Nanoscience and Nanotechnology Commons^™

Atomic Force Microscope Imaging Of Dna And Multi Walled Carbon Nanotubes, Jacob Hohnbaum

Mechanical Engineering Undergraduate Honors Theses

The Micro and Nano System Laboratory at the University of Arkansas currently is equipped with an Atomic Force Microscope (AFM). This device can be used to measure objects with resolution on the nanometer scale, but there are a number of technical difficulties in performing scans of carbon nanotubes and DNA. The goal of this research is to successfully perform scans on both carbon nanotubes and DNA and to also establish laboratory processing protocols to re-perform such scans in the future. Previous works performed by other researchers in the laboratory provided basic protocols with which to begin the present research. These …

Improved Hole-Injection Contact For Top-Emitting Polymeric Diodes, Juo-Hao Li, Jinsong Huang, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

In this letter, an efficient hole-injection contact was achieved for the top-emitting polymeric light-emitting diodes (PLEDs). The anode has a structure of metal/molybdenum oxide/ poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS). It has been found that hole injection was significantly improved by inserting a thin layer of MoO₃ between aluminum and PEDOT:PSS. An ultraviolet photoelectron spectroscopy (UPS) was used to investigate the change of work function, and photovoltaic measurement confirmed that the improved hole injection is due to the reduction of barrier height, resulted from the addition of transition metal oxide. PEDOT:PSS layer was found necessary in anode structure to further enhance the …

Low Voltage And Fast Speed All-Polymeric Optocouplers, Yan Yao, Hsiang-Yu Chen, Jinsong Huang, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

An all-polymeric optocoupler has been demonstrated with a polymer light-emitting diode (PLED) as the light source (input unit) and a polymer/fullerene photodiode (PD) as the detector (output unit). The electroluminescence (EL) peak of the PLED is 560 nm, and the entire EL spectrum is within the response range of the PD. The optocoupler can work at low driving voltages, 5 V on the PLED and 0 V on the PD. The output photocurrent increases linearly with input current, and the current density transfer ratio reaches 1.5%. The frequency response of the optocoupler is at 500 kHz. With comparable performance to …

Origin Of Photomultiplication In C60 Based Devices, Jinsong Huang, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

In this manuscript, the origin of the photomultiplication effect was studied in C₆₀ based devices by evaluating the wavelength dependent external and internal quantum efficiencies under various biases. The effect of materials with disordered structures on the photomultiplication effect was determined by intentionally integrating both ordered and disordered material structures into one organic solar cell device with a configuration of indium tin oxide/poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS)/pentacene/C₆₀ fullerene/bathocuproine (BCP)/Al. Our results show that both the disordered structure of C₆₀ and the charge trapping effect at the C₆₀ /PEDOT:PSS interface contribute to the photomultiplication effect. By studying the C60-only …

Deck-Mounted Steel Post Barrier System, John D. Reid, Ronald K. Faller, Jason A. Hascall

Department of Mechanical and Materials Engineering: Faculty Publications

An existing mountable safety barrier system, previously crash tested successfully on a wood bridge deck, was evaluated for use on a fiber reinforced plastic (FRP) bridge deck. In an attempt to avoid expensive full-scale crash testing, components of the existing system were evaluated using worst case conditions on two dynamic bogie crash tests and a series of computer simulations using nonlinear finite-element analysis. Simulation results closely approximated the physical results, with both displaying similar deformation, damage, and force levels. Both testing and simulation demonstrated that the barrier should function sufficiently if used on the FRP deck system. Further, the development …

Regional Mechanical Properties And Stress Analysis Of The Human Anterior Lens Capsule, Ryan M. Pedrigi, G. David, J. Dziezyc, J. D. Humphrey

Department of Mechanical and Materials Engineering: Faculty Publications

The lens capsule of the eye functions, in part, as a deformable support through which the ciliary body applies tractions that can alter lens curvature and corresponding refractive power during the process of accommodation. Although it has long been recognized that characterization of the mechanical properties of the lens capsule is fundamental to understanding this physiologic process as well as clinical interventions, prior data have been limited by one-dimensional testing of excised specimens despite the existence of multiaxial loading in vivo. In this paper, we employ a novel experimental approach to study in situ the regional, multiaxial mechanical behavior of …

A Scientific Foundation Of Collaborative Engineering, S. C.-Y. Lu, W. Elmaraghy, G. Schuh, R. Wilhelm

Department of Mechanical and Materials Engineering: Faculty Publications

Collaborative engineering is the practical application of collaboration sciences to the engineering domain. In today’s highly connected technology-driven economy, the production industry must rely on the best practices of collaborative engineering to stay competitive when designing, manufacturing, and operating complex machines, processes, and systems on a global scale. Despite its importance, collaborative engineering is currently more of a practiced art than a scientific discipline. A better understanding of how engineers should collaborate with all stakeholders to accomplish complex tasks that fulfill our increasing social responsibilities is a grand challenge. However, because we currently lack well-defined sciences of human collaboration, we …

Modeling Redox-Based Magnetohydrodynamics In Three-Dimensional Microfluidic Channels, Hussameddine S. Kabbani, Aihua Wang, Xiaobing Luo, Shizhi Qian

Mechanical Engineering Faculty Research

RedOx-based magnetohydrodynamic MHD[1] flows in three-dimensional microfluidic channels are investigated theoretically with a coupled mathematical model consisting of the Nernst-Planck equations for the concentrations of ionic species, the local electroneutrality condition for the electric potential, and the Navier-Stokes equations for the flow field. A potential difference is externally applied across two planar electrodes positioned along the opposing walls of a microchannel that is filled with a dilute RedOx electrolyte solution, and a Faradaic current transmitted through the solution results. The entire device is positioned under a magnetic field which can be provided by either a permanent magnet or an electromagnet. …

Single-Sided Crash Cushion System, John D. Reid, John R. Rohde, Dean L. Sicking

Department of Mechanical and Materials Engineering: Faculty Publications

A single-sided crash attenuation cushion system having an impact head and three stage energy absorption mechanism. The energy absorbing mechanism has a mandrel for deforming thin-walled tubes in a controlled collapse to absorb impact forces from a colliding vehicle. The third stage of the absorption mechanism includes an additional deformable compressible tube between the fixed-object hazard and the thin walled tubes.

End Splice Assembly For Box-Beam Guardrail And Terminal Systemis, John D. Reid, John R. Rohde, Dean L. Sicking, King K. Mak

Department of Mechanical and Materials Engineering: Faculty Publications

An end splice assembly for a box-beam guardrail and terminal system having a first stage rail element and a second stage rail element. The assembly has two major connecting components. Upper and lower bent plate channels and upper and lower channel splice plates. The channels and plates have side walls which extend laterally to one another when the two rail elements are mated. The channels and plates are fastened together to provide moment strength to the splice within the system.

Preparation Of High-Strength Nanometer Scale Twinned Coating And Foil, Xinghang Zhang, Amit Misra, Michael Nastasi, Richard G. Hoagland

Department of Mechanical and Materials Engineering: Faculty Publications

Very high strength single phase stainless steel coating has been prepared by magnetron sputtering onto a substrate. The coating has a unique microstructure of nanometer spaced twins that are parallel to each other and to the substrate surface. For cases where the coating and substrate do not bind strongly, the coating can be peeled off to provide foil.

Modeling And Representation Of Geometric Tolerances Information In Integrated Measurement Processes, Xiaoping Zhao, T. M. Kethara Pasupathy, Robert G. Wilhelm

Department of Mechanical and Materials Engineering: Faculty Publications

Modeling and representation of geometric tolerances information across an enterprise is viable due to the advances in Internet technologies and increasing integration requirements from industry. In Integrated Measurement Processes (IMP), geometric tolerances data model must support different models from several well-defined standards: including ASME Y14.5M-1994, STEP, DMIS, and others. In this paper, we propose a layered conformance level geometric tolerances representation model. This model uses the widely applied ASME Y14.5M-1994 as its foundation layer by abstracting most information from this standard. The additional geometric tolerances information defined by DMIS and STEP is incorporated into this model to form corresponding conformance …

Flexible Tools For Specifying Design Variation, Trichy Pasupathy, Xiaoping Zhao, Robert Wilhelm

Department of Mechanical and Materials Engineering: Faculty Publications

This paper describes flexible tools for specifying design variations that are based on nonuniform profile tolerance definitions. These tools specify bounds of design performance that can be used for negotiation among engineers in a collaborative design process. These specification methods allow for the capture of many different design functions that are not easily described with current tool designs. In addition, these specification methods lend themselves to efficient verification methods. Profile tolerance definitions provide the most general variation controls for complex mechanical surfaces. Common design practices and engineering standards for profile tolerances exhibit many weaknesses and limitations. We present a rationale …

Nanoparticle-Induced Negative Differential Resistance And Memory Effect In Polymer Bistable Light-Emitting Device, Ricky J. Tseng, Jianyong Ouyang, Chih-Wei Chu, Jinsong Huang, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Recently, electrical bistability was demonstrated in polymer thin films incorporated with metal nanoparticles [J. Ouyang, C. W. Chu, C. R. Szmanda, L. P. Ma, and Y. Yang, Nat. Mater. 3, 918 (2004)]. In this letter, we show the evidence that electrons are the dominant charge carriers in these bistable devices. Direct integration of bistable polymer layer with a light-emitting polymer layer shows a unique light-emitting property modulated by the electrical bistability. A unique negative differential resistance induced by the charged gold nanoparticles is observed due to the charge trapping effect from the nanoparticles when interfaced with the light-emitting layer.

In Vivo Laparoscopic Robotics, Mark E. Rentschler, Stephen R. Platt, Jason Dumpert, Shane M. Farritor, Dmitry Oleynikov

Department of Mechanical and Materials Engineering: Faculty Publications

Robotic laparoscopic surgery is evolving to include in vivo robotic assistants. The impetus for the development of this technology is to provide surgeons with additional viewpoints and unconstrained manipulators that improve safety and reduce patient trauma. A family of these robots have been developed to provide vision and task assistance. Fixed-base and mobile robots have been designed and tested in animal models with much success. A cholecystectomy, prostatectomy, and nephrectomy have all been performed with the assistance of these robots. These early successful tests show how in vivo laparoscopic robotics may be part of the next advancement in surgical technology.

The Role Of Electrospinning In The Emerging Field Of Nanomedicine, S. Y. Chew, Y. Wen, Yuris A. Dzenis, K. W. Leong

Department of Mechanical and Materials Engineering: Faculty Publications

The fact that in vivo the extracellular matrix or substratum with which cells interact often includes topography at the nanoscale underscores the importance of investigating cell-substrate interactions and performing cell culture at the submicron scale. An important and exciting direction of research in nanomedicine would be to gain an understanding and exploit the cellular response to nanostructures. Electrospinning is a simple and versatile technique that can produce a macroporous scaffold comprising randomly oriented or aligned nanofibers. It can also accommodate the incorporation of drug delivery function into the fibrous scaffold. Endowed with both topographical and biochemical signals such electrospun nanofibrous …

Efficient Inverted Polymer Solar Cells, G. Li, C.-W. Chu, V. Shrotriya, Jinsong Huang, Y. Yang

Department of Mechanical and Materials Engineering: Faculty Publications

We investigate the effect of interfacial buffer layers—vanadium oxide (V₂O₅) and cesium carbonate (Cs₂CO₃)—on the performance of polymer solar cells based on regioregular poly-(3-hexylthiophene) and [6,6]-phenyl C₆₀ butyric acid methyl ester blend. The polarity of solar cells can be controlled by the relative positions of these two interfacial layers. Efficient inverted polymer solar cells were fabricated with the structure of indium tin oxide (ITO)/Cs₂CO₃/polymer blend/vanadium oxide (V₂O₅)/aluminum (Al). Short-circuit current of 8.42 mA/cm2, open-circuit voltage of 0.56 V, and power conversion efficiency of …

Improving The Power Efficiency Of White Light-Emitting Diode By Doping Electron Transport Material, Jinsong Huang, Wei-Jen Hou, Juo-Hao Li, Gang Li, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Highly efficient white light emission was realized via the partial energy transfer from blue host polyfluorene (PF) to orange light emission dopant rubrene. A more balanced charge transport was achieved by adding an electron transport material, 2-(4-biphenylyl)-5-(4-tertbutylphenyl)-1,3,4-oxadiazole (PBD), into the PF-rubrene system to enhance the electron transportation. Efficiency improvement by as much as a factor of 2 has been observed through the addition of PBD. These devices can easily reach high luminance at low driving voltages, thus achieving high power efficiency at high luminance (14.8, 13.5, and 12.0 lm/W at the luminances of 1000, 2000, and 4000 cd/m², …

Piezoelectromagnetic Waves In A Ceramic Plate Between Two Ceramic Half-Spaces, S. N. Jiang, Q. Jiang, X. F. Li, S. H. Guo, H. G. Zhou, J. S. Chang

Department of Mechanical and Materials Engineering: Faculty Publications

We analyze the propagation of piezoelectromagnetic waves guided by a plate of polarized ceramics between two ceramic half-spaces. An exact dispersion relation is obtained, which reduces to a few known elastic, electromagnetic, and quasistatic piezoelectric wave solutions in the literature as special cases. Numerical solutions to the equation that determines the dispersion relation show the existence of guided waves. The results are useful for acoustic wave and microwave devices.

Evolutionary Algorithm For The Placement Of Fluid Power Valves On A Valve Stand, Trichy M. Kethara Pasupathy, Ravi Teja Seethamraju, Robert G. Wilhelm

Department of Mechanical and Materials Engineering: Faculty Publications

The choice of placement of fluid power valves on a valve stand and routing by pipes has an impact on operational costs. Choosing the right placement that provides optimum routing configuration or determining the optimum routing for a chosen placement are both computationally hard problems. An evolutionary algorithm (EA), to minimize operational costs while optimizing placement and routing of valves, is developed here. The best practices in the industry are abstracted and implemented in the EA. In this paper, the algorithm and its performance for examples with varying complexities are presented. Our results meet or exceed experienced designers’ solutions.

Electronic Commerce Negotiation In A Supply Chain Via Constraint Evaluation, R. Wilhelm, B. Chu, R. Sun

Department of Mechanical and Materials Engineering: Faculty Publications

Negotiation is of critical importance in e-commerce applications where the supply chain is dynamic and reconfiguring. In this research supply chain negotiation problems are addressed as constraint-satisfaction problems. In general each negotiation is handled in the largest scope possible to avoid the suboptimality that can result from many local solutions. This global approach, however, must be balanced with time constraints that apply in e-commerce supply chain execution. In this paper, we describe a new approach for e-commerce supply chain negotiation via constraint evaluation. As well, results from prototype software, distributed across the internet, are discussed. Beyond the general formulation, we …

Influence Of Composition And Heat-Treatment On The Charge Transport Properties Of Poly(3-Hexylthiophene) And [6,6]-Phenyl C61-Butyric Acid Methyl Ester Blends, Jinsong Huang, Gang Li, Yang Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C₆₁-butyric acid methyl ester (PCBM) blends have been demonstrated to form highly efficient polymer photovoltaic devices. In this letter, the time-of-flight technique is used to investigate the influence of composition and heat treatment on charge transport properties of P3HT and PCBM blends. The transport of electrons and holes both display a transition from dispersive to nondispersive and return to dispersive again as the percentage of PCBM increases. A balanced mobility of both electron and hole is obtained at a composition of 1:1 weight ratio, and it is nearly independent of the electrical field in …

Science For Stewardship: Multidisciplinary Research On Uss Arizona, Matthew A. Russell, Larry E. Murphy, Donald L. Johnson, Timothy J. Foecke, Pamela J. Morris, Raphy Mitchell

Department of Mechanical and Materials Engineering: Faculty Publications

The National Park Service’s Submerged Resources Center and USS Arizona Memorial are conducting and coordinating research directed at understanding the nature and rate of natural processes affecting the deterioration of the USS Arizona in Pearl Harbor, Hawaii. The USS Arizona Preservation Project is designed to be multi-year, interdisciplinary and cumulative, with each element contributing to developing an overall management strategy designed to minimize environmental hazard from fuel oil release and provide the basic research required to make informed management decisions for long-term preservation. The primary project focus is toward acquiring requisite data for understanding the complex corrosion and deterioration processes …

Bar Clamp Having Ergonomic Handle, M. Susan Hallbeck, Myung-Chul Jung

Department of Mechanical and Materials Engineering: Faculty Publications

The present invention generally relates to a handle assembly for a hand operable bar clamp having a fixed jaw, a movable jaw and a drive for translating the movable jaw towards the fixed jaw. The assembly includes a handgrip and a trigger handle. The handgrip having an elongated rear portion has a generally rounded surface and being contoured to complement the natural transverse curve pf a human palm. The trigger handle is pivotal with respect to the handgrip. The trigger handle included an elongated front portion having a rounded front surface and being contoured to complement the natural palmer curve …

Trailer Mounted Bursting Energy Absorption System, John D. Reid, John R. Rohde, Dean L. Sicking

Department of Mechanical and Materials Engineering: Faculty Publications

A portable crash attenuation System having a trailer frame and an energy absorption mechanism attached thereto. The absorption mechanism has a first Stage pivotably connected to a Second Stage and the Second Stage is pivotably connected to the frame. By pivoting the Stages about hinges the attenuation System may be folded from an extended, deployed position or mode to a shortened transit mode for easy relocation of the entire attenuation System.

Optically Transparent, Scratch-Resistant, Diamond-Like Carbon Coatings, Xiao-Ming He, Deok-Hyung Lee, Michael A. Nastasi, Kevin C. Walter, Michel G. Tuszewski

Department of Mechanical and Materials Engineering: Faculty Publications

A plasma-based method for the deposition of diamond-like carbon (DLC) coatings is described. The process uses a radio-frequency inductively coupled discharge to generate a plasma at relatively low gas pressures. The deposition process is environmentally friendly and scaleble to large areas, and components that have geometrically complicated surfaces can be processed. The method has been used to deposit abherent 100-400 nm thick DLC coatings on metals, glass, and polymers. These coatings are between three and four times harder than steel and are therefore scratch resistant, and transparent to visible light. Boron and silicon doping of the DLC coatings have produced …

Method For Producing Fluorinated Damond-Like Carbon Films, Marko J. Hakovirta, Michael Nastasi, Deok-Hyung Lee, Xiao-Ming He

Department of Mechanical and Materials Engineering: Faculty Publications

Fluorinated, diamond-like carbon (F-DLC) films are produced by a pulsed, glow-discharge plasma immersion ion processing procedure. The pulsed, glow-discharge plasma was generated at a pressure of 1 Pa from an acetylene (CH) and hexafluoroethane (CF) gas mixture, and the fluorinated, diamond-like carbon films were deposited on silicon <100>Substrates. The film hardness and wear resistance were found to be strongly dependent on the fluorine content incorporated into the coatings. The hardness of the F-DLC films was found to decrease considerably when the fluorine content in the coatings reached about 20%. The contact angle of water on the F-DLC coatings was found …

Microstructural Study Of Nanoprecipitates In Rra Treated Al-7075 T6 Using Afm/Ufm/Stem, Samuel J.M. Kuhr, Margaret Pinnell, Daniel Eylon

Mechanical and Aerospace Engineering Faculty Publications

7075 T651 aluminum alloy is frequently used in aircraft applications for its high strength to weight ratio. However, aircraft parts made of this alloy have been plagued by stress corrosion cracking (SCC). Retrogression and re-aging (RRA) is a post T651 two-stage heat treatment that provides improved SCC resistance with minimal loss in tensile strength. In this study, various forms of microscopy and mechanical testing are used to investigate how the RRA process affects the microstructure.

The microscopic observations in this paper show that the precipitates in the aluminum alloy coarsen and that the grain boundary regions are depleted of copper …

Alloy States In Dilute Gaas1-XNX Alloys (X<1%), X. D. Luo, Jinsong Huang, Z. Y. Xu, C. L. Yang, J. Liu, W. K. Ge, Y. Zhang, A. Mascarenhas, H. P. Xin, C. W. Tu

Department of Mechanical and Materials Engineering: Faculty Publications

A set of GaAs_1-xN_x samples with small nitrogen composition (x<1%) were investigated by continuous-wave photoluminescence (PL), pulse-wave excitation PL, and time-resolved PL. In the PL spectra, an extra transition located at the higher-energy side of the commonly reported N-related emissions was observed. By measuring the PL dependence on temperature and excitation power, the PL peak was identified as a transition of alloy band edge-related recombination in GaAsN. The PL dynamics further confirms its intrinsic nature as being associated with the band edge rather than N-related bound states.

Rectangular Bursting Energy Absorber, John D. Reid, John R. Rohde, Dean L. Sicking

Department of Mechanical and Materials Engineering: Faculty Publications

A bursting energy absorber System having an impact head, and energy absorption mechanism. The energy absorbing mechanism has a generally rectangular mandrel for rupturing cooperating thin-walled generally rectangular tubes in a controlled rupture to absorb impact forces for a colliding vehicle. A frame may be used to mount the System to a truck, trailer, guardrail, median barrier end treatment, or a crash cushion. Stress concetrators such as saw cuts or scoring may be incorporated into the absorption tubes to selectively control rupturing and energy dissipation. The mandrels may be tapered, rectangulary shaped with beveled edges to reduce frictional forces along …