Metallurgy Commons^™

Fabrication Of Solid Solution Tungsten-Rhenium Alloys By High Energy Ball Milling And Spark Plasma Sintering, Cory C. Sparks

Boise State University Theses and Dissertations

Tungsten-rhenium powders of varying compositions were fabricated by spark plasma sintering (SPS). In initial exploration of the parameter space, W-25 at% Re powders were blended and consolidated by SPS at 1500 to 1900°C with sintering dwell times of 0 to 60 minutes. In addition, the influence of milling was investigated. W-25 at% Re powders were high-energy ball milled at 200 to 400 rpm for 5 hours and consolidated at 1700°C with sintering dwell times of 0 to 60 minutes. The sample densities, grain sizes, porosities, contamination level, and hardness values were measured. The intermetallic content, specifically the fraction of σ-phase, …

Processing, Microstructures, And Mechanical Behavior Of High-Entropy Alloys, Zhi Tang

Masters Theses

Recently, high-entropy alloys (HEAs) have attracted increasing attentions because of their unique compositions, microstructures, and adjustable properties. In this work, microstructure and phase composition of the AlCoCrFeNi high-entropy alloy (HEA) were studied in as-cast and heat-treated conditions. Using a combination of Electron Backscatter Diffraction (EBSD), X-ray energy spectroscopy analysis, and synchrotron X-ray diffraction techniques, two nonequilibrium phases were identified in the as-cast condition: BCC_A2 and B2. Long-term heat treatment transformed these nonequilibrium phases into four equilibrium phases: FCC_A1, BCC_A2, B2, and σ [sigma] phase. The electron microscopic results were consistent with thermodynamic simulations of the equilibrium …

Fatigue Behavior Of High-Entropy Alloys, Michael Alexander Hemphill

Masters Theses

Research was performed on the Al₉Co_18.2Cr_18.2Cu_18.2Fe_18.2Ni_18.2 [subscripts atomic percent] and Al_7.5Cr_22.5Fe₃₅Mn₂₀Ni₁₅ high-entropy alloys (HEAs) in an attempt to study their fatigue behavior. The present investigation shows encouraging fatigue-resistance characteristics due to their high fatigue lives of various samples at relatively high stresses. The current results indicate that the fatigue behavior of HEAs compares favorably to many conventional alloys, such as steels, titanium alloys, and advanced bulk metallic glasses with a fatigue-endurance limit of the Al₉Co_18.2Cr_{18.2 …}

Dynamical Properties Of Ferroelectric Perovskites (Ba,Sr)Tio3 And Pb(Zr,Ti)O3 Systems From First Principles, Jeevaka Weerasinghe

Graduate Theses and Dissertations

A first-principles-based effective Hamiltonian scheme which incorporates coupling between ferroelectric (FE) and antiferrodistortive (AFD) motions is applied to Pb(Zr,Ti)O₃ alloys. It validates the existence of two modes of E symmetry (rather than the single E(1TO) soft mode) in the 50-75 cm^-1 range for temperatures smaller than 200 K and for compositions falling within the Rhombohedral R3c phase. Coupling between long-range-ordered FE and AFD motions is shown to be the cause of the additional mode and more insight into its nature is provided. This scheme is further used to reveal a field-induced anticrossing involving FE and AFD degrees of …

Development And Use Of A Simple Test Method To Evaluate Reheat Cracking Sensitivity In The Weld Deposit Region Of A Submerged Arc Weld, Maxwell Calder Trent

Masters Theses

Several fabricators have recently noted the occurrence of reheat cracking in the weld deposits of 2¼[ two and one fourth]Cr‑1Mo‑¼[one fourth]V (22V) during the fabrication of pressure vessels used in the petrochemical industry. Due to increased oversight now required during fabrication of already expensive pressure vessels, studies have commenced worldwide in an effort to identify root causes and formulate mitigating actions to weld reheat cracking issues. The Materials Joining Group (MJG) at the University of Tennessee at Knoxville (UTK) have adapted an existing reheat cracking test originally developed for use with alloys similar to 22V. This original C‑Ring test was …

Characterization And Analysis Of Low Room Temperature Ductility Nickel-Based Superalloy 718 Plus For Aircraft Engine Forgings, Jonathon Bracci

Materials Engineering

Schlosser Forge Co. forges low pressure turbine (LPT) cases from the nickel based superalloy 718 Plus using the ring rolling forging process. Schlosser has been experiencing low room temperature ductility problems in a number of their 718 Plus LPT cases. LPT cases are required to pass a 4D tensile test at room temperature with a minimum of 15 percent elongation. The ductility problem was reduced by increasing the forging temperature from 1825˚F to 1850˚F. Analysis was performed on 718 Plus samples taken from forged LPT cases that failed the room temperature ductility requirement and ones that passed the requirement. The …

Effects Of Beta Stabilizers On Quench Delay Susceptibility Of Ti-6al-4v, Kyle Logan

Materials Engineering

Tensile samples of Titanium 6Al-4V (Ti-6Al-4V) were machined from forgings containing rich and poor amounts of beta stabilizers in their compositions. The tensile samples were each heat treated two times. In the first round of heat treatments, the samples were either beta solution treated (BST), or solution treated (ST). Each sample was water quenched with varying quench delays of 10, 20, and 30 seconds. BST treated specimens were then overaged at 1350°F for 2 hours and air cooled (BSTOA); while the ST treated samples were aged at 990°F for 6 hours and air cooled (STA). Following heat treating, the tensile …

Discontinuous Grain Boundaries Of Forged René 41, Steven Crump

Materials Engineering

Forged components must pass a grain size specification (grain size, distribution) for acceptance in an application. The varying amounts of plastic deformation during forging can lead to abnormally large recrystallized grain sizes in certain regions of the part, which will not pass specification. The question exists whether these abnormally coarse grains are truly comprised of poly crystalline fine grains with grain boundaries resistant to etching techniques. To investigate this abnormal grain size effect, a cross section of a forged René 41 nickel-based superalloy aircraft engine ring was cut and sectioned into six segments. Those segments were then prepared for microstructural …

Effect Of Heating Temperature, Heating Time And Initial Microstructure On Recrystallization Of Waspaloy During Heating For Forging, Marissa Hill

Materials Engineering

A fine, uniform grain size is required for creep limited Waspaloy in aircraft engine applications. Upon heating, Waspaloy does not always recrystallize in a uniform manner resulting in occasional large grains with a majority of the grains meeting the grain size requirements. Waspaloy’s microstructure was analyzed with different heat treatments and in the as-forged condition. The strengthening mechanism is the gamma prime phase. The gamma prime solvus temperature is 1908°F so the different heat treatments were determined around that temperature, as well as the forging temperature range of 1800-2150°F. At the 1850°F heat treatment, the microstructure recrystallized with small grains, …

Morphology And Roughness Of Al2o3 On Ferritic Stainless Steel Foil For Diesel Catalytic Converter Applications, Megan Butala

Materials Engineering

The improved thermal properties of metal-substrate catalytic converters enable effective catalysis sooner after ignition than traditional ceramic monoliths, resulting in less harmful emissions. ACAT Global, a manufacturer of stainless steel catalytic converters, uses ferritic stainless steel substrates for low temperature catalytic converters for diesel automobiles. Production begins with an oxidizing heat treatment to increase surface roughness. The success of the second production step, the application of catalyst-containing ceramic slurry (washcoat), depends on the surface roughness that results from oxidation. Formation of the primary oxide of interest, alumina (Al₂O₃), is controlled by the stainless steel foil composition, …

Microstructural Characterization Of Ti-6al-4v And Its Relationship To Sample Geometry, Blake Gaspar

Materials Engineering

A problem exists with a part produced by forging made by Shultz Steel of Ti-6Al-4V in the variance of properties throughout the part. There is one specific region that exhibits the most variance. The purpose of the report is to determine any microstructural differences within the region of interest in the part. When microstructures of the inner section and outer section of the part were looked at it was determined that they exhibited a martensitic structure. There was a noticeable difference in the lath structure between sections. The outer region contained larger more widely spread laths of an average length …

Effects Of Annealing/Solution Treating And Aging On Longitudinal And Transverse Properties Of Ti-6al-4v Forgings, Blake Reller

Materials Engineering

Forty-eight subsize round-bar tensile samples (ASTM E8) were machined from 3-in-thick forgings of Ti-6Al-4V. Half of these samples were cut so the axis aligned with the longitudinal (LG) direction of the forging, the other half were cut to align with the transverse (LT) direction. Four samples from each direction were subjected to one of six heat treatments so that a total of eight samples received each treatment. Annealed samples were held at 1350°F for two hours, then air cooled. Solution treated and aged (STA) samples were solution treated at one of five temperatures between 1785°F and 1435°F for one hour …

Analyzing The Corrosion Resistance Of Ni-Shield 200 Coatings At Different Temperatures When Exposed To Sulphuric Acid, Alex Hussinger

Materials Engineering

Six steel samples each were twin wire arc sprayed with Hastelloy C-276 or Nickel-Shield 200 coatings approximately 0.020″ thick. These samples were then cut into 3″ by 3″ squares. A 2″ diamond grit hole saw was used to abrade and polish to a smooth surface a ring in the middle in order to get an O-ring mechanical seal. The samples were then weighed and loaded into a jig that started from the bottom up with a stainless steel plate, then the sample, then a Viton O-ring, a ¾″ thick glass plate with a 1 3/4″ hole cut in it, another …

Characterization Of Positive Macrosegregation At The Subsurface Of Direct-Chill Cast 7050 Aluminum Forging Billets, Aaron Youril

Materials Engineering

Segregation of alloying elements during casting of forging billets may persist to the final forged component leading to unacceptable surface appearance. Determination of the elements or compounds that segregate is the essential first step to solving this problem. Differential Scanning Calorimetry (DSC) was used to determine a composition profile of the macrosegregation occurring at the subsurface of an as-cast 7050 aluminum alloy billet. Data collection was carried out by separating 10 to 20 mg samples from the outer centimeter along the radius of the billet, as well as samples from the bulk interior of the billet for comparison with the …

Effect Of Oxidation On Weld Strengthof Dissimilar Resistance Weld Interface Between 304 Stainless Steeland Near Equiatomic Austenitic Nitinol Guide Wire, Matthew Rudow

Master's Theses

Abbott Vascular encountered strength and variability issues when attempting to resistively weld 304 Stainless Steel to equiatomic Nitinol. Initial observations suggested that passivation layer (Cr₂O₃, TiO₂) formation affected the weld interface. One hundred 304 Stainless Steel/Nitinol pairs were allowed to oxidize in air at room temperature for allowed periods of time (.1, 1, 3, 5, 7, 12, 16, 24, 168, and 336 hours). Each pair was welded resistively with constant current. A Miyachi/Unitek Advanced Data Analysis Monitor (ADAM) recorded the peak resistance at the instance the weld was made. Resistances were compared to Instron …

Metallurgical Effects On Long-Term Creep-Rupture In A New Nickel-Based Alloy, John P Shingledecker

Doctoral Dissertations

A series of creep-rupture studies were conducted on a new nickel-based alloy, Inconel Alloy 740, for use in Advanced Ultrasupercritical (A-USC) Steam boiler applications. The research quantitatively showed, for the first time, that the formation of a small amount of eta phase during long-term creep testing at 750 degrees Celsius does not degrade the rupture strength or ductility of the alloy. A unique full-scale pressurized tubular creep test was conducted, and a new analysis methodology was developed to evaluate the effect of cold-straining on the creep performance of tube bends made from the alloy. The results showed that 15% cold-work …

Investigation Of The Use Of Micro-Mechanical Testing To Analyze The Mechanical Anisotropy Of The Zr-2.5%Nb Pressure Tube Alloy, Richard O. Oviasuyi

Electronic Thesis and Dissertation Repository

Maintaining a safe operation of nuclear power plants is the primary requirement of nuclear power generating organizations worldwide. This necessitates the use of highly effective methods for assessing the mechanical properties of reactor materials and components. This is important since all components located in a nuclear reactor core experience high levels of neutron irradiation which cause defects to be formed in the metals’ crystal structure. The density of these crystal defects increases with increasing exposure to neutrons and cause the crystalline metal to become harder and simultaneously more brittle. This change in mechanical properties is potentially detrimental to the safe …

Plastic Strain Accommodation And Acoustic Emission During Melting Of Embedded Indium Particles In Aluminum, Michael M. Kuba

Masters Theses

"Melting of micron-sized (0.2 to 3 µm diameter) indium particles embedded in an aluminum matrix was discovered to produce acoustic emission. Melting of embedded immiscible particles produces a pure dilation during the phase transformation and has no long-range diffusion field to control the speed of transformation. It was found that acoustic emission can no longer be considered as a criterion of displacive transformations and that melting of micron-sized embedded particles is strain energy controlled. Acoustic emission was confirmed to result from the rapid relaxation of aluminum around indium particles embedded on grain boundaries. Prismatic punching of dislocation loops is proposed …

Development Of Third Generation Advanced High Strength Steels, Meghan C. Mcgrath

Doctoral Dissertations

"Lightweight duplex steels with combinations of either bainite, acicular ferrite, and austenite or martensite and austenite were investigated as third generation advanced high strength steels targeted for automotive applications. Large additions of manganese (>13 wt%) and carbon (

Duplex steels with different volume fractions of primary δ -ferrite were used to study the crystallography of austenite formed during the peritectic reaction. Solute profiles across the peritectic interface showed aluminum segregated near the interface which promoted bainitic ferrite formation. Thermal treatments were used to manipulate the concentration and type of oxides and the ferrite plate density was found to correlate …

Friction Stir Welding Of High Temperature Alloys, Jiye Wang

Doctoral Dissertations

"Friction stir welding (FSW) of Ti-6Al-4V alloy, nickel-based and iron-based oxide dispersion strengthened (ODS) alloys (MA754 and MA956) has been studied. The main aspects covered include tool evaluation, microstructural evolution, mechanical properties, and correlation between processing, microstructure and mechanical properties. Tool performance study was carried out for Ti-6Al-4V alloy with refractory tools made of W-1.1%La₂O₃ and two different grades of WC-Co based materials. The results showed that tool degradation can be attributed to mechanical and chemical interaction with processed material. The nature of tool-workpiece interaction was tool material dependent and influenced the resultant microstructure and weld quality in the stirred …

Influence Of Microstructural Length Scale On Deformation Behavior Of Magnesium Alloys, Wei Yuan

Doctoral Dissertations

"Friction stir processing (FSP) is emerging as an effective tool for microstructural modification. Mg-Al-Zn alloys with different aluminum contents were subjected to FSP to achieve fine grained and ultrafine grained (UFG) structure. The objective of this work was to study the influence of microstructural length scale on the governing deformation and strengthening mechanisms of FSP magnesium alloys.

FSP introduced strong basal fiber texture and processing parameter dependent grain/precipitate size and distribution. Grain refinement promoted non-basal dislocation activation at room temperature. The strength of the alloy increased as a consequence of grain refinement following classic Hall-Petch relationship to different extents due …