Metallurgy Commons^™

Zinc Plating From Alkaline Non-Cyanide Bath, Abdul J. Mohammed

Masters Theses

“Alkaline non-cyanide zinc plating baths are preferred when trying to avoid the toxicity of cyanide baths or corrosivity of acid baths. Without additives, alkaline zincate baths produce powdery non-adherent deposits which have no use in commercial plating. Additives must be added at optimum concentrations to produce adherent, bright and uniform zinc deposits. In this study electrochemical tests were used to determine effects of additives on cathodic polarization, throwing power and morphology of deposits. Current density distribution in a unique bath of 37.5 g L^-1 Zn and 210 g L^-1 NaOH was modelled using COMSOL and validated two plating …

Assessing Mechanical Performance Of Dissimilar Steel Systems Made Via Wire-Arc Additive Manufacturing, Obed Daniel Acevedo

Masters Theses

Hot stamping is part of a specific type of metalworking procedure widely used in the automotive industry. This research seeks to help make hot stamp tooling component production more cost-effective by using large-scale additive manufacturing. Additive manufacturing can produce dissimilar steel components that can be more cost-effective and time-efficient and allow for complex geometries to be made. A dissimilar steel system consisting of 410 martensitic stainless steel and AWS ER70S-6 mild steel is proposed to make hot stamps, making them more cost-efficient. However, the material interface's mechanical behavior in 410SS-mild steel additively manufactured material systems is not well understood. This …

Optimization Of The Practice Of Slow Cooling Steel Bars: A Redesign And Modernization Of Materials, Eryn Johnston

Mechanical Engineering Undergraduate Honors Theses

Throughout the process of steel making, certain grades of steel are a higher risk for defects caused by the inability to quickly diffuse hydrogen through the steel when cooled to room temperature at a normal rate based on the ambient air temperature. To reduce the hydrogen flaking defects that are caused due to hydrogen entrapment in the steel, the process of slow cooling is utilized. This process reduces the cooling rate of steel bars by keeping them at a higher temperature for extended periods and in turn gives the hydrogen a chance to fully dissipate from the steel. In many …

Preliminary Investigations Into Selective Laser Melting, David Takeo Otsu

Master's Theses

Selective laser melting is a promising metallic additive manufacturing process with many potential applications in a variety of industries. Through a gracious donation made by Lawrence Livermore National Laboratory, California Polytechnic State University received and installed an SLM 125 HL selective laser melting machine in February 2017. As part of the initial setup effort, a preliminary machine verification study was conducted to evaluate the general print quality of the machine with default parameter settings. Coincidentally, the as-printed microstructure of SLM components was evaluated through nil strength fracture surface examination, an alternative to conventional polish-and-etch metallography. A diverse set of components …

Process Development And Implementation For The Imaging Of Heat Treated A2 Steel For Consolidation Into An Atlas, Jessica Roberts

Senior Honors Projects, 2010-2019

Material processes, properties, and microstructure are interconnected, often visualized as the points of a triangle. Changing the process a material goes through will in turn change the properties and microstructure of that material. In materials research and education (specifically with metals), comparison between research or experiment results and scholarly-accepted results is important. When reading textbooks addressing different properties of metals and the process of metal treatment, images are often shown of the various microstructures associated with each property or process stage. The difficulty comes in trying to compare the stages or properties to one another; often different materials and processes …

Metallurgical Optimization Of High Strength Cast Steels With Stage I Tempering, Terrell Owen Webb Jr.

Doctoral Dissertations

“Eglin steel was developed by the U.S. Air Force and Ellwood National Forge Company as a cost-effective, ultrahigh strength steel for use in armament, aerospace, and commercial applications. Eglin steel has been successfully substituted for high alloy steels, such as AF1410 and HP-9-4-20/30, to produce the casing for “bunker buster” bombs where penetration of concrete barriers and rock at high velocity ( > 1000 ft/sec) is desired. Unlike AF1410 and HP-9-4-20/30, Eglin steel is low nickel (nominal 1 wt.%) and contains no cobalt. Given the successful performance of Eglin steel in the casings applications, the Department of Defense has directed that …

An Intercritical Heat Treatment Study Of High Strength, Microalloyed Ferrous Open Die Forgings, Kelly Elizabeth Stewart

Materials Engineering

High strength, low alloy steel is most commonly utilized in plate or sheet form-with a thickness under 4 in, one unconventional application however, is open die forging where cross-sectional area can be as large as 9.5 in by 11.5 in. When forging to larger section size than one would thermo-mechanically roll sheet steel, a new set of complications, such as variation in microstructure and mechanical properties, arise. This study investigates the heat treatment and processing options needed to negate the inherent microstructural irregularity and Charpy V-Notch (CVN) toughness variation. Intercritical heat treatment—normalizing and then quench and tempering above the A …

Mechanical Properties And Microstructures Of Incoloy 909 Rolled Rings Subjected To A Modified Forging Cycle, Colin Lee Elliott Glaves

Materials Engineering

The microstructure of rolled rings of Incoloy 909 nickel-iron-cobalt superalloy subjected to a standard customer solution and aging treatment exhibited unacceptably large grains. Samples cut from a failed ring were mounted and polished for analysis. The samples were etched with a modified Kalling’s waterless reagent and metallographic analysis was done to identify characteristic large grain structures distributed among the desired smaller grain structures. The large grains were identified and noted for comparison to later samples. Two test rings were forged out of Incoloy 909 using revised forging procedures involving reduced soak temperatures before each forging step. Metallographic samples were cut …

Investigation Of The Ternary System Silver-Aluminum-Indium (Ag-Al-In), Elvin H. Beardslee

Bachelors Theses and Reports, 1928 - 1970

This thesis paper contains material pertaining to & preliminary investigation of the ternary system Ag-Al-In. Procedures in this preliminary investigation are discussed in detail.

Physico-Chemical Principles Of Sixteenth Century Metallurgy, Robert E. Johnson

Bachelors Theses and Reports, 1928 - 1970

Following a review of sixteenth century metallurgical literature and a discussion of Gibbs free energy, this thesis discusses thermodynamic considerations of galena (PbS) reduction by iron from a lead assay of this period. The importance of fluxes in this assay is emphasized. The discussion covers both equilibrium and non-equilibrium conditions at 1100 degrees Celsius. Possible substitutes for iron are also covered.

Information from twenty-one small controlled lead assays is correlated with the thermodynamic discussion to determine the purpose of each constituent in the assay.

The Effect Of Ph Upon Chelation Reactions In Montmorillonite Clays, Joseph Michael Keane

Bachelors Theses and Reports, 1928 - 1970

The purpose of this thesis is to investigate several chelation reactions and determine the effect of variable pH upon these reactions.

Microradiography Of Metals And Alloys Using A Medical X-Ray Unit, W. R. Byrne

Bachelors Theses and Reports, 1928 - 1970

There is no doubt that the microradiograph technique is of value to the metallurgist. A three-dimensional picture to supplement the photomicrographs should give a true picture of the microstructure. Microradiography can be used where etchants can not differentiate between the various components or where no etchant can be found suitable for a particular alloy.

Investigation Of Inclusions In Armco Ingot Iron, Edwin J. Duncan

Bachelors Theses and Reports, 1928 - 1970

Various chemical and electrolytic separation methods were investigated in an attempt to separate the in­clusions in Armco ingot iron. Residues obtained were X-rayed for identification purposes. The microstruc­tures of this iron were studied with the object of de­termining the relative sizes, locations, and possible compositions of the inclusions.

Polarographic Determination Of Germanium, Calvin Leo Stevenson

Bachelors Theses and Reports, 1928 - 1970

In the past germanium has been determined by either wet methods or by the spectograph; the spectograph being used for the determination of very small amounts of ger­manium and wet methods used when more than one hundredth of one percent germanium is present. Both of these analyti­cal schemes have weaknesses.

The Decomposition Of Calcium Tungstate And Synthetic Scheelite With Hydrochloric Acid, Robert R. Beebe

Bachelors Theses and Reports, 1928 - 1970

The decomposition of scheelite with hydrochloric acid was studied under conditions of variable acid concentration, time and temperature. The reactions were traced by weigh­ing material untransformed and, in some cases, by analyzing the transformation products.

A Study Of The Effects Of The Chloride Ion On The Lead-Silver Anodes And On The Lead Tenor Of The Zinc Deposit In Zinc Electrolysis, William A. Mitchell

Bachelors Theses and Reports, 1928 - 1970

The electrolyte used in the commercial production of electrolytic zinc from zinc sulphate solutions contains small amounts of impurities each of which has its own effects upon the process. Impurities such as antimony, cobalt, nickel, and iron tend to lower the current efficiency while other impurities such as chlorine, fluorine, and nitrates tend to increase the corrosion of the lead anodes and thereby increase the lead tenor of the zinc deposit.

A Study Of The Beneficiation Of Low-Grade Domestic Chromite, Darrell Edward Bodie

Bachelors Theses and Reports, 1928 - 1970

Chromite, a strategic mineral, is being consumed in ever increasing quantities in the United States today. Although the United States imports practically all of the chromite that is being consumed, it is gradually becoming necessary to exploit the low-grade deposits that are located within the United States, and also the low-grade deposits of Canada.

The Mechanical Production Of Zinc Dust, Charles A. Schroer

Bachelors Theses and Reports, 1928 - 1970

The object of this thesis is to produce zinc dust suitable for zinc leach purification, by direct application of a mechanical force on a stream of molten zinc.The project is a continuation of work done by Mr. D. S. Gleason, while working for his Master of Science degree in the spring of 1952.

The Mechanical Production Of Zinc Dust, Robert F. Payne

Bachelors Theses and Reports, 1928 - 1970

It was the purpose of this investigation to delve further into the possibility of producing, by mechanical means, a zinc dust which might be suitable for the puri­fication of zinc leach solution.

The Immersion Coating Of Indium Upon Magnesium From Sulphate Solutions Containing Flourides, John J. Harrington

Bachelors Theses and Reports, 1928 - 1970

The thesis problem that will be discussed in this report is an investiga­tion of a method of plating a coating of indium upon magnesium and magnesium alloys. The method used to accomplish the final results is the immersion pro­cess. It can be defined as the process of coating a metal with a second metal by immersing the first in a solution containing ions of the second.

The Occurrence Of Molybdenite In The United States, Alaska, Canada, And Newfoundland, Richard W. Brummett

Bachelors Theses and Reports, 1928 - 1970

In this study of molybdenite and its occurrence, the pub­lished literature on 66 separate deposits was reviewed, sum­marized, and coordinated. The following descriptions are in­tended to point out the important features of molybdenite oc­currences as described in the literature.

Variation Of Induction And Hysteresis Curves For The Heusler Alloy, Cu2mna1, Ford W. Knight

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the fundamental magnetic characteristics of induction and hysteresis, for the alloy Cu₂MnAl. This is a ternary, ferromagnetic Heusler alloy. The problem is not only to determine these characteristics for the alloy as-cast but to heat treat it and observe the manner in which different heat treat­ments affect these two fundamental magnetic characteristics.

The Metallography Of Aluminum Casting Alloys, Donald D. Goehler

Bachelors Theses and Reports, 1928 - 1970

The purpose of this thesis is to supply the Montana School of Mines with an up to date source of information concerning the metallography of aluminum casting alloys. This thesis is designed as a continuing project. Ultimately, it is hoped that a catalog containing all the typical structures of aluminum casting alloys will develop.

An Investigation Of The Hardening Properties Of Some Alpha Copper Indium Alloys, Charles W. Mcpherson

Bachelors Theses and Reports, 1928 - 1970

Precipitation hardening alloys has assumed a major role in modern da^y development of alloys. In his search for stronger, harder materials, the metallurgist has often been limited by the cost of metals which posses the needed properties.

Electrowinning With Amalgam Electrode, Ralph V. Anderson Jr.

Bachelors Theses and Reports, 1928 - 1970

Amalgam Metallurgy, a relatively new expression in the technology of metal extraction, was first chosen to describe certain new processes developed at the Duisburg Copper Works in Germany. The idea of using mercury, a costly and poisonous metal, as an intermediate in heavy chemical industry and in polarography are of recent origin; with the exception of a series of patents of little signif­icance and occasional comments in the literature, the work is hardly known.

The Influence Of Copper Upon The Age Hardening Properties Of Steel, Andre Rey

Bachelors Theses and Reports, 1928 - 1970

The virtues of alloy steels have been widely publi­cized in both technical literature and everyday adver­tising. Nearly everyone possessing a slight knowledge of metallurgy knows the beneficial effects of chromium in the manufacture of stainless steels, or the importance of nickel, molybdenum, vanadium, and other common elements used to alloy steels.

The Electrolytic Purification Of An Impure Cadmium Sulfate Solution With A Cell Utilizing A Mercury Cathode And A Lead Anode, W. D. Mcmaster

Bachelors Theses and Reports, 1928 - 1970

Cadmium is produced solely as a by-product and all cadmium of commerce is obtained from zinc ores. It is a rare occurrence when zinc deposits are found which do not contain some cadmium.

Determination Of The Activities Of Indium And Mercury And The Vapor Pressures Of Mercury Over These Amalgams From 0.00216 To 0.02494 Mole Fraction Indium At 25 C And From 0.00067 To 0.02410 Mole Fraction Indium At 70 C By Electromotive Force Measurements, Arthur H. Lutts

Bachelors Theses and Reports, 1928 - 1970

This work was performed to determine by experimental means the activities of both indium and mercury and the vapor pressures of mercury over these amalgams at 25 and 70 C.

Electrowinning Versus Electrorefining Of Blister Copper, Frank J. Vorell

Bachelors Theses and Reports, 1928 - 1970

In the following sections of this report, I will discuss as fully as possible both the theo­retical and practical aspects of the roasting, leaching, and electrowinning steps, as well as the economic considerations of the process. The results of my laboratory work will, of course, be integrated to the process.

Resistance Of Solid Inconel To Attack By Liquid Indium, David C. Hendra

Bachelors Theses and Reports, 1928 - 1970

The role of liquid metals in industry is rap­idly becoming of increasing importance. The phys­ical and chemical tendencies of metals in the liq­uid condition must be ascertained before a metal in this form can be put to practical usage. In very many stages of mineral processing and recovery, in molten-metal baths for temperature control on heat treating, and in several industries where heat transfer is an important aspect, metals may be at one time or another in a liquid condition.