Ceramic Materials Commons^™

Manufacturing Of A Ceramic Turbine Rotor For A Compact Jet Engine, Bryan T. Leicht

Theses and Dissertations

The primary goal of this study was to develop a low-cost, timely, scalable manufacturing method that produced a ceramic turbine that can be tested as a drop-in replacement on a JetCat P400 small scale gas turbine engine. This research compared two processes for manufacturing a ceramic turbine utilizing a pour casting method and 3D printing using stereolithography ceramic manufacturing (SLCM). The pour casting method used Silicon Nitride to create a cast turbine using a sacrificial 3D printed mold. The SLCM method evaluated producing an alumina turbine using an ADMATEC Admaflex 300 SLCM printer to directly print a ceramic turbine. This …

Thermal Considerations For Film Cooling Materials With Anisotropic Thermal Conductivity, Carol E. Bryant

Theses and Dissertations

Higher performance requirements and reduced core sizes are driving increases in turbine inlet temperature in gas turbine engines, surpassing the melting point of advanced materials. Newer materials, such as composites, are being introduced into the hot sections of gas turbine engines. Components in the hot section use film cooling to prevent melting. One unique aspect of some high-temperature composites is they have a bulk anisotropic thermal conductivity, therefore heat flow differs relative to traditional metallic components. Film cooling designs can be revolutionized by leveraging anisotropy in high-temperature materials. The purpose of this research is to examine thermal considerations for using …

Creep Behavior And Deformation Mechanisms Of Spark Plasma Sintered Oxide Ceramics For Aerospace Systems At 1300˚C - 1400˚C, David D. Swanson

Theses and Dissertations

The mechanical behavior of YAG and LuAG was investigated at elevated temperatures. The specific materials investigated in this work include high-purity, polycrystalline YAG, high-purity, polycrystalline LuAG, and two doped variants of YAG: 2at% Yb-doped, polycrystalline YAG and 2at% Er-doped, polycrystalline YAG. Several billets of each material were prepared and processed by means of spark plasma sintering (SPS). Many different sintering parameters were utilized in order to obtain materials with various physical properties and to identify the effects of sintering parameters on the average grain size of the resulting materials. The compressive creep behavior of these materials was investigated at 1300°C …

Review: Factors Affecting Composite Laminates Against Lightning Strikes, Aaryan Manoj Nair

Publications and Research

Lightning strike protection (LSP) have recently been a newly developing field particularly with the emergence of graphene thin film integration into carbon fiber composite structures. This technology has a widespread application in airplanes, wind turbines, and other instruments which are susceptible to frequent lightning strikes. Electrical discharge of the instrument in a safe manner is vital for the safety of the passengers (in the case of flights) as well as the integrity of the aircraft structures because of their specific mechanical and structural properties, which are essential for their functioning. The purpose of the study is to fabricate graphene thin …

Static Fatigue Of Hi-Nicalon™ S Ceramic Fiber Tows At 600°C In Air And Silicic Acid-Saturated Steam, Caleigh M. Nelson

Theses and Dissertations

Ceramic matrix composites (CMCs) have the potential to be utilized in applications such as hypersonic vehicles, aircraft leading edges, hot sections of engines, and rocket nozzles. Of particular interest are advanced SiC/SiC composites that can withstand the elevated temperatures and harsh oxidizing environments while maintaining their properties and structural integrity under an applied load. Steam, a major component of combustion environment, is one such aggressive oxidizing environment. As steam passes through the SiC/SiC composite, entering the composite interior through the cracks in the SiC matrix, it becomes saturated with silicic acid, Si(OH)₄. Before incorporating SiC/SiC composites in the …

Fatigue Of Two Oxide/Oxide Ceramic Matrix Composites At 1200°C In Air And In Steam. Effect Of Diamond Drilled Effusion Holes, Anthony R. Cabri

Theses and Dissertations

The tension-tension fatigue behavior of two oxide-oxide ceramic matrix composites (CMCs) was investigated at 1200°C in laboratory air and steam. Both composites consist of a porous oxide matrix reinforced with laminated, woven mullite/alumina (NextelTM720) fibers. The first composite had an alumina matrix, while the second had an alumina-mullite matrix. First, we assessed the effects of incorporating mullite into the matrix material on fatigue performance by studying the tension-tension fatigue behavior of alumina-mullite matrix CMC. Second, we evaluated the effects of effusion holes on the alumina matrix CMC's fatigue performance. Specimens containing an array of 17 effusion holes of 0.5-mm diameter …

Fatigue Behavior Of An Advanced Melt-Infiltrated Sic/Sic Composite With Environmental Barrier Coating At 1200°C In Air And In Steam, Thaddeus M. Williams

Theses and Dissertations

Advanced aerospace applications such as aircraft turbine engine components, hypersonic flight vehicles, and spacecraft reentry thermal protection systems require structural materials that have superior long-term mechanical properties under high temperature, high pressure, and varying environmental factors, such as moisture. Because of their low density, high strength and fracture toughness at high temperatures SiC fiber-reinforced SiC matrix composites are being evaluated for aircraft engine hot-section components. In these applications the composites will be subjected to various types of mechanical loadings at elevated temperatures in oxidizing environments. Because their constituents are intrinsically oxidation-prone, the most significant problem hindering SiC/SiC composites is oxidation …

Interlaminar Damage Detection In Composite Materials, Hariharan Rangarajan

Williams Honors College, Honors Research Projects

Using ceramic matrix composites (CMCs) for high-temperature applications in jet engines increases durability and reduces weight and cooling requirements resulting in improved efficiency and fuel savings. Understanding, detecting, and monitoring different types of damage is essential to achieve optimal performance of CMC components. The Direct Current Potential Drop (DCPD) method is a non-destructive technique of estimating damage in composite materials.

DCPD technique works by measuring nodal potential differences when current is flown through the material. Direct current spreading in different woven and laminate composites is modeled to follow a ladder resistor network in which the nodal voltages decrease exponentially as …

Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 1100°C In Air And In Silicic Acid-Saturated Steam, Logan M. Gumucio

Theses and Dissertations

Innovations in SiC based ceramic matrix composites (CMCs) have yielded exceptional high-temperature properties and performance in aggressive oxidizing environments. These material characteristics provide potential avenues for future advancements in many applications where current metallic alloys perform near their operating temperature limits in a harsh environment. As steam (typically present in these environments) enters through cracks in the matrix of a SiC/SiC composite, it leaches Si and becomes saturated with silicic acid, Si(OH)₄, prior to attacking the reinforcing SiC fibers. Therefore, it is paramount that a thorough understanding of the performance and durability of SiC fibers be obtained under …

Creep Of Hafnium Diboride -20 Vol% Silicon Carbide At 1500°C In Air, Glen E. Pry

Theses and Dissertations

Refractory metal borides, commonly referred to as Ultra High Temperature Ceramics (UHTCs), exhibit a number of unique properties, such as extremely high melting temperature and hardness, chemical stability, high electrical and thermal conductivity and corrosion resistance. It has been demonstrated that the addition of SiC improves the oxidation resistance of ZrB2- and HfB2-based UHTCs above 1200°C by modifying the composition of the oxide scale. Addition of SiC retards the oxidation rate of ZrB2 and HfB2 by forming a protective layer of borosilicate glass. Creep deformation is one of the critical criterion for structural application of ceramics at elevated temperatures. Compression …

Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 1000°C In Air And In Silicic Acid-Saturated Steam, Brian G. Kroeger

Theses and Dissertations

Advanced SiC/SiC ceramic matrix composites (CMCs) are being considered for a variety of applications. Of interest is their ability to withstand exposure to high temperature in an aggressive oxidizing environment. The presence of steam creates such an environment. As steam traverses across a SiC/SiC composite and through cracks in the SiC matrix, it becomes saturated with silicic acid, Si(OH)₄. It is essential to understand the long-term impacts and durability of SiC/SiC CMCs that have been exposed to such a demanding environment. The present research investigated creep of Hi-Nicalon™ S SiC fibers at 1000°C in air and in silicic …

Optimal Sintering Temperature Of Ceria-Doped Scandia Stabilized Zirconia For Use In Solid Oxide Fuel Cells, Amanda K. Assuncao

Honors Undergraduate Theses

Carbon emissions are known to cause decay of the Ozone layer in addition to creating pollutant, poisonous air. This has become a growing concern among scientists and engineers across the globe; if this issue is not addressed, it is likely that the Earth will suffer catastrophic consequences. One of the main culprits of these harmful carbon emissions is fuel combustion. Between vehicles, power plants, airplanes, and ships, the world consumes an extraordinary amount of oil and fuel which all contributes to the emissions problem. Therefore, it is crucial to develop alternative energy sources that minimize the impact on the environment. …

Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 700°C In Air And In Silicic Acid-Saturated Steam, Matthew W. Piper

Theses and Dissertations

Aircraft structural and engine components are subjected to elevated temperature and steam environments during operation. Turbine blades experience particularly harsh conditions that are approaching the operating temperature limits of current Nickel-based superalloys even with active cooling. Ceramic matrix composites (CMCs), which demonstrate high specific strength and specific stiffness and maintain these properties at elevated temperatures such that active cooling is not required, are prime candidates to replace superalloys as the materials for turbine blades. Ceramic matrix composites are composite materials that consist of a ceramic matrix with fiber reinforcement. This research investigated a silicon carbide (SiC) fiber, Hi-Nicalon™ S, which …

Hydrogen Fuel Cell Analysis: Lessons Learned From Stationary Power Generation Final Report, Scott E. Grasman, John W. Sheffield, Fatih Dogan, Sunggyu Lee, Umit O. Koylu, Angie Rolufs

Materials Science and Engineering Faculty Research & Creative Works

This study considered opportunities for hydrogen in stationary applications in order to make recommendations related to RD&D strategies that incorporate lessons learned and best practices from relevant national and international stationary power efforts, as well as cost and environmental modeling of pathways. The study analyzed the different strategies utilized in power generation systems and identified the different challenges and opportunities for producing and using hydrogen as an energy carrier. Specific objectives included both a synopsis/critical analysis of lessons learned from previous stationary power programs and recommendations for a strategy for hydrogen infrastructure deployment. This strategy incorporates all hydrogen pathways and …

Studies Of Dynamic Crack Propagation And Crack Branching With Peridynamics, Youn Doh Ha, Florin Bobaru

Department of Engineering Mechanics: Faculty Publications

In this paper we discuss the peridynamic analysis of dynamic crack branching in brittle materials and show results of convergence studies under uniform grid refinement (m-convergence) and under decreasing the peridynamic horizon (δ-convergence). Comparisons with experimentally obtained values are made for the crack-tip propagation speed with three different peridynamic horizons.We also analyze the influence of the particular shape of themicro-modulus function and of different materials (Duran 50 glass and soda-lime glass) on the crack propagation behavior. We show that the peridynamic solution for this problem captures all the main features, observed experimentally, of dynamic crack propagation and branching, as well …

Ceramic Matrix Composite Characterization Under A Combustion And Loading Environment, Andrew R. Nye

Theses and Dissertations

Lightweight materials that can withstand high temperatures and corrosive environments are constantly sought after in the aerospace industry, typically for Gas Turbine Engine (GTE) application. These materials need to retain their strength throughout the long service period they would see in the combustor and turbine components of a GTE. One material that is ideal for these types of applications is an oxide/oxide Ceramic Matrix Composite (CMC). The fatigue behavior of the oxide/oxide CMC Nextel^TM 720/Alumina (N720/A) was investigated in a unique high temperature environment. N720/A consisted of an 8-harness satin weave of Nextel^TM aluminum oxide/silicon oxide fibers bound …

Effects Of Environment On Creep Behavior Of Nextel720/Alumina-Mullite Ceramic Composite With ±45º Fiber Orientation At 1200ºc, Muzaffer Ozer

Theses and Dissertations

The present effort will investigate the off-axis creep behavior of the Nexte720/Alumina-Mullite CMC, a material system which relies on a porous alumina/mullite matrix for damage tolerance as compared to the pure alumina matrix in earlier studies. This research evaluated the creep behavior of N720/AM with a ± 45° fiber orientation at 1200°C in: laboratory air, steam, and argon environments. Creep-rupture tests at the creep stress levels of: 32, 30, 26, and 20 MPa were conducted in each environment. Additionally 35 MPa stress level examined in air and 13 MPa stress level examined both in air and steam. The N720/AM with …

Analysis Of Multi-Layered Materials Under High Velocity Impact Using Cth, Jason K. Lee

Theses and Dissertations

Multi-layer armor containing ceramic and metallic layers has become more common in the past two decades. Typically, ceramics have high compressive strength which combined with their low density make them highly desirable for armor applications. This research effort numerically simulates high velocity impact of cylindrical projectiles on multi-layer metallic and ceramic targets of finite thickness. The impact of the projectile occurs normal to the surface of the target. The projectiles used are made of either S7 tool steel or tungsten. The targets consist of either rolled homogeneous armor, 4340 steel and boron carbide ceramic or rolled homogeneous armor and boron …

Effects Of Environment On Creep Behavior Of Nextel 720/Alumina-Mullite Ceramic Composite At 1200°C, Christopher L. Genelin

Theses and Dissertations

The creep behavior of an oxide-oxide ceramic matrix composite (CMC) was investigated at 1200°C in laboratory air, in steam and in argon. The composite consisted of a porous alumina-mullite matrix reinforced with laminated, woven mullite/alumina (Nextel/720) fibers. The composite had no fiber coating and relied on its porous alumina/mullite matrix for flaw tolerance. Tensile stress-strain behavior was investigated and the tensile properties were measured at 1200°C in laboratory air. Tensile creep behavior of the CMC was examined for creep stress levels of 73, 91, 114 and 136 MPa. Creep run-out, set to 100 h, was achieved for stress levels ≤ …

2nd Annual Undergraduate Research Conference Abstract Book, University Of Missouri--Rolla

Undergraduate Research Conference at Missouri S&T

No abstract provided.

Investigation Into The Behavior Of Geometrically Nonlinear Composite Arches, John C. Bailey

Theses and Dissertations

This research modifies the existing finite element formulation of a potential energy based large deformation and moderate rotation theory. Hermitian shape functions replace the existing linear bending angle interpolations. Negligible differences between the two formulations indicate the underlying kinematics limit the accuracy, not the finite element interpolations. Using the new program, numerous nonlinear arch geometries are modeled to investigate the effects of arc length and thickness variations. Local and global snapping phenomena are captured as well as through the thickness shear driven nonlinearities.

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite At Elevated Temperature Under Tension-Tension Loading, Craig D. Steiner

Theses and Dissertations

This study investigated the fatigue behavior and damage mechanisms of a [0-90]_4s SiC-MAS ceramic matrix composite under tension-tension loading at two elevated temperatures and two frequencies. Stress and strain hystereses, maximum and minimum strain, and modulus of elasticity were evaluated to characterize the material behavior. Microscopy and fractography were used to evaluate damage progression and mechanisms. Fatigue life was independent of frequency at both temperatures.

Characterization Of Fatigue Behavior Of 2-D Woven Fabric Reinforced Ceramic Matrix Composite At Elevated Temperature, Daniel J. Groner

Theses and Dissertations

This study investigated the fatigue behavior and associated damage mechanisms in notched and unnotched enhanced Sic-SiC ceramic matrix composite specimens at 1100°C. Stiffness degradation, strain variation, and hysteresis were evaluated to characterize material behavior. Microscopic examination was performed to characterize damage mechanisms. During high cycle-low stress fatigue tests, far less fiber-matrix interface debond was evident than in low cycle-high stress fatigue tests. Notched specimens exhibited minimal stress concentration during monotonic tensile testing and minimal notch sensitivity during fatigue testing. Damage mechanisms were also similar to unnotched.

Fatigue Behavior Of A Cross-Ply Ceramic Matrix Composite Subjected To Tension-Tension Cycling With Hold Time, Scott A. Grant

Theses and Dissertations

This study was carried out to investigate the elevated temperature behavior of the SiC-MAS5 cross- ply [0-90]_4S ceramic matrix composite manufactured by Corning Inc. to fatigue with loading waveforms that combine the characteristics of stress rupture and high cycle fatigue. The test results were compiled in the form of S-N (cycles to failure), S-T (exposure time versus cycles to failure), S-S (energy exposure versus cycles to failure), normalized modulus degradation, strain progression, and hysteresis loop progression. From the mechanical behavior demonstrated by these curves, relationships between the effect of the environment and loading waveform were developed. In addition, a …

Failure Characterization Of A Fiber Reinforced Ceramic Matrix Composite With Circular Holes, Daniel E. Bullock

Theses and Dissertations

The purpose of this study was to investigate the performance of a fiber reinforced ceramic matrix composite with circular holes. The specific objectives were to (1) determine the relationship between tensile failure stress and the ratio of hole diameter to specimen width, and (2) to examine the initiation and progression of damage. The ceramic matrix composite used was SiC/ 1723, composed of continuous silicon titanium carbide fibers in an aluminosilicate glass ceramic matrix. Uniaxial tensile tests were performed at room temperature on two different layups; unidirectional [0]₈, and [0/90]_2s symmetric. Each layup was tested at three diameter-to-width …