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Theses/Dissertations

2021

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Full-Text Articles in Metallurgy

Study Of Alloy And Process Modifications To Design Hydrogen Resilient High Hardness Steels, William R. Williams Dec 2021

Study Of Alloy And Process Modifications To Design Hydrogen Resilient High Hardness Steels, William R. Williams

Theses and Dissertations

High hardness steels (HHS) are vulnerable to hydrogen embrittlement, which can lead to rapid degradation of mechanical properties. Improved resistance to hydrogen embrittlement would be beneficial to many industries including construction, automotive, and military. A comparison study was performed to assess the hydrogen susceptibility of select commercially available and in-house designed HHS alloys. Slow strain rate tensile tests, performed with specimens charged with various levels of hydrogen, provided a macroscopic view of the onset of hydrogen embrittlement. Hydrogen permeation and thermal desorption spectroscopy tests determined the uptake and diffusivity of hydrogen through the material. The evaluation of hydrogen susceptibility for …


Fundamentals Of Cavity Formation In Α-Fe And Fe-Cr Alloys, Yan-Ru Lin Dec 2021

Fundamentals Of Cavity Formation In Α-Fe And Fe-Cr Alloys, Yan-Ru Lin

Doctoral Dissertations

Ferritic-martensitic steels are attractive candidate materials for fusion and advanced fission reactors primarily due to their low swelling characteristic, attractive thermo-mechanical properties, and the potential for development of nanostructured ferritic alloys. However, significant discrepancies exist regarding the effect of solutes and irradiation temperature on cavity swelling under ion versus neutron irradiation conditions. Several mechanisms have been proposed that may affect cavity swelling, but no general theory or model has received complete acceptance to explain these phenomena.

To better understand the formation of cavities in ferritic steels, we have performed multi-temperature (400-550°C) single-beam and simultaneous dual-beam irradiations (ex-situ and in-situ) on …


Assessing Mechanical Performance Of Dissimilar Steel Systems Made Via Wire-Arc Additive Manufacturing, Obed Daniel Acevedo Dec 2021

Assessing Mechanical Performance Of Dissimilar Steel Systems Made Via Wire-Arc Additive Manufacturing, Obed Daniel Acevedo

Masters Theses

Hot stamping is part of a specific type of metalworking procedure widely used in the automotive industry. This research seeks to help make hot stamp tooling component production more cost-effective by using large-scale additive manufacturing. Additive manufacturing can produce dissimilar steel components that can be more cost-effective and time-efficient and allow for complex geometries to be made. A dissimilar steel system consisting of 410 martensitic stainless steel and AWS ER70S-6 mild steel is proposed to make hot stamps, making them more cost-efficient. However, the material interface's mechanical behavior in 410SS-mild steel additively manufactured material systems is not well understood. This …


Laser Surface Treatment And Laser Powder Bed Fusion Additive Manufacturing Study Using Custom Designed 3d Printer And The Application Of Machine Learning In Materials Science, Hao Wen Aug 2021

Laser Surface Treatment And Laser Powder Bed Fusion Additive Manufacturing Study Using Custom Designed 3d Printer And The Application Of Machine Learning In Materials Science, Hao Wen

LSU Doctoral Dissertations

Selective Laser Melting (SLM) is a laser powder bed fusion (L-PBF) based additive manufacturing (AM) method, which uses a laser beam to melt the selected areas of the metal powder bed. A customized SLM 3D printer that can handle a small quantity of metal powders was built in the lab to achieve versatile research purposes. The hardware design, electrical diagrams, and software functions are introduced in Chapter 2. Several laser surface engineering and SLM experiments were conducted using this customized machine which showed the functionality of the machine and some prospective fields that this machine can be utilized. Chapter 3 …


Studies Of Creep Damage In The Heat-Affected Zone Of 9cr-1mo-Vnb Steel Weldments, John William Bohling Aug 2021

Studies Of Creep Damage In The Heat-Affected Zone Of 9cr-1mo-Vnb Steel Weldments, John William Bohling

Doctoral Dissertations

Creep strength enhanced ferritic (CSEF) steels are used in power plants for high temperature, pressure-containing welded components such as steam headers. One CSEF steel, 9Cr-1Mo-VNb or Grade 91, often exhibits localized creep deformation and cavitation in the weld heat-affected zone (HAZ), identified as Type IV creep damage. Three Grade 91 weldments were evaluated by creep testing and microstructural characterization using optical and scanning electron microscopy, combined with image analysis, to investigate microstructure evolution and creep damage. Two weldments fabricated from dissimilar base metals were used for direct comparison of creep damage in two materials simultaneously during cross-weld testing. Longitudinal creep …


Transients In Plastic Instabilities During Thermo-Mechanical Reversals In An Additively Manufactured Ti6al4v, Sabina C. Kumar Aug 2021

Transients In Plastic Instabilities During Thermo-Mechanical Reversals In An Additively Manufactured Ti6al4v, Sabina C. Kumar

Doctoral Dissertations

A complex interaction of process variables in an evolving geometry during Additive Manufacturing (AM), can bring about spatial and temporal transients of temperature and stress within each layer in a part. Although AM shares commonalities with conventional processing techniques such as casting, welding, and thermo-mechanical process, published literature has shown that the steady-state conditions are not strictly valid during AM process. Macro-scale fluctuations of thermal gradients (dT/dx: 103 to 107 K/m) combined with local changes in thermal expansion coefficients, crystallographic strains and localized stress-strain constitutive properties in conjunction with thermal cycles, can bring about a plastic strain gradient …


Anisotropic Plasticity Modeling Of Thin Sheets And Its Application To Micro Channel Forming Of Steel Foils, Jie Sheng Jul 2021

Anisotropic Plasticity Modeling Of Thin Sheets And Its Application To Micro Channel Forming Of Steel Foils, Jie Sheng

Mechanical Engineering Research Theses and Dissertations

Thin sheet metals and ultrathin metal foils produced by industrial rolling processes are textured polycrystalline materials and their mechanical behaviors may depend strongly on the orientation of applied loading. Consideration of such plastic anisotropy in advanced modeling of these materials is of the paramount importance in designing optimal manufacturing processes for automotive and other applications using finite element methods. This research addresses several critical issues in anisotropic plasticity modeling and its applications in analyzing micro channel forming of ultrathin stainless-steel foils. An experimental study has first been carried out on the accuracy and sensitivity of measuring the plastic strain ratios …


A Computational Study Of Radiation Damage In Bilayer Silicon-Gold Structures, Cameron Hopper Jul 2021

A Computational Study Of Radiation Damage In Bilayer Silicon-Gold Structures, Cameron Hopper

Graduate Theses and Dissertations

Irradiation from sources such as nuclear reactors bombard materials with neutrons and heavy ions. The primary consequence of this irradiation is the displacement of atoms from their atomic structure. As the structure becomes damaged, the mechanical properties can change. Eventually, this can result in a failure due to embrittlement. This type of damage is hard to detect and can result in sudden, unexpected failure. Therefore, focusing on managing the consequences of irradiation has been a heavily researched topic. To manage irradiation, the focus is primarily to manage the voids and interstitials that appear during irradiation. Grain boundaries and amorphous regions …


Electrochemical Deposition In Energy Storage Devices, Witness Atutala Martin Jul 2021

Electrochemical Deposition In Energy Storage Devices, Witness Atutala Martin

Graduate Theses and Dissertations

Metals, whether in a solid or soluble ion form, are a vital part of any electrochemical storage system. More so, Li metal is widely considered as the ideal anode because of its low density and low electrochemical potential (-3.04 V vs. the standard hydrogen electrode – SHE). However, just like most metals, it does not plate or strip evenly during cycling which can lead to cycling performance issues, short cycling lifespans, and even safety concerns brought about by dendrites that can cause internal short-circuiting within cells. This research focused on investigating the electroplating of metals in both aqueous and non-aqueous …


Metallurgical And Thermal Processing Investigation Of Additively Manufactured Superalloys Jbk-75 And Nasa-Hr-1, Allyse Birken, Derek Noel Jun 2021

Metallurgical And Thermal Processing Investigation Of Additively Manufactured Superalloys Jbk-75 And Nasa-Hr-1, Allyse Birken, Derek Noel

Materials Engineering

Aerojet Rocketdyne is investigating the use of directed energy deposition (DED), an additive manufacturing process, to reduce cost and lead time for manufacturing complex rocket engine components for their RS-25 engines. JBK-75 and NASA-HR-1, two Fe-Ni-base, age-hardenable (γ′) superalloys, are used for nozzle structural jackets and hot gas manifolds. Currently, these parts are produced using traditional forging or casting methods followed by intensive machining operations. Additionally, these alloys were designed for use in the wrought condition and require a different set of post-processing heat treatments when produced using DED due to their dendritic, segregated microstructure in the as-built condition. Homogenization …


Effect Of Distal Core Flattening On 304 Stainless Steel Guide Wires, Khanh Phan Jun 2021

Effect Of Distal Core Flattening On 304 Stainless Steel Guide Wires, Khanh Phan

Materials Engineering

Abbott Vascular produces a variety of medical guide wires to accommodate a wide array of minimally invasive medical procedures. Certain types of these wires have the distal core flattened to improve specific properties such as flexibility and steerability. However, it is unknown how this affects the other mechanical properties of the wire. Abbott Vascular provided two types of wire to test the effects of distal core flattening on the mechanical performance of the wires. One group of wires was made from 304 single spring stainless steel with no flattening performed. The other group of wires was made from 304 triple …


Strengthening Of 7175 Aluminum Alloy Through Multi-Step Aging Process, Colin E. Masterson, Ryland W. Jolliffe Jun 2021

Strengthening Of 7175 Aluminum Alloy Through Multi-Step Aging Process, Colin E. Masterson, Ryland W. Jolliffe

Materials Engineering

7175 is a heat-treatable aluminum alloy commonly used in aerospace forgings. This alloy is aged with a multi-step heat treatment. This treatment must balance strength with stress corrosion cracking resistance through a degree of overaging. The team was tasked by Weber Metals to increase the strength of this treatment without sacrificing stress corrosion cracking resistance. Both two-step and retrogression and reaging treatments were tested in experiments to find a heat treatment that could increase the yield and tensile strength by 1-2 ksi while maintaining a minimum electrochemical conductivity equivalence of 38% relative to copper. Two-step aging is the more conventional …


Minimizing Leakage In Thin Walled Structures Printed Through Selective Laser Melting, Andrew Spencer Yap Jun 2021

Minimizing Leakage In Thin Walled Structures Printed Through Selective Laser Melting, Andrew Spencer Yap

Master's Theses

In this project, the scan strategy of selective laser melting (SLM) for thin walled structures was investigated by changing laser parameters and tool path. Producing thin walled structures is difficult due to defects such as warpage and porosity. A layer on the SLM 125 consists of hatch volume, fill contours, and borders, however, for thin walls, hatch volume can become unavailable, resulting in a solely border/fill contour laser tool path.

Three central composite designs (CCD) were created to optimize the laser parameters of borders to minimize leakage rate and porosity. The two factors changed were border laser power and scanning …


Microstructural Characterization And Analysis Of Laser-Powder Bed Fusion Grcop-84 By Metallurgical And Neutron Scattering Methods, Robert Minneci May 2021

Microstructural Characterization And Analysis Of Laser-Powder Bed Fusion Grcop-84 By Metallurgical And Neutron Scattering Methods, Robert Minneci

Doctoral Dissertations

GRCop-84 or Cu-8Cr-4Nb (atomic %) is a structural high-heat-flux Cu alloy that is dispersion strengthened by C15 Laves Cr2Nb [Niobium Chromide] that has seen significant development with laser additive manufacturing (AM), specifically laser-powder bed fusion (L-PBF) in recent years. A review of the development, properties, and performance of GRCop alloys has been conducted and provides pertinent background. The body of research provides fundamental understanding regarding microstructure evolution and phase interaction of GRCop-84 through characterization by neutron and X-ray scattering and metallographic techniques. This research is intended to bridge fundamental research of L-PBF, Cu alloys, structural thermal conductors, and …


Local Dynamics And Atomic-Level Structures In Metallic Liquids And Glasses, Zengquan Wang May 2021

Local Dynamics And Atomic-Level Structures In Metallic Liquids And Glasses, Zengquan Wang

Doctoral Dissertations

Structure and dynamics at the atomic level in metallic glasses and liquids are poorly understood when compared to the crystalline solids. For instance, even though viscosity is the basic property of liquids, its atomistic origin is not well elucidated. Also, the physics of the fragility of liquids and the crossover phenomenon is far from full understanding. Earlier, through molecular dynamics (MD) simulations a direct connection was found between the timescale describing the macroscopic viscous behavior, the Maxwell relaxation time (tM = h/G, h is the shear viscosity and G is the high-frequency shear modulus) and …


Study Of Laser Based Additive Manufacturing For Titanium And Copper Alloys, Congyuan Zeng Mar 2021

Study Of Laser Based Additive Manufacturing For Titanium And Copper Alloys, Congyuan Zeng

LSU Doctoral Dissertations

Material processing by laser is increasingly applied in industrial applications for its outstanding characteristics, such as localized heating, high efficiency, and high manufacturing precision. In this study, two kinds of laser material processing strategies were investigated, namely laser surface engineering and laser-powder-bed fusion additive manufacturing, with pure titanium and copper alloys as target materials, respectively.

For laser surface engineering related studies, the work includes the investigation of the dynamic interactions between titanium and pure nitrogen or ambient air under transient laser processing conditions. Thanks to the in-situ synchrotron X-ray diffraction tests, the high-temperature reaction steps between titanium and pure nitrogen/ambient …


Modeling Of Rare Earth Solvent Extraction Process For Flowsheet Design And Optimization, Vaibhav Kumar Srivastava Jan 2021

Modeling Of Rare Earth Solvent Extraction Process For Flowsheet Design And Optimization, Vaibhav Kumar Srivastava

Theses and Dissertations--Mining Engineering

The separation and purification of rare earth elements (REEs) into individual products has been a topic of significant interest for researchers and engineers for many decades. The prime reason for such sustained interest is due to REEs’ demand and application in modern technology, as well as the challenges associated with their separation and purification. The chemical similarity of rare earth group elements is responsible for difficult separability which makes purification of individual elements challenging. Despite associated complications, processes such as solvent extraction (SX) and ion-exchange have been successfully utilized in the separation and production of REEs on pilot and commercial …


การศึกษาผลของการเจือซิลิกอนในกระบวนการอะลูมิไนซิงแบบผงโดยใช้ผงซิลิกอนไดออกไซด์ต่อโครงสร้างจุลภาค และพฤติกรรมการเกิดออกซิเดชันของชั้นสารประกอบเชิงโลหะนิกเกิล-อะลูมิเนียมบนโลหะผสมพิเศษ In800ht, ณัฐพงษ์ หนันต๊ะ Jan 2021

การศึกษาผลของการเจือซิลิกอนในกระบวนการอะลูมิไนซิงแบบผงโดยใช้ผงซิลิกอนไดออกไซด์ต่อโครงสร้างจุลภาค และพฤติกรรมการเกิดออกซิเดชันของชั้นสารประกอบเชิงโลหะนิกเกิล-อะลูมิเนียมบนโลหะผสมพิเศษ In800ht, ณัฐพงษ์ หนันต๊ะ

Chulalongkorn University Theses and Dissertations (Chula ETD)

ในงานวิจัยนี้ศึกษาผลของเติม SiO2 ในกระบวนอะลูมิไนซิงแบบผงชนิด high-activity โลหะผสมพิเศษ IN800HT ที่มีการเจือซิลิกอนในช่วง 0-37.5 at% อ้างอิงจากสัดส่วนของซิลิกอนที่ได้และอะลูมิเนียมที่เหลือจากปฏิกิริยารีดักชัน โดยวิเคราะห์ผ่านโครงสร้างจุลภาค องค์ประกอบทางเคมี และชนิดของสารประกอบอะลูมิไนด์ของชั้นเคลือบที่เกิดขึ้นจากการเตรียมที่อุณหภูมิ 1000 °C เป็นเวลา 4 ชั่วโมง จากการทดลองพบว่า ชั้นเคลือบของตัวอย่างที่ไม่มีการเจือซิลิกอนประกอบไปด้วย 3 ชั้นย่อย คือ (i) ชั้นนอกที่ของผสมระหว่างสารประกอบอะลูนิไนด์ที่มีความเข้มข้นของอะลูมิเนียมสูง (ii) ชั้นกลางที่มีสารประกอบอะลูมิไนด์ hyperstoichiometric β-(Fe,Ni)Al เป็นหลัก และ (iii) ชั้น interdiffusion zone (IDZ) ที่เป็นชั้นในสุด ซึ่งบ่งบอกถึงการแพร่ของอะลูมิเนียมเข้าไปในโลหะผสมพิเศษ IN800HT ความหนาของแต่ละชั้นย่อยได้รับผลกระทบจากปริมาณ SiO2 ที่เติมลงไป การละลายของซิลิกอนในสารประกอบอะลูมิไนด์มีปริมาณน้อยกว่า 5 at.% เมื่อมีการเจือซิลิกอนในปริมาณสูงขึ้น จะเกิดการแยกตัวของซิลิกอน (Si segregation) บริเวณชั้น IDZ หรือพื้นที่แยกตัวในชั้นกลางของตัวอย่างที่มีการเจือซิลิกอน การเจือซิลิกอนในกระบวนการอะลูมิไนซิงแบบผงโดยใช้ซิลิกอนไดออกไซด์ประสบความสำเร็จเนื่องจากการลดลงของ thermodynamic activity ของ Al สำหรับการทดสอบ cyclic oxidation ที่อุณหภูมิ 1,000°C ภายใต้สภาวะบรรยากาศอากาศแห้งเป็นระยะเวลา 104 ชั่วโมง พบว่า ตัวอย่างที่มีการเจือซิลิกอนมีการเพิ่มขึ้นของน้ำหนักต่ำกว่าตัวอย่างที่ไม่มีการเจือซิลิกอน พฤติกรรมการเกิดออกซิเดชันแบบ sub-parabolic growth เกิดขึ้นในกรณีของ (1) โลหะผสมพิเศษ IN800HT (3) ตัวอย่างที่ไม่มีการเจือซิลิกอน และ (3) เจือซิลิกอนในปริมาณ 37.5 at% มี ในขณะที่ตัวอย่างที่มีการเจือซิลิกอน 12.5 at% และ 25.0 at% มีพฤติกรรมการเกิดออกซิเดชันแบบ linear growth เป็นหลัก


The Investigation Of The Underlying Microstructure Associated With Fracture Features In 6061 Cold Sprayed Aluminum, Justin White Jan 2021

The Investigation Of The Underlying Microstructure Associated With Fracture Features In 6061 Cold Sprayed Aluminum, Justin White

UNF Graduate Theses and Dissertations

Cold gas dynamic spraying commonly known as cold spray is a process currently used for restoration, re-tolerancing, and application of coatings. With additional resources allocated towards the development of a through process model aimed at predicting the properties of bulk material produced via the Cold Spray process, more lab testing and investigation must be done to capture the effects of the varying microstructure in CS materials. The properties of ultra-fine-grained materials are derived from data collected from coarse grained materials and processes that do not accurately capture the effects as elevated strain rates and ultra-fine-grained materials. The lack of property …


Thermomechanical Mechanisms That Cause Adhesion Of Aluminum High Pressure Die Castings To The Die, Alex Monroe Jan 2021

Thermomechanical Mechanisms That Cause Adhesion Of Aluminum High Pressure Die Castings To The Die, Alex Monroe

Dissertations, Master's Theses and Master's Reports

In high pressure die casting (HPDC) of aluminum, cast material adhering to die is a significant defect. Adhesion occurs in two primary ways. The casting may stick preventing its removal from the die. Aluminum can also adhere to the die and buildup in local areas on the die surface with additional casting cycles. This second form of adhesion is called soldering. Lubricant is the best technology to control all forms of adhesion, but it comes at the cost of casting porosity, blisters, reduced die life, and increased die casting machine wear. New strategies to prevent adhesion are desired to eliminate …


The Effects Of Molybdenum, Chromium, And Niobium On Gray Iron For Brake Rotor Applications, Matthew Hasbrouck Jan 2021

The Effects Of Molybdenum, Chromium, And Niobium On Gray Iron For Brake Rotor Applications, Matthew Hasbrouck

Dissertations, Master's Theses and Master's Reports

Brake rotor composition and microstructure must be optimized for thermal and mechanical performance to avoid thermal-mechanical cracking, excessive wear, and to reduce noise. Niobium is an element that increases the strength and wear resistance of gray iron; however, the interaction of niobium with other common alloying elements (chromium and molybdenum) is not well understood. Thirteen gray cast iron alloys were produced with varying levels of carbon equivalent (CE), Cr, Mo, and Nb. Bars with four different diameters (8, 14, 22, and 30 mm) were cast from each alloy and microstructural and physical properties such as graphite flake morphology, pearlite spacing, …


Atomistic Monte Carlo Simulation Study Of Phase Transitions In Metal Alloys, Xiaoxu Guo Jan 2021

Atomistic Monte Carlo Simulation Study Of Phase Transitions In Metal Alloys, Xiaoxu Guo

Dissertations, Master's Theses and Master's Reports

The atomic-scale Monte Carlo simulation study focuses on the intrinsic behaviors of a defect-free crystal that undergoes a cubic-to-tetragonal martensitic transformation. The quasi-spin variable associated with the lattice sites characterizes the local unit cells of the orientation variants of the ground-state martensite phase, which interact with each other through long-range elastic interactions. It is shown that the diffuse scattering in the premartensitic austenite state results from the spatial correlation of the atomic-scale heterogeneous lattice displacements and manifests the displacement short-range ordering. The effects of temperature, elastic anisotropy, and shear modulus softening on the diffuse scattering and displacement short-range ordering are …


Analyzing Variation In Dispersoid Formation In Aluminum Alloys By Minor Changes In Homogenization Temperature, Brendan Treanore Jan 2021

Analyzing Variation In Dispersoid Formation In Aluminum Alloys By Minor Changes In Homogenization Temperature, Brendan Treanore

Dissertations, Master's Theses and Master's Reports

The homogenization of billets in the aluminum extrusion industry is a critical step that removes chemical segregation from casting, dissolves low melting point phases, forms nanoscale dispersoid phases, and promotes the beta to alpha transformation of iron particles in the matrix. With ever increasing use of aluminum extrusion in the automotive industry there is a constant need for increased efficiency and consistency in processing of extruded aluminum. The work in this thesis explores the effects of 10°C differences in the homogenization temperature on the formation of dispersoids in 6082 alloys used in the automotive industry. The role of dispersoids is …


ผลของอุณหภูมิและเวลาการอบอ่อนที่มีต่อโครงสร้างและประสิทธิภาพการกักเก็บประจุสังกะสีไอออนของผงทังสเตน, กอกฤษต สองเมือง Jan 2021

ผลของอุณหภูมิและเวลาการอบอ่อนที่มีต่อโครงสร้างและประสิทธิภาพการกักเก็บประจุสังกะสีไอออนของผงทังสเตน, กอกฤษต สองเมือง

Chulalongkorn University Theses and Dissertations (Chula ETD)

แบตเตอรี่สังกะสีไอออนแบบชาร์จได้ (ZIB) ถือเป็นหนึ่งในอุปกรณ์กักเก็บพลังงานที่น่าสนใจ เนื่องจากมีคุณสมบัติด้านความปลอดภัยและคุ้มค่าของราคา อย่างไรก็ตาม งานวิจัยศึกษาวัสดุแคโทดของแบตเตอรี่ ZIB เพื่อให้ได้แบตเตอรี่ที่มีความจุสูงและหมุนเวียนนั้นยังมีไม่แพร่หลาย ดังนั้นการศึกษาวัสดุแคโทดยังคงต้องการการศึกษาเพิ่มเติม ในงานวิจัยนี้ได้ทำการศึกษาขั้วแคโทดสำหรับใช้ในแบตเตอรี่ ZIB โดยใช้ทังสเตนออกไซด์เป็นวัสดุแคโทดสำหรับ ZIB จากงานวิจัยพบว่าขั้วแคโทดทังสเตนออกไซด์ให้ค่าความจุของแบตเตอรี่อยู่ที่ 158 mA h g-1 ณ กระแส 0.1A g-1 อีกทั้งมีประสิทธิภาพการใช้ซ้ำที่ 96% ในการทดสอบจนถึง 1,000 รอบ และมีค่าความหนาแน่นของพลังงานที่โดดเด่น อยู่ที่ 102Wh kg-1 ที่ 116 W kg-1 นอกจากนี้ งานวิจัยนี้ยังแสดงให้เห็นภาพจำลองกลไกในการแทรกตัวของสังกะสีไอออน Zn2+ แบบย้อนกลับในโครงสร้างขั้วแคโทด ดังนั้นงานวิจัยนี้ถือเป็นแนวทางการศึกษาและออกแบบเพื่อใช้ทังสเตนออกไซด์เป็นขั้วแคโทดในแบตเตอรี่ ZIB ที่มีสมรรถนะสูง


New Horizons For Processing And Utilizing Red Mud, M. Archambo Jan 2021

New Horizons For Processing And Utilizing Red Mud, M. Archambo

Dissertations, Master's Theses and Master's Reports

Red mud is an industrial slurry waste that is produced as a byproduct of the Bayer process for alumina. The waste is generated in large quantities, up to a ratio of 2:1 against the valued product alumina. Red mud exhibits many chemical and physical properties that categorize it as a hazardous material. Due to the addition of sodium hydroxide in processing, the pH is typically at values close to 13. Small particle size discourages separation from water for disposal, so drying red mud happens over many years.

The pH of red mud can be reduced with inexpensive reagents. Carbon dioxide …


Role Of Eta Phase Evolution On Creep Properties Of Nickel Base Superalloys Used In Advanced Electric Power Generation Plants, Ninad Mohale Jan 2021

Role Of Eta Phase Evolution On Creep Properties Of Nickel Base Superalloys Used In Advanced Electric Power Generation Plants, Ninad Mohale

Dissertations, Master's Theses and Master's Reports

Advanced fossil energy power generation plants require materials that withstand high temperatures and corrosive environments. One such material that is used in steam turbines is Nimonic 263. It is a nickel-base superalloy that is principally strengthened by gamma primephase (Ni3(Ti, Al)) and has an L12structure. At extended times and at turbine operating temperatures however, eta (Ni3Ti) phase is known to form at the expense of gamma prime. Eta has a complex DO24structure and is the stable phase between 750°C and 900°C, but with slow kinetics of formation. Little is understood about eta …


Jominy Hardenability Tester Redesign, Dennis Kopacz, Shadoe Beatty, Thomas Benenati, Jared Mclean, Matthew Yokosuk Jan 2021

Jominy Hardenability Tester Redesign, Dennis Kopacz, Shadoe Beatty, Thomas Benenati, Jared Mclean, Matthew Yokosuk

Williams Honors College, Honors Research Projects

Our project is Redesigning a Hardenability Tester. The goal of this project is to figure out how to incorporate an intensive quenching system to the current design from last years group. An intensive quench is a new system that is safer to harden steel and it hardens steel more effectively than other quenching processes. This will be achieved through testing the initial design to make sure it is able to run. After that as a group we will take this system through a design process to introduce a safe process of intensive quenching to the tester.


การผลิตโฟมอะลูมิเนียมโดยใช้ลูกบอลเกลือที่ออกแบบเป็นตัวสร้างรูพรุน, จุฑานนท์ บุญประเสริฐ Jan 2021

การผลิตโฟมอะลูมิเนียมโดยใช้ลูกบอลเกลือที่ออกแบบเป็นตัวสร้างรูพรุน, จุฑานนท์ บุญประเสริฐ

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้มีจุดประสงค์เพื่อศึกษากระบวนการผลิตโฟมอะลูมิเนียมที่มีโครงสร้างรูพรุนแบบเปิดด้วยการใช้ลูกบอลเกลือเป็นตัวสร้างรูพรุนรวมถึงสมบัติทางกลของโฟมอะลูมิเนียม โดยเริ่มต้นศึกษาการผลิตและสมบัติของลูกบอลเกลือซึ่งมีรูปร่างทรงกลม โดยเลือกใช้ลูกบอลเกลือเส้นผ่านศูนย์กลาง 5 mm และอะลูมิเนียมผสมเกรด ADC 12 เพื่อนำไปผลิตโฟมอะลูมิเนียมด้วยวิธีการหล่อแบบแทรกซึมที่ใช้ความดันที่อุณหภูมิ 650 และ 700°C โดยใช้แรงดันจากแก๊สอาร์กอน 1 และ 2 bar และใช้ระยะเวลาหลอม 10 และ 30 นาที ผลการศึกษาสมบัติของลูกบอลเกลือพบว่าโครงสร้างจุลภาคของลูกบอลเกลือหลังการเผาผนึกมีความเป็นเนื้อเดียวกันมากขึ้น ส่งผลให้ความแข็งแรงอัดของลูกบอลเกลือสูงขึ้น กระบวนการผลิตนี้สามารถผลิตโฟมอะลูมิเนียมที่มีรูพรุนแบบเปิดได้ ซึ่งโครงสร้างของชิ้นงานโฟมจะมีโพรงอากาศขนาดใหญ่เนื่องจากการแทรกซึมของน้ำโลหะอะลูมิเนียมเพียงบางส่วนในชิ้นงานเมื่อใช้อุณหภูมิ 650°C ความดัน 1 bar และเวลา 10 นาที โครงสร้างจุลภาคของชิ้นงานโฟมประกอบด้วยเนื้อพื้นเมตริกซ์อะลูมิเนียมที่มีเฟสซิลิกอนกระจายตัวอยู่ นอกจากนี้ ความแข็งแรงอัดของโฟมอะลูมิเนียมขึ้นอยู่กับอุณหภูมิ แรงดัน และเวลาที่ใช้ในการผลิต โดยที่อุณหภูมิ 700°C ชิ้นงานส่วนใหญ่มีความแข็งแรงจุดครากสูงกว่าชิ้นงานที่อุณหภูมิ 650°C และส่งผลให้การดูดซับพลังงานของชิ้นงานใกล้เคียงกันมากขึ้น เช่นเดียวกับการเพิ่มแรงดันจาก 1 เป็น 2 bar ในขณะที่ระยะเวลาในการหล่อชิ้นงานส่งผลให้ความแข็งแรงจุดครากของชิ้นงานใกล้เคียงกันมากขึ้น และทำให้การดูดซับพลังงานของชิ้นงานสูงขึ้น เมื่อเพิ่มระยะเวลาการหล่อจาก 10 เป็น 30 นาที


Viability Of A Proposed Transparent Fluid Model For Analog Metal Casting Filling Process, Andres Segura Irazoqui Jan 2021

Viability Of A Proposed Transparent Fluid Model For Analog Metal Casting Filling Process, Andres Segura Irazoqui

Dissertations and Theses @ UNI

No abstract provided.


Anaerobic Reductive Bioleaching Of Manganese Ores, Neha Sharma Jan 2021

Anaerobic Reductive Bioleaching Of Manganese Ores, Neha Sharma

Dissertations, Master's Theses and Master's Reports

The increasing demand of manganese in the industries and various hindrances in its production from low grade ores by conventional method has made it imperative for researchers around the world to develop a method of manganese extraction from low grade ores that is both environment friendly and economical. Bioleaching has shown significant potential in manganese extraction and efficiencies of extraction have been found to be 70-98% with the help of various bacteria and fungi.

This study focuses on extraction of manganese with the help of mixed bacterial strains that have been collected from their natural anaerobic environment. The extraction of …