Mechanical Engineering Commons^™

A Digital Twin Based Forecasting Framework For Power Flow Management In Dc Microgrids, Kerry Sado, Jarrett Peskar, Austin Downey, Jamil A. Khan, Kristen Booth

Faculty Publications

The ability to forecast system conditions is integral to the definition and functionality of digital twins. While forecasting methods have been explored for use in digital twin systems, the integration of feedback mechanisms for real-time forecasting and in-situ decision-making in DC microgrids has not been extensively investigated. This research develops a modular forecasting framework tailored for digital twins in DC microgrids to enable real-time monitoring, online forecasting, and decision-making. DC microgrids, characterized by dynamic load variations, benefit from advanced predictive capabilities to maintain stability and operational efficiency. The proposed digital twin-based forecasting framework addresses these challenges by providing real-time predictive …

Si-Doped Ain Using Pulsed Metalorganic Chemical Vapor Deposition And Doping, Tariq Jamil, Abdullah Al Mamun Mazumder, Mohammod Ali, Jingyu Lin, Hongxing Jiang, Grigory Simin, M. Asif Khan

Faculty Publications

In this paper we describe a pulsed metalorganic chemical vapor deposition (MOCVD) Si-doping approach for AlN epilayers over bulk AlN. The Al-rich growth/doping conditions in the pulsed MOCVD process resulted in n-AlN layers with transmission line model currents that were an order higher than for structures on layers that were grown/doped at identical temperatures using the conventional MOCVD process. Our work demonstrated that like the other reported approaches such as UV exposure during growth, the pulsed MOCVD process is also very effective in reducing point defects by the defect quasi-Fermi level-chemical potential control.

Co2 Electrolysis Using Metal-Supported Solid Oxide Cells With Infiltrated Pr0.5Sr0.4Mn0.2Fe0.8O3−Δ Catalyst, Boxun Hu, Ka-Young Park, Asia Sarycheva, Robert Kostecki, Fanglin Chen, Michael C. Tucker

Faculty Publications

Electrochemical conversion of CO₂ to CO is demonstrated with symmetric-structured metal supported solid oxide cells (MS-SOC). Perovskite Pr_0.5Sr_0.4Mn_0.2Fe0.8O_3−δ (PSMF) and Pr₆O₁₁ catalysts were infiltrated into the MS-SOC cathode and anode, using 3 cycles with firing at 850 °C and 8 cycles with firing at 800 °C, respectively. Upon reduction during operation, the perovskite PSMF was transformed to Ruddlesden–Popper structure with a highly efficient electrocatalytic activity. The impact of operating temperature (600–800 °C) and overpotential (0–1.8 V) on the CO₂ conversion was investigated. The highest CO₂ conversion …

Sno2 Modified Csh2Po4 (Cdp) Protonic Electrolyte For An Electrochemical Hydrogen Pump, Minal Gupta, Kangkang Zhang, Kevin Huang

Faculty Publications

CsH₂PO₄ (CDP) is a well-known super-protonic conductor. However, it must operate under high humidity conditions to prevent dehydration and fast conductivity decay. Herein, we report that adding hydrophilic SnO₂ into CDP can suppress the rate of dehydration of CDP, thus stabilizing protonic conductivity over a broader range of water partial pressures (pH₂O). A total of seven compositions of (1 − x)CDP/(x)SnO₂ were prepared, where 5 ≤ x ≤ 40 (wt%), and examined for their phasal, microstructural, and vibrational properties using X-ray diffraction, field emission scanning electron microscopy, and …

Sno2 Modified Csh2Po4 (Cdp) Protonic Electrolyte For An Electrochemical Hydrogen Pump, Minal Gupta, Kangkang Zhang, Kevin Huang

Faculty Publications

CsH₂PO₄ (CDP) is a well-known super-protonic conductor. However, it must operate under high humidity conditions to prevent dehydration and fast conductivity decay. Herein, we report that adding hydrophilic SnO2 into CDP can suppress the rate of dehydration of CDP, thus stabilizing protonic conductivity over a broader range of water partial pressures (pH2O). A total of seven compositions of (1 - x)CDP/(x)SnO₂ were prepared, where 5 ≤ x ≤ 40 (wt%), and examined for their phasal, microstructural, and vibrational properties using X-ray diffraction, field emission scanning electron microscopy, and Raman spectroscopy. The signature of H₂O …

A Generalized Coherence Framework For Quantifying Input Contributions In Multi-Input Systems With Correlated Or Uncorrelated Inputs, Nolan H. Howes, Matthew S. Allen, Dario Farina, Steven Knight Charles

Faculty Publications

In multi-input systems, it is often necessary to quantify the contribution of each input to an output. Such contribution analysis is frequently performed using coherence. However, when correlation is present between inputs, existing coherence measures do not accurately quantify the contribution of individual inputs, except in special cases. Here we propose an expanded coherence framework that enables contribution analysis in any multi-input system, regardless of input correlation. We bridged the gap by defining three new coherence measures: component, excluded, and isolated coherence. Component coherence is an intermediate measure that decomposes measured output power into components attributable to inputs directly vs …

Mill Power Consumption And Fuel Particle Size Distribution While Co-Milling Bituminous Coal With Steam-Exploded Woody Biomass In A Conventional Bowl Mill, Brian Schoof, Rajarshi Roy, Regan Kuttler, Parker Latour, Scott Montgomery, Jacob Tuttle, Gwendolyn Bennett Bennett, Brian D. Iverson, Andrew Fry

Faculty Publications

The mill behavior of a 312 Combustion Engineering Raymond Bowl Mill was studied with five blends of Utah bituminous coal and steam-exploded woody biomass, ranging from 100 % coal to 100 % biomass. Mill power consumption increased with biomass content, peaking at 187 % of the power required for 100 % coal before the mill faulted at 100 % biomass. After repositioning the rollers, power consumption for 100 % biomass decreased by 13 % compared to 100 % coal. SEM images revealed that milled biomass particles were non-spherical, indicating some fibrous structure remained post steam-explosion. The particle size distribution (PSD) …

Drop Dynamics During Condensation On Superhydrophobic Surfaces In Vapor Shear Flow, Shaur Humayun, R. Daniel Maynes, Julie Crockett, Brian D. Iverson

Faculty Publications

Accurate models for predicting drop dynamics, such as maximum drop departure sizes, are crucial for estimating heat transfer rates during condensation on superhydrophobic (SH) surfaces. Previous studies have focused on examining the heat transfer rates for SH surfaces under the influence of gravity or vapor flowing over the surface. This study investigates the impact of surface solid fraction and texture scale on drop mobility in a condensing environment with a humid air flow. Experiments recorded condensation with varying surface feature sizes from micro- to nano scale under different flow rates. Video analysis detected the drop-size distribution and maximum drop departure …

Internally Stowed, Radially Deployed Radiator Panels For Passive Cubesat Thermal Control, Josh R. Cannon, Kyle N. Havey, Noah S. Housley, Rydge B. Mulford, Brian D. Iverson

Faculty Publications

CubeSats experience significant thermal loads due to solar irradiation and the dissipation from electrical components. The high heat dissipation per unit volume can lead to mission failure if not properly managed. Deployable radiators that are externally stowed and passively actuated in response to changes in CubeSat temperature have been explored as a viable solution. This work describes a radially deployed fin array that is stowed within the CubeSat body when the required heat dissipation is low and passively deploys when the required heat dissipation is high. Internal stowage improves thermal transport to the deployable fins and minimizes heat loss when …

Actuator Disk Model For Aeropropulsive Coupling Effects In Vortex Particle Method, Eduardo Alvarez, Vineet Ahuja, Vinod Lakshminarayan, Aaron Perry, Ryan Anderson, Andrew Ning

Faculty Publications

Blown lift and distributed electric propulsion aircraft pose strong aeropropulsive coupling effects that cannot be ignored during the early stages of design. In this study, we develop an advanced actuator disk model (ADM) for aeropropulsive coupling effects of ducted fans with the vortex particle method (VPM). The advanced ADM consists of (1) an actuator disk at the rotor plane, (2) a surface vortex sheet modeling the mixing and convection of blade tip vorticity along walls, and (3) a powered wake at the exhaust. With these three components, a propulsion jet with an arbitrary velocity profile is formed and interactions with …

Comparing The Sensitivity And Specificity Of Novel Motor Assessments For Traumatic Brain Injury, Paula K. Johnson, Ariana M. Hedges-Muncy, Erin D. Bigler, Lorie Richards, Steven Knight Charles

Faculty Publications

Background: Portable technology that records movements with high accuracy provides potential for sensitive clinical movement tests for individuals who experienced a traumatic brain injury (TBI). Objective: (1)To present impairments assessed using markerless motion capture (MMC) and (2) to compare the sensitivity and specificity of the MMCmediated tests to each other and to common clinical tests. Design: Screening study, using as criterion standard the ability to classify participant with TBI versus control participant. Setting: Research laboratory. Participants: The study included 30 individuals with TBI and 101 control participants. Entry criteria included most recent head injury < 5 years old, no history of movement issues prior to injury, no movement-affecting medications, and sufficient cognitive ability to follow instructions. Interventions: Not applicable. Main Outcome Measures: Performance on MMC-mediated tests and existing clinical analogs. MMC-mediated tests included finger oscillation, simple reaction time, and visually guided movement tasks. For comparison, participants also completed the following clinical tests: Halstead–Reitan finger tapping, simple reaction time test, and Beery Visuomotor Integration test. Impairments were identified as test scores of participants with TBI that fell outside of the 95% interval of control participants’ test scores. Random forest analysis was used to calculate the sensitivity and specificity of MMC and clinical tests according to their ability to correctly classify participants with TBI and control participants. Results: MMC-mediated tests revealed impairments in more participants with TBI than clinical tests in all three TBI groups (mild, repeated, and moderate to severe). Similarly, MMC-mediated tests revealed a higher percentage of scores as impairments than clinical tests in all three groups with TBI. Furthermore, MMC-mediated tests proved more sensitive and more specific than clinical tests (70% versus 50% and 98% versus 93%, respectively). Conclusion: MMC-mediated tests are sensitive and specific (compared to traditional clinical tests) and have potential to fill a gap in clinical care of TBI.

Evaluation Of Impact Energy In Composites Using Acoustic Emission Sensing Technique, Li Ai, Tanner Mesaric, Sydney Flowers, Sydney Houck, Joshua Widawsky, Paul Ziehl

Faculty Publications

A major challenge faced by composite materials is impact, which can result in unexpected damage and degradation. Impact events can cause significant structural damage that may not be immediately visible, leading to a reduction in the material’s mechanical properties and overall performance. This paper presents an impact assessment method using acoustic emission (AE) sensing technology. The primary goal of this approach is to determine the extent of impact damage on composite components by analyzing AE signals produced under operating stress conditions. An advanced algorithm is proposed to predict the probability that the damage falls into various damage categories, providing a …

Introducing The Second-Order Features Adjoint Sensitivity Analysis Methodology For Neural Ordinary Differential Equations—Ii: Illustrative Application To Heat And Energy Transfer In The Nordheim–Fuchs Phenomenological Model For Reactor Safety, Dan Gabriel Cacuci

Faculty Publications

This work presents an illustrative application of the newly developed “Second-Order Features Adjoint Sensitivity Analysis Methodology for Neural Ordinary Differential Equations (2nd-FASAM-NODE)” methodology to determine most efficiently the exact expressions of the first- and second-order sensitivities of NODE decoder responses to the neural net’s underlying parameters (weights and initial conditions). The application of the 2nd-FASAM-NODE methodology will be illustrated using the Nordheim–Fuchs phenomenological model for reactor safety, which describes a short-time self-limiting power transient in a nuclear reactor system having a negative temperature coefficient in which a large amount of reactivity is suddenly inserted. The representative model responses that will …

Introducing The Second-Order Features Adjoint Sensitivity Analysis Methodology For Neural Ordinary Differential Equations—I: Mathematical Framework, Dan Gabriel Cacuci

Faculty Publications

This work introduces the mathematical framework of the novel “First-Order Features Adjoint Sensitivity Analysis Methodology for Neural Ordinary Differential Equations” (1st-FASAM-NODE). The 1st-FASAM-NODE methodology produces and computes most efficiently the exact expressions of all of the first-order sensitivities of NODE-decoder responses with respect to the parameters underlying the NODE’s decoder, hidden layers, and encoder, after having optimized the NODE-net to represent the physical system under consideration. Building on the 1st-FASAM-NODE, this work subsequently introduces the mathematical framework of the novel “Second-Order Features Adjoint Sensitivity Analysis Methodology for Neural Ordinary Differential Equations (2nd-FASAM-NODE)”. The 2nd-FASAM-NODE methodology efficiently computes the exact expressions …

Impact Of Vaporization On Drop Aerobreakup, B. Boyd, S. Becker, Yue Stanley Ling

Faculty Publications

Aerodynamic breakup of vaporizing drops is commonly seen in many spray applications. While it is well known that vaporization can modulate interfacial instabilities, the impact of vaporization on drop aerobreakup is poorly understood. Detailed interface-resolved simulations were performed to systematically study the effect of vaporization, characterized by the Stefan number, on the drop breakup and acceleration for different Weber numbers and density ratios. It is observed that the resulting asymmetric vaporization rates and strengths of Stefan flow on the windward and leeward sides of the drop hinder bag development and prevent drop breakup. The critical Weber number thus generally increases …

Influence Of Redox Engineering On The Trade-Off Relationship Between Thermopower And Electrical Conductivity In Lanthanum Titanium Based Transition Metal Oxides, Mohammad El Loubani, Gene Yang, Seyed Morteza Taghavi Kouzehkanan, Tae-Sik Oh, Santosh Kiran Balijepalli, Dongkyu Lee

Faculty Publications

Discovery of new materials plays a critical role in developing advanced high-temperature thermoelectric (TE) applications. Transition metal oxides (TMOs) are one of the attractive candidates for high-temperature TE applications due to their thermal and chemical stability. However, the trade-off relationship between thermopower (S) and electrical conductivity (σ) limits the maximum attainable power factor (PF), thereby hindering improvements in TE conversion efficiency. To overcome this trade-off relationship, the emerging approach of the redox-driven metal exsolution in TMOs shows promise in improving both S and σ. However, the effect of metal exsolution with different particle sizes and …

In Situ Assembly Enabling Adhesive-Free Bonding Of Large Area Electronic Sensors To Concrete For Structural Health Monitoring, Emmanuel Ogunniyi, Han Liu, Austin Downey, Simon Laflamme, Caroline Bennett, William Collins, Hongki Jo, Paul Ziehl

Faculty Publications

Cracks developed in concrete infrastructure are one of the primary mechanisms that degrade their structural integrity, which may result in structural failures. Previous research on soft elastomeric capacitors (SEC) has shown their viability for structural health monitoring of structural materials, including concrete, steel, and fiberglass composites. The SEC, or its derivative version with a corrugated geometry termed corrugated SEC or cSEC, is a parallel plate capacitor. Prior work demonstrated that it was possible to directly paint the electrode interfacing with the structural material onto the structure and adhere the rest of the pre-fabricated sensor onto the wet interface, thereby eliminating …

Boosting Steam Tolerance And Electrochemical Performance Of An La0.6Sr0.4Co0.2,Fe0.8O3− Δ-Based Air Electrode For Protonic Ceramic Electrochemical Cells, Lei Wu, Jiqiang Sun, Huiyang Qi, Baofeng Tu, Chunyan Xiong, Fanglin Chen, Peng Qiu

Faculty Publications

La_0.6Sr_0.4Co_0.2Fe_0.8O_3−δ (LSCF) is the state-of-the-art air electrode material for solid oxide electrochemical cells using oxide-ion electrolytes, yet its application in proton ceramic electrochemical cells (PCCs) remains limited, mainly attributed to its instability under operating conditions of high temperature and high humidity. To address this issue, coating a PrCoO_3−δ (PCO) catalyst onto the LSCF scaffold has been evaluated in this study. The introduction of the PCO coating not only enhances the LSCF electrode's electrochemical performance but also significantly improves its steam tolerance by preventing direct contact between steam and …

First-Order Comprehensive Adjoint Sensitivity Analysis Methodology For Neural Ordinary Differential Equations: Mathematical Framework And Illustrative Application To The Nordheim–Fuchs Reactor Safety Model, Dan Gabriel Cacuci

Faculty Publications

This work introduces the mathematical framework of the novel “First-Order Comprehensive Adjoint Sensitivity Analysis Methodology for Neural Ordinary Differential Equations” (1st-CASAM-NODE) which yields exact expressions for the first-order sensitivities of NODE decoder responses to the NODE parameters, including encoder initial conditions, while enabling the most efficient computation of these sensitivities. The application of the 1st-CASAM-NODE is illustrated by using the Nordheim–Fuchs reactor dynamics/safety phenomenological model, which is representative of physical systems that would be modeled by NODE while admitting exact analytical solutions for all quantities of interest (hidden states, decoder outputs, sensitivities with respect to all parameters and initial conditions, …

Enhancing Crossflow Dynamics Through The Gas Injection From Multiple Cylinders, Sahrish B. Naqvi, Sadia Siddiqa, Maciej Matyka, Rama S. R. Gorla, Md. Mamum Molla

Faculty Publications

We investigate unsteady, two-dimensional laminar fluid flow around cylinders, focusing on understanding the impact of injecting methane gas through two diametrically opposite arcs on the cylinder in the crossflow of the second fluid. This study encompasses applications in mixing and dispersion, which are crucial in various technological and natural processes. Our analysis addresses velocity field’s contribution to the spatiotemporal distribution of transported quantities. We observed that mixing induces a transition from laminar to turbulent flow. Depending on the injected-to-crossflow velocity ratios, the wake vortices downstream of cylinder arrays separate from or connect to the injected gas. This phenomenon significantly impacts …

Effects Of Fluid Slip On Heat Transfer In The Thin Film Region In A Microchannel, Rama S. R. Gorla, John Brewer, Abdeel Roman

Faculty Publications

A theoretical study was undertaken to investigate the influence of interfacial slip on evaporation of a thin liquid film in a microfluidic channel. The disjoining pressure and the capillary force which drive the liquid flow at the liquid-vapor interface in thin film region are adopted. The evaporating thin film region is an extended meniscus beyond the apparent contact line at a liquid/solid interface. Thin film evaporation plays a key role in a highly efficient heat pipe. Slip length was found to affect the heat transfer in the microchannel by altering the thin film geometry.

Review Of Fourth-Order Predictive Modeling And Illustrative Application To A Nuclear Reactor Benchmark. I. Typical High-Order Sensitivity And Uncertainty Analysis, Dan Gabriel Cacuci, Ruixian Fang

Faculty Publications

This work (in two parts) will review the recently developed predictive modeling methodology called “4th-BERRU-PM” and its applicability to nuclear energy systems as exemplified by an illustrative application to the Polyethylene-Reflected Plutonium (acronym: PERP) OECD/NEA reactor physics benchmark. The acronym 4th-BERRU-PM designates the “Fourth-Order Best-Estimate Results with Reduced Uncertainties Predictive Modeling” methodology, which uses the Maximum Entropy (MaxEnt) principle to incorporate fourth-order experimental and computational information, including fourth (and higher) order sensitivities of computed model responses to model parameters, while yielding best-estimate results with reduced uncertainties for the first fourth-order moments (mean values, covariance, skewness, and kurtosis) of the optimally …

Transient Heat Transfer To Rolling Or Sliding Drops On Inclined Heated Superhydrophobic Surfaces, Joseph Furner, Daniel Maynes, Brian D. Iverson, Julie Crockett

Faculty Publications

The thermal transport to drops that roll or slide down heated superhydrophobic surfaces is explored. High-speed infrared imaging is performed to provide time-resolved measurement of the heat transfer to the drop. Data are obtained for drops moving along smooth hydrophobic and structured superhydrophobic surfaces. Both post and rib style structures with surface solid fractions ranging from 0.06 to 1.0 are considered. The inclination angle of the surfaces was varied from 10 deg to 25 deg, and the drop volume was varied from 12 to 40 µL. The measurements reveal that the drop speed is a strong function of both the …

Trajectory Optimization Of Evtol And Conventional Aircraft: A Comparative Analysis Of Vortex Particle Method And Vortex Lattice + Blade Element Momentum Theory, Andrew Tagg, Ryan Anderson, Cibin Joseph, Andrew Ning

Faculty Publications

Trajectory optimization of aircraft transition maneuvers can significantly influence the design of these systems, particularly when making decisions about aircraft geometry, propulsion sizing, and control system design. This paper presents the trajectory optimization of air vehicles including electric vertical takeoff and landing (eVTOL) as well as conventional aircraft. The study evaluates the influence of fidelity in trajectory design by comparing the use of two aerodynamic methods in the context of trajectory optimization. The mid-fidelity method utilizes a vortex lattice method (VLM) to model lifting surfaces while employing blade element momentum theory (BEMT) to model rudimentary rotor-wing interactions. The high-fidelity approach …

Geometrically Exact Beam Theory For Gradient-Based Optimization, Taylor Mcdonnell, Andrew Ning

Faculty Publications

Decades of research have progressed geometrically exact beam theory to the point where it is now an invaluable resource for analyzing and modeling highly flexible slender structures. Large-scale optimization using geometrically exact beam theory remains nontrivial, however, due to the inability of gradient-free optimizers to handle large numbers of design variables in a computationally efficient manner and the difficulties associated with obtaining smooth, accurate, and efficiently calculated design sensitivities for gradient-based optimization. To overcome these challenges, this paper presents a finite-element implementation of geometrically exact beam theory which has been developed specifically for gradient-based optimization. A key feature of this …

Derivative Propagation Through Vortex Particle Method Simulation, Eric Green, Andrew Ning

Faculty Publications

Automatic differentiation (AD) is a powerful tool for evaluating numerical derivatives. In particular, reverse-mode AD provides numerical gradients in a way that is insensitive to the number of input variables. This makes reverse-mode AD well-suited for solving large optimization problems. However, reverse-mode AD has a particularly large associated memory cost because most intermediate values in operations need to be cached. This is problematic for large problems such as aerodynamics simulations, though, since the memory requirements can quickly become impractical. The solution implemented in this work is to provide analytic pullback expressions for functions for which many of the intermediate values …

Ductape: A Steady-State, Axisymmetric Ducted Fan Analysis Code Designed For Gradient-Based Optimization, Judd Mehr, Andrew Ning

Faculty Publications

Electric ducted fans have become an intriguing option for the propulsion systems of clean, quiet advanced air mobility technologies due to their potential benefits in both aerodynamic efficiency and reduced noise profiles compared to open rotor systems. Exploration of conceptual electric ducted fan design in the context of novel, and often complex, applications may be greatly aided by the use of optimization techniques. Specifically, gradient-based optimization lends itself to the exploration of large, complex, multi-disciplinary systems due to its inherent scalability. Despite ducted fans/propellers having been relatively well studied for the last century, modern, gradient-based, optimization-ready analysis tools for ducted …

Solving Unsteady Potential Flow Problems In O(N) Time, Ryan Anderson, Andrew Ning

Faculty Publications

Design of vertical takeoff and landing aircraft is challenging in part due to significant aerodynamic interactions between rotors and wings. Computational models can aid in their design, but are computationally expensive. 3-D panel methods coupled with vortex particle wakes offer an attractive solution, but solving for the panel strengths scales poorly for large problems. Multigrid methods, such as Krylov subspace methods in conjunction with the fast multipole method (FMM), have been demonstrated to reduce the scaling to O(𝑁). We explore the performance and limitations of the Krylov-FMM method, traditional matrix-powered GMRES, LU decomposition, and a novel O(𝑁) multigrid approach to …

Correction: Graph Theory And Graph Neural Network Assisted High-Throughput Crystal Structure Prediction And Screening For Energy Conversion And Storage, Joshua Ojih, Mohammed Al-Fahdi, Yagang Yao, Jianjun Hu, Ming Hu

Faculty Publications

Correction for ‘Graph theory and graph neural network assisted high-throughput crystal structure prediction and screening for energy conversion and storage’ by Joshua Ojih et al., J. Mater. Chem. A, 2024, 12, 8502–8515, https://doi.org/10.1039/D3TA06190F.

On page 8511 in section 3.2 of the published article, the text “The single values of bonding and antibonding for each structure are obtained by performing integration over COHP curves for each atomic pair as evaluated by the LOBSTER package” should have included citations to six references. The missing references are listed below as ref. 1–6.

The Royal Society of Chemistry apologises for …

A Redox-Reversible A/B-Site Co-Doped Bafeo3 Electrode For Direct Hydrocarbon Solid Oxide Fuel Cells, Haixia Li, Wanhua Wang, Kai Zhao, Ka-Young Park, Taehee Lee, Ramin Babazadeh Dizaj, Andreas Heyden, Dong Ding, Fanglin Chen

Faculty Publications

Solid oxide fuel cells (SOFCs) can directly convert the chemical energy in fuel to electrical energy with fuel flexibility; however, the conventional nickel-based anodes face great challenges due to coking upon direct oxidation of hydrocarbon fuels and redox instability. Thus, developing new anode materials which can provide high coking resistance as well as redox stability is crucial. In this work, Ba_0.6La_0.4Fe_0.8Mo_0.1Ni_0.1O_3−δ (BLFMN) has been synthesized in air using a sol–gel combustion method, resulting in a dual phase consisting of a cubic BLFMN main phase and scheelite BaMoO_{4 …}