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Full-Text Articles in Mechanical Engineering

Ndt And Shm Methods Of Damage Detection In Welded Structures, Saad Mohammed Jan 2016

Ndt And Shm Methods Of Damage Detection In Welded Structures, Saad Mohammed

Theses and Dissertations

There has been an increasing demand for Nondestructive Testing (NDT) and Structural Health Monitoring (SHM) techniques to continuously monitor during all processes of a structure to prevent catastrophic failure and reduce maintenance costs. NDT and SHM are inspection processes which form part of the quality assurance/quality control (QA/QC) scheme. Among NDT and SHM methods, ultrasonic and guided wave techniques are the most commonly and widely used in industry. Ultrasonic methods provide the advantage of accurately locating and dimensioning defects within structures. Most of these structures consist of welded joints because welding is an economical and efficient method for obtaining a …


Effects Of Process Variants On Metallurgical And Mechanical Properties In Friction Stir Welding Of Aluminum Alloys, Xiaomin Huang Jan 2016

Effects Of Process Variants On Metallurgical And Mechanical Properties In Friction Stir Welding Of Aluminum Alloys, Xiaomin Huang

Theses and Dissertations

Conventional shoulder friction stir welding (CSFSW) produces uneven heat input through welded material thickness: higher close to the top and lower close to the bottom. When CSFSW is applied on certain aluminum alloys, such as 7xxx and 2xxx series high strength aluminum alloys which contain low melting point intermetallic, overheating and local melting may happen close to weld crown. Stationary shoulder friction stir welding (SSFSW) may generate much more uniform heat input through plate thickness than CSFSW due to the non-rotating shoulder and rotating pin. Therefore, overheating and local melting are expected to be avoided in SSFSW. Furthermore, local properties …


Numerical Studies Of Arterial Tissue Failure, Xiaochang Leng Jan 2016

Numerical Studies Of Arterial Tissue Failure, Xiaochang Leng

Theses and Dissertations

Arterial tissue failure leads to a number of potentially life-threatening clinical conditions, such as atherosclerotic plaque rupture and aortic dissection which develop unpredictably and rapidly in vivo. Thus, a full understanding of the two conditions will provide a solid basis for medical advances in the intervention and prevention of the occurrence of this life-threatening event. The present work aims to develop a cohesive zone model (CZM) approach for analysis and simulation of arterial tissue failure, such as plaque and fibrous cap delamination and tearing, and to validate simulation predictions with experimental results.

To characterize the hysteresis phenomenon of diseased aortic …


Nano Oil Additives And Their Effect On Uh-60 Auxiliary Power Unit Performance, James Patrick Folk Jan 2016

Nano Oil Additives And Their Effect On Uh-60 Auxiliary Power Unit Performance, James Patrick Folk

Theses and Dissertations

This study is designed to research the tribological properties of nano oils developed by NanoPro MT and to determine their effects on fuel consumption in an UH-60 Blackhawk Auxiliary Power Unit (APU). For this work, two different nano oils were tested and compared against the performance of conventional oil. The first nano oil mixture contains proprietary nanodiamond particles and the second nano oil contains a mix of zinc sulfide, boron nitride, and graphene particles. Aeroshell 560 was used as the conventional oil and was blended with the nano particles to create both nano oils. This oil meets the military specifications …


Studies Of Asphalt Roofing Sealant Failure For Shingle Systems Subjected To High Wind Conditions For Both Elastic And Viscoelastic Sealant Material Response, Artem Aleshin Jan 2016

Studies Of Asphalt Roofing Sealant Failure For Shingle Systems Subjected To High Wind Conditions For Both Elastic And Viscoelastic Sealant Material Response, Artem Aleshin

Theses and Dissertations

It has been documented that the sealant between asphalt roof shingles may delaminate at significantly lower wind speeds than those for which they are rated, with major consequences on safety and repair costs. In perspective, developing more resilient material systems and devising more effective installation procedures are sensible strategies to mitigate this problem. A practical approach may also entail adding a second self-sealing strip. In the first portion of this thesis, the elastic structural response of an asphalt roof shingle-sealant system consisting of individual three-tab shingles, which are bonded to the underlying shingles with two sealant strips and are subjected …


Estimation Of Basic And Mission Benefit Of Condition-Based Maintenance Deployment In Hums Equipped Ah-64 Aircraft Using Nlp And Regression Analysis, Tanzina Zaman Jan 2016

Estimation Of Basic And Mission Benefit Of Condition-Based Maintenance Deployment In Hums Equipped Ah-64 Aircraft Using Nlp And Regression Analysis, Tanzina Zaman

Theses and Dissertations

Condition-based maintenance (CBM) is a maintenance practice that involves regular monitoring of the mechanical condition of components of interest, processing of information collected, and then decision-making to ensure both maximizing the time interval between repairs and minimizing the number of unscheduled failures. CBM also offers early detection of failure which can prevent major breakdowns and repairs. Vibration monitoring is one of the effective techniques for condition monitoring. Health and Usage Monitoring System (HUMS) is a powerful tool for aviation industry which monitors health status and trending data. Vibration Monitoring Unit (VMU) and Modernized Signal Processing Unit (MSPU) are two forms …


Physics Based Modeling Of Guided Waves For Detection And Characterization Of Structural Damage In Nde And Shm, Banibrata Poddar Jan 2016

Physics Based Modeling Of Guided Waves For Detection And Characterization Of Structural Damage In Nde And Shm, Banibrata Poddar

Theses and Dissertations

Guided waves based damage detection techniques are popular for their ease of generation and detection along with their ability to travel long distances. Accurate and efficient modeling is a key for successful implementation of guided waves for NDE/SHM. However, efficient prediction of scattering from various damage is challenging due to the complex nature of these guided waves.

This dissertation presents as physics based efficient and accurate modeling techniques to predict ultrasonic wave propagation and their interaction with various damage. Detection and characterization of damage in structures can typically be divided into two categories, active and passive. This research is aimed …


A Multiphysics Modeling Of Solid Oxide Metal-Air Redox Battery, Md Ahsan Uddin Dec 2015

A Multiphysics Modeling Of Solid Oxide Metal-Air Redox Battery, Md Ahsan Uddin

Theses and Dissertations

Cost-effective and large scale energy storage is essential for the growth of the future’s ‘‘green energy’’ infrastructure. Among the energy storage technologies currently being used, rechargeable batteries represent a class of advanced electrical energy storage (EES) mechanisms that can be valuable for the future renewable integration and smart grid. Rechargeable batteries have innumerous advantages over the conventional pumped hydro and compressed-air energy storage system. Now days, There are various types of rechargeable batteries available to work as an energy storage device in a smart grid but it still needs many breakthroughs to become commercially viable for stationary energy storage. First …


Bio-Inspired Design Of Mechanical Band Pass Sensor With The Ability To Scavenge Energy, Md Riaz Uddin Ahmed Dec 2015

Bio-Inspired Design Of Mechanical Band Pass Sensor With The Ability To Scavenge Energy, Md Riaz Uddin Ahmed

Theses and Dissertations

Primary objective of this work is to introduce the multi-scale computational model for the bio-inspired acousto-ultrasonic band pass sensor that are capable of mechanically sense and/or filter wide range user defined frequencies. Selecting a particular and/or a distinct band of frequencies is essential for many applications in science engineering and technologies. For example design of sensors in chemical, biomedical and biological applications; device application for acoustic modulation by breaking the acoustic reciprocity and the sensors used in precision manufacturing applications requires sensing and/or filtering of wide range of acousto-ultrasonic frequencies. Presently, electronic devices are widely employed in commercial applications for …


Wavelet Analysis Of Periodic Error In Heterodyne Interferometry, Chao Lu Dec 2015

Wavelet Analysis Of Periodic Error In Heterodyne Interferometry, Chao Lu

Theses and Dissertations

Heterodyne displacement measuring interferometry provides important metrology for applications requiring high resolution and accuracy. Heterodyne Michelson interferometers use a two-frequency laser source and separate the two optical frequencies into one fixed length and one variable length path via polarization. Ideally these two beams are linearly polarized and orthogonal so that only one frequency is directed toward each path. An interference signal is obtained by recombining the light from the two paths; this results in a measurement signal at the heterodyne (split) frequency of the laser source. This measurement signal is compared to the optical reference signal. Motion in the measurement …


Guided Wave Based Integrated Structural Health Monitoring And Nondestructive Evaluation, Zhenhua Tian Dec 2015

Guided Wave Based Integrated Structural Health Monitoring And Nondestructive Evaluation, Zhenhua Tian

Theses and Dissertations

Damage detection and health monitoring are critical for ensuring the structural safety in various fields, such as aerospace, civil and nuclear engineering. Structural health monitoring (SHM) performs online nondestructive evaluation (NDE) and can predict the structural remaining life through appropriate diagnosis and prognosis technologies. Among various SHM/NDE technologies, guided ultrasonic waves have shown great potential for fast and large area SHM/NDE, due to their sensitivity to small defects and capability to propagate long distances. Recent advances in guided wave based SHM/NDE technologies have demonstrated the feasibility of detecting damage in simple structures such as metallic plates and pipes. However, there …


Size-Controlled Large-Diameter And Few-Walled Carbon Nanotube Catalysts For Oxygen Reduction, Xianliang Wang, Qing Li, Hengyu Pan, Ye Lin, Yujie Ke, Haiyang Sheng, Mark T. Swihart, Gang Wu Nov 2015

Size-Controlled Large-Diameter And Few-Walled Carbon Nanotube Catalysts For Oxygen Reduction, Xianliang Wang, Qing Li, Hengyu Pan, Ye Lin, Yujie Ke, Haiyang Sheng, Mark T. Swihart, Gang Wu

Faculty Publications

We demonstrate a new strategy for tuning the size of large-diameter and few-walled nitrogen-doped carbon nanotubes (N-CNTs) from 50 to 150 nm by varying the transition metal (TM = Fe, Co, Ni or Mn) used to catalyze graphitization of dicyandiamide. Fe yielded the largest tubes, followed by Co and Ni, while Mn produced a clot-like carbon morphology. We show that morphology is correlated with electrocatalytic activity for the oxygen reduction reaction (ORR). A clear trend of Fe > Co > Ni > Mn for the ORR catalytic activity was observed, in both alkaline media and more demanding acidic media. The Fe-derived N-CNTs exhibited …


Electrochemical Capture Of Co2 From Natural Gas Using A High-Temperature Ceramic-Carbonate Membrane, Jingjing Tong, Lingling Zhan, Jie Fang, Minfang Han, Kevin Huang Jan 2015

Electrochemical Capture Of Co2 From Natural Gas Using A High-Temperature Ceramic-Carbonate Membrane, Jingjing Tong, Lingling Zhan, Jie Fang, Minfang Han, Kevin Huang

Faculty Publications

This study reports the first investigation of using a ceramic-carbonate dual-phase membrane to electrochemically separate CO2 from a simulated natural gas. The CO2 permeation flux density was systematically studied as a function of temperature, CO2 partial pressure and time. As expected, the flux density was observed to increase with temperature and CO2 partial pressure. Long-term stability test showed that flux density experienced an initial performance-improving “break-in” period followed by a slow decay. Post-test microstructural analysis suggested that a gradual loss of carbonate during the test could be the cause of the flux-time behavior observed.


Quantification Of The Effect Of Tool Geometric Features On Aspects Of Friction Stir Welding, Md. Reza-E-Rabby Jan 2015

Quantification Of The Effect Of Tool Geometric Features On Aspects Of Friction Stir Welding, Md. Reza-E-Rabby

Theses and Dissertations

In the friction stir welding (FSW) process, tool stirring and synchronized movement of the weld materials along a pre-existing seam line causes thermal gradients and severe plastic deformation resulting in the bonding of the adjacent materials. For a given set of welding parameters, tool pin geometries (dimensions, shape) and vertical/helical features that dictate the material motion also have significant effects on process response variables during FSW. Among the primary process controlling parameters in FSW, tool pin geometry and feature vary multifariously in terms of shape, dimensions, feature insertion technique depending on the weld material and application of joint. The current …


Design Of Experiments Analysis Of Non-Standard Inputs For The Optimization Of Friction Stir Welding, Ryan Widejko Jan 2015

Design Of Experiments Analysis Of Non-Standard Inputs For The Optimization Of Friction Stir Welding, Ryan Widejko

Theses and Dissertations

The purpose of this study was to use non-standard Design of Experiments (DoE) inputs in Friction Stir Welding (FSW) to deduce relationships between various weld input and response variables. Typically, inputs for FSW DoE are tool rotational speed, welding speed and forge force. In this study, three different input factors were investigated: travel speed, thermal boundary conditions (TBC), and advance per revolution (APR). The experimental design included a full factorial with each factor at two levels plus two centerpoint runs. Response variables included weld temperature, microstructure, hardness, power, weld energy, and in plane forces.

An investigation of the effect of …


Methods For Determining Grease Service Levels In An Ah-64d Intermediate Gearbox Using On-Board Sensors, Travis Steven Edwards Jan 2015

Methods For Determining Grease Service Levels In An Ah-64d Intermediate Gearbox Using On-Board Sensors, Travis Steven Edwards

Theses and Dissertations

The intermediate gearbox (IGB) on the AH-64D was chosen as the subject for this study based on the persistent grease leaks that require grounding aircraft. The aircraft is not currently equipped with a method of detecting grease loss during flight, so techniques for analyzing the usefulness of old metrics and possible new techniques can be tested. The main objective of this study is to use the aircraft’s on-board sensors to develop a method of determining the lubrication level of the IGB. Currently, the most reliable method for detecting a fault on the aircraft is through the use of vibration-based condition …


Fabrication And Characterization Of Anode-Supported Micro-Tubular Solide Oxide Fuel Cell By Phase Inversion Method, Cong Ren Jan 2015

Fabrication And Characterization Of Anode-Supported Micro-Tubular Solide Oxide Fuel Cell By Phase Inversion Method, Cong Ren

Theses and Dissertations

Nowadays, the micro-tubular solid oxide fuel cells (MT-SOFCs), especially the anode supported MT-SOFCs have been extensively developed to be applied for SOFC stacks designation, which can be potentially used for portable power sources and vehicle power supply. To prepare MT-SOFCs with high electrochemical performance, one of the main strategies is to optimize the microstructure of the anode support. Recently, a novel phase inversion method has been applied to prepare the anode support with a unique asymmetrical microstructure, which can improve the electrochemical performance of the MT-SOFCs. Since several process parameters of the phase inversion method can influence the pore formation …


Predictive Methods For End Of Life Prognosis In Composites, Vamsee Vadlamudi Jan 2015

Predictive Methods For End Of Life Prognosis In Composites, Vamsee Vadlamudi

Theses and Dissertations

The long-term properties of continuous fiber reinforced composite materials are increasingly important as applications in airplanes, cars, and other safety critical structures are growing rapidly. The mechanical, electrical, and thermal properties of composite materials are altered by the initiation and accumulation of discrete fracture events whose distribution and eventual interaction defines the limits of design, such as strength and life. There is a correlation that exists between the long term behavior of those materials under combined mechanical, thermal, and electrical fields, and the functional properties and characteristics of the composite materials that requires a fundamental understanding of the material state …


La0.7Sr0.3Fe0.7Ga0.3O3-Δ As Electrode Material For A Symmetrical Solid Oxide Fuel Cell, Zhibin Yang, Yu Chen, Chao Jin, Guoliang Xiao, Minfang Han, Fanglin Chen Jan 2015

La0.7Sr0.3Fe0.7Ga0.3O3-Δ As Electrode Material For A Symmetrical Solid Oxide Fuel Cell, Zhibin Yang, Yu Chen, Chao Jin, Guoliang Xiao, Minfang Han, Fanglin Chen

Faculty Publications

In this research, La0.7Sr0.3Fe0.7Ga0.3O3−δ (LSFG) perovskite oxide was successfully prepared using a microwave-assisted combustion method, and employed as both anode and cathode in symmetrical solid oxide fuel cells. A maximum power density of 489 mW cm−2 was achieved at 800 °C with wet H2 as the fuel and ambient air as the oxidant in a single cell with the configuration LSFG|La0.8Sr0.2Ga0.83Mg0.17O3−δ|LSFG. Furthermore, the cells demonstrated good stability in H2 and acceptable sulfur tolerance.


Stabilizing Electrochemical Carbon Capture Membrane With Al2O3 Thin-Film Overcoating Synthesized By Chemical Vapor Deposition, Jingjing Tong, Fengzhan Si, Lingling Zhang, Jie Fang, Minfang Han, Kevin Huang Jan 2015

Stabilizing Electrochemical Carbon Capture Membrane With Al2O3 Thin-Film Overcoating Synthesized By Chemical Vapor Deposition, Jingjing Tong, Fengzhan Si, Lingling Zhang, Jie Fang, Minfang Han, Kevin Huang

Faculty Publications

Development of high-efficiency and cost-effective carbon capture technology is a central element of our effort to battle the global warming and climate change. Here we report that the unique high-flux and high-selectivity of electrochemical silver-carbonate dual-phase membranes can be retained for an extended period of operation by overcoating the surfaces of porous silver matrix with a uniform layer of Al2O3 thin-film derived from chemical vapor deposition.


La0.6Sr1.4Mno4+Δ Layered Perovskite Oxide: Enhanced Catalytic Activity For The Oxygen Reduction Reaction, Yarong Wang, Zhibin Yang, Fanliang Liu, Chao Jin, Jiao Wu, Ming Shen, Ruizhi Yang, Fanglin Chen Jan 2015

La0.6Sr1.4Mno4+Δ Layered Perovskite Oxide: Enhanced Catalytic Activity For The Oxygen Reduction Reaction, Yarong Wang, Zhibin Yang, Fanliang Liu, Chao Jin, Jiao Wu, Ming Shen, Ruizhi Yang, Fanglin Chen

Faculty Publications

Efficient electrocatalysts for the oxygen reduction reaction (ORR) is a critical factor to influence the performance of lithium–oxygen batteries. In this study, La0.6Sr1.4MnO4+δ layered perovskite oxide as a highly active electrocatalyst for the ORR has been prepared, and a carbon-coating layer with thickness <5 nm has been successfully introduced to enhance the electronic conductivity of the as-prepared oxide. XRD, XPS, Raman, SEM and TEM measurements were carried out to characterize the crystalline structure and morphology of these samples. Rotating ring-disk electrode (RRDE) technique has been used to study catalytic activities of the as-prepared catalysts for the ORR in 0.1 M KOH media. RRDE results reveal that carbon-coated La0.6Sr1.4MnO4+δ exhibits better catalytic activity for the ORR. For the carbon-coated La0.6Sr1.4MnO4+δ, the ORR proceeds predominately via a direct four electron process, and a maximum cathodic current density of 6.70 mA cm−2 at 2500 rpm has been obtained, …


A Reversible And Stable Flake-Like Licoo2 Cathode For Lithium Ion Batteries, Tao Wei, Rui Zeng, Yongming Sun, Yunhui Huang, Kevin Huang Dec 2014

A Reversible And Stable Flake-Like Licoo2 Cathode For Lithium Ion Batteries, Tao Wei, Rui Zeng, Yongming Sun, Yunhui Huang, Kevin Huang

Faculty Publications

A dense and thick flake-like cathode structure was demonstrated to have a preferential crystallographic orientation for Li+ migration and a better tolerance to cracking, both of which enable a reversible and stable capacity at moderate rates from 0.1 to 2 C.


Fabrication And Characterization Of Novel Electrodes For Solid Oxide Fuel Cell For Efficient Energy Conversion, Yu Chen Dec 2014

Fabrication And Characterization Of Novel Electrodes For Solid Oxide Fuel Cell For Efficient Energy Conversion, Yu Chen

Theses and Dissertations

Solid oxide fuel cells (SOFCs) have been considered as one of the most promising technologies for future energy conversion since they can in principle be operated with fuels ranging from H2 to any hydrocarbon fuel. However, the system cost and coking (when using hydrocarbon as fuel) issues for the state-of-art electrode materials/designs often limit their further application. The objective of this Ph.D dissertation is aiming at overcoming these problems and accelerating SOFC commercialization. One approach to cost reduction is lowering the SOFC operating temperature to below 800 or even 600 oC, so that inexpensive materials can be used and quick …


Low Reynolds Number Turbulence: Mechanisms And Applications, Wei Zhao Dec 2014

Low Reynolds Number Turbulence: Mechanisms And Applications, Wei Zhao

Theses and Dissertations

Turbulence, as one of "the most important unsolved classical problem in physics" (R. Feynman, 1932), has been investigated for more than 130 years. Conventionally, turbulence is believed to be a phenomenon of high Reynolds numbers (Re). However, we find that turbulence can also be achieved at low Re by proper external forcing, either in macroflows or in microflows. In macroflows, the characteristics of high Re turbulence can be achieved in confined flows, when the bulk flow Re is around 400, by external forcing at its optimal frequency (Wang 2003; Wang 2006). Interestingly, the optimal narrow band of frequency is fixed …


Applications Of Advanced Imaging Methods: Macro-Scale Studies Of Woven Composites And Micro-Scale Measurements On Heated Ic Packages, Siming Guo Dec 2014

Applications Of Advanced Imaging Methods: Macro-Scale Studies Of Woven Composites And Micro-Scale Measurements On Heated Ic Packages, Siming Guo

Theses and Dissertations

As a representative advanced imaging technique, the digital image correlation (DIC) method has been well established and widely used for deformation measurements in experimental mechanics. This methodology, both 2D and 3D, provides qualitative and quantitative information regarding the specimen’s non-uniform deformation response. Its full-field capabilities and non-contacting approach are especially advantageous when applied to heterogeneous material systems such as fiber-reinforced composites and integrated chip (IC) packages. To increase understanding of damage evolution in advanced composite material systems, a series of large deflection bending-compression experiments and model predictions have been performed for a woven glass-epoxy composite material system. Stereo digital image …


Behavior Of Piezoelectric Wafer Active Sensor In Various Media, Tuncay Kamas Dec 2014

Behavior Of Piezoelectric Wafer Active Sensor In Various Media, Tuncay Kamas

Theses and Dissertations

The dissertation addresses structural health monitoring (SHM) techniques using ultrasonic waves generated by piezoelectric wafer active sensors (PWAS) with an emphasis on the development of theoretical models of standing harmonic waves and guided waves. The focal objective of the research is to extend the theoretical study of electro-mechanical coupled PWAS as a resonator/transducer that interacts with standing and traveling waves in various media through electro-mechanical impedance spectroscopy (EMIS) method and guided wave propagation. The analytical models are developed and the coupled field finite element analysis (CF-FEA) models are simulated and verified with experiments. The dissertation is divided into two parts …


Cost Avoidance Analysis Of Military Aircraft Components Utilizing Condition-Based Maintenance Practices, Erin Ballentine Dec 2014

Cost Avoidance Analysis Of Military Aircraft Components Utilizing Condition-Based Maintenance Practices, Erin Ballentine

Theses and Dissertations

This research involves two major case studies. Both look at the current maintenance practices done by the United States Army and propose a solution for improvement utilizing condition-based maintenance (CBM) practices. Each study details a cost avoidance that can be earned by implementing the solutions and the resulting benefits that can be experienced. Case Study I is a return on investment (ROI) that analyzes the benefits of the implementation of elastomeric wedges as vibration control on the Apache (AH-64D) aircraft. Analysis of the material and operational costs shows that the use of self-adhering elastomeric trailing edge wedges on the Apache …


On The Development Of High Strain Rate Experiments For The Characterization Of Engineering Materials, Silas P. Mallon Dec 2014

On The Development Of High Strain Rate Experiments For The Characterization Of Engineering Materials, Silas P. Mallon

Theses and Dissertations

In order to predict the damage accumulation and failure processes associated with highly dynamic events such as blast loading, shock wave loading, and ballistic impact loading, a commensurate understanding of the fundamental constitutive and fracture behavior of materials subjected to such high rate loading conditions is necessary. In this effort, high strain rate experimental facilities consisting of a shock tube apparatus and a torsional split Hopkinson bar apparatus have been designed, constructed, and subsequently used to investigate the mechanical properties of an array of engineering materials subjected to a variety of dynamic loading conditions. Designs for the experimental equipment utilized …


Direct Synthesis Of Methane From Co2-H2O Co-Electrolysis In Tubular Solid Oxide Electrolysis Cells, Long Chen, Fanglin Chen, Changrong Xia Dec 2014

Direct Synthesis Of Methane From Co2-H2O Co-Electrolysis In Tubular Solid Oxide Electrolysis Cells, Long Chen, Fanglin Chen, Changrong Xia

Faculty Publications

Directly converting CO2 to hydrocarbons offers a potential route for carbon-neutral energy technologies. Here we report a novel design, integrating the high-temperature CO2–H2O co-electrolysis and low-temperature Fischer–Tropsch synthesis in a single tubular unit, for the direct synthesis of methane from CO2 with a substantial yield of 11.84%.


Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang Nov 2014

Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang

Faculty Publications

Chalcopyrite CuInS2 (CIS) hierarchical structures composed of nanoflakes with a thickness of about 5 nm were synthesized by a facial solvothermal method. The thermodynamically metastable wurtzite phase CIS would be obtained by using InCl3 instead of In(NO3)3 as In precursor. The effects of the In precursor and the volume of concentrated HCl aqueous solution on the phases and morphologies of CIS nanocrystals have been systematically investigated. Experimental results indicated that the obtained phases of CIS nanocrystals were predominantly determined by precursor-induced intermediate products. The photocatalytic properties of chalcopyrite and wurtzite CIS in visible-light-driven degradation of …