Mining Engineering Commons^™

A Review Of Gallium And Germanium Recovery From Industrial Solid Residues, Ernest V. Oteng, Marthias Silwamba, Lana Alagha, Alex Luyima

Mining Engineering Faculty Research & Creative Works

The global demand for critical elements such as gallium (Ga) and germanium (Ge), and the shift toward circular mining has accelerated the development of new extraction and recovery processing these metals from industrial solid residues. This transition is driven by a substantial surge in demand for advanced technologies and the depletion of primary ore. Consequently, industrial solid residues, particularly zinc processing residues, smelter slags, flue dusts, and coal fly ash, are emerging as viable alternative sources. These residues incorporate Ga and Ge through isomorphic substitution in phases such as ferrites, silicates, and glassy aluminosilicates, and are enriched by industrial processes, …

Microwave Thermal Pre-Treatment To Improve Nickel Extraction From Lateritic Ore, Johana Borda, Daniel Sosa, Robinson Torres

Journal of Sustainable Mining

Two heat treatment processes for a nickeliferous laterite sample are presented, one by the conventional muffle route and the other by microwave. The heating was carried out in order to improve the dissolution of nickel in an acid medium. The study describes the changes observed in the mineral for the increase in temperature as a consequence of radiation in the microwave and in the muffle. The changes in the mineral crystalline phases were analyzed by X-ray diffraction. The leaching media consisted of a 1 M sulfuric acid solution at ambient conditions for 7 h. The interaction between the reagent and …

An Acid Baking Approach To Enhance Rare Earth Element Recovery From Bituminous Coal Sources, Ahmad Nawab

Theses and Dissertations--Mining Engineering

Rare earth elements (REE) are a group of 17 elements typically classified as light and heavy rare earth elements, which play a crucial role in developing the latest technologies for energy, defense, and medical sectors. Even though REEs have been found in more than 200 minerals, only bastnaesite, monazite and xenotime are commercially exploited for REE extraction. However, the recent exponential increase in REE demand has spurred countries such as the United States into research for the extraction of REEs from secondary sources such as coal, acid mine drainage, and coal ash. Several coal sources (e.g., Fire Clay seam coal) …

Development Of A Hydrometallurgical Process For The Extraction Of Cobalt, Manganese, And Nickel From Acid Mine Drainage Treatment Byproduct, Alejandro Agudelo Mira

Graduate Theses, Dissertations, and Problem Reports (ETD)

Critical minerals (CMs) are defined as crucial elements for the country's economy due to the development of new cutting-edge applications and the risk of an eventual disruption in their supply chain. The unique chemical and physical properties of the CMs have made these elements decisive in the growth of industries such as telecommunications, army, medicine, Aerospace, etc. In 2022, the US Geological Survey established a list of 50 CMs, including manganese, cobalt, nickel, aluminum, magnesium, and others. Of the total of CMs, 26 are 100% imported from outside the United States (Venditti, 2022).

Driven by the ever-increasing demand for critical …

Selective Recovery Of Rare Earth Elements From Acid Mine Drainage Treatment Byproduct, Zeynep Cicek

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rare earth elements (REEs) are critical in emerging clean energy, advanced technologies, and military defense applications due to their unique physical, chemical, optical, and luminescent properties. Given the potential supply chain restrictions imposed by one country's dominance in the global REE market and the consistently growing demand for REEs, developing the US domestic REE supply chain is imperative. Thus, alternative sources are crucial to supply the demand and prevent interruption in manufacturing products that consume REEs. Concurrently, acid mine drainage (AMD) is a long-standing and widespread global challenge the mining industry encounters. AMD is generated in large volumes and continuously …

An Acid Baking Approach To Enhance Heavy Rare Earth Recovery From Bituminous Coal-Based Sources, Ahmad Nawab, Xinbo Yang, Rick Q. Honaker

Mining Engineering Faculty Publications

The recovery of rare earth elements (REEs) from secondary resources, particularly coal-based materials, has recently received attention due to supply and demand imbalance. Research reported to date indicates that a high REE recovery can be realized when treating bituminous coal sources using strong acid solutions of approximately100 g/L or higher. This study introduces an approach to enhance the total rare earth recovery (TREE), especially for heavy rare earth elements (HREEs), from these coal sources at significantly lower acid concentrations. Based on the presence of REE minerals like monazite and xenotime, a detailed investigation was undertaken to quantify three pre-leach treatment …

Application Of Eh-Ph Diagrams On Acid Leaching Systems For The Recovery Of Rees From Bastnaesite, Monazite And Xenotime, Peijia Lin, Xinbo Yang, Joshua M. Werner, Rick Q. Honaker

Mining Engineering Faculty Publications

Bastnaesite, monazite and xenotime are rare earth minerals (REMs) that are typical sources for rare earth elements (REEs). To advance the understanding of their leaching and precipitation behavior in different hydrometallurgical processes, Eh-pH diagrams were constructed and modified using the HSC 9.9 software. The aqueous stability of rare earth elements in H₂O and acid leaching systems, i.e., the REE-Ligands-H₂O systems, were depicted and studied based on the Eh-pH diagrams. This study considers the most relevant lixiviants, their resulting equilibrium states and the importance in the hydrometallurgical recovery of rare earth elements (REMs). A literature review was …

Distribution And Occurrence Of Uranium In Coal And Its Migration Behavior During The Coal Utilization, Wang Wenfeng, Wang Wenlong, Liu Shuangshuang, Bai Hongyang, Wang Yulong, Duan Piaopiao, Qin Kemin, Chen Yilin

Coal Geology & Exploration

Coal and uranium resources are closely related in spatial disposition as well as mineralization, and the reasonable development, utilization and pollution control of them play an essential role in the sustainable development of our national economy and society. Based on a large number of literature research and the previous results of our research group, some conclusions were drawn with regard to the distribution and occurrence of uranium in coal `and its migration in the process of coal preparation, combustion and leaching:(1) The enrichment and mineralization of uranium in coal has reflected the evolution of coal-forming tectonics:The U-rich coal in Southwest …

Leaching Kinetics Of Rare Earth Elements From Fire Clay Seam Coal, Xinbo Yang, Rick Q. Honaker

Mining Engineering Faculty Publications

Recovery of rare earth elements (REEs) from coal samples collected from the Fire Clay coal seam using diluted mineral acid solutions was investigated. The initial processing step was coal recovery using conventional froth flotation which concentrated the REEs in tailing material resulting in an upgrade to values around 700 ppm on a dry whole mass basis. Leaching experiments were performed on the flotation tailings material using a 1.2 M sulfuric acid solution adjusted to a temperature of 75 °C to study the extractability of REEs from coal material. The effect of particle size, leaching time, leaching temperature, and solid concentration …

Characterization Of Rare Earth Elements In The Illinois Basin Coals, Alireza Valian

Theses and Dissertations--Mining Engineering

The purpose of this study is to characterize the distribution and occurrence of rare earth elements (REEs) in the coal and coal-related material from the Illinois Basin. For characterizing the distribution of REEs, 17 core samples were investigated from various parts in the basin. Also, several individual samples from coal preparation plants and isolated geological occurrences were included in the study. In result, the average REE concentrations were calculated on a bed-to-bed basis, although the distribution of REEs in the coal beds was found laterally and vertically heterogeneous. A number of trends were found that describe the variations. Most importantly, …

Leaching Characteristics Of Rare Earth Elements From Bituminous Coal-Based Sources, Xinbo Yang

Theses and Dissertations--Mining Engineering

The demand for rare earth elements (REEs) has increased over the last decade due to applications in high technology devices including those in the defense industry. The recovery of REEs from primary sources such as rare earth minerals are viable using physical separations followed by chemical processing. However, weak market values and environmental concerns have limited the viability of such operations. On the other hand, REE recovery from secondary sources such as apatite ore, bauxite waste, and waste recycling, provides an opportunity to take advantage of a resource that does not require mining costs as well as other associated costs …

Operation And Process Control Development For A Pilot-Scale Leaching And Solvent Extraction Circuit Recovering Rare Earth Elements From Coal-Based Sources, Douglas Kweku Addo

Theses and Dissertations--Mining Engineering

The US Department of Energy in 2010 has identified several rare earth elements as critical materials to enable clean technologies. As part of ongoing research in REEs (rare earth elements) recovery from coal sources, the University of Kentucky has designed, developed and is demonstrating a ¼ ton/hour pilot-scale processing plant to produce high-grade REEs from coal sources. Due to the need to control critical variables (e.g. pH, tank level, etc.), process control is required. To ensure adequate process control, a study was conducted on leaching and solvent extraction control to evaluate the potential of achieving low-cost REE recovery in addition …

Spatial Analysis Of Mount St. Helens Tephra Leachate Compositions: Implications For Future Sampling Strategies, P. M. Ayris, P. Delmelle, B. Pereira, E. C. Maters, D. E. Damby, A. J. Durant, D. B. Dingwell

Michigan Tech Publications, Part 1

Tephra particles in physically and chemically evolving volcanic plumes and clouds carry soluble sulphate and halide salts to the Earth’s surface, ultimately depositing volcanogenic compounds into terrestrial or aquatic environments. Upon leaching of tephra in water, these salts dissolve rapidly. Previous studies have investigated the spatial and temporal variability of tephra leachate compositions during an eruption in order to gain insight into the mechanisms of gas-tephra interaction which emplace those salts. However, the leachate datasets analysed are typically small and may poorly represent the natural variability and complexity of tephra deposits. Here, we have conducted a retrospective analysis of published …

Sustainable Disposal Of Coal Processing Waste Streams, Mohammad Rezaee

Theses and Dissertations--Mining Engineering

Modern coal preparation facilities incorporate a wide array of solid-solid and solid-liquid separation processes for rejecting mineral matter to meet market specifications. The coarse mineral matter is typically placed into engineered refuse piles whereas the fine refuse is either stored in impoundments or co-disposed with the coarse refuse. The discharge water from the refuse material represents an environmental concern due to the potential release of trace elements, and the subsequent elevation of total dissolved solids and conductivity. The research findings reported in this dissertation addresses sustainable coal processing waste disposal through using strategies aimed at minimizing the environmental impacts. To …

Development Of Strategies To Minimize The Release Of Trace Elements From Coal Waste Sources, Mohammad Rezaee

Theses and Dissertations--Mining Engineering

To assess strategies aimed at minimizing the release of trace elements and the impact of disposal of coal waste materials on the environment, two long-term leaching experiments of up to five months duration were performed using waste materials from two plants cleaning high and low sulfur bituminous coal. The tests evaluated the mobility of major trace elements under different disposal scenarios: (i) a static leaching test designed to simulate the quiescent conditions encountered by coal waste material stored under water in a stable impoundment, and (ii) a dynamic test to simulate waste materials exposed to the atmosphere, either in variable …