Error Reduction For The Determination Of Transverse Moduli Of Single-Strand Carbon Fibers Via Atomic Force Microscopy, Joshua D. Frey

Theses and Dissertations

The transverse modulus of single strand carbon fibers is measured using PeakForce Atomic Force Microscopy - Quantitative Nanomechanical Measurement to less than 5 percent error for 11 types of carbon fiber with longitudinal moduli between 924-231 GPA, including export-controlled fibers. Statistical methods are employed to improve the quality of data to exclude outliers within an measurement and within the sample set. A positive linear correlation between the longitudinal and transverse modulus with an R2=0.76 is found. Pitch-based fibers exhibit lower measurement error than PAN-based fibers, while PAN fibers exhibited no apparent modulus correlation when the Pitch fibers are …

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Theoretical Study On Electrical Properties Of Molecular Junctions Of Viologen Derivatives, Zhuan-Yun Cai, Jia Liu, Si-Yuan Guan, De-Yin Wu, Zhong-Qun Tian Feb 2021

Theoretical Study On Electrical Properties Of Molecular Junctions Of Viologen Derivatives, Zhuan-Yun Cai, Jia Liu, Si-Yuan Guan, De-Yin Wu, Zhong-Qun Tian

Journal of Electrochemistry

In this paper, the electrical properties of molecular junctions formed N,N′-bis(4-thioalkyl)-4,4′-bipyridinium (viologen) moiety between two gold (Au) electrodes have been investigated by combining density functional theory and non-equilibrium Green’s functional approach. To modulate the viologen molecule to be a cation with one and two positive charges (V+ and V2+), we introduce one and two trifluoroacetic acid ions (TFA-) around the molecule, respectively. The valence states of V+ and V2+ are confirmed by checking Mulliken and NBO charges. Then the relationship between molecular conductance and electronic structures of the neutral state …

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Preparation Of Pdcoir Tetrahedron Nanocatalysts And Its Performance Toward Ethanol Oxidation Reaction, Zhi-Yuan Yu, Rui Huang, Jie Liu, Guang Li, Qian-Tong Song, Shi-Gang Sun Feb 2021

Preparation Of Pdcoir Tetrahedron Nanocatalysts And Its Performance Toward Ethanol Oxidation Reaction, Zhi-Yuan Yu, Rui Huang, Jie Liu, Guang Li, Qian-Tong Song, Shi-Gang Sun

Journal of Electrochemistry

As a new energy conversion device, direct ethanol fuel cells (DEFCs) are widely concerned because of their remarkable advantages such as high theoretical energy density and wide fuel sources. However, the rapid development of DEFCs has been severely impeded due to the sluggish kinetic process and toxic intermediates especially in their anodic reactions. Palladium (Pd)-based materials are considered to be excellent anode catalysts for DEFCs, especially under alkaline conditions. And further improving their performance is an important direction to promote the development of DEFCs. Surface structure and composition are the key factors affecting the performance of catalysts which can be …

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Combined Applications Of Photocurrent Spectroscopy, Photoluminescence Spectroscopy And Uv-Vis Spectroscopy For Nano-Semiconductor Based Photoelectric Devices, Si-Da Bian, Jian-Zhang Zhou, Zhong-Hua Lin Feb 2021

Combined Applications Of Photocurrent Spectroscopy, Photoluminescence Spectroscopy And Uv-Vis Spectroscopy For Nano-Semiconductor Based Photoelectric Devices, Si-Da Bian, Jian-Zhang Zhou, Zhong-Hua Lin

Journal of Electrochemistry

The electronic structures and properties of nano-semiconductors are quite different from those of bulk semiconductors due to the nano-size effect (such as quantum size effect). Moreover, when the nano-semiconductor materials are deposited onto the substrate to construct a device, their electronic properties are also affected by the substrate or other components, which may lead to different performances of nano-semiconductors based photoelectric devices, and consequently, different corresponding characterization methods are needed. The combination of photocurrent spectroscopy, photoluminescence spectroscopy with UV-Vis absorption spectroscopy can provide a more comprehensive characterization for the electronic properties and photoelectrochemical performances of nano-semiconductors in photoelectric devices. Our …

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Study On Li3Bo3 Interface Modification Of Garnet Solid Electrolyte, Gui-Wei Chen, Zheng-Liang Gong Feb 2021

Study On Li3Bo3 Interface Modification Of Garnet Solid Electrolyte, Gui-Wei Chen, Zheng-Liang Gong

Journal of Electrochemistry

Garnet solid-state electrolytes have become the research hotspot due to their high ionic conductivity, wide electrochemical stability window and good air stability. However, there are still a series of problems to be solved. The poor contact between the lithium (Li) metal and garnet pellet make it difficult to build stable ion diffusion channels, resulting in large interfacial resistance. The continuous growth of lithium dendrites can penetrate the electrolyte pellet and cause a short circuit in the solid-state battery. Herein, a novel strategy is proposed to improve the wettability of LLZTO electrolyte with Li metal, via interfacial modification of LLZTO electrolyte …

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Chilling And Heat Accumulation Of Fruit And Nut Trees And Flower Bud Vulnerability To Early Spring Low Temperatures In New Mexico: Meteorological Approach, Koffi Djaman, Komlan Koudahe, Murali Darapuneni, Suat Irkmak Feb 2021

Chilling And Heat Accumulation Of Fruit And Nut Trees And Flower Bud Vulnerability To Early Spring Low Temperatures In New Mexico: Meteorological Approach, Koffi Djaman, Komlan Koudahe, Murali Darapuneni, Suat Irkmak

Department of Mechanical and Materials Engineering: Faculty Publications

Fruit and nut trees production is an important activity across the southwest United States and this production is greatly impacted by the local climate. Temperature is the main environmental factor influencing the growth and the productivity of the fruit and nut trees as it affects the trees’ physiology and the vulnerability of flower bud, flowers, and young fruit and nut to the low temperatures or spring frost. The objective of the present study is to estimate the chilling and heat accumulation of fruit and nut trees across New Mexico. Three study sites as Fabian Garcia, Los Lunas, and Farmington were …

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Exploring The Silent Aspect Of Carbon Nanopores, Teresa J. Bandosz Feb 2021

Exploring The Silent Aspect Of Carbon Nanopores, Teresa J. Bandosz

Publications and Research

Recently, owing to the discovery of graphene, porous carbons experienced a revitalization in their explorations. However, nowadays, the focus is more on search for suitable energy advancing catalysts sensing, energy storage or thermal/light absorbing features than on separations. In many of these processes, adsorption, although not emphasized sufficiently, can be a significant step. It can just provide a surface accumulation of molecules used in other application-driving chemical or physical phenomena or can be even an additional mechanism adding to the efficiency of the overall performance. However, that aspect of confined molecules in pores and their involvement in the overall performance …

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Characterization Of The Strain-Rate–Dependent Mechanical Response Of Single Cell–Cell Junctions, Amir Monemian Esfahani, Jordan Rosenbohm, Bahareh Tajvidi Safa, Nickolay V. Lavrik, Grayson Minnick, Quan Zhou, Fang Kong, Xiaowei Jin, Eunju Kim, Ying Liu, Yongfeng Lu, Jung Yul Lim, James K. Wahl Iii, Ming Dao, Changjin Huang, Ruiguo Yang Feb 2021

Characterization Of The Strain-Rate–Dependent Mechanical Response Of Single Cell–Cell Junctions, Amir Monemian Esfahani, Jordan Rosenbohm, Bahareh Tajvidi Safa, Nickolay V. Lavrik, Grayson Minnick, Quan Zhou, Fang Kong, Xiaowei Jin, Eunju Kim, Ying Liu, Yongfeng Lu, Jung Yul Lim, James K. Wahl Iii, Ming Dao, Changjin Huang, Ruiguo Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Cell–cell adhesions are often subjected to mechanical strains of different rates and magnitudes in normal tissue function. However, the rate-dependent mechanical behavior of individual cell– cell adhesions has not been fully characterized due to the lack of proper experimental techniques and therefore remains elusive. This is particularly true under large strain conditions, which may potentially lead to cell–cell adhesion dissociation and ultimately tissue fracture. In this study, we designed and fabricated a single-cell adhesion micro tensile tester (SCAμTT) using twophoton polymerization and performed displacement-controlled tensile tests of individual pairs of adherent epithelial cells with a mature cell–cell adhesion. Straining the …

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Irrigation Management In Potato (Solanum Tuberosum L.) Production: A Review, Koffi Djaman, Suat Irkmak, Komlan Koudahe, Samuel Allen Feb 2021

Irrigation Management In Potato (Solanum Tuberosum L.) Production: A Review, Koffi Djaman, Suat Irkmak, Komlan Koudahe, Samuel Allen

Department of Mechanical and Materials Engineering: Faculty Publications

Limited water resources coupled with the increase of the human population calls for more efficient use of water in irrigated agriculture. Potato (Solanum tuberosum L.) is one of the most widely grown crops worldwide and is very sensitive to water stress due to its shallow rooting system. With the dilemma of potato sensitivity to drought and limited available water resources restricting crop production, researchers and crop growers have been investigating different approaches for optimizing potato yield and improving crop water use efficiency under different irrigation methods. While potato response to water is affected by other management practices such as fertilizer …

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