Structural Materials Commons^™

Advanced Manufacturing Of Multifunctional Shape Memory Polymer Composites And Self-Healing Systems, John B. Konlan

LSU Doctoral Dissertations

The need for multifunctional light weight structures for engineering applications is on the rise. Multifunctional composites are desired because of their ability to combine multiple functionalities into one structure. The advantages of a high strength-to-weight ratio of multifunctional composites make them desirable and suitable for use in energy-efficient applications. Shape-memory polymers (SMPs) have attracted interest over the past several decades because of their multifunctional nature. They have found use in many applications such as aerospace, satellites, automobiles, textiles, and biomedical devices, where lightweight and multifunctionality are key. The self-healing nature of most SMPs makes them suitable for use in lightweight …

Development Of Multifunctional Wood Composites With Integrated Phase Change Materials For Enhanced Thermal Management, Self-Healing, And Sustainability., Emmanuel Igbokwe

LSU Master's Theses

Abstract

This study focused on incorporating self-healing, flame retardancy, and energy harvesting capabilities into the wood composite to contribute to more sustainable and energy-efficient building practices. Oriented strand board has been widely used as sheath for roofing or dry walls in residential buildings. Residential buildings account for a large portion of energy consumption. Therefore, an oriented strand board with energy harvesting capability is highly desired. Additionally, flame retardancy and damage self-healing and end-of-life recycling are also critical features for buildings.

In this study, we prepared a novel oriented strand board by constructing sandwich structures. The face sheets of the sandwich …

An In-Situ Method For Quantifying Entropy Generation In Fatigue Via A Novel Thermographic Approach, Peyton J. Wilson

LSU Master's Theses

This work features a new approach that is used to measure the rate of plastic work during a cyclic fatigue test, based on the first and second laws of thermodynamics. Using the one-dimensional Fourier heat equation coupled with the concept of fracture fatigue entropy, the rate of plastic work during fatigue can be measured without the need to interrupt a fatigue test, and the accumulated entropy to failure can be quantified. Experimental fatigue tests are conducted on Aluminum 6061-T6 specimens under cyclic axial loading and Carbon Steel 1018 specimens under fully reversed cyclic bending loading. The obtained results in addition …

A Study On High-Frequency Bending Fatigue, Microhardness, Tensile Strength, And Microstructure Of Parts Made Using Atomic Diffusion Additive Manufacturing (Adam) And Additive Friction Stir Deposition (Afsd), Hamed Ghadimi

LSU Doctoral Dissertations

This dissertation reports the findings of several studies on the mechanical and microstructural properties of parts made using atomic diffusion additive manufacturing (ADAM) and additive friction stir deposition (AFSD). The design of a small-sized bending-fatigue test specimen for an ultrasonic fatigue testing system is reported in Chapter 1. The design was optimized based on the finite element analysis and analytical solution. The stress–life (S–N) curve is obtained for Inconel alloy 718. Chapter 2 presents the findings of ultrasonic bending-fatigue and tensile tests carried out on the ADAM test specimens. The S-N curves were created in the very high-cycle fatigue regime. …

Evaluation Of Novel Jointless Engineered Cementitious Composites Ultrathin Whitetopping (Ecc-Utw), Ricardo Hungria

LSU Doctoral Dissertations

Ultrathin Whitetopping (UTW) is a rehabilitation technique that consists of placing a thin layer of concrete over a damaged asphalt pavement. While UTWs have demonstrated satisfactory performance in field tests, the inherent brittleness of concrete has led to the appearance of distresses. To address these distresses, Engineered Cementitious Composites (ECC) have been proposed for UTW applications, thanks to their exceptional attributes, including tensile ductility, flexural performance, and fatigue resistance. In this study, an ECC-UTW was constructed to investigate its potential as a viable solution. The project comprised two 18.3 m ECC sections with different thicknesses, namely 63.5 mm and 101.6 …

Atomistic Simulation Studies Of Thin Film Growth And Plastic Deformation In Metals And Metal/Ceramic Nanostructures, Reza Namakian

LSU Doctoral Dissertations

Despite the significant improvements in manufacturing and synthesis processes of metals and ceramics in the past decades, there are still areas in which the procedure is still frequently more of an art or skill rather than a science. Therefore, systematic and combined experimental and computational studies are required to facilitate the development of techniques that offer thorough understanding of the events taking place during manufacturing and synthesis processes. With regard to these issues, it is paramount to address microscale characterizations and atomic scale understanding of the events during fabrication processes. One of the focuses of this study is unraveling fundamental …

Optimizing The Self-Healing Efficiency Of Hydrogel Encapsulated Bacteria In Concrete, Ricardo Hungria

LSU Master's Theses

Calcium carbonate precipitation through microbial means is a promising pathway for concrete self-healing technologies, mainly for its microcrack sealing attributes. The main goal of this project was to study and optimize the crack healing efficiency of hydrogel encapsulated bacteria in concrete. To achieve this purpose, Bacillus pseudiformus was implemented as the bacteria strain at a concentration of 10⁸ cells/ml. This bacterium strain along with yeast extract was combined along with three different mineral precursors corresponding to magnesium acetate, calcium lactate, and sodium lactate. All these three precursors were evaluated at two concentrations (67.76 mM/l and 75 mM/l). For each …

Study Of Laser Based Additive Manufacturing For Titanium And Copper Alloys, Congyuan Zeng

LSU Doctoral Dissertations

Material processing by laser is increasingly applied in industrial applications for its outstanding characteristics, such as localized heating, high efficiency, and high manufacturing precision. In this study, two kinds of laser material processing strategies were investigated, namely laser surface engineering and laser-powder-bed fusion additive manufacturing, with pure titanium and copper alloys as target materials, respectively.

For laser surface engineering related studies, the work includes the investigation of the dynamic interactions between titanium and pure nitrogen or ambient air under transient laser processing conditions. Thanks to the in-situ synchrotron X-ray diffraction tests, the high-temperature reaction steps between titanium and pure nitrogen/ambient …

Vanadium-Based Nanomaterials For Improved Zn Ion Storage, Jianwei Lai

LSU Master's Theses

Rechargeable aqueous zinc-ion batteries (ZIBs) have been intensively studied as novel promising large-scale energy storage systems recently, owing to their advantages of high abundance, cost effectiveness, and high safety. However, the development of suitable cathode materials with superior performance are severely hampered by the sluggish kinetics of Zn²⁺ with divalent charge in the host structure.

Our Work demonstrates boosting the electrochemical performances of nanostructured cathode materials for aqueous ZIBs. The first project is focused on the interlayer-expanded V₆O₁₃∙nH₂O nanosheets as promising cathodes. Benefiting from the synthetic merits of its favorable architecture and expanded …

Soil-Recycled Aggregate-Geopolymer Road Base/Subbase Mixtures: Steps Towards Sustainability, Mohammad Khattak, Daniel Odion

Data

Corresponding data set for Tran-SET Project No. 18GTLSU10. Abstract of the final report is stated below for reference:

"This study deals with the development of Soil-Geopolymer mixtures using flyash, alkali activator and recycled aggregates (RAG) including recycled concrete (RCA) and reclaimed asphalt (RAP) as an alternative to soil-cement for pavement base and subbase layers. Several mix constituents were varied such as flyash type and content, RCA and RAP content and ratio of sodium silicate and sodium hydroxide. Experiment design was established and mechanical and durability characteristics of Soil-RAG-Geopolymer mixtures were evaluated and then compared to the conventional soil-cement mixtures. The …

Reduction Of Structural Damage From The Thermal Expansion Of Concrete Using Multifunctional Materials, Darren Hartl, Mirmilad Mirsayar

Data

Corresponding data set for Tran-SET Project No. 18STTAM01. Abstract of the final report is stated below for reference:

"This study leveraged past successes in the analysis and design of shape memory alloy (SMA) components to address the issue of thermal expansion in concrete structures. Since the SMA used in the current work is relatively cheaper than other common SMAs (less than $50/lb compared to NiTi which is $200/lb due to difficulties in processing), it is anticipated that the findings of the study could be implemented in real infrastructures made of concrete, asphalt concrete, and other complex large infrastructure. Low-cost Fe-SMAs …

Reduction Of Structural Damage From The Thermal Expansion Of Concrete Using Multifunctional Materials, Darren Hartl, Mirmilad Mirsayar

Publications

This study leveraged past successes in the analysis and design of shape memory alloy (SMA) components to address the issue of thermal expansion in concrete structures. Since the SMA used in the current work is relatively cheaper than other common SMAs (less than $50/lb compared to NiTi which is $200/lb due to difficulties in processing), it is anticipated that the findings of the study could be implemented in real infrastructures made of concrete, asphalt concrete, and other complex large infrastructure. Low-cost Fe-SMAs and other multifunctional materials can be considered as a replacement for components made of steel (e.g., in reinforced …

Soil-Recycled Aggregate-Geopolymer Road Base/Subbase Mixtures: Steps Towards Sustainability, Mohammad Khattak, Daniel Odion

Publications

This study deals with the development of Soil-Geopolymer mixtures using flyash, alkali activator and recycled aggregates (RAG) including recycled concrete (RCA) and reclaimed asphalt (RAP) as an alternative to soil-cement for pavement base and subbase layers. Several mix constituents were varied such as flyash type and content, RCA and RAP content and ratio of sodium silicate and sodium hydroxide. Experiment design was established and mechanical and durability characteristics of Soil-RAG-Geopolymer mixtures were evaluated and then compared to the conventional soil-cement mixtures. The results of the testing showed that for the selected Soil-RAG-Geopolymer mixtures the strength, stiffness, permanent deformation, and durability …

Mitigating Reflective Cracking Through The Use Of A Ductile Concrete Interlayer, Qian Zhang, Mohammad Khattak, Adway Das

Data

Corresponding data set for Tran-SET Project No. 18PLSU13. Abstract of the final report is stated below for reference:

"Reflective cracking is considered one of the most important issues that causes premature deterioration of composite pavements. Many types of mitigation methods have been studied in the past. However, they are either not effective in delaying the reflective cracking, or they only extend the service life by a few years. To address this critical issue and significantly extend the service life of the composite pavement, in this research, a ductile interlayer made of engineered cementitious composites (ECC) was proposed. It was hypothesized …

Development Of Geopolymer-Based Cement And Soil Stabilizers For Transportation Infrastructure, Miladin Radovic, Anand Puppala

Data

Corresponding data set for Tran-SET Project No. 18CTAM03. Abstract of the final report is stated below for reference:

"Geopolymer Cement (GPC) has drawn much attention in the recent years as an alternative to Ordinary Portland Cement (OPC) for soil stabilization, pavements, bridges and other transportation structures due to their good mechanical properties in comparison to OPC. In addition, GPC can be processed at room temperatures from aqueous solutions of waste materials (e.g. fly ash) or abundant natural sources (e.g. clay), thereby significantly reducing CO2 production associated with processing of OPC. As such, GPC proves to be a more sustainable and …

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Data

Corresponding data set for Tran-SET Project No. 18STUTA01. Abstract of the final report is stated below for reference:

"This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth …

Investigation Of Physical And Dynamic Properties Of High Porous Concrete, Ildar Akhmadullin

Publications

This project pursued two main objectives: (1) providing opportunities to Baton Rouge Community College (BRCC) students to develop hands-on laboratory skills and exposure to the transportation field, and (2) investigating porous concrete properties. Several BRCC student groups performed the work presented within this report; students prepared samples with different porosity and permeability according to standard specifications. The testing of the samples was performed at the Louisiana Transportation Research Center (LTRC) facility under the supervision of LTRC specialists. Findings indicate that the porosity of samples is backward proportional to the compression strength. This function is not linear but can be estimated …

Toward Non-Corrosion And Highly Sustainable Structural Members By Using Ultra-High-Performance Materials For Transportation Infrastructure, Shih-Ho Chao, Ashish Karmacharya

Publications

This research focused on investigating a highly sustainable and efficient reinforced concrete structural member for future infrastructure by utilizing emerging high-performance materials. These materials include ultra-high-performance fiber-reinforced concrete (UHP-FRC) and corrosion-resistant high-strength fiber-reinforced polymer (FRP) bars. Four reduced scale UHP-FRC specimens were tested under large displacement reversals to prove the proposed new ductile-concrete strong-reinforcement (DCSR) design concept by fully utilizing these ultra-high-performance materials. Micro steel fibers were incorporated into three specimens and ultra-high molecular weight polyethylene fibers were blended into the fourth specimen. One specimen with ASTM A1035 MMFX high-strength steel rebars, one with high-strength glass fiber reinforced polymer (GFRP) …

Development Of Geopolymer-Based Cement And Soil Stabilizers For Transportation Infrastructure, Miladin Radovic, Anand Puppala

Publications

Geopolymer Cement (GPC) has drawn much attention in the recent years as an alternative to Ordinary Portland Cement (OPC) for soil stabilization, pavements, bridges and other transportation structures due to their good mechanical properties in comparison to OPC. In addition, GPC can be processed at room temperatures from aqueous solutions of waste materials (e.g. fly ash) or abundant natural sources (e.g. clay), thereby significantly reducing CO2 production associated with processing of OPC. As such, GPC proves to be a more sustainable and environmentally friendly alternative than OPC. This research explores methods to develop GPC with desired properties and evaluate their …

Use Of Rice Husk Ash (Rha) In Flowable Fill Concrete Mix Material, Zahid Hossain, Kazi Tamzidul Islam

Data

Corresponding data set for Tran-SET Project No. 18CASU03. Abstract of the final report is stated below for reference:

"In the way of finding sustainable development, the flowable fill is a relatively new construction technology. Flowable fill is a self-compacting material, which has been developed in recent years. Flowable fill has been used for different applications such as backfilling walls, sewer trenches, bridge abutments, conduit trenches, pile excavations, and retaining walls. This study examines the potential uses of Rice Husk Ash (RHA) as a sustainable cementitious material (SCM) in the preparation of flowable fill concrete. (RHA is an agricultural by-product of …

Self-Healing Concrete Using Encapsulated Bacterial Spores In A Simulated Hot Subtropical Climate, Marwa Hassan, Jose Milla, Tyson Rupnow, Ahsennur Soysal

Data

Corresponding data set for Tran-SET Project No. 18CLSU02. Abstract of the final report is stated below for reference:

"Bacterial concrete has become one of the most promising self-healing alternatives due to its capability to seal crack widths through microbial induced calcite precipitation (MICP). In this study, two bacterial strains were embedded at varying dosages (by weight of cement) in concrete. Beam specimens were used to identify the maximum crack-sealing efficiency, while cylinder samples were used to determine their effects on the intrinsic mechanical properties, as well as its stiffness recovery over time after inducing damage. The concrete specimens were cured …

Use Of Bagasse Ash As A Concrete Additive For Road Pavement Application, Gabriel Arce, Marwa Hassan, Maria Gutierrez-Wing, Michele Barbato

Data

Corresponding data set for Tran-SET Project No. 18CLSU03. Abstract of the final report is stated below for reference:

"The objective of this study was to evaluate the use of sugarcane bagasse ash (SCBA) as a partial replacement of cement in concrete for road pavement application. The study explored the pozzolanic activity of SCBA produced from three different processing methodologies (i.e., raw SCBA, controlled SCBA and post-processed SCBA). The experimental results revealed that SCBA produced by the controlled burning of sugarcane bagasse fiber (SBF) at 650°C and grinding (C-650), presented the maximum pozzolanic activity. However, this SCBA production process was deemed …

Uhpc Shear Keys In Concrete Bridge Superstructures, Craig Newtson, Brad Weldon, Elsy Flores, Jordan Varbel, William Toledo

Data

Corresponding data set for Tran-SET Project No. 18CNMS01. Abstract of the final report is stated below for reference:

"This research investigated the use of locally produced ultra-high performance concrete (UHPC) as a grouting material to repair deteriorated shear keys. Shear keys are used in adjacent girder superstructures to produce monolithic behavior and load transfer across the structure. Shear key durability is a concern since shear key degradation can jeopardize the integrity of the structure. Transportation agencies have reported that 75% of distress in adjacent girder bridges is due to cracking and de-bonding along shear keys. Previous research has shown that …

Uhpc Shear Keys In Concrete Bridge Superstructures, Craig Newtson, Brad Weldon, Elsy Flores, Jordan Varbel, William Toledo

Publications

This research investigated the use of locally produced ultra-high performance concrete (UHPC) as a grouting material to repair deteriorated shear keys. Shear keys are used in adjacent girder superstructures to produce monolithic behavior and load transfer across the structure. Shear key durability is a concern since shear key degradation can jeopardize the integrity of the structure. Transportation agencies have reported that 75% of distress in adjacent girder bridges is due to cracking and de-bonding along shear keys. Previous research has shown that locally produced UHPC has excellent mechanical and durability properties. UHPC has also been shown to have good bonding …

Disaster Resilient And Self-Assessing Multifunctional Transportation Structures, Ibrahim Karaman, Darren Hartl

Data

Corresponding data set for Tran-SET Project No. 18STTAM02. Abstract of the final report is stated below for reference:

"This research designs and characterizes multifunctional materials, in particular inexpensive shape memory alloys, for transportation structures that possess excellent mechanical properties and self-sensing capabilities for strengthening and health monitoring. The properties are the Fe-SMAs are sensitive to part size in that the grain size of the material, which can be grown to several inches, should exceed the smallest dimension of the part. In the current work, maximum part size of the large dimension Fe-SMA rods were determined through detailed microstructural investigations. Samples …

Workforce Development Symposiums For Uhpc, Brad Weldon, Craig Newtson, Grace Mcmurry, Leticia Davila

Publications

Ultra-high performance concrete (UHPC) is a cementitious material with a dense microstructure that contributes to high compressive strengths as well as enhanced durability properties. UHPC also possesses significant post-cracking strength and ductility due to the addition of fibers. These characteristics produce a material that provides advantages over conventional concrete; however, high costs attributed to materials and production, lack of industry familiarity and knowledge, and the absence of standardized design procedures have impeded its widespread use. To help disseminate knowledge on UHPC, two workforce development symposiums on UHPC were held in Las Cruces, New Mexico. The symposiums consisted of presentations and …

Disaster Resilient And Self-Assessing Multifunctional Transportation Structures, Ibrahim Karaman, Darren Hartl

Publications

This research designs and characterizes multifunctional materials, in particular inexpensive shape memory alloys, for transportation structures that possess excellent mechanical properties and self-sensing capabilities for strengthening and health monitoring. The properties are the Fe-SMAs are sensitive to part size in that the grain size of the material, which can be grown to several inches, should exceed the smallest dimension of the part. In the current work, maximum part size of the large dimension Fe-SMA rods were determined through detailed microstructural investigations. Samples were subjected to abnormal grain growth heat treatments and found out that part size be increased up to …

High Enthalpy Storage Thermoset Network With Giant Stress And Energy Output In Rubbery State And Associated Applications, Jizhou Fan

LSU Doctoral Dissertations

In this study, a new shape memory thermoset network with giant stress and energy output in rubbery state is synthesized and studied firstly since the low output in stress and energy in rubbery state has been a bottleneck for wide-spread applications of thermoset shape memory polymers (SMPs). Traditionally, stress or energy storage in thermoset network is through entropy reduction by mechanical deformation or programming. We here report another mechanism for energy storage, which stores energy primarily through enthalpy increase by stretched bonds during programming. As compared to entropy-driven counterparts, which usually have a stable recovery stress from tenths to several …

Microstructural Characterization Of Shear Transformation Zones And Modeling Indentation Size Effect In Amorphous Polymers, Leila Malekmotiei

LSU Doctoral Dissertations

The first aim of this work is developing a procedure for experimental and analytical characterization of nano-scale microstructures which mediate large scale deformation in amorphous polymers. Glassy polymers are extensively used as high impact resistant, low density, and clear materials in industries. Nevertheless, their response under severe loading conditions is yet to be appropriately unraveled. Due to the lack of long-range order in the microstructures of glassy solids, their plastic deformation is different from that in crystalline solids. Shear Transformation Zones (STZs) are believed to be the main plasticity carriers in amorphous solids and defined as the localized atomic or …