Materials Science and Engineering Commons^™

Quantum-Based First-Principles Study Of Gas Molecules (O2 , Co2 , No2 ) Interaction On Monolayer Germanene, Arief Hermanto, Harmon Prayogi, Ari Dwi Nugraheni, Juliasih Partini, Sholihun Sholihun

Journal of Metals, Materials and Minerals

We perform calculations of the adsorption energy of O2, CO2, and NO2 molecules on germanene by using the density functional theory (DFT). We find two favorable configurations for O2, the U-site and V-site configurations with similar adsorption energies of -4.10 and -4.32 eV. As for NO2, we find two favorable configurations, the T-site and DB-site configurations. The T-site configuration is 0.98 eV more stable than the IB-site one, and both configurations are chemically adsorbed by germanene. On the contrary for CO2, we find a T-site configuration with adsorption energy of 0.42 eV and the configuration physically adsorbed by germanene.

Synthesis And Modification Of Nickel Hydroxide Particle Synthesized By Self-Assembly And Electron Beam Irradiation Technique For Photocatalyst Activity, Narisara Saechin, Sumitra Sripho, Thitirat Rattanawongwiboon, Sakchai Laksee, Pattra Lertsarawut, Wilasinee Kingkam, Sarute Ummartyotin

Journal of Metals, Materials and Minerals

The purpose of this work is to study the methyl orange removal of Ni(OH)2 nanoparticles. The photo-catalyst activity is investigated based on UV lamp of 18 watt. Ni(OH)2 is synthesized by a self-assembly process and then exposed to electron beam radiation at 10 MeV energy with various doses ranging from 50 kGy to 500 kGy. The properties of Ni(OH)2 nanoparticles are then evaluated. No significant change of functional group and percent of crystallinity are observed. The morphology is uniformly presented as a plate-like. The specific surface area, pore size and pore volume are reduced. Point of zero charge confirmed that …

Effect Of Calcination Frequency On The Thermoelectric Properties Of Ti Doped Cucro By Solid State Method, Doli Bonardo, Nono Darsono, Syahrul Humaidi, Agung Imaduddin, Noni Surtiana Silalahi

Journal of Metals, Materials and Minerals

In this study, the influence of titanium oxide (TiO2) dopants and varying calcination processes on the thermoelectric properties of CuCrO2 was systematically explored. It was emphasized that these factors were not only affecting dislocation density but also exerting a profound influence on thermoelectric performance through the modulation of Seebeck coefficient and resistivity. The findings highlighted CrT-2, which incorporated TiO2 and underwent a two-time calcination process, as the top-performing sample in terms of power factor values, underscoring the significance of TiO2 as a dopant for enhancing thermoelectric efficiency. Conversely, Cr-4, exposed to four calcination cycles, exhibited slightly lower power factor values …

Electrical And Water Resistance Properties Of Conductive Paste Based On Gold/Silver Composites, Sutthipoj Wongrerkdee, Supab Choopun, Pichitchai Pimpang

Journal of Metals, Materials and Minerals

This study aimed to investigate the effects of a corrosive environment on both the electrical and the water resistance properties of conductive paste based on gold/silver composites. The conductive paste was prepared by incorporating silver and gold powders, polyvinyl acetate, polyvinyl chloride as adhesive components, and methyl isobutyl ketone as a diluent. The gold/silver composite powder was prepared with different mass ratios of gold and silver. The paste was coated on a substrate and heated at 80℃ to form the conductive paste film. Characterizations of conductive paste were performed by using FT-IR spectroscopy, electrometry, cyclic voltammetry, and contact angle measurements. …

Molybdenum Disulfide-Zirconium Dioxide Composite With Enhance Supercapacitance Performance, Razan Nadhim Shaker, Sami Mohammed, Yousra Ali Abdulsayed

Journal of Metals, Materials and Minerals

As a supercapacitor active material, molybdenum disulfide (MoS2) layer offers good conductivity, large surface area, and electrochemical stability. In practice, however, its capacitance is low in comparison to other materials. This work synthesized MoS2-zirconium dioxide (ZrO2) composite in a simple, high-throughput way to test it as a supercapacitor active layer. During the tests, the composite shows a gravimetric capacitance of 500.0 F⸳g-1, while MoS2 and ZrO2 have capacitances of 265.12 and 152.43, respectively. The increase in capacitance of composite stems from the synergistic effect between ZrO2's pseudocapacitor behavior and MoS2's electric double layer capacitance (EDLC). Moreover, the composite has a …

Dome Tester, Clark Bates, Nikolas M. Kulin

Williams Honors College, Honors Research Projects

We are reconfiguring and modifying the previously built dome tester to be more user friendly and mechanically applicable. This has a long-term goal of being a usable teaching tool for manufacturing education within the college of engineering and polymer sciences. The dome tester pushes a metal dome into a clamped sheet of metal to test its forming limits and where necking occurs. We have implemented a better method of viewing the sheet sample as it is being deformed, and improved measuring methods for the distance a sample is deformed. By introducing these changes in conjunction with improved documentation of the …

Wetting Transition Of Texturized Surfaces, Jenna Stephens

Williams Honors College, Honors Research Projects

Building on previous research, this project aims to continue the investigation of the wettability of various liquids on a uniform, texturized surface. Different surface energies can impact the wettability of a surface. The surface can be hydrophilic, hydrophobic, or in between. The goal of this project is to research how features of texturized surfaces affect the wetting transition of water, oil, and a mixture of both. Additionally, this project aims to improve the quality of the 3D printed surfaces. The surfaces that will be studied are constructed using UV cured resin 3D printing and are made up of an array …

Defining The Proper Operating Time For The Septa Extractor, Abigail Jones

Williams Honors College, Honors Research Projects

Anionic polymerizations are a common type of reaction used to produce synthetic rubber. During these reactions, it is necessary to charge initiators, modifiers, and other substances, through pressurized containers that are sealed with rubber septa. These septa prevent oxygen and moisture from entering the pressurized container, and the reactor, though they need to be cleaned before use to remove other impurities. Currently a glass Soxhlet Extractor is used to remove such impurities, and though effective, it has a limited capacity, so it has to run frequently. This limitation led to the commissioning of the Septa Extractor, which is an automated …

Comparison Of The Thermal Stability In Equal-Channel-Angular-Pressed And High-Pressure-Torsion-Processed Fe–21cr–5al Alloy, Maalavan Arivu, Andrew Hoffman, Jiaqi Duan, Jonathan Poplawsky, Xinchang Zhang, Frank W. Liou, Rinat Islamgaliev, Ruslan Valiev, Haiming Wen

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Nanostructured Steels Are Expected to Have Enhanced Irradiation Tolerance and Improved Strength. However, They Suffer from Poor Microstructural Stability at Elevated Temperatures. in This Study, Fe–21Cr–5Al–0.026C (Wt%) Kanthal D (KD) Alloy Belonging to a Class of (FeCrAl) Alloys Considered for Accident-Tolerant Fuel Cladding in Light-Water Reactors is Nanostructured using Two Severe Plastic Deformation Techniques of Equal-Channel Angular Pressing (ECAP) and High-Pressure Torsion (HPT), and their Thermal Stability between 500–700 °C is Studied and Compared. ECAP KD is Found to Be Thermally Stable Up to 500 °C, Whereas HPT KD is Unstable at 500 °C. Microstructural Characterization Reveals that ECAP KD …

Microstructure, Mechanical Properties And Oxidation Behavior Of Refractory Multi-Principal Element Alloys By Laser Remelting And Conventional Manufacturing, Visharad Jalan, Seth Crawford, Sung Heng Wu, Frank W. Liou, Haiming Wen

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Refractory Multi-Principal Element Alloys (RMPEAs), HfNbTaTiZr, (HfNbTaTiZr)₉Cr, and (HfNbTaTiZr)₉Al, Were Manufactured using Vacuum Arc Melting Followed by Laser Remelting to Mimic Additive Manufacturing. the Microhardness of the As-Cast HfNbTaTiZr, (HfNbTaTiZr)₉Cr, and (HfNbTaTiZr)₉Al Samples after Arc Melting Was Measured as 6.20, 7.63, and 6.89 Gpa, respectively. after Laser Remelting and Re-Solidification, the Hardness Increased by ~ 30% for Each Composition; the Hardest Was (HfNbTaTiZr)₉Cr Measured at 9.60 GPa, While the Softest Was HfNbTaTiZr with a Hardness of 8.42 GPa, Which Was Still Harder Compared to All the Other Samples. the Addition …

Correction: Modeling Phase Selection And Extended Solubility In Rapid Solidified Alloys (Metallurgical And Materials Transactions A, (2023), 10.1007/S11661-023-07221-7), Azeez Akinbo, Yijia Gu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

In the original online version of this article the reference citation in Fig. 3b was incorrect. The original article was corrected.

Preparation, Cure, And Characterization Of Cyanate Ester-Epoxy Blends Containing Reactive Flame Retardants, Mustafa Mukhtar, Donald A. Klosterman

Chemical and Materials Engineering Faculty Publications

Cyanate ester resins are sometimes mixed with lower cost epoxy monomers to modify cost, toughness, and processing capabilities. Despite the high performance of these thermosetting polymers, flame retardancy remains an issue. This study examined blends of three different commercial cyanate ester monomers (LVT-100, LECy, and XU-71787.02) and diglycidyl ether of bisphenol A (DGEBA) at 50/50 wt% of each type. The blends were successfully reacted with two reactive flame retardants (FR): 9,10-dihydro-9-ox-9-phosphaphenanthrene-10-oxide (DOPO) and poly(m-phenylene methylphosphonate) (PMP) at phosphorus contents ranging from 0 to 3 wt%. The curing behavior of EP/CE blends was investigated using differential scanning calorimetry (DSC). It was …

Development Of Inconel 718f And Inconel 718e Powders For Parts Manufacturing Utilizing Binder Jet Three-Dimensional Printing And Compressed Pellet Methods, Duncan Eric Manor Ii

Graduate Theses, Dissertations, and Problem Reports (ETD)

Alloy Inconel 718 is a Ni based superalloy used for high temperature applications including turbine blades, turbocharger rotors and nuclear reactors. Inconel 718 is a popular commercial atomized powder that has limitations in performance for use in additive manufacturing applications due to poor part quality and efficiency of current fabrication methods. Developing new compositions and additive manufacturing (AM) methodologies of IN718 is critical to improve the quality and the efficiency of IN718 parts manufacturing. Developing new additive manufacturing methodology that produces higher quality parts made of IN718 as compared to current methods has the potential to greatly impact industry, academia, …

Investigation Of Oxidation And Corrosion Resistance Of Ni-Based Alloys And Stainless Steels Under Co2 Environments At Elevated Temperatures, Spencer Roy Fultineer

Graduate Theses, Dissertations, and Problem Reports (ETD)

High mechanical strength integrity, high robustness towards oxidation, and high resistance to carburization under CO2 environments at elevated temperatures are usually required for metallic systems that are employed for power generation. INCONEL 625 is a nickel-based superalloy that started development in the 1950s. This material was designed with the distinct purpose of use in high-temperature and high-pressure systems. While various materials possess the physical properties to handle these conditions, the creation of IN625 addresses the need for a material to withstand the highly corrosive properties of these kinds of environments. In order to evaluate the oxidation and corrosion resistance of …

Stability Of Ruddlesden-Popper Phase Lanthanum Nickelate As Air Electrode For Reversible Solid Oxide Cells, Daniel De Lorenzo Moreira

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis studied the long-term stability of Ruddlesden-Popper phase Lanthanum Nickelate under operating conditions as the air electrode for Reversible Solid Oxide Cells (R-SOC). Renewable energies have gone through increase in popularity throughout the last decades, mainly due to the consequences of the rapid population growth in the world. These new energies have been pointed as the rightful successor of fossil fuel energies in order to decrease the environmental impact of our day-to-day life. Solid Oxide Fuel Cells as well as Solid Oxide Electrolysis Cells are believed to be the key to stabilizing the energy supply when environmental conditions are …

Material Characterization Of Thermoplastic Polyurethane (Tpu) And Thermoplastic Elastomers (Tpe) For Development Of 3d-Printed Surrogate Organs For Medical Training, Anastasia Elizabeth Lucci

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cadaveric specimens are a necessary, albeit limited, resource for training medical students on basic surgical skills. The availability of surrogate 3D-printed organs would readily allow access to resources that could reduce or potentially eliminate the need for cadaveric specimens or, at a minimum, provide students the opportunity to practice with 3D-printed surrogates before transitioning to those specimens. This research focuses on determining which thermoplastic material most closely mimics mechanical properties such as hardness and stiffness of human organs and allows 3D printing surrogate organs to be used as safe, educational tools. Relatively “soft” materials such as thermoplastic polyurethanes (TPU) and …

Manganese-Based A-Site High-Entropy Perovskite Oxides For Solar Thermochemical Hydrogen Production, Cijie Liu

Graduate Theses, Dissertations, and Problem Reports (ETD)

Non-stoichiometric perovskite oxides have been studied as a new family of redox oxides for solar thermochemical hydrogen (STCH) production owing to their favourable thermodynamic properties. However, conventional perovskite oxides suffer from limited phase stability and kinetic properties, and poor cyclability. Here, we report a strategy of introducing A-site multi-principal-component mixing to develop a high-entropy perovskite oxide, (La_1/6Pr_1/6Nd_1/6Gd_1/6Sr_1/6Ba_1/6)MnO₃ (LPNGSB_Mn), which shows desirable thermodynamic and kinetics properties as well as excellent phase stability and cycling durability. LPNGSB_Mn exhibits enhanced hydrogen production (~77.5 mmol moloxide^–1) compared to (La …

Development Of High Kinetic Inductance Superconducting Nanowire Devices On High Permittivity Strontium Titanate Substrates, Jamie Timmons

UNF Graduate Theses and Dissertations

This thesis involves the fabrication and characterization of devices made from two different superconducting materials: yttrium barium copper oxide (YBCO), a high-TC complex oxide, and niobium nitride (NbN), a low-TC transition metal nitride. Both types of devices are fabricated on strontium titanate substrates, which provides a good lattice match to YBCO and also an extremely large permittivity at low temperature. We demonstrate that wet etching of YBCO thin films via bromine can be a viable microfrabriation technique for the material. Using approximately 35 nm thick epitaxially grown YBCO on an STO substrate, we were able to fabricate YBCO “microwires” with …

An Experimental Study On The Mechanical Properties And Chemical Composition Of Lcd 3d Printed Specimens, Sebastian Gomez

College of Graduate Studies: Theses & Dissertations

Additive manufacturing technologies have been enhanced throughout the years yet have surprised the manufacturing industry due to their high-end surface finish and dimensional accuracy. Different experiments have been done to identify a specific phenomenon known in the vat-polymerization field. Distortion and dimensional inaccuracy tend to affect the overall properties of the process, either physical or chemical. This approach allows the understanding of how the physical properties have been affected and how to study the chemical properties to avoid this type of phenomenon. The chemical reaction between polymer and UV light has been studied and experimented with to the point that …

Understanding The Feasibility Of Improving Interfacial Properties In Direct Ink Writing Of Silicone-Polyurethane Resin Hybrid Material, Ayobami Samuel Akinfenwa

College of Graduate Studies: Theses & Dissertations

The progress in materials engineering and the ability to make various models possible have made soft robotics a popular alternative to traditional robotics. Still, soft robots need various parts, like Printed Circuit Boards (PCBs), batteries, cables, fittings, and more, to work correctly or to get attached to other complex parts. These parts can have different material properties, like elastic moduli, strength, etc. Because of these differences, mechanical failures happen at the points where two materials meet, making soft robots less durable and less lasting in real-life situations due to failure. Conventionally, the fabrication of soft robot parts is through moulding. …

Design And Fabrication Of A High-Performance Heat Exchanger Using An Optimized Three-Dimensional Surface Structure Through Additive Manufacturing, Seth T. Waters

College of Graduate Studies: Theses & Dissertations

A heat exchanger is a device used to transfer thermal energy between two intertwining fluid pathways. In this study, the design of a novel heat exchanger is proposed using functional gradient double gyroid structure. The complex internal geometries of the gyroid structure significantly increases the surface area to volume ratio, and potentially could expressively improve efficiency of the heat transfer. The proposed idea provides a new approach for the design of a high-efficiency heat exchanger. In order to fabricate the complex structured heat exchanger system additive manufacturing is adapted instead of traditionally subtractive manufacturing techniques or casting. The prototypes of …

Aerosol Synthesis Of Tungsten Bronze Particles For Nir Shielding, Hao Tu

Theses and Dissertations

This dissertation emphasizes the need for efficient energy use in buildings and transportation due to global warming and the energy crisis. It suggests that improving energy efficiency can help reduce energy consumption and emissions and support sustainability. The dissertation introduces various transparent materials that can block near-infrared (NIR) radiation from solar radiation to save energy and money, and it highlights the growing market value of such products. The dissertation compares tungsten bronze with other NIR shielding materials and shows its advantages. The dissertation introduces a cheap and environmentally friendly method for continuously producing tungsten bronze particles via aerosol synthesis. Particle …

An Updated Analytical Method For Predicting The Bracing Behavior Of Z-Purlin Supported Standing Seam Diaphragm Systems, Michael W. Seek

Engineering Technology Faculty Publications

Roof systems utilizing Z-purlins as a secondary member supporting a standing seam panel system are used extensively by the metal building industry. The Z-purlins rely on the diaphragm action in the standing seam panel system to provide lateral support and transfer forces to anchorages. The behavior of the standing seam system is highly nonlinear making prediction of the interaction between the Z-purlin and the standing seam system difficult. To better understand the behavior of the interaction between the purlins and the panel system, a series of non-linear shell finite element models were developed based on the test results of simple …

Classifying Sidewalk Materials Using Multi-Modal Data, Jiawei Liu

Dissertations and Theses

Navigating safely and independently presents considerable challenges for people who are blind or have low vision (BLV), as it requires a comprehensive understanding of their neighborhood environment. Our user study reveals that materials and objects on sidewalks play a crucial role in navigation tasks. Unfortunately, current methods for assessing sidewalk materials are suboptimal, often relying on labor-intensive and expensive manual assessments that fail to capture the full range of sidewalk features critical to individuals with BLV.

In response to this problem, this master’s thesis investigates deep learning approaches specifically designed for the classification of multi-modal sidewalk materials. The proposed framework …

Radiation Shielding Effectiveness Of Hafnium Diboride (Hfb2) Reinforced Epoxy Composites For Enhanced Radiation Protection And Safety, Furkan Erdogan

Theses and Dissertations

This thesis investigates the radiation shielding effectiveness of hafnium diboride (HfB2) reinforced epoxy composites, with the aim of enhancing radiation protection and safety in various applications. The study focuses on the development and characterization of HfB2-epoxy composites with varying weight percentages of HfB2 nanoparticles, as well as on the evaluation of their shielding effectiveness against gamma rays and thermal neutrons. The radiation shielding performance of the composites is assessed using gamma-ray spectroscopy and neutron counting, and the neutron attenuation efficacy is compared with that of 5% borated high-dense polyethylene. The results indicate that the HfB2-epoxy composites exhibit promising radiation shielding …

Development Of Polymeric Sorbents As Reusable Filtration Systems For Remediation Of Pfas Contaminated Water, E. Molly Frazar

Theses and Dissertations--Chemical and Materials Engineering

Decades of use of per- and polyfluoroalkyl substances (PFAS) in a multitude of consumer and industry-based products have led to a devastating amount of soil and water contamination. Although these chemicals and compounds possess advantageous qualities – such as that of PFAS in the role of fire-fighting foams that have no doubt saved countless lives and homes, we must take responsibility for the anthropogenic hazards that threaten our global health. This entails being able to cost-effectively remediate problems created in the past from overuse of toxic substances that could negatively impact our future, and in this case, the future of …

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …

Surface Properties, Work Function, And Thermionic Electron Emission Characterization Of Materials For Next-Generation Dispenser Cathodes, Antonio Mantica

Theses and Dissertations--Chemical and Materials Engineering

A dispenser cathode’s ability to thermionically emit electrons is highly dependent on its material properties, especially those of the surface. Understanding the relationship between surface properties and electron emission, therefore, is vital to reach the next generation of the many vacuum electron devices (VEDs) that rely on the physics of electron emission. In the past century, many techniques have been developed to characterize material surfaces and quantify thermionic emission. These techniques are based on a wide range of different physical phenomena, including measuring photoemission via the photoelectric effect, measuring the electrostatic potential between metals in electrical contact, and current collection …

Solid-State Electrolytes For Long Duration Molten Sodium Batteries, Ryan C. Hill

Theses and Dissertations--Chemical and Materials Engineering

Rechargeable batteries have become a staple of modern society, driving the development and expansion of portable electronics and electric vehicles. The long lifetime and high energy density provided by batteries have made them excellent candidates for use in the emerging field of long duration, grid-scale energy storage. However, traditional battery chemistries, such as Li-ion, are not an ideal solution for grid-scale storage, due to high-cost raw materials that are often sourced from volatile markets. Sodium-based batteries are a promising alternative for long duration storage, owing to the domestic abundance of raw materials and energy densities that nearly rival that of …

Diffuse Scattering And 3d-∆Pdf Analyses: Order-Disorder Phase Transitions In (Sr1−Xcax)3rh4sn13 And Nano2, Puspa Upreti

Graduate Research Theses & Dissertations

Classification of structural phase transitions as being of the displacive or order-disorder types is usually done based on spectroscopic measurements performed above the transition. Transitions of the displacive type typically occur when soft phonon modes condense upon approaching the phase transition, whereas those of the order-disorder type are characterized by structures in which the atoms are located randomly above the phase transition at T* at the minima of a multiwell potential. In the ordered state, i.e., when T

We have performed single crystal x-ray scattering experiments and three-dimensional pair distribution functions (3D-∆PDF) analyses to understand the nature of phase transitions …