Energy Systems Commons^™

Bulk Storage (10,000+ Tons) Of Fly Ash, Fgd Gypsum, Limestone And Coal At Power Stations In Concrete Domes, Benjamin Davis, Zachary Fillmore, Michael Hunter

World of Coal Ash Proceedings

No abstract provided.

Soil Mixing And Slurry Trench Cutoff Walls For Coal Combustion Residue Sites, Jeffrey C. Evans, Daniel Ruffing

World of Coal Ash Proceedings

No abstract provided.

Cost-Effective, Environmentally-Friendly Ash Beneficiation Technology, Scott Ziegler

World of Coal Ash Proceedings

No abstract provided.

The Utilization Of Dry Scrubber Material For The Production Of Calcium Sulfoaluminate Clinkers And Cements, Tristana Y. Duvallet, Robert B. Jewell, Anne E. Oberlink, Thomas L. Robl

World of Coal Ash Proceedings

No abstract provided.

Net Environmental Benefit Analysis (Neba) For Ccr Pond Closure Decisions -- A Pathway To Meaningful Citizen Engagement And Reducing The Potential For Unnecessary Litigation, Chris Hardin, Ric Traver

World of Coal Ash Proceedings

No abstract provided.

Challenges Met In Using Bottom Ash As A Landfill Drainage Media, William M. Strachan

World of Coal Ash Proceedings

No abstract provided.

Two Bottom Ash Management/Handling System Enhancement Case Studies – From Technology Evaluation And Design Through Construction And Performance Verification, George Mckenzie, Aaron Davis, Chris Pickelmann, Jason Obermeyer

World of Coal Ash Proceedings

No abstract provided.

Slurry-Trench Cutoff Walls For The Containment Of The Coal Combustion Residuals (Ccr) Impacted Groundwater: Evaluation Of Hydraulic Conductivity And Consolidation Properties Of Soil-Bentonite Backfills, Y.L. Yang, Krishna Reddy, Y.J. Du, R.D. Fan

World of Coal Ash Proceedings

No abstract provided.

Ccp Beneficial Use Risk Assessment: Case Studies For Three Different Applications, Andrew Bittner, Ari Lewis

World of Coal Ash Proceedings

No abstract provided.

Corrective Measures/Corrective Action (Cm/Ca) Strategies That Effectively Integrate Engineered Pond Closures And Short/Long-Term Groundwater Management With Case Study Examples, Steve Putrich

World of Coal Ash Proceedings

No abstract provided.

Managing Landfill Leachate In A World Without Ash Basins: Lessons Learned And Practical Considerations, Evan Andrews, Michael Lazar

World of Coal Ash Proceedings

No abstract provided.

Developing Enhanced Monitored Natural Attenuation Strategies Using Reactive Transport Models, Pj Nolan, Hugh Davies, Greg Hebeler, Rens Verburg

World of Coal Ash Proceedings

No abstract provided.

Enhancing Coal Ash Impoundment Closure Using Value Engineering, Holt Wheeler, Trey Mangers, Paul Lear

World of Coal Ash Proceedings

No abstract provided.

Experimental Test Method To Determine The Reactivity Of Fly Ash For Use In Concrete Mixture Proportioning, Antara Choudry, Deborah Glosser, O. Burkan Isgor, W. Jason Weiss

World of Coal Ash Proceedings

No abstract provided.

Overview Of Epri Research On Environmental Issues And Beneficial Use Of Coal Combustion Products, Bruce Hensel, Ken Ladwig

World of Coal Ash Proceedings

No abstract provided.

Is My Site A Candidate For A Groundwater Natural Attenuation Remedy? A Geochemist’S Perspective, Bob Glazier

World of Coal Ash Proceedings

No abstract provided.

Impoundment Closure Enhancement Measures To Support Groundwater Compliance, John Hesemann, Wayne Weber, Eric Dulle

World of Coal Ash Proceedings

No abstract provided.

Panel On Liquefaction Of Ponded Fly Ash: From Laboratory To Practice, Tarunjit S. Butalia

World of Coal Ash Proceedings

No abstract provided.

Fluorescence Of Cdse/Zns Quantum Dots In Toluene: Effect Of Cyclic Temperature, Ting Chen, Weiling Luan, Shaofu Zhang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Quantum dots (QDs) are the potential material for the application in optical thermometry, and have been successfully applied to solar cells, LEDs, bio-labeling, structural health monitoring, etc. In this paper, we study the fluorescence properties of CdSe/ZnS QDs in toluene under the action of heating-cooling cycles. The experimental results show that, in a heating-cooling cycle, increasing temperature causes red-shift of the emission peak and the decrease of the PL intensity, and decreasing temperature causes blue-shift of the emission peak and the increase of the PL intensity. The surface structures of the QDs likely are dependent on the cycle numbers, which …

Design And Testing Of A Wind Energy Harnessing System For Forced Convective Drying Of Grain In Low Wind Speed, Warm And Humid Climates, Francis Akumabi Agbali

Theses and Dissertations--Biosystems and Agricultural Engineering

Forced convective drying using a wind turbine mechanically connected to a ventilation fan was hypothesized for low cost and rapid grain drying in developing countries. The idea was tested using an expandable wind turbine blade system with variable pitch, at low wind speeds in a wind tunnel. The design was based on empirical and theoretical models embedded in a graphical user interface (GUI) created to estimate airflow-power requirements for drying ear corn. Output airflow (0.0016 - 0.0052 m³kg^-1s^-1) increased within the study wind speed range (2.0 - 5.5 m/s). System efficiency peak (8.6%) was …

Performance Of C2H4 Reductant In Activated-Carbon-Supported Mnox-Based Scr Catalyst At Low Temperatures, Guangli Liu, Dongtai Han, Jie Cheng, Yongshi Feng, Wenbin Quan, Li Yang, Kozo Saito

Mechanical Engineering Faculty Publications

Hydrocarbons as reductants show promising results for replacing NH₃ in SCR technology. Therefore, considerable interest exists for developing low-temperature (< 200 °C) and environmentally friendly HC-SCR catalysts. Hence, C₂H₄ was examined as a reductant using activated-carbon-supported MnOx-based catalyst in low-temperature SCR operation. Its sensitivity to Mn concentration and operating temperature was parametrically studied, the results of which showed that the catalyst activity followed the order of 130 °C > 150 °C > 180 °C with an optimized Mn concentration near 3.0 wt.%. However, rapid deactivation of catalytic activity also occurred when using C₂H₄ as the reductant. The mechanism of deactivation was explored and is …

3d Numerical Study Of Multiphase Counter-Current Flow Within A Packed Bed For Post Combustion Carbon Dioxide Capture, Li Yang, Fang Liu, Zhengchang Song, Kunlei Liu, Kozo Saito

Mechanical Engineering Faculty Publications

The hydrodynamics within counter-current flow packed beds is of vital importance to provide insight into the design and operational parameters that may impact reactor and reaction efficiencies in processes used for post combustion CO₂ capture. However, the multiphase counter-current flows in random packing used in these processes are complicated to visualize. Hence, this work aimed at developing a computational fluid dynamics (CFD) model to study more precisely the complex details of flow inside a packed bed. The simulation results clearly demonstrated the development of, and changes in, liquid distributions, wetted areas, and film thickness under various gas and liquid …

Pressure-Driven Stabilization Of Capacitive Deionization, Landon S. Caudill

Theses and Dissertations--Mechanical and Aerospace Engineering

The effects of system pressure on the performance stability of flow-through capacitive deionization (CDI) cells was investigated. Initial data showed that the highly porous carbon electrodes possessed air/oxygen in the micropores, and the increased system pressure boosts the gases solubility in saline solution and carries them out of the cell in the effluent. Upon applying a potential difference to the electrodes, capacitive-based ion adsorption occurs in competition with faradaic reactions that consume oxygen. Through the addition of backpressure, the rate of degradation decreases, allowing the cell to maintain its salt adsorption capacity (SAC) longer. The removal of oxygen from the …

Note On The Rate And Energy Efficiency Limits For Additive Manufacturing, Timothy Gutowski, Sheng Jiang, Daniel Cooper, Gero Corman, Michael Hausmann, Jan-Anders Manson, Timo Schudeleit, Konrad Wegener, Matias Sabelle, Jorge Ramos-Grez, Dusan P. Sekulic

Mechanical Engineering Faculty Publications

We review the process rates and energy intensities of various additive processing technologies and focus on recent progress in improving these metrics for laser powder bed fusion processing of metals, and filament and pellet extrusion processing of polymers and composites. Over the last decade, observed progress in raw build rates has been quite substantial, with laser metal processes improving by about 1 order of magnitude, and polymer extrusion processes by more than 2 orders of magnitude. We develop simple heat transfer models that explain these improvements, point to other possible strategies for improvement, and highlight rate limits. We observe a …

Solubility And Thermodynamic Modeling Of Carcinogenic Nitrosamines In Aqueous Amine Solvents For Co2 Capture, Jesse Thompson, Naser Matin, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

A better understanding of key fundamental properties of nitrosamines, including their solubility in aqueous amine solvents, is needed to understand and accurately model the vapor-phase emission levels from operating CO₂ capture systems. In this work, the first experimental Henry's volatility coefficient of a nitrosamine was obtained with a novel method using static headspace solid phase micro extraction (SPME) and gas chromatography mass spectrometry (GC/MS). The experimentally determined Henry's volatility coefficient of nitrosopyrrolidine (NPY) was found to be around 0.02 (dimensionless) at 25 °C, and falls in the range of a semi-volatile compound. A linear temperature dependency of the Henry's …

Techno-Economic Analysis Of A Secondary Air Stripper Process, J. R. Heberle, Heather Nikolic, Jesse Thompson, Kunlei Liu, Lora L. Pinkerton, David Brubaker, James C. Simpson, Song Wu, Abhoyjit S. Bhown

Center for Applied Energy Research Faculty and Staff Publications

We present results of an initial techno-economic assessment on a post-combustion CO₂ capture process developed by the Center for Applied Energy Research (CAER) at the University of Kentucky using Mitsubishi Hitachi Power Systems’ H3-1 aqueous amine solvent. The analysis is based on data collected at a 0.7 MWe pilot unit combined with laboratory data and process simulations. The process adds a secondary air stripper to a conventional solvent process, which increases the cyclic loading of the solvent in two ways. First, air strips additional CO₂ from the solvent downstream of the conventional steam-heated thermal stripper. This extra stripping …

Thermal Degradation Pathways Of Aqueous Diamine Co2 Capture Solvents, Jesse Thompson, Henry Richburg, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

Diamines have shown promise as CO₂ capture solvents, yet very little is known about their pathway for thermal degradation. In this study, diamine thermal degradation was quantitatively monitored in lab-scale experiments on four aqueous diamine solvents; ethylenediamine (EDA) 1,2-propanediamine (1,2-DAP), 1,3-diaminopropane (1,3-DAP) and N-methyl-1,2-ethanediamine (NMEDA), to gain a more comprehensive understanding of their degradation pathway(s). The major degradation products were identified by high resolution time-of-flight mass spectrometry (TOF-MS). Degradation pathways were proposed showing that the primary thermal degradation route for this class of amine are through carbamate formation followed by intermolecular cyclization to form an imidazolidinone or nucleophilic attack …

An Analysis Of Energy Resources Utilization For Two Metal Joining Manufacturing Processes, Jonathan Gasser

Theses and Dissertations--Mechanical and Aerospace Engineering

Sustainable manufacturing involves utilizing energy resources efficiently. Currently, the state of sustainability for a given manufacturing process is described by most in a qualitative sense as opposed to using quantitative metrics. This thesis offers a segment of analysis needed to understand the state of sustainability in the context of energy resource utilization. This was accomplished by measuring the order of magnitude difference between the energy consumption of a manufacturing process vs. the theoretical minimum amount of energy required to complete the same task (aluminum T-joint bond). This analysis was completed for a TIG welding process and a controlled atmosphere brazing …

Axial Compressor Flow Behavior Near The Aerodynamic Stability Limit, Bradley D. Butler

Theses and Dissertations--Mechanical and Aerospace Engineering

In this investigation, casing mounted high frequency response pressure transducers are used to characterize the flow behavior near the aerodynamic stability limit of a low speed single stage axial flow compressor. Time variant pressure measurements are acquired at discrete operating points up to the stall inception point and during the transition to rotating stall, for a length of time no shorter than 900 rotor revolutions. The experimental data is analyzed using multiple techniques in the time and frequency domains.

Experimental results have shown an increase in the breakdown of flow periodicity as the flow coefficient is reduced. Below a flow …

Cerium Oxide (Ceo2) Promoted Oxygen Carrier Development And Scale Modeling Study For Chemical Looping Combustion, Fang Liu

Theses and Dissertations--Mechanical and Aerospace Engineering

According to IPCC reports, the greenhouse gas CO₂ is responsible for global climate change. Studies show that CO₂ concentration reached a level of 400 ppm in 2013, or 40 % above pre-industrial levels. The contribution of CO₂ from industrial activity to increasing global CO₂ concentrations is widely accepted and points to the need to reduce the emission of this greenhouse gas.One possible combustion technology that shows promise for reducing CO₂ emissions is chemical looping combustion (CLC). It is an oxy-fuel technology, but has the advantages of in situ oxygen separation, low NO_x emissions and …