Mechanical Engineering Commons^™

Nanoparticle Formation And Coating Using Supercritical Fluids, Abhijit Aniruddha Gokhale

Dissertations

Jet breakup phenomenon and nanoparticle formation

The focus of this dissertation is to study the SAS process to manufacture nanoparticles with minimum agglomeration, controlled size and size distribution. Solution jet breakup and solvent evaporation into supercritical fluid (SC CO₂) is studied using high speed charged coupled device (CCD) camera facilitated with double shot particle image veloimetry (PIV) laser and a high pressure view cell. Particles formation using SAS is studied. Polyvinylpyrrolidone (PVP) particles are formed using micron size capillary nozzles and combination of thermodynamically good and poor solvents in order to achieve nano-sized particles with reduced agglomeration and …

Investigation Of Formation And Applications Of High-Speed Liquid Projectiles, Oleg Petrenko

Dissertations

The work comprises experimental and numerical studies of generation and application of high-speed liquid projectiles. Numerical models were created for a projectile formation by two kinds of launchers, water extruder and water cannon. In the water extruder the kinetic energy of a fast moving piston is transferred to the water load and extrudes the load at a high speed. By contrast in the water cannon the water load itself accumulates the kinetic energy from the expanding combustion gasses. Then, in the course of water motion through the converging nozzle the energy is redistributed between head and tail of the projectile. …

Flow Characteristics And Phase Interactions Of Evaporating Sprays In Gas-Solid Suspensions, Muhammad Mushahid Rafique Qureshi

Dissertations

Evaporating spray jets have a wide range of applications in many industrial processes such as fluidized catalytic cracking of crude oil in petroleum refinery, coal gasification, fluidized coking to make synthetic crude oil, and condensed mode gas polymerization. The rapid evaporation of spray jets significantly affects the gas-solids mixing, solids concentration, gas/solids temperature and gas/solids velocity acceleration. The complex interactions mechanism of phase change, three phase interaction, heat and mass transfer of gas, solids and evaporating droplets dominate the process efficiency and product quality. In such three-phase flows, the phase transport characteristics are influenced by both droplet-gas interaction and droplet-solid …

Numerical Analysis Of The Operation Of A Water Cannon, Teymuraz G. Bitadze

Theses

This study was designed to investigate the operational process of a launcher for generation of high speed water projectiles, and it involved the optimization of the geometry of a launcher body. The objective of the optimization of the internal geometry was to increase the effective momentum of the projectile while the optimization of the external geometry resulted in the reduction of the mass of the launcher.

In the course of the optimization of the internal geometry the exit velocity variation was determined, and used to compute an effective projectile momentum, which actually affects a workpiece. In this research, it was …

Burmester Curve And Numerical Motion Generation Of Grashof Mechanisms With Perimeter And Transmission Angle Optimization In Mathcad, Peter J. Martin

Theses

An infinite number of planar four-bar mechanism solutions exist for a series of prescribed rigid-body positions. Given a set of Burmester curves or numerically-generated fixed and moving pivot curves, sorting through the limitless number of possible mechanism solutions to find one that ensures full link rotatibility, satisfies compactness criteria and produces feasible transmission angles can be a daunting task. In this work, two algorithms are developed and presented by which the user can select optimum planar four-bar motion generators (optimum with respect to Grashof criteria, mechanism perimeter criteria and transmission angle criteria) from a set of all mechanism solutions produced …

Constitutive Modeling Of The Thermo-Mechanics Associated With Crystallizable Shape Memory Polymers, Gautam Barot

Dissertations

This research addresses issues central to material modeling and process simulations. Here, issues related for developing constitutive model for crystallizable shape memory polymers are addressed in details. Shape memory polymers are novel material that can be easily formed into complex shapes, retaining memory of their original shape even after undergoing large deformations. The temporary shape is stable and return to the original shape is triggered by a suitable mechanism such heating the polymer above a transition temperature. Crystallizable shape memory polymers are called crystallizable because the temporary shape is fixed by a crystalline phase, while return to the original shape …

Dem Simulated Floor Pressure Induced By A Granular Column, Shawn A. Chester

Theses

At the end of the 19th century, H. A. Janssen discovered that the bottom floor pressure in a cylindrical container of granular material asymptotes exponentially to a value less than the weight of the material i.e., the pressure becomes independent of the fill height of the column. This phenomenon is investigated using discrete element simulations of inelastic, frictional spheres in a cylindrical vessel having a particle-to-cylinder diameter ratio at approximately 13.3 or 26.6, with varying bed heights in both cases. The axial pressure profile and the load experienced by a piston that is supporting the granular column are computed. In …

Effect Of Polymorphic Phase Transformations Within An Alumina Layer On The Ignition Of Aluminum Particles, Mikhaylo Aleksiyovych Trunov

Dissertations

Experimental measurements of aluminum ignition temperature and models used to describe aluminum ignition are reviewed. It is shown that the current models cannot describe ignition of aluminum powders of different sizes and ignited under various experimental conditions. The properties of and phase changes occurring in the alumina scale existing on the surface of aluminum particles at different temperatures are systematically studied. The mechanism of aluminum oxidation is quantified and a new simplified ignition model is developed.

Thermogravimetry was used to study the oxidation of aluminum powders of various particle sizes and surface morphologies in oxygen at temperatures up to 1500°C. …

Synthesis And Characterization Of Mechanically Alloyed Aluminum-Based Compounds As High Energy Density Materials, Xiaoying Zhu

Dissertations

A new type of metastable reactive powders for potential use as high energy density materials in propellants, explosives, and pyrotechnics was developed. These powders are intended to replace aluminum typically added to energetic formulations to increase reaction enthalpy and temperature. The new materials are metastable aluminum-based alloys, which enable achievement of substantially reduced ignition temperatures and accelerated bulk burn rates compared to aluminum. Titanium and lithium were used as alloying components. The materials properties and characteristics leading to their enhanced combustion performance were investigated. The powders were prepared using mechanical alloying and characterized using X-Ray Diffraction (XRD), Scanning Electron Microscopy …

Dry Magnetic Assisted Impaction Mixing Of Sub-Micron Boron And Barium Chromate For A Time Delay Composition, Ryan Barrow

Theses

The objective of this investigation is to improve the mixture homogeneity of, Boron and Barium Chromate, a delay composition called T-10, using a novel dry mixing technique, , called the Magnetic Assisted Impaction Mixing (MAIM). Two additional mixing methods, ultra-sonic mixing and shaker mixing (dry and wet), were used for comparative analysis, to evaluate the mixing effectiveness of the MAIM which was also compared to two Navy mixed T-l0 samples. Characterization of the homogeneity is described by how well boron is effectively distributed throughout the mixture, which is a challenging task since the mixture's composition is 3% Boron versus 97% …

Dynamic Simulations Of Particle Suspensions Subjected To An External Electric-Field, Xianjin Jiang

Dissertations

A numerical method is performed to study the suspension of polarizable particles in nonconductive solvents subjected to external electric fields. Such particles experience both hydrodynamic and electrostatic interactions. The hydrodynamic force acting on the particles is determined using the Stokesian dynamics method under the assumption that the Reynolds number is much smaller than 1, while the electrostatic force is determined by differentiating the electrostatic energy of the suspension, which is computed from the induced particle dipoles. In addition, the multiple image method is used to compensate for the electrostatic force when two particles are close to each other. Because the …

Modeling, Design, And Fabrication Of Pulsed Fluidic Micro-Actuators, Max Roman

Dissertations

The forced vibration of a thin flexible plate or membrane in a sealed cavity with a small opening can cause fluid to be pumped into and out-of the cavity. At particular frequencies and amplitudes of vibration, a streaming of vortex rings can occur near the orifice. These vortex rings move under their own self-induced momentum. Downstream of the opening the rings ultimately break up and can form a fully developed jet. This work is dedicated to the analysis, design, and fabrication of electrostatic micro fluidic actuators, which use the pulsing mechanism described above to generate a fluid flow. Particle Image …

The Effects Of Aging On Cardiac Mechanics, Samuel C. Lieber

Dissertations

It is well established that the aging heart exhibits left ventricular (LV) diastolic dysfunction and changes in mechanical properties, which have been attributed to alterations in the extracellular matrix (ECM). The investigators tested the hypothesis that the mechanical properties of cardiac myocytes significantly change with aging thereby contributing to the LV diastolic dysfunction. Cellular mechanical properties were determined by indenting cells with an atomic force microscope (AFM). The indentation results were interpreted by modeling the AFM probe as a blunted cone and determining an apparent elastic modulus (B) with classical infinitesimal strain theory (CIST). A commercially available finite element software …

Doppler Ultrasound Technique Used To Determine The Blood Flow Viscosity In The Middle Cerebral Artery Of A Canine Animal Model, Raj P. Ganpath

Theses

The cerebral blood flow velocity in the middle cerebral artery of an canine animal model was measured using the Doppler Ultrasound technique. A transducer was designed with a 20 MHz piezoelectric crystal and used for the application. An in vitro calibration system was designed and machined for the purpose of testing and calibrating every transducer before using it in vivo. Preliminary tests included experiments on the in vitro system and measurement of blood flow velocity in the human wrist artery (metacarpal artery). The effect of using different transmission media (agarose and gelatin) was determined through the many in vitro and …

Robust Techniques And Applications In Fuzzy Clustering, Amit Banerjee

Dissertations

This dissertation addresses issues central to frizzy classification. The issue of sensitivity to noise and outliers of least squares minimization based clustering techniques, such as Fuzzy c-Means (FCM) and its variants is addressed. In this work, two novel and robust clustering schemes are presented and analyzed in detail. They approach the problem of robustness from different perspectives. The first scheme scales down the FCM memberships of data points based on the distance of the points from the cluster centers. Scaling done on outliers reduces their membership in true clusters. This scheme, known as the Mega-clustering, defines a conceptual mega-cluster which …

A Gait Generation Mechanism For Leg Rehabilitation Therapy, Yazan Ahmad Manna

Theses

While most take their ability to walk for granted, some are unable to walk secondary to any number of pathologies, such as traumatic brain injury (TBI), spinal cord injury (SCI), cerebrovascular accidents (CVA), cerebral palsy (CP), multiple sclerosis (MS), Parkinson's disease, as well as various orthopedic conditions. Decreased activity has been shown to be associated with rapidly deconditioning and other co-morbidities. Rehabilitation techniques that afford patients the ability to begin reconditioning through walking sooner may ultimately enhance their return to a better quality of life.

The overall goal of this study is to design a gait generation mechanism for rehabilitation …

Evaporating Cross Flow Spray Jets In Gas-Solid Circulating Fluidized Bed, Tong Hoon Lee

Dissertations

Three-phase flow of solid-gas suspension with liquid spray is found in many industrial applications, including fluidized catalytic cracking in petroleum refinery process, and wet scrubbing process. This dissertation study is aimed to understand the gas-solid-liquid three-phase flow structure, phase interactions and transport in a gas-solid circulating fluidized bed where an evaporating cross-flow liquid spray jet from a rectangular nozzle with a fan angle is injected. The investigation is based on both numerical and experimental approaches. The numerical study is for detailed field descriptions of the flow structure, phase interaction and distributions whereas the experimental study is for simulation validations. The …

Direct Numerical Simulations And Experimental Investigation Of Dielectrophoresis, Arun Thankamony John-Kadaksham

Dissertations

This dissertation deals with the numerical and experimental studies of the phenomenon of dielectrophoresis, i.e., the motion of neutral particles in nonuniform electric fields. Dielectrophoresis is the translatory motion of neutral particles suspended in a dielectric medium when they are subjected to an external nonuniform electric field. The translatory motion occurs because a force called the dielectrophoretic force, which depends on the spatial variation of the electric field, acts on the particles. As the generation of force involves no moving parts and the particles can be moved without touching them, dielectrophoresis can be used in many applications, including manipulation and …

Simulation Of Creep In Nickel Based Single Crystal Superalloys, Yunhong Pang

Dissertations

Nickel based single crystal Superalloys are finding wide spread use in high temperature gas turbines and other similar applications because of their superior high-temperature strength and creep properties as compared to the other materials. This is due to two factors: solid solution and precipitation strengthening of the gamma (γ) and gamma prime (γ') phases, and the elimination of grain boundaries. Creep of Nickel based single crystal Superalloys are caused by two primary mechanisms, dislocation creep and diffusion creep. Several factors that affect the creep life of Nickel based single crystal Superalloys are the specific microstructure, stress, temperature and rafting. Also, …

Gas Fluidization Of Nanoparticles, Qun Yu

Dissertations

The primary objective of this study is to perform a systematic investigation on the gas fluidization of various nanoparticle agglomerates. Firstly, the gas fluidization characteristics and regime classifications without any additional external force fields are identified using both experimental measurements and modeling. Secondly, the effect of introducing certain external force fields on nanoparticle fluidization is experimentally investigated. Two external force fields were applied: sound waves from a loud speaker (acoustic assistance) and in-bed magnets that were excited by an external oscillating magnetic field (magnetic assistance). Thirdly, exploratory experimental research on the use of nanoparticle agglomerates as a granular filtration media …

Experimental Technique For Studying High-Temperature Phase Equilibria In Reactive Molten Metal Based Systems, Alexandre Ermoline

Dissertations

The general objective of this work is to develop an experimental technique for studying the high-temperature phase compositions and phase equilibria in molten metal-based binary and ternary systems, such as Zr-O-N, B-N-O, Al-O, and others. A specific material system of Zr-O-N was selected for studying and testing this technique.

The information about the high-temperature phase equilibria in reactive metal-based systems is scarce and their studying is difficult because of chemical reactions occurring between samples and essentially any container materials, and causing contamination of the system.

Containerless microgravity experiments for studying equilibria in molten metal-gas systems were designed to be conducted …

Computational Studies Of Viscoelastic Multiphase Flows, Shriram B. Pillapakkam

Dissertations

A finite element code based on the level set method is developed for performing two and three dimensional direct numerical simulations (DNS) of viscoelastic two-phase flow problems. The Oldroyd-B constitutive equation is used to model the viscoelastic liquid. The code is used to study transient and steady state shapes of Newtonian and viscoelastic drops in simple shear and buoyancy driven flows. The roles of the governing dimensionless parameters: Capillary number (Ca), Deborah Number (De) and the polymer concentration parameter c, in determining deformation of drops and bubbles, are also analyzed.

The numerical code permits us to vary Ca, De and …

Investigation Of Static And Dynamic Enhancement Of Laminar Natural Convection Cooling Of Electronics, Laurie Ann Florio

Dissertations

With the proliferation of consumer electronics devices and the increasingly demanding thermal control requirements for such devices, more effective and efficient means of cooling electronics are needed. The feasibility of three alternative approaches to enhancing pure natural convection cooling of electronics is investigated in the current research. The three static or dynamic methods investigated are alternate cross-flow passages, the strategic placement of transversely oscillating plates near the heat sources and a combined method using both the cross-flow passages and the strategically placed oscillating plates. These cooling methods are intended to operate in the regime for which natural convection cooling is …

Heat Transfer Model For The Ignition Of Metal Powder On A Heated Filament, Trent Stanton Ward

Theses

The thermal processes leading to ignition of metal powders in environments that experience rapid temperature changes are currently poorly understood. In this research, a methodology for studying and quantification of such processes is developed. In the experimental case study, the ignition temperature of Mg powder coated on the surface of an electrically heated filament is detected optically at different heating rates. To interpret the results, a heat transfer model has been developed for a multilayer powder coating on top of an electrically heated filament. The coating is modeled using a hexagonal close packed geometry and the heat transfer equations are …

The Design Of Adjustable Spherical Mechanisms Using Plane-To-Sphere And Sphere-To-Plane Projections, Wen-Tzong Lee

Dissertations

The spherical mechanism is a particular type of spatial mechanism. Due to the orientation of its joint axes and the curvature of its links, the workspaces of spherical mechanisms (whether line segments, closed loops or area regions) are spherical in curvature. This characteristic of spherical mechanisms makes them quite effective and practical in motion path and function generation applications requiring spherical rigid body kinematics.

Although there are design methods available for spherical mechanisms, most of these methods do not consider the design of a single adjustable spherical mechanism. With an adjustable spherical mechanism, the user could for example, relocate the …

3-D Numerical Simulation Of Reactive Extrusion And Its Application To Polymerization Of Ε-Caprolactone In Co-Rotating Twin-Screw Extruders, Linjie Zhu

Dissertations

A 3-D numerical simulation model was proposed to predict the polymerization of ε-caprolactone in fully-filled conveying elements and kneading blocks of co-rotating twin-screw extruders, in which the kinetics equation for polymerization is coupled with continuity equation, momentum equation, and energy equation. With the 3-D model, parametric studies have been carried out to investigate the effects of screw configurations, screw diameter, operational conditions, values of heat from reaction, initiator concentration, and heat transfer conditions at barrel surface upon the polymerization progress. Two simulation models for the polymerization in the partially-filled channels were developed based on the conveying mechanisms of the reaction …

Effect Of Fullerene Containing Lubricants On Wear Resistance Of Machine Components In Boundary Lubrication, Andriy Titov

Dissertations

Fullerenes, a new form of carbon nanomaterials, possess unique physical and mechanical properties that make their use as additives to liquid lubricants potentially beneficial. The goal of this study was to investigate the effect of fullerene containing lubricants on wear resistance of steel-bronze couples operating under boundary lubrication conditions. A mathematical model of deformed asperity contact was built to calculate real contact area and real contact pressure. Computer controlled wear friction testing methodology and equipment were designed, developed and implemented for obtaining reliable and objective experimental data. In addition, optical and scanning electron microscopy and standard surface texture analysis were …

Migration Of An Intruder Particle In A Boundary Driven Shear Flow, Jian Liu

Dissertations

This study reports on three-dimensional, discrete element simulations of a single large spherical intruder in a Couette shear flow composed of uniform sized particles. The simulation results are useful in providing a numerical reproduction of the experiments for size segregation and mixing. This in turn has a major importance in many industries which are concerned with handling of particles and powders, such as pharmaceutical manufacturing, agriculture, chemical and mineral processing.

Discrete element simulations are carried out using the "soft sphere" model of Walton, et. al., which provides a method for obtaining the information at a macroscopic level from multi-body collisions …

Vibration-Induced Densification Of Granule Materials, Ninghua Zhang

Dissertations

Physical experiments as well as discrete element simulations of vibration are carried out. The use of different amplitudes and frequencies are applied in the experiments to facilitate the observation of densification trends with mono-disperse acrylic spheres and multi-disperse polyethylene pellets. For mono-disperse acrylic spheres, four densification trends are found at different vibration conditions, and attaining the "maximum density" is closely related to the combination of vibration frequency and amplitude, in agreement with experiments in the literature. For multi-disperse polyethylene pellets, there is a substantial increase in solids fraction due to the effects of particle shape and surface friction. Computer simulations …

Dielectrophoretic Manipulation Of Biological And Non-Biological Analytes In A Microfluidic Channel, Dawn J. Bennett

Dissertations

Micro-total-analytical systems (μTASs) for analyzing chemical/biological substances are now used across a wide variety of applications ranging from biological warfare agent detection to the healthcare industry. The first step in the operation of a μTAS consists of concentrating and separating the analytes of interest from the background matrix and positioning them into selected locations for subsequent analysis. The use of ac electric fields was demonstrated to have promising potential for a μTAS because the application of an ac field suppresses undesirable electrolytic effects in the liquid. The main purpose of this work is to study micro-scale phenomena in a flowing …