Metallurgy Commons^™

The Mechanism Of Radiation-Induced Nanocluster Evolution In Oxide Dispersion Strengthened And Ferritic-Martensitic Alloys, Matthew John Swenson

Boise State University Theses and Dissertations

The objective of this study is to evaluate the mechanism of irradiation-induced nanoparticle evolution in a model Fe-9%Cr oxide dispersion strengthened steel and commercial ferritic-martensitic alloys HCM12A and HT9. Each alloy is irradiated with Fe²⁺ ions, protons, or neutrons to doses ranging from 1-100 displacements per atoms at 500°C. The morphology of nanoclusters are characterized using atom probe tomography. The evolution of clusters in each alloy are notably different with each irradiating particle, and the competing effects of ballistic dissolution and radiation-enhanced, diffusion-driven growth are attributed to the respective differences in cluster evolution. A phase evolution model, originally theorized …

Characterization Of Slm Printed 316l Stainless Steel And Investigation Of Microlattice Geometry, Finley H. Marbury

Materials Engineering

The goal of this project was firstly to characterize Cal Poly’s SLM printed 316L stainless steel. SEM analysis showed Cal Poly’s as-printed 316L material to have a cellular dendritic microstructure containing mostly austenite and a small amount of δ-ferrite. After being heat treated to eliminate warp, its yeild and ultimate tensile strength were on par with the literature, however higher modulus and lower elongation were observed. XRD analysis confirmed residual stresses in the material, and that grains are preferentially oriented in both heat treated and non heat treated samples. The amount of porosity in the material was found to be …

Characterization Of The 15-5 Stainless Steel Electric Discharge Machining Recast Layer, Julian R. Lohser, Rhys W. Gilmore

Materials Engineering

Electric discharge machining (EDM) is a non-conventional machining process that is used for tough, hard materials or materials that require no tool force. Wire EDM produces a recast layer and heat-affected zone as a result of rapid melting and quenching at the surface of the cut. A secondary machining operation has been required to remove this layer. Previous estimates of the depth of the recast layer are likely too conservative due to improvements in the technology; therefore, the goal of this study is to characterize and more accurately investigate the size of the layer. Two EDM machine parameters, voltage and …

Tensile Properties Of High-Strength Connecting Rod Bolts, Leland K. Lam

Materials Engineering

Oliver Racing Parts (ORP) is looking to optimize the manufacturing process for high-strength connecting rod bolts. A high yield strength is desired for the bolts because deformation would result in a loss of engine performance. A high tensile strength is also necessary to prevent catastrophic failure if deformation occurs. A high ductility as a proxy for toughness is attractive for resisting crack nucleation and growth during cyclic loading. Bolts were made of MP35N, a nickel-cobalt multiphase alloy; MLX-17, a precipitation hardenable stainless steel; 8740, a low alloy steel; and H11, a chromium hot-work tool steel. The temperature of the most …

Straightening Of Investment Casting Ni-Based Superalloys, Silvia Squillaci, Janessa Cabrera

Materials Engineering

Samples belonging to four different designs of afterburner flaps, available in the as-cast, solutionized and aged conditions, underwent 4-point bend testing to fracture to investigate straightening. The average maximum load values of the second design samples in the as-cast, solutionized and aged conditions were respectively 33 kN, 29 kN and 27 kN. Regarding the fourth design samples, the average maximum load for the as-cast, solutionized and aged conditions were respectively 23 kN, 28 kN, and 25 kN. The other parameter measured during testing was the maximum extension at fracture. All as-cast samples belonging to the second design fractured at values …

Effect Of Composition And Build Direction On Additively Manufactured Hastelloy X Alloys, Justin A. Spitzer, Jeffrey T. Schloetter, Sarah Zerga

Materials Engineering

Microcracking has caused premature failure and reduction in properties in additively manufactured (AM) Hastelloy X. The purpose of this research is to meet or exceed the mechanical properties of wrought Hastelloy X by modifying the composition and build direction of Hastelloy X manufactured using Direct Metal Deposition (DMD). Tensile testing, scanning electron microscopy (SEM), and metallography were performed on the samples. ANOVA was used to analyze the dependence that the properties had on build direction and composition. The nominal composition wrought samples had a yield strength of 310.1 MPa and a 60.79% Elongation. Alloy P60-X18 in a horizontal build had …

Comparison Of Intrusive And Non-Intrusive Methods For Corrosion Monitoring Of Fuel Processing Systems, Armando Jacob Espinoza, Thomas Conner Field

Materials Engineering

This presentation contains an assessment of the best overall corrosion monitoring device, intrusive or non-intrusive, for use in the petrochemical industry. Corrosion in the petrochemical industry is a large issue because it causes a deterioration of pipe integrity in fuel processing systems. A reduction of pipe wall integrity due to corrosion could result in a leak or an explosion of fuel processing lines since those systems function at high pressures. The use of corrosion monitoring systems in the petrochemical industry helps to detect early signs of corrosion prior to failure so that proper maintenance can be performed to prevent catastrophe. …

Predicting Service Life Of 347 Stainless Steel Pipes By Carburization Rate Measurement, Tyler L. Sura

Materials Engineering

Chevron Corporation and other refiners face challenges predicting the service life of piping in coker furnaces. This is largely due to a build up coke on a single surface of the piping. This coke build up results in carbon penetration into the surface of the 347 stainless steel used for the pipes. Carbon penetration can lead to degradation of the surface and ultimately, the failure of the pipe. Current modeling software has difficulty predicting the influence of sulfur on the carbon penetration rate. This study aims to provide a baseline for further study into the subject. The carbon penetration rate …

Development Of Low Cost Braze Alloys For Aerospace Applications, Alyssa M. Elliott, Sandy Babich, Blake Whitmee

Materials Engineering

Non-precious metal braze alloys can help lower the cost of brazing, which is a commonly-used joining process in the aerospace industry. A-286, a stainless steel superalloy, and Inconel© 718, a nickel-based superalloy, are both commonly used alloys at Aerojet Rocketdyne. Both alloys were brazed into butt joints using nickel-based braze alloys: AMS 4776, 4777, and 4778. The brazed samples were machined into a modified version of the ASTM E8 subsize specimen samples and tensile tested to compare the strength and calculated elongation of the brazed samples to the base metals’ properties. All of the brazed samples fractured at the joint, …

Preliminary Investigations Into Selective Laser Melting, David Takeo Otsu

Master's Theses

Selective laser melting is a promising metallic additive manufacturing process with many potential applications in a variety of industries. Through a gracious donation made by Lawrence Livermore National Laboratory, California Polytechnic State University received and installed an SLM 125 HL selective laser melting machine in February 2017. As part of the initial setup effort, a preliminary machine verification study was conducted to evaluate the general print quality of the machine with default parameter settings. Coincidentally, the as-printed microstructure of SLM components was evaluated through nil strength fracture surface examination, an alternative to conventional polish-and-etch metallography. A diverse set of components …

The Magnetic, Electrical And Structural Properties Of Copper-Permalloy Alloys, Makram A. Qader, A. Vishina, Lei Yu, Cougar Garcia, Rakesh K. Singh, Nicholas D. Rizzo, Mengchu Huang, Ralph Chamberlin, Kirill Belashchenko, Mark Van Schilfgaarde, N. Newman

Kirill Belashchenko Publications

Copper-permalloy [Cu_1–x(Ni₈₀Fe₂₀)_x] alloy films were deposited by co-sputtering and their chemical, structural, magnetic, and electrical properties were characterized. These films are found to have favorable weak ferromagnetic properties for low temperature magnetoelectronic applications. Our results show that by varying the composition, the saturation magnetization (M_s) can be tuned from 700 emu/cm³ to 0 and the Curie temperature (T_c), can be adjusted from 900 K to 0 K. The M_s and T_c are found to scale linearly between x = 25% and 100%. Electronic structure calculations …

Kinked Tensile Behavior Of Cold Worked Nitinol, Grant R. Caraway, Samuel J. Canovas

Materials Engineering

To characterize the decrease in ductility caused by an induced stress concentration as a function of various levels of cold work and heat treatment, Nitinol medical guide wires with a .004″ diameter were tested using both a standard, straight tensile test and a modified, bent tensile test. The ratio of the two break loads (bent:straight) for identically processed samples was used as a proxy for measuring the ductility of the guide wires: the higher the ratio, the more ductile the sample. The average break load ratio as a function of increased cold work, decreased from 1.27 to 0.91 for the …

Process Development And Implementation For The Imaging Of Heat Treated A2 Steel For Consolidation Into An Atlas, Jessica Roberts

Senior Honors Projects, 2010-2019

Material processes, properties, and microstructure are interconnected, often visualized as the points of a triangle. Changing the process a material goes through will in turn change the properties and microstructure of that material. In materials research and education (specifically with metals), comparison between research or experiment results and scholarly-accepted results is important. When reading textbooks addressing different properties of metals and the process of metal treatment, images are often shown of the various microstructures associated with each property or process stage. The difficulty comes in trying to compare the stages or properties to one another; often different materials and processes …

Characterization Of Plastic Deformation Evolution In Single Crystal And Nanocrystalline Cu During Shock By Atomistic Simulations, Mehrdad Mirzaei Sichani

Graduate Theses and Dissertations

The objective of this dissertation is to characterize the evolution of plastic deformation mechanisms in single crystal and nanocrystalline Cu models during shock by atomistic simulations. Molecular dynamics (MD) simulations are performed for a range of particle velocities from 0.5 to 1.7 km/s and initial temperatures of 5, 300 and 600 K for single crystal models as well as particle velocities from 1.5 to 3.4 km/s for nanocrystalline models with grain diameters of 6, 11, 16 and 26 nm. For single crystal models, four different shock directions are selected, <100>, <110>, <111> and <321>, and dislocation density behind the shock wave …

Fabrication And Study Of The Structure And Magnetism Of Rare-Earth Free Nanoclusters, Bhaskar Das

Department of Physics and Astronomy: Dissertations, Theses, and Student Research

No abstract provided.

Adsorption Of Salicylhydroxamic Acid On Selected Rare Earth Oxides And Carbonates, Greer Galt

Graduate Theses & Non-Theses

Adsorption behavior of the anionic collector salicylhydroxamic acid (SHA) on a selected group of rare earth oxides (REOs) and carbonates (RECs) was studied via experimental methods and modelling software. Synthetic oxide and carbonate powders of the rare earth elements cerium (Ce), praseodymium (Pr), europium (Eu), and terbium (Tb) were tested for this research. Studies were conducted at different pH levels to analyze the kinetics of collector adsorption onto the oxide and carbonate surfaces in attempts to optimize recovery parameters for commercial flotation processes using SHA. In addition, thermodynamic software StabCal was implemented to compare theoretical adsorption behavior of collectors SHA …

A Plastic Design Method For Rc Moment Frame Buildings Against Progressive Collapse, Hadi Faghihmaleki

Makara Journal of Technology

In this study, progressive collapse potential of generic 3-, 8- and 12-storey RC moment frame buildings designed based on IBC-2006 code was investigated by performing non-linear static and dynamic analyses. It was observed that the model structures had high potential for progressive collapse when the second floor column was suddenly removed. Then, the size of beams required to satisfy the failure criteria for progressive collapse was obtained by using the virtual work method; i.e., using the equilibrium of the external work done by gravity load due to loss of a column and the internal work done by plastic rotation of …

In Vitro Toxicity Evaluation Of Caffeine Imprinted Polymer (Caf-Mip) For Decaffeination Method On Normal Chang Liver Cells, Fatimah Hashim, Faizatul Shimal Mehamod, Naizatul Akmal Nawi

Makara Journal of Technology

Over consuming of caffeine is one of the factors to a few health problems such as insomnia, hypertension and cardiovascular disease. This preliminary study was conducted to evaluate the Caffeine-Imprinted Polymer (CAF-MIP) toxicity that was synthesized for a new alternative method for decaffeination. It is crucial to evaluate the toxicity of CAF-MIPas this product is potential to be used as complimentary with any drinks containing caffeine. In this study, the CAF-MIP toxicity potential was confirmed on Normal Chang Liver cell (NCLC) based on its IC50 value andacridine orange and propidium iodide (AO/PI) staining for mode of cell death observation.Proliferation assay …

Sorption And Ion Exchange Behaviour Of Natural Zeolite Packing, Chandra Wahyu Purnomo, Bernice Lenora, Wiratni Budhijanto, Hirofumi Hinode

Makara Journal of Technology

It is well known that zeolite is an efficient metal ions adsorbent. The excess charge of the zeolite building blocks i.e. (AlO4)-5 and (SiO4)-4 creating a negative surface charge that attract metal cations. Beside the surface charge, zeolite also has three dimensional pore structure and reasonably large surface area which also can be used as adsorption sites. Ease of cation uptake make it suitable for many process with adsorption and desorption application. This study was conducted to observe the sorption and ion exchange behaviour of zeolite-betonite rings toward iron and cobalt cations. The results shows that the adsorption patterns follow …

Encapsulation Process Of Propolis Extract By Casein Micelle Improves Sunscreen Activity, Muhamad Sahlan, Dara Dienayati, Darul Hamdi, Soraya Zahra, Heri Hermansyah, Malyn Chulasiri

Makara Journal of Technology

Propolis, a wax bee glue, have antioxidant activity and effective as broad spectrum UVB and UVA photoprotection sunscreens agent. To improve photoprotection activity in sunscreen cream, the propolis was encapsulated by casein micelle. The Indonesian propolis was extracted by ethanol and separated the wax by freeze precipitation. The extract was encapsulated by casein and reduced their size by ball mill homogenizer with the encapsulation efficiency about 80% and size of particles about 80 nm. The particles was applied in sunscreen cream, evaluate their stabillity and photoprotection activity Sun Protection Factor (SPF) spectrophotometer (Optometric 290s). The results shows that the selected …

Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel

Makara Journal of Technology

Development of fuel cladding and structural materials in Pb-Bi environment, especially at high temperature, is a critical issue for the deployment of LFR (Lead alloy-cooled Fast Reactor) and ADS (Accelerator Driven Transmutation System). This is because of the corrosive characteristic of Pb-Bi to metals as constituent materials of fuel cladding and structural of the reactors. Corrosion test of a high-chromium austenitic stainless steel i.e. SS316Ti in molten Pb-Bi at 550 ºC has been carried out for about 300 hours continuously. The characterization using SEM-EDS (Scanning Electron Microscopy - Energy Dispersive X-ray Spectroscopy) showed that an iron oxide as the outer …

Synthesis Of Libob Fine Powder To Increase Solubility, Etty Marti Wigayati, Titik Lestariningsih, Christin Rina Ratri, Ibrahim Purawiardi, Bambang Prihandoko

Makara Journal of Technology

Lithium bis (oxalate) borate or LiBOB compound has captured interest of researchers, because it is potentially viable to be used as electrolyte salt in lithium-ion battery system. This compound is easy to synthesize and considered to be more environmentally friendly compared to conventional electrolyte salt because LiBOB does not contain halogen element. This research focused on the synthesis of LiBOB fine powder, which main purpose is improving LiBOB salt solubility in liquid electrolyte solution. This will aid the ion transfer between electrodes which in turn will increase the electrolyte performance. Solid state reaction was employed in this experiment. Synthesis of …

Influence Of Polyethylene Glycol (Peg) In Cmc-Nh4br Based Polymer Electrolytes: Conductivity And Electrical Study, Nur Khalidah Zainuddin, Ahmad Salihin Samsudin

Makara Journal of Technology

The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable …

Purification Simulation With Vapor Permeation And Distillation-Adsorption In Bioethanol Plant, Misri Gozan, Mia Sari Setiawan, Kenny Lischer

Makara Journal of Technology

High purity of Bioethanol is required in biofuel mixing with gasoline (EXX). In bioethanol production line, the azeotropic property of ethanol-water becomes the barrier for purification process. This study examined two bioethanol separation processes by support of simulation tools, Superpro Designer 9.0 software. Ethanol purity and a low costeconomical process were the major considerations. Purification method of vapor permeation membrane technology was compared with distillation-adsorption method. Data from previous lab experiments and some literatures were used. The results showed that distillation-adsorption method is more economical compared to vapor permeation technology. Payback period of the simulation is 3.9 years and 4.3 …

Tailoring Magnetic Behavior Of Cofemnnix (X = Al, Cr, Ga, And Sn) High Entropy Alloys By Metal Doping, Tingting Zuo, Michael C. Gao, Lizhi Ouyang, Xiao Yang, Yongqiang Cheng, Rui Feng, Shuying Chen, Peter K. Liaw, Jeffrey A. Hawk, Yong Zhang

Mathematical Sciences Faculty Research

Magnetic materials with excellent performances are desired for functional applications. Based on the high-entropy effect, a system of CoFeMnNiX (X = Al, Cr, Ga, and Sn) magnetic alloys are designed and investigated. The dramatic change in phase structures from face-centered-cubic (FCC) to ordered body-centered-cubic (BCC) phases, caused by adding Al, Ga, and Sn in CoFeMnNiX alloys, originates from the potent short-range chemical order in the liquid state predicted by ab initio molecular dynamics (AIMD) simulations. This phase transition leads to the significant enhancement of the saturation magnetization (Ms), e.g., the CoFeMnNiAl alloy has Ms of 147.86 Am2/kg. First-principles density functional …

Design And Validation Of Novel Potential High Entropy Alloys, Boliang Zhang

LSU Doctoral Dissertations

The design approach and validation of single phase senary refractory high entropy alloys (HEAs) MoNbTaTiVW and HfNbTaTiVZr were presented in first part of this dissertation. The design approach was to combine phase diagram inspection of available binary and ternary systems and Calculation of Phase Diagrams (CALPHAD) prediction. Experiments using X-ray diffraction and scanning electron microscopy techniques verified single phase microstructure in body centered cubic lattice for both alloys. The observed elemental segregation agrees well with the solidification prediction using Scheil model. The lattice constant, density and microhardness were measured to be 0.3216 nm, 4.954 GPa and 11.70 g/cm³ for …

Tensile Specimen Punch, John Allen

All Undergraduate Projects

This project comes from a need to have tensile specimens made for the MET 351, Metallurgy/Materials and Processes, and 426, Applied Strengths of Materials, labs. This punch is designed to be used with an arbor press to create the desired tensile specimen shape out of plastic blanks. The initial concept was suggested by Dr. Craig Johnson. The designs went through many changes, for example getting rid of the sides originally proposed to hold the specimen in place, and modifications to other parts to make them more efficient. Additional parts were also added to the design with the help and advice …

Thermal Analysis Of 3d Printed 420 Stainless Steel, Adithya Pothuri

All Graduate Theses, Dissertations, and Other Capstone Projects

Additive manufacturing opens new possibilities in the manufacturing industry. 3D printing is a form of additive manufacturing. 3D printers will have a significant influence over the industrial market, with extremely positive effects in no time. The main aim of this research is to determine the effect of process parameters of Binder Jet manufactured 420 Stainless Steel (420SS) parts on thermal properties such as thermal conductivity. Different parameters, such as layer thickness, sintering time and sintering temperature were varied. A full factorial design of experiment matrix was made by varying these parameters using two levels. Testing showed that different parameters affected …

Shape Memory Behavior Of Dense And Porous Niti Alloys Fabricated By Selective Laser Melting, Soheil Saedi

Theses and Dissertations--Mechanical and Aerospace Engineering

Selective Laser Melting (SLM) of Additive Manufacturing is an attractive fabrication method that employs CAD data to selectively melt the metal powder layer by layer via a laser beam and produce a 3D part. This method not only opens a new window in overcoming traditional NiTi fabrication problems but also for producing porous or complex shaped structures. The combination of SLM fabrication advantages with the unique properties of NiTi alloys, such as shape memory effect, superelasticity, high ductility, work output, corrosion, biocompatibility, etc. makes SLM NiTi alloys extremely promising for numerous applications.

The SLM process parameters such as laser power, …

Effects Of Temperature, Orientation, Load Level And Indenter Shape On The Indentation Response Of Niti-Based Shape Memory Alloys, Peizhen Li

Theses and Dissertations--Mechanical and Aerospace Engineering

Owing the capability of recovering large deformations through reversible phase transformation, shape memory alloys (SMAs) are well-known for their unique behaviors such as shape memory effect (SME) and superelasticity (SE), which can also be characterized by instrumented indentation techniques. Nickel titanium (NiTi) SMAs have been extensively used for nano/micro-indentation studies and widely applied to biomedical and other elaborate medical devices.

In this study, indentation responses of NiTi, NiTiHf, NiTiHfPd and NiTiHfCu alloys were investigated using spherical and Berkovich indenters at room temperature. Spherical and Berkovich indentation hardness, modulus, and work/depth recoverable ratio of these NiTi-based alloys were revealed as a …