Energy Systems Commons^™

Thermal Heterogeneity And Lithium Plating During Fast Charging Of Lithium-Ion Battery., Ayodeji Avis Adeniran

Electronic Theses and Dissertations

Presently, widespread adoption of electric vehicles (EVs) is hindered by challenges associated with XFC, including heat generation, lithium plating, and accelerated battery degradation. This dissertation addresses these barriers through two coordinated themes—lithium plating and thermal management—spanning four manuscripts that integrate operando diagnostics, physics-based simulation, and module-level design optimization. The first theme seeks a fundamental investigation into the dynamic interplay between temperature heterogeneity and lithium plating during fast charging, a phenomenon that poses significant limitations on the performance of graphite-based anodes. Firstly, a custom operando cell with a sapphire window was designed to enable synchronized MWIR thermography and optical imaging of …

Thermal Characterization Of Lithium-Ion Batteries Under Fast Charging Conditions Using Infrared Imaging., Gowthaman Punithakumar

Electronic Theses and Dissertations

Lithium-ion batteries are widely used across various industries due to their long lifespan, high energy density, low self-discharge rate, and absence of memory effect. However, fast charging of Li-ion batteries can cause problems like lithium plating, mechanical damage, and overheating. Temperature plays a key role in battery performance. Measuring temperature accurately is important to improve battery life, efficiency, and safety. However, accurately measuring a battery's internal temperature remains challenging, and the appropriate measurement method depends on factors like range, accuracy, resolution, and cost. Choosing the right temperature measurement method depends on range, accuracy, resolution, and cost. In this study, we …

Synthesis And Doping Effects In Highly Conductive Chalcogenide Solid Electrolytes., Selim Halacoglu

Electronic Theses and Dissertations

Lithium and sodium ion batteries have been a vital component in the growth of small, portable electronic devices and EVs over the past 30 years. For future energy needs, changes to battery chemistry and composition will be necessary for two primary reasons: safer and higher energy batteries. Metal anodes have not seen widespread commercialization because of their propensity to react aggressively with the flammable liquid electrolytes commonly used in modern batteries. Non-flammable solid-state batteries (SSB) with solid electrolytes can safely be used with metal anodes, potentially providing a solution to both problems. The future perspective of safer battery is that …

Barocaloric Heat Pumps Based On Soft Materials., Naveen Weerasekera

Electronic Theses and Dissertations

Solid-state refrigeration offers a promising alternative to traditional vapor compression systems that are relatively inefficient, unreliable, and have a high global warming potential. Various solid-state cooling technologies, including those based on electrocaloric, magnetocaloric, and elastocaloric effects have been investigated in the recent past. However, concerns regarding their efficiency, scalability and cost remain. Refrigeration and heat pump technologies based on the barocaloric effect (temperature/entropy change due to hydrostatic pressure) hold great promise but have received comparatively less attention. Barocaloric heating/cooling based on low cost, compressible soft materials with large barocaloric response have the potential to pave the way for efficient, scalable, …

Quantum-Powered Battery Scheduling In Modern Distribution Grids, Diba Ehsani

Electronic Theses and Dissertations

The rising need for exploiting a novel and evolved computation is an increasing concern in the power distribution system to address the exponential growth of distribution-connected devices. Scheduling numerous battery energy storage systems in an optimal way is one of the emerging challenges that will be more noticeable as the number of batteries, including residential, community, and vehicle batteries, increases in the grid. This thesis focuses on this topic and offers a necessary component in building the quantum-compatible distribution system of the future. Using a constrained quadratic model (CQM) on D-Wave’s hybrid solver as well as a binary quadratic model …

Feasibility Study Of Managing Peak Cooling Loads To Achieve Energy Cost Reduction In A Northern Climate Campus, Mark Rizkalla

Electronic Theses and Dissertations

South Dakota State University Facilities and Services Office is facing the challenge of paying high electricity bills every year, the potential of campus growth will add more burden on the energy needed to cover this demand, especially in summer months when high cooling loads are added to the electrical loads which lead to the peak loads that costs SDSU a large amount of money. The purpose of this research is to study the feasibility of managing the peak loads to reduce energy costs by applying a suitable system that fits SDSU campus nature. The methodology used is studying the capability …

The Modernization Of Large Power Transformer Tanks, Babajide O. Williams

Electronic Theses and Dissertations

Due to the current demands placed on the power grid in terms of climate change, increasing urbanization, and terrorist attacks, the U.S. government in response to these demands, mandated that all the grid components be modernized in order to increase their reliability. As a critical component of the grid, Large Power Transformers (LPTs) play a key role in ensuring sustainable power generation and distribution. A literature search performed in this work and the analysis of data retrieved from the search showed that the tanks of these LPTs are critical to their durability, longevity, and reliability. Therefore, the reliability of LPTs …

Super P-Sulfur Cathodes For Quasi-Solid-State Lithium-Sulfur-Batteries., Milinda Bharatha Kalutara Koralalage

Electronic Theses and Dissertations

Lithium-Sulfur (Li-S) batteries have become a promising candidate to meet the current energy storage demand, with its natural abundance of materials, high theoretical capacity of 1672 mAhg-1, high energy density of 2600 Whkg-1, low cost and lower environmental impact. Sulfide based solid state electrolytes (SSEs) have received greater attention due to their higher ionic conductivity, compatible interface with sulfur-based cathodes, and lower grain boundary resistance. However, the interface between SSEs and cathodes has become a challenge in all solid-state Li-S batteries due to the rigidity of the participating surfaces. A hybrid electrolyte containing SSE coupled with a small amount of …

Assessing The Economic Feasibility Of Capturing And Utilizing Carbon Dioxide From Ethanol Production In South Dakota, Makiah Stukel

Electronic Theses and Dissertations

Since the Industrial Revolution, anthropogenic greenhouse gas (GHG) emissions have spiked dramatically, prompting discussions on climate change. Mitigating climate change requires significant reductions in global carbon dioxide (CO2) emissions as CO2 is the most abundant anthropogenic GHG. A process that assists in offsetting the exponential growth in CO2 emissions is carbon capture and storage (CCS). Integrating carbon capture technology into the ethanol industry can provide an economically feasible way to achieve net reductions in CO2 emissions. The proposed work investigates the economic viability of applying CCS technologies to the 16 ethanol facilities in South Dakota (SD) and quantifies the potential …

Nucleate Boiling Under Different Gravity Values: Numerical Simulations & Data-Driven Techniques., Sandipan Banerjee

Electronic Theses and Dissertations

Nucleate boiling is important in nuclear applications and cooling applications under earth gravity conditions. Under reduced gravity or microgravity environment, it is significant too, especially in space exploration applications. Although multiple studies have been performed on nucleate boiling, the effect of gravity on nucleate boiling is not well understood. This dissertation primarily deals with numerical simulations of nucleate boiling using an adaptive Moment-of-Fluid (MoF) method for a single vapor bubble (water vapor or Perfluoro-n-hexane) in saturated liquid for different gravity levels. Results concerning the growth rate of the bubble, specifically the departure diameter and departure time have been provided. The …

Atomistic Investigation Of Phase Stability And Sodium Ion Conduction In Sulfide Electrolytes., Sabina Zakhidovna Chertmanova

Electronic Theses and Dissertations

In this thesis, we employ a combination of density functional theory (DFT) calculations, and ab initio molecular dynamics (AIMD) simulations to identify the effect of chemical doping on (a) thermodynamic phase stability, and (b) Na-ion conduction in Na₃SbS₄ (NSS) solid-state electrolytes. We found that (a) Se doped electrolytes, namely, Na₃SbS_exS_4-x undergo a tetragonal-to-cubic structural phase transition at x > 3 (Se-rich), and (b) the size, valence, and electronegativity of chemical dopants that substitute Na in Na₃SbS₄ have a cumulative profound impact on Na-ion conductivity. Specifically, substituting Na with higher valence …

Design Of A 300cm2 Pemfc Stack With Force And Cfd Simulation To Optimize Flow Channels, Gasket Design, And Clamping Forces., Robert M. Ench

Electronic Theses and Dissertations

Proton exchange membrane fuel cells are important to the future of green energy as hydrogen can be made with green technologies and store energy for later use. Fuel cells can efficiently convert the hydrogen to electricity as needed. This study uses Solidworks simulation to make design improvements to the fuel cell before the prototype build stage of testing; this saves money and time by reducing the prototype builds needed.

In this study, a multi-channel serpentine design with two outlets versus a single outlet is evaluated using CFD to investigate pressure drop. Lower pressure drops are desirable as less energy input …

Dynamic Analysis And Fabrication Of A Bi-Stable Structure Designed For Mems Energy Harvesting Applications., Masoud Derakhshani

Electronic Theses and Dissertations

Thanks to the rapid growth in demand for power in remote locations, scientists’ attention has been drawn to vibration energy harvesting as an alternative to batteries. Over the past ten years, the energy harvesting community has focused on bistable structures as a means of broadening the working frequency range and, by extension, the effective efficiency of vibration-based power scavenging systems. In the current study, a new method is implemented to statically and dynamically analyze a bistable buckled, multi-component coupled structure designed specifically for low-frequency vibration energy harvesting systems in both macro and MEMS-scale sizes. Furthermore, several micro-fabrication steps using advanced …

Energy Efficiency And Alternative Energy Generation In Existing Buildings On A College Campus, Sameer Keshavan

Electronic Theses and Dissertations

Universities and colleges are looking for ways to be sustainable and save energy costs on their campuses. In terms of raw dollars, “America’s colleges and universities spend almost $7 billion a year in energy and utilities”. Campus buildings consume more than 80% of the energy utilized by the universities and it is often used in the form of electricity for lighting, ventilation, air-conditioning, and natural gas for heating. By reducing energy use, it will translate into cost savings that could be utilized towards student programs, facility improvements, and other university initiatives. This can be achieved by energy conservation efforts and …

Dynamic Behavior And Performance Of Different Types Of Multi-Effect Desalination Plants, Mohamed Abdelkareem

Electronic Theses and Dissertations

Water and energy are two of the most vital resources for the socio-economic development and sustenance of humanity on earth. Desalination of seawater has been practiced for some decades and is a well-established means of water supply. However, this process consumes large amounts of energy and the global energy supply is also faced with some challenges. In this research, multi-effect desalination (MED) has been selected due to lower cost, lower operating temperature and efficient in terms of primary energy and electricity consumption compared to other thermal desalination systems. The motivation for this research is to address thermo-economics and dynamic behavior …

Lithium Molybdate-Sulfur Battery., Ruchira Ravinath Dharmasena

Electronic Theses and Dissertations

Rechargeable energy storage systems play a vital role in today’s automobile industry with the emergence of electric vehicles (EVs). In order to meet the targets set by the department of energy (DOE), there is an immediate need of new battery chemistries with higher energy density than the current Li- ion technology. Lithium–sulfur (Li–S) batteries have attracted enormous attention in the energy-storage, due to their high specific energy density of 2600 Wh kg^-1 and operational voltage of 2.0 V. Despite the promising electrochemical characteristics, Li-S batteries suffer from serious technical challenges such as dissolution of polysulfides Li₂S_{x …}

Modeling And Study Of Thermal Effects On Battery Pack Using Phase Change Materials, Umang Selokar

Electronic Theses and Dissertations

The scope of the current research is to reduce the temperature distribution area in Li-ion cell and the battery pack with respect to time in battery design, using CFD technology (Computational Fluid Dynamics) in ANSYS fluent. A 3D model was design in CAD software (CATIA) and analyzed in ANSYS fluent to study the thermal behavior of the designed battery pack. An analytical thermal model was generated to evaluate the heat generation rate passing throughout the battery pack. The battery pack were analyzed and simulated on two different designs. One battery design is modeled with and without insulation (superwool EST compression …

Low Temperature Desiccants In Atmospheric Water Generation., Sunil Gupta

Electronic Theses and Dissertations

Surging global water demand as well as changes to weather patterns and over exploitation of natural water sources, such as ground water, has made potable water a critical resource in many parts of the World already – one rapidly heading towards a crisis situation. Desalination has been adopted as a solution – this is however energy intensive and impractical for most of the developing countries - those most in need of water. A renewable source of energy is solar thermal and solar photovoltaic. A plentiful source of water is the humidity in the atmosphere. This research is to push the …

Selecting The Most Effective Energy Modeling Tool Based On A Project Requirement, Sodiq Akande

Electronic Theses and Dissertations

Building energy usage can be derived and controlled by performing building energy modeling. BEM can be performed using numerous software tools such as DesignBuilder, OpenStudio, EnergyPlus etc. These modeling tools can be sorted into three different modeling categories: Black-box, Gray-box and White-box. It is important for a modeler to be able to quickly select the proper tool from the proper category to meet the need of the project. To validate the method of categorizing tools, the three models generated using tools from each category and the modeling outputs required were compared. Each model was designed to estimate the amount of …

Optimal Operation Of Integrated Microgrids, Abdullah Albaker

Electronic Theses and Dissertations

Microgrids' deployments are increasing and projected to increase even more in future due to the significant advantages that are provided by this technology for end-use customers. However, microgrids can be connected to each other to create integrated microgrids system, which can further promote the anticipated and desired benefits. An integrated operation of microgrids can potentially improve the local power system reliability and resilience, increase the individual microgrids' economic benefits, and promote further utilization of renewable energy resources. Integrating microgrids, to achieve a microgrid network or cluster, is expected be an essential application towards smarter power grids and a key operational …

Development Of An Indoor Multirotor Testbed For Experimentation On Autonomous Guidance Strategies, Kidus Guye

Electronic Theses and Dissertations

Despite the vast popularity of rotary wing unmanned aerial vehicles and research centres that develop their guidance software, there are only a limited number of references that provide an exhaustive description of a step-by-step procedure to build-up a multirotor testbed. In response to such need, the first part of this thesis aims to describe, in detail, the complete procedure to establish and operate an autonomous multirotor unmanned aerial vehicle indoor experimental platform to test and validate guidance, navigation and control strategies. Both hardware and software aspects of the testbed are described to offer a complete understanding of the different aspects. …

Simulation Of Non-Premixed Ethylene-Air Crossflow Jet Flame, Jennifer Onyinye Chikelu

Electronic Theses and Dissertations

Computational fluid dynamics tool has been employed in the past to determine and analyze efficiency or performance in combustion engines and for combustion analysis. This paper represents a systematic investigation on the best model predicts the temperature and soot production in coflow jet flame, by applying various RANS turbulent model, soot models and radiation models in presence or absence of gravity. It also applies this model predicted in crossflow jet flame and investigates the velocity ratio (ratio of the velocity of fuel jet to the velocity of air stream) variation effect on temperature and soot production. ANSYS-Fluent CFD software tool …

Hosting Capacity Optimization In Modern Distribution Grids, Mansoor T. Alturki

Electronic Theses and Dissertations

The availability of distributed renewable energy resources and the anticipated increase in new types of loads are changing the way electricity is being produced and supplied to consumers. This shift is moving away from a network delivering power solely from centralized power plants towards a decentralized network which supplements its power production by incorporating local distributed generators (DGs). However, the increased integration of DGs into existing distribution networks is impacting their behavior in terms of voltage profile, reliability, and power quality. To determine the maximum amount of DG that distribution grids can accommodate the concept of hosting capacity is introduced. …

Automated Cfd Optimization To Maximize Wind Farms Performance And Land Use, Rafael Valotta Rodrigues

Electronic Theses and Dissertations

In this research, a computational system was designed to analyze and optimize the layout of wind farms under variable operational conditions. At first, a wind turbine computational fluid dynamic (CFD) model was developed covering the near wake. The near wake flow field was validated against near wake velocity data from the MEXICO experiment. The CFD simulation demonstrated that the tip speed ratio and the pitch angle greatly influence the near wake behavior, affecting the velocity deficit and the turbulence intensity profile in this region. The CFD model was extended to cover the far wake, aiming to become a computational tool …

Piezoelectric Bistable Buckled Beam Energy Harvester., Brian Edward Allgeier

Electronic Theses and Dissertations

A novel energy harvesting device design is presented to be created via microfabrication techniques. Such devices have countless applications for powering low-current electrical devices, especially wireless sensors or transmitters. This micro-electromechanical system (MEMS) design utilizes the piezoelectric response of a bistable buckled beam to gather electrical energy via ambient vibrations. While many traditional piezoelectric energy harvesters (PEH) consist of simple cantilever beam geometries, this nonlinear design utilizes inertial effects of torsional lever arms to actuate a central buckled beam to snap between its two stable states; such an abrupt strain on the piezoelectric beam potentially produces a significantly increased electrical …

Evaluation Of Two-Phase Evaporation Pressure Drop Correlations For Low Refrigerant Mass Flux., Anna Fenko

Electronic Theses and Dissertations

This study was conducted to evaluate three currently popular two-phase pressure drop models for extremely low velocity refrigerant flow through smooth circular evaporators in household refrigeration systems. Experimental data was taken at mass fluxes under 70 kg/m²s for two refrigerants, R134A and R600A, internal diameters of aluminum evaporators ranging from 0.186 to 0.317 inches, U-bend internal radii ranging from 0.342 to 0.750 inches in horizontal and vertical orientations of evaporators. The geometry of the samples closely resembled a commonly used serpentine shape with multiple U-bends experiencing both, up- and down-flow of the refrigerant. Two empirical models, Müller-Steinhagen & …