Structural Materials Commons^™

Flexural Performance Of Deficient Rc Beams Repaired With Gfrp Composite, Zena Aljazaeri, Hayder Alghazali, Zuhair Al-Jaberi, John J. Myers

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Fiber-reinforced polymer composite materials have been improved for use in repairing and strengthening existing infrastructure over the past few decades. This case study focuses on the effect of confinement with GFRP strips on the structural performance of out-of-service beams in bridge applications due to the impact of over-height vehicles or inadequate lap-spliced reinforcements. In this study, beams with inadequate lap splices in the tension zone were utilized to mimic the damaged area in out-of-service RC beams. The proposed repair technique is a glass fiber-reinforced polymer (GFRP) composite in the form of longitudinal sheets and U-wrapped strips. The experimental study determined …

Magnetic Field-Induced Transformation In Polycrystalline Ni2mnal Heusler Type Magnetic Shape Memory Alloy, Choji J. Daches, Joseph W. Newkirk, Mario Buchely, Laura N. Bartlett

Materials Science and Engineering Faculty Research & Creative Works

The martensitic and magnetic transformations, as well as the mechanical properties, of Ni₂MnAl alloys in as-cast (AC) and heat-treated (HT) conditions were investigated. Magnetic-field-induced strain was evaluated via magnetostriction, with reversible strains of 0.14% and 0.2% achieved in the martensitic phase at 2 K for the AC and HT alloys, respectively. Transformation temperatures and Curie temperatures were determined under constant applied magnetic field, revealing that γ-phase inclusions in the AC microstructure suppress antiferromagnetic domain response, yielding a lower magnetization (∼8.4 emu g⁻¹) compared to the HT alloy (∼13.4 emu g⁻¹). Both alloys exhibited hysteretic behavior in the martensitic state and …

Coupled Multiphysics Transport-Reaction Modeling Framework For Combustion Synthesis Of Cement Phases: Insights Into Β-C2s Formation And Wavefront Dynamics, Sayee Srikarah Volaity, Shubham Agrawal, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Biofuel-based combustion synthesis (BCS) processes offer low-temperature, low-carbon routes to lime and clinker production. However, they involve tightly coupled interactions between heat transfer, gas flow, and sequential solid-state reactions within reactive pellets. Experiments typically provide surface temperature evolution and final phase assemblages but give limited insight into the conversion process and the interaction between composition and process conditions. A coupled transport-reaction framework is developed here to resolve this limitation─the synthesis of β-C2S (belite), a major cementing phase, serving as an example. Transient conservation equations for energy, momentum, and species are solved for a porous pellet exchanging heat and mass with …

A Hybrid Mechano-Thermal Route To Synthesize Reactive Pozzolans From Clay Minerals: A Case Of Kaolinite, Oluwadamilare Charles Adesina, Bryan K. Aylas-Paredes, Brian R. Cherry, Luciano A. Gobbo, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Aluminosilicate resources from unconventional sources offer promising potential for developing low-carbon supplementary cementitious materials (SCMs), yet their activation typically requires energy-intensive thermal processing. Kaolinite is a geographically abundant and highly attractive precursor clay mineral to reduce the clinker factor in concrete. By integrating mechano- and thermo- chemistry sequentially in a novel hybrid mechano-thermal activation (MTA) strategy for clay mineral activation, the dehydroxylation of pure kaolinite polymorphs KGa-1b and KGa-2 for enhanced pozzolanic reactivity is unlocked at temperatures that are lower than those needed for conventional thermal activation (TA). The mechano-chemical activation (MCA) step that induces significant structural defects and disorder …

A Performance-Weighted Environmental Assessment Of Ultra-High-Volume Fly Ash Substitution In Portland Cement Concrete, Youngguk Seo, M.A. Karim, Teddy Tzvetkov, Joshua Hardy

Faculty Articles

Fly ash substitution for cement in Portland cement concrete (PCC) has been regarded as a sustainable solution, but its widespread application remains constrained by concerns over mechanical performance and durability of PCC, especially at higher replacement rates. This study evaluates PCC mixes incorporating fly ash Type C (FA-C) or Type F (FA-F) across cement replacement rates from 10% to 90%, tracking fresh-state workability, compressive strength, and surface electrical resistivity at 7, 14, and 28 curing days. A process-based life cycle assessment (LCA) with the TRACI 2.1 method quantified global warming potential (GWP, kg CO₂/m³) under a …

A Maintenance-Aware Machine Learning Framework For Network-Level Highway Pavement Condition Prediction, Jin Hwan Kim, Guk Gon Song, Youngguk Seo

Faculty Articles

This study develops and validates maintenance-aware machine learning models for predicting the Highway Pavement Condition Index (HPCI) on the Korean expressway network. Multiple regression and tree-based models were trained and tested using the pavement condition surveys archived in the Highway Pavement Management System (HPMS). A stacking regressor that integrates random forest, gradient boosting, and extreme gradient boosting as base learners exhibited the most robust predictions. Performance metrics indicated that the stacking ensemble achieved a mean absolute error of 0.21, a root mean square error of 0.31, and a coefficient of determination exceeding 0.73 on the testing dataset. Also, the residuals …

In-Operando Imaging For Mechanistic Insights And Process Optimization In The Biofuel-Driven Combustion Synthesis Of Cement And Precursor Phases, Shubham Agrawal, Jeffrey J. Long, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Biofuel-based combustion synthesis (BCS) is a promising low-carbon pathway for decarbonizing cement production, providing an alternative to the fossil-fuel-driven clinkering process typically conducted at ∼1450 °C. Understanding microscale combustion mechanisms is essential to efficiently transfer biofuel-generated heat to cement precursors for targeted phase formation. Unlike previous studies focusing on macro-scale parameters such as fuel content/type, porosity, and holding temperature, this work provides mechanistic insights into microscale combustion behavior, linking microstructural phenomena with macro-scale processing conditions to guide parameter optimization. In-operando microscale imaging was employed to examine combustion wave propagation, spatio-temporal temperature evolution, and microstructural transformations within reactive pellets. Two combustion …

Effect Of Curing Duration On Bridge Deck Concrete Performance, Zhaniya Omarova

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

This study evaluates the influence of curing duration on the performance of bridge deck concrete and investigates the feasibility of reducing curing periods without compromising structural and durability properties. Two concrete mixtures, a standard Nebraska Department of Transportation (NDOT) bridge deck mix (47BD) and an optimized reduced-cement-content mix (O47BD-R100), were evaluated under multiple curing durations Fresh, early-age, mechanical, durability, and shrinkage properties were assessed to characterize the effect of curing on concrete behavior. Internal relative humidity and temperature were monitored using embedded sensors to investigate moisture diffusion and its role in shrinkage development for lab specimens and full-scale slabs.

Results …

Co-Calcination Of Limestone And Clay Enhances The Performance Of Limestone Calcined Clay Cement (Lc3), Oluwadamilare Charles Adesina, Sahil Surehali, Avinaya Tripathi, Kayla Lauren Lee, Bryan K. Aylas-Paredes, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Limestone-calcined clay cements (LC³) reduce the environmental impact of cement production and accelerate the industry transition toward carbon neutrality. While conventional LC³ with 50% clinker replacement (LC³-50) demonstrate long-term performance comparable to ordinary Portland cement (OPC) in concrete, early-age performance is generally compromised. This study explores for the first time, joint thermal treatment—that is, co-calcination—of limestone (LS) and bulk kaolinitic clay in mass ratios of 1:1 to 1:4 under a calcination regime specifically designed to ensure activation of the clay mineral. The co-calcination converts a small fraction of LS to metastable CaO, thus providing an …

Data Set, R Scripts And Script Outputs For Manuscript: Manufacturing Systems: Characteristics And Dynamics, Alan J. Fitzmorris

Graduate Research Data

This file repository contains fifteen computer-generated datasets, two naturally occurring datasets, nineteen shipbuilding shop datasets, and sixty-one concrete plant datasets.  Each data set contains subdirectories associated with various aspects of the data analysis, including stationarity analysis, dynamic system analysis, and complexity analysis.  In each case, applicable R scripts are included.  The text file entitled “Directory_and_File_Names” depicts the directory structure and associated file names for a total of 225 directories encompassing 8008 files.

Thermal Transformations And Mechanical Properties Of All-D-Metal Mn2fecu Heusler-Type Shape Memory Alloy, Choji J. Daches, Joseph W. Newkirk, Mario Buchely

Materials Science and Engineering Faculty Research & Creative Works

All-d-metal Heusler alloys are emerging functional materials in which magnetic ordering, lattice distortion, and mechanical behavior are strongly coupled through d–d electronic interactions. This study systematically investigates the structural, thermal, magnetic, and mechanical properties of Mn₂FeCu synthesized within a Heusler-type compositional framework. SEM/EDS revealed a dual-phase FCC-based microstructure consisting of Mn–Fe–rich and Mn–Cu–rich domains, while XRD confirmed FCC symmetry with compositional partitioning rather than full L2₁ ordering. Differential scanning calorimetry identified partial melting of the Cu-rich phase near ~ 900 °C. Dilatometry showed a thermoelastic FCC → FCT transformation at ~ 770–780 °C with a recoverable strain of ~ 0.067%. …

The Effects Of Mold Flux Contamination On Oxide Scale Formation And Hydro-Descaling Efficiency During Steel Processing, Tochukwu Princewill Ojiako, Richard Osei, Mario Buchely, Haiming Wen, Simon Lekakh, Ronald O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Oxide scale formation during thin-slab continuous casting has a complex structure, which is influenced by mold flux contamination, that modifies interfacial reactions during solidification, subsequent reheating, and descaling. While individual aspects of the oxidation behavior of carbon steel have been previously examined, the synergetic effects of mold flux contamination during continuous casting and subsequent reheating on scale modification and the efficiency of hydraulic descaling remain inadequately studied. This study quantitatively examines the effect of flux composition on oxide scale evolution, adhesion, and hydraulic removal in low-carbon steel under simulated industrial conditions. Slab samples with as-cast, cleaned, and flux-coated surfaces were …

Effect Of Complex Alloying Elements On Oxide Scale Formation And Water-Jet Descaling Performance On Continuously Cast Low-Carbon Steels, Tochukwu P. Ojiako, Tsvetkov Dmitry, Mario Buchely, Haiming Wen, Simon N. Lekakh, Ronald J. O'Malley

Materials Science and Engineering Faculty Research & Creative Works

The formation and evolution of oxide scale in contact with mold flux during continuous casting, subsequent reheating, and hydraulic descaling are strongly governed by steel chemistry. To elucidate the effect of complex alloying elements (Si, Mn, and Cr), two industrially produced continuously cast low-carbon steel grades for manufacturing stamped parts (a base and alloyed steel grade) were investigated. The objective was to determine how alloying elements influence oxidation behavior, scale morphology, interfacial adhesion, and water-jet descaling efficiency. Continuously cast slab specimens were subjected to controlled thermal and atmospheric oxidation cycles simulating multistage industrial practice. Three initial surface conditions (industrial as-cast, …

Modeling Of Transformation Temperatures In Cast Martensitic Stainless Steels-Ca6nm: Effects Of Composition, Heating Rate, And Grain Size, Ugochukwu Agbedo, Mario Buchely, Laura Bartlett, Caelan Kennedy

Materials Science and Engineering Faculty Research & Creative Works

Accurate prediction of the critical transformation temperatures Ac1 and Ac3 is one of the essential factors in the heat treatment of CA6NM cast martensitic stainless steel. In this study, the influence of alloy composition, heating rate, and prior austenite grain size on the critical temperatures was quantified using dilatometric measurements and statistical modeling. Six heat treatment conditions produced prior austenite grain sizes ranging from ~75 to 247 µm. Experimental results showed that grain size variations produced only minor changes in Ac1 and Ac3, indicating a weak dependence of transformation temperatures on prior austenite grain size within the investigated range. In …

Multiphysics Simulation And Experimental Validation Of Phase Transformation And Hardness In Jominy End-Quenched Low-Alloy Steels, J. S. Alabi, E. Heidari, M. F. Buchely, K. Chandrashekhara, S. N. Lekakh, R. J. O'Malley, V. A. Athavale, A. Kumar

Materials Science and Engineering Faculty Research & Creative Works

High-volume industrial continuous hot-rolled steel heat treatment processes involve sophisticated multi-phase modeling. The performance of a given process can be optimized by coupling phase transformation kinetics with the cooling conditions of the process. This study develops a multiphysics model to simulate an intensive quenching process for steel, which is inherently transient and highly dependent on numerous parameters. The simulated object was a Jominy end-quenched specimen geometry using two commercial steels, AISI 4130 and AISI 4140, with the goal of transferring a verified methodology to the heat treatment process for industrial heavy-section products (bars, slabs). The simulation employs thermal, mechanical, and …

Data Driven Design Of Ultra High Performance Concrete Prospects And Application, Bryan K. Aylas-Paredes, Taihao Han, Advaith Neithalath, Jie Huang, Ashutosh Goel, Aditya Kumar, Narayanan Neithalath

Electrical and Computer Engineering Faculty Research & Creative Works

Ultra-high-performance concrete (UHPC) is a specialized class of cementitious composites that is increasingly used in various applications, including bridge decks, connections between precast components, piers, columns, overlays, and the repair and strengthening of bridge elements. The mechanical and durability properties of UHPC are significantly influenced by factors such as low water-to-binder ratios, the inclusion of supplementary cementitious materials (SCMs), and fiber reinforcement. Machine learning (ML) has been employed to predict the performance of UHPC and optimize its mixture designs by using various raw materials. This study first provides a comprehensive review of ML applications in UHPC, focusing on predicting workability, …

Bond Behavior Of Full-Scale Beams Using Sustainable Self-Compacting Concrete, Hayder H. Alghazali, Atheer H.M. Algburi, John J. Myers

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Sustainable concrete is a step towards greener and more eco-friendly concrete construction practices, helping to solve global environmental problems. The present study focuses on the bond behavior between steel reinforcement and greener self-compacting concrete, specifically sustainable self-compacting concrete (SUS-SCC). Three SUS-SCC mixtures with different fly ash (FA) to cement replacement levels of [50, 60, and 70% (by mass)] were developed. Twelve full-scale SUS-SCC beams with a cross-section of (305 x 57) mm and a total length of 3048 mm were cast and tested using a four-point load test setup. The effect of longitudinal and lateral steel reinforcement ratios in the …

Elucidating The Effects Of Water Activity On The Hydration Kinetics And Thermodynamics Of Ye’Elimite–Calcium Sulfate Hydrate Systems, Godwin I. Ogbuehi, Rupack R. Halder, Aditya Kumar, Gaurav Sant, Monday U. Okoronkwo

Materials Science and Engineering Faculty Research & Creative Works

Relative humidity and water activity (aH) reductions have been known to suppress the hydration of anhydrous cement clinker phases. However, the relationship between ye'elimite (C4A3$) hydration kinetics and water activity remain unclear. This study employs experimental and thermodynamic modeling approaches to investigate the influence of water activity on ye'elimite hydration in the "C4A3$ + water", and "C4A3$ + gypsum + water" systems. Experimental findings indicate that as water activity decreases, C4A3$ hydration diminishes until the reaction is brought to a halt at a threshold aH. The critical aHand corresponding solubility constant of C4A3$ (KC4A3S¯) estimated from thermodynamic analysis are 0.46 …

Characterization Of The Fatigue Threshold Behavior Of Uhmwpe, Bethany B. Smith, Anurag Roy, Robert O. Ritchie, Lisa A. Pruitt

Faculty Journal Articles

Ultra-high-molecular-weight-polyethylene (UHMWPE) has been the material of choice for bearings in total joint replacements (TJRs) for decades as a result of its excellent wear resistance, chemical inertness, energetic toughness, low friction, and biocompatibility. Utilization of this polymer in orthopedic devices requires oxidation, wear, and fatigue resistance. Balancing these important properties by tailoring processing techniques and modulating microstructural features has been an ongoing endeavor in the field. Research into the clinical applications of UHMWPE has primarily focused on the challenges of wear and oxidation while studies into the realm of fatigue have been more limited. Literature gaps exist in fully understanding …

Microstructure Densification In Cement Pastes Enabled By Novel Graphene Types, Sahil Surehali, Taihao Han, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

The primary barriers hindering graphene's widespread adoption as a performance-enhancing additive in cement-based systems have traditionally been its prohibitive cost and the sustainability concerns associated with conventional manufacturing processes. However, these impediments have recently been mitigated by advancements in detonation synthesis techniques, enabling scalable, cost-effective, and environmentally favorable production of novel graphene types—specifically fractal graphene (FG) and reactive graphene (RG). This paper explores the influence of ultra-low dosages of FG and RG (≤ 0.04 % by mass of cement, which results in ∼20 % increase in compressive strengths) on the pore-structure features of cement pastes. Compared to the control paste, …

Enabling Carbon Dioxide Mineralization And Active Set Control In Portlandite-Based Cementitious Suspensions, Xiaodi Dai, Sharu Bhagavathi Kandy, Rui Xiao, Manas Sarkar, Shubham Wani, Thiyagarajan Ranganathan, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gädt, Samanvaya Srivastava, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

The real-time control of concrete's stiffening allows users to better control pumping and extrusion during 3D-printing processes. Here, a portlandite-based cementitious formulation (i.e., slurry or suspension) that features the potential for rapid CO₂ uptake is adapted for 3D-printing applications. In particular, we showcase a portlandite-fly ash binder system combined with a thermo responsive polymer, wherein precise control via thermal activation allows set control and rapid solidification. Through the thermally induced polymerization of polyacrylamide, the hybrid binder system rapidly undergoes stiffening at trigger onset temperatures ranging from 60 °C to 80 °C, exhibiting average stiffening rates of up to 2600 …

Recent Progress And Scientific Challenges In Wire-Arc Additive Manufacturing Of Metallic Multi-Material Structures, Sainand M. Jadhav, Sambhaji Kusekar, Akash Belure, Satyavan Digole, Abhijeet Mali, Muralimohan Cheepu, Manoj Mugale, Suhas Alkunte, Duckbong Kim

Faculty Articles

Metallic multi-material structures are heterogeneous structures characterized by changing composition, microstructures, and site-specific characteristics, advantageous for numerous applications where multifunctionality is desired. Metallic multi-material structures are known as bimetallic structures (BSs), which are functionally graded materials (FGMs). In recent years, wire-arc additive manufacturing (WAAM) advanced as a promising additive manufacturing process to realize the fabrication of these structures due to its high deposition rate, cost-effectiveness, and material utilization efficiency. This review presents a comprehensive overview of the recent progress, processing strategies, and scientific challenges in WAAM of multi-material structures. The paper begins with an introduction to multi-material structures, followed by …

Dealuminated Metakaolin In Supplementary Cementitious Material And Alkali-Activated Systems: A Review, Amany G. Micheal Prof., Mostafa Adel Elsebaei Eng., Maria Mavroulidou Prof., Maria Centeno Assoc. Prof., Rabee Shamass Senior Lec., Ottavia Rispolio Mrs.

Architectural Engineering

This paper presents a comprehensive review of dealuminated metakaolin (DK), a hazardous industrial by-product generated by the aluminium sulphate (alum) industry and evaluates its potential as a component in cementitious systems for the partial or full replacement of Portland cement (PC). Positioned within the context of waste valorisation in concrete, the review aims to establish a critical understanding of DK formation, properties, and reactivity, particularly its pozzolanic potential, to assess its suitability for use as a supplementary cementitious material (SCM), or as a precursor in alkali-activated cement (AAC) systems for concrete. A systematic methodology is used to extract and synthesise …

Ultra-Low Dosages Of Novel Graphene Types Enhance The Rheological Properties And Buildability Of 3d Printed Binders, Sahil Surehali, Akshay Venkatachalam, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

The use of graphene as a high-performance concrete additive is attractive; but, its cost and concerns about production scalability and dispersion efficiency in concrete are impediments to widespread use. This study explores the impact of ultra-low dosages (≤0.02 % by mass of binder) of two novel graphene types—fractal graphene (FG) and reactive graphene (RG)—produced through a cost-effective, environmentally friendly, and scalable process, on the rheological properties of 3D-printable concrete. Both FG and RG significantly enhance the dynamic and static yield stresses and viscoelastic properties of the binder, with RG-modified mixtures exhibiting slightly more pronounced enhancements due to the presence of …

Numerical Simulation Of Heat Transfer In Self-Propagating High-Temperature Synthesis (Shs)-Based Calcination Of Limestone, Sayee Srikarah Volaity, Shubham Agrawal, Srinivas Kilambi, Patrick Phelan, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Calcination of limestone, a high temperature (∼900 °C) process that emits 44 % of the mass of limestone as CO₂, is a critical process in the production of many industrially important materials. To soften the CO₂-related impacts of traditional calcination, and to enable ultrafast synthesis of lime, a novel approach based on self-propagating high-temperature synthesis (SHS) has been put forward. SHS uses exothermic heat released by the combustion of fuel intermixed with the reactants to advance the reaction, and hence requires the provision of lower external temperatures. This study introduces a microstructure-guided modeling approach to understand …

Intelligent Turning Cyber-Physical Systems Modeling Using Sysml, Prithbey Raj Dey, David Lee Enke, Mario F. Buchely

Engineering Management and Systems Engineering Faculty Research & Creative Works

Cyber-Physical Systems (CPS) support industrial automation that incorporates people, hardware, signal, computation, and control using networking to achieve desired results. The complex automated CPS design demands a standard and comprehensive approach to appropriately identify the system requirements, define the architecture, and model the relationships among the software and hardware components. Systems Modeling Language (SysML) provides the capability for a comprehensive modeling to capture the desired design requirements in the systems architecture. SysML enables performance estimation of the model by analyzing constraints while identifying interactions among the components through various behavioral diagrams. In this paper, SysML is applied to the design …

Design And Function Of Thermoresponsive-Ultrafast Stiffening Suspension Formulations For 3d Printing, Sharu Bhagavathi Kandy, Sebastian Remke, Thiyagarajan Ranganathan, Shubham Kiran Wani, Xiaodi Dai, Narayanan Neithalath, Aditya Kumar, Mathieu Bauchy, Edward Garboczi, Torben Gädt, Samanvaya Srivastava, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

An inability to accurately control the rate and extent of solidification of cementitious suspensions is a major impediment to creating geometrically complex structural shapes via 3D printing. In this work, we have developed a thermoresponsive rapid stiffening system that will stiffen suspensions of minerals such as quartz, limestone, portlandite, and Ordinary Portland Cement (OPC) over a wide pH range. When exposed to trigger temperatures between 40 °C and 70 °C, the polymer binder system undergoes a thermally triggered free radical polymerization (FRP) reaction, leading to an ultrafast stiffening of the suspension at an average rate on the order of 1 …

A Low-Carbon Approach For Lime Production Using Self-Propagating High Temperature Synthesis-Driven Limestone Calcination, Shubham Agrawal, Sayee Srikarah Volaity, Srinivas Kilambi, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Limestone calcination produces calcium oxide (or lime), that forms the basis for the manufacturing of many critical engineering materials such as cement and iron-and-steel. Limestone calcination—an endothermic reaction—is regarded as one of the most energy-and-CO₂ intensive industrial chemical reactions, and is facilitated by fossil fuels, since the high temperature requirement (∼900 °C) renders it less conducive to electrification through renewable energy sources. In this study, a novel, low-temperature (∼450 °C) pathway for ultrafast calcination of limestone using combustion synthesis or self-propagating high-temperature synthesis (SHS) is developed. SHS leverages exothermic heat from the combustion of lignin or biomass—as low-carbon fuels—mixed …

Rheology And Early-Age Structure Development In Binary And Ternary Blends Modified With Novel Graphene Types, Sahil Surehali, Collin Gustafson, Sayee Srikarah Volaity, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Interest in the use of graphene to enhance the properties of cementitious materials is growing, but major impediments in implementation are the cost of graphene and changes in binder rheology attributable to these nanomaterials. This study explores the influence of novel, cost-effective, environment-friendly, and mass-producible graphene on the rheology and early-age structure development of cementitious binders. Two novel graphene types—fractal graphene (FG) and reactive graphene (RG)—are used in plain cement mixtures as well as those containing 30 % (by mass) of fly ash and/or limestone powder, at low dosages of ≤0.02 % by mass of binder. The early- and later-age …

Effects Of Gypsum And Limestone On Early-Age Hydration And Strength Optimization In Belite Calcium Sulfoaluminate Cement, Sai Akshay Ponduru, Bryan K. Aylas-Paredes, Taihao Han, Advaith Neithalath, Narayanan Neithalath, Gaurav Sant, Aditya Kumar

Materials Science and Engineering Faculty Research & Creative Works

Belite calcium sulfoaluminate cement (CSAB), an alternative to Portland cement, exhibits excellent strength at both early and later ages. However, due to its high belite content, the carbon reduction from this type of cement is not sufficient when compared to other alternative cements. To further enhance CSAB's sustainability, this study investigates the performance of CSAB when partially replaced by low-carbon mineral additives (i.e., limestone and gypsum). The primary objective is to identify the optimal mixture design by incorporating gypsum and limestone to formulate a sustainable binder that maintains high compressive strength. The CSAB is replaced (with both additives) by up …