Materials Science and Engineering Commons^™

Size Distribution, Elemental Composition And Morphology Of Nanoparticles Separated From Respirable Coal Mine Dust, Shoeleh Assemi, Lei Pan, Xuming Wang, Titilayo Akinseye, Jan D. Miller

Michigan Tech Publications, Part 1

Nanoparticles, defined as particles with one dimension below 100 nm, contribute little to the total mass concentration in respirable coal mine dust (RCMD) toxicological studies, but they could have a considerable part in the adverse health effects by RCMD inhalation. It has been shown that inhaled nanoparticles can penetrate deep into the lung and could plausibly contribute to acute and chronic pulmonary diseases by triggering oxidative stress formation and inducing inflammation. RCMD nanoparticles from samples collected in an underground mine in the United States were analyzed by a particle separation technique, field-flow fractionation (FFF), for size, morphology, and elemental composition. …

Effect Of Sc On Recrystallization Resistance Of Aa7050, Keaton Schmidt

Dissertations, Master's Theses and Master's Reports

The extrusion process involves high temperatures and strains that can result in undesirable microstructures, especially along the surface. Extruded alloys tend to exhibit surface recrystallization during heat treating at regions of higher strains, which can lead to reduced fatigue strength and corrosion resistance. By adding Sc to AA7050, nano-sized dispersoids are formed with Sc cores and Zr shells that restrict recrystallization more than the base alloy that only utilizes Zr. Billets with varying Sc content and a control with only Zr were cast, and extrusions were made in order to compare surface microstructures at varying strains in the as-extruded and …

Quantifying The Evolution Of Strengthening Mechanisms For Commercially Produced Niobium And Titanium Hsla Steel Sheet, Isabella M.W. Jaszczak

Dissertations, Master's Theses and Master's Reports

Strength uniformity along the coil length of commercially produced high-strength, low-alloy (HSLA) steel hot-rolled sheet is crucial to avoid the downgrading of product that does not meet strength specifications. In addition to contributing to precipitation strengthening through the growth of niobium-titanium carbides ((Nb,Ti)-C), niobium hinders austenite recrystallization and refines ferrite grain size. The potency of these strengthening mechanisms relies heavily on the austenite to ferrite transformation kinetics of the hot-rolling process. While niobium’s effect on precipitation strengthening, Hall-Petch strengthening, dislocation strengthening, and solute strengthening have all been studied in literature independently, the interactions of these mechanisms with each other and …

Optimizing The Extrudability Of 6082 Aluminum By Varying The Magnesium And Silicon Concentration, Eli A. Harma

Dissertations, Master's Theses and Master's Reports

Alloy 6082 aluminum is used for high-volume manufacturing in the automotive industry due to its high strength, impact performance, and corrosion resistance. However, given these improved properties, the alloy has decreased formability compared to other 6xxx series alloys, especially in the extrusion process. Controlling the dynamic recovery and recrystallization properties by changing the additions of Mg and Si can improve the hot deformation properties. Five alloys of varying Mg and Si concentrations between 0.6 to 1.2wt% Mg and 0.7 to 1.3wt% Si were made with constant concentrations of Cr, Fe, and Mn and the same homogenization heat treatment. The proposed …

Nanomaterials For Cardiovascular Engineering, Roya Bagheri

Dissertations, Master's Theses and Master's Reports

Cardiovascular diseases and disorders (i.e., those related to heart and blood vessels) are the main reasons for mortality worldwide. Nanomaterials, with their unique morphologies and properties, have a great potential for advancing cardiovascular engineering to treat diseases and disorders. In this dissertation, several cardiovascular applications of conductive nanomaterials were investigated. First, a conductive nanomaterial was explored to fabricate biohybrid nanomaterial-cardiomyocyte (CM – heart muscle cell) systems. Using Carbon Nanotube (CNT) forest as a 3D porous and conductive scaffold was investigated. The influence of the CNT forest on the viability, attachment, and spreading of CMs and their genetic information was …

Molecular Dynamics Modeling Of Polymers For Aerospace Composites, Swapnil Sambhaji Bamane

Dissertations, Master's Theses and Master's Reports

Polymer matrix composite materials are widely used as structural materials in aerospace and aeronautical vehicles. Resin/reinforcement wetting and the effect of polymerization on the thermo-mechanical properties of the resin are key parameters in the manufacturing of aerospace composite materials. Determining the contact angle between combinations of liquid resin and reinforcement surfaces is a common method for quantifying wettability. It is challenging to determine contact angle values experimentally of high-performance resins on CNT materials such as CNT, graphene, bundles or yarns, and BNNT surfaces. It is also experimentally difficult to determine the effect of polymerization reaction on material properties of a …

Development Of Corn Kernel-Based Biocomposite Films For Food Packaging Applications, Swastika Bera

Electronic Theses and Dissertations

Most of the current and active food packaging resources and methods are nonbiodegradable and nonrenewable therefore harmful to the environment. Due to this, alternate sources of food packaging materials are in high demand. In this study, a bio-composite film has been developed, with Corn kernel powder as fiber reinforcement which is mixed with gelatin, and lignin two biopolymers as the matrix. The effect of Corn Kernel (CK) reinforcement on the Gelatin/Lignin (G/L) matrix on mechanical and barrier properties has been studied. CK has shown great potential as reinforcement to natural polymer, gelatin, and lignin (G/L) for food packaging applications as …

Investigation Of Oxidation And Corrosion Resistance Of Ni-Based Alloys And Stainless Steels Under Co2 Environments At Elevated Temperatures, Spencer Roy Fultineer

Graduate Theses, Dissertations, and Problem Reports (ETD)

High mechanical strength integrity, high robustness towards oxidation, and high resistance to carburization under CO2 environments at elevated temperatures are usually required for metallic systems that are employed for power generation. INCONEL 625 is a nickel-based superalloy that started development in the 1950s. This material was designed with the distinct purpose of use in high-temperature and high-pressure systems. While various materials possess the physical properties to handle these conditions, the creation of IN625 addresses the need for a material to withstand the highly corrosive properties of these kinds of environments. In order to evaluate the oxidation and corrosion resistance of …

Development Of Inconel 718f And Inconel 718e Powders For Parts Manufacturing Utilizing Binder Jet Three-Dimensional Printing And Compressed Pellet Methods, Duncan Eric Manor Ii

Graduate Theses, Dissertations, and Problem Reports (ETD)

Alloy Inconel 718 is a Ni based superalloy used for high temperature applications including turbine blades, turbocharger rotors and nuclear reactors. Inconel 718 is a popular commercial atomized powder that has limitations in performance for use in additive manufacturing applications due to poor part quality and efficiency of current fabrication methods. Developing new compositions and additive manufacturing (AM) methodologies of IN718 is critical to improve the quality and the efficiency of IN718 parts manufacturing. Developing new additive manufacturing methodology that produces higher quality parts made of IN718 as compared to current methods has the potential to greatly impact industry, academia, …

Material Characterization Of Thermoplastic Polyurethane (Tpu) And Thermoplastic Elastomers (Tpe) For Development Of 3d-Printed Surrogate Organs For Medical Training, Anastasia Elizabeth Lucci

Graduate Theses, Dissertations, and Problem Reports (ETD)

Cadaveric specimens are a necessary, albeit limited, resource for training medical students on basic surgical skills. The availability of surrogate 3D-printed organs would readily allow access to resources that could reduce or potentially eliminate the need for cadaveric specimens or, at a minimum, provide students the opportunity to practice with 3D-printed surrogates before transitioning to those specimens. This research focuses on determining which thermoplastic material most closely mimics mechanical properties such as hardness and stiffness of human organs and allows 3D printing surrogate organs to be used as safe, educational tools. Relatively “soft” materials such as thermoplastic polyurethanes (TPU) and …

Elastic Properties Of The Non-Mixing Copper Donor Assisted Material In Friction Stir Welding Of Aluminum Alloys Using Nanoindentation, M. Ojha, A. H. Al-Allaq, Y. S. Mohammed, S. N. Bhukya, Z. Wu, A. A. Elmustafa

Mechanical & Aerospace Engineering Faculty Publications

Friction stir welding of high-strength materials such as steels is the impeded by the lack of the vast heat input needed to start the process. Contact friction is considered the most dominant source of heat generation for FSW steels which tends to cause severe wear conditions of the tool hear. To relieve the extreme wear conditions that occur on the tool heads because of FSW steels, we introduce the non-mixing Cu donor stir material to friction stir welding of aluminum alloys. The elastic properties of the Cu donor assisted friction stir welded aluminum alloys are measured using nanoindentation. The hardness …

A Partial Discharge Inception Voltage Modeling Approach, Shilpi Mukherjee, Tristan Mark Evans, David Huitink, H. Alan Mantooth

Electrical Engineering Faculty Publications and Presentations

A partial discharge inception voltage modeling approach promoting design-for-reliability considerations in advanced power modules is presented. As power modules are being operated at higher voltages and become more compact to meet power density demands, there is an increased risk of partial discharge, the silent precursor to electrical breakdown that degrades insulation material. The trade-off between voltage class and module compaction must be quantified. This work presents a methodology to model the tradeoff for any substrate and encapsulant material. A surface charge density-based partial discharge inception voltage (PDIV) model was developed to overcome the challenges in electric field-based models. The model …

Developing Mesoporous Silica Nanoparticle-Based Stimuli-Responsive Nanocarriers For Delivery Of Small Molecule Therapeutics Against Colon Cancer Cells, Nisitha Lakmal Wellala Wijewantha

Dissertations and Theses

This dissertation delves into the innovative application of mesoporous silica nanoparticles (MSNs) for targeted drug delivery in colorectal cancer (CRC), one of the most prevalent and deadly forms of cancer worldwide. The initial focus of the research is on developing enzyme-responsive MSNs loaded with veratridine (VTD), an alkaloid derived from natural sources that demonstrates potent anticancer activity. The nanoparticles have been engineered to deliver VTD selectively to CRC cells, releasing the payload upon being exposed to specific enzymes primarily secreted by these cells. This strategy has dual advantages of amplifying the anticancer effects while minimizing potential side effects on healthy …

High Energy Blue Light Induces Oxidative Stress And Retinal Cell Apoptosis, Jessica Malinsky

Capstone Showcase

Blue light (BL) is a high energy, short wavelength spanning 400 to 500 nm. Found in technological and environmental forms, BL has been shown to induce photochemical damage of the retina by reactive oxygen species (ROS) production. Excess ROS leads to oxidative stress, which disrupts retinal mitochondrial structure and function. As mitochondria amply occupy photoreceptors, they also contribute to oxidative stress due to their selectively significant absorption of BL at 400 to 500 nm. ROS generation that induces oxidative stress subsequently promotes retinal mitochondrial apoptosis. BL filtering and preventative mechanisms have been suggested to improve or repair BL-induced retinal damage, …

Solid-State Shear Pulverization: A Comprehensive Study On Polymer Processing Technology From A Systematic Innovation Perspective, Tyler A. Will

Master’s Theses

Solid-state shear pulverization (SSSP) is a continuous and scalable processing technique that imposes mechanochemical changes in polymer-based materials. It has been shown to impart beneficial properties onto homopolymers or create copolymers and composites through continuous fragmentation and fusion. The unique technology employs cold temperature to keep the polymer in the solid state. This thesis investigates industrial polymer processing in the context of real-world applications. This thesis analyzes SSSP using an organized methodology called systematic innovation (SI). SI facilitates problem solving by assisting engineers in conducting root cause analysis around a material and studying the physical setup of the equipment.

This …

Temperature-Dependent Diffusion In Block Copolymer Organogels, Ridwana Bashar

Master’s Theses

Organogels are often considered for transport-based applications such as transdermal drug delivery vehicles and gel actuators due to their unique properties. Recent consideration of styrenic block copolymer based organogels’ application in transdermal drug delivery requires an extensive investigation of drug diffusion behavior through these gels to assess their applicability. Temperature is a major influencing parameter on diffusion. The goal of this research is to better understand the impact of temperature on diffusion in styrenic triblock copolymer organogels. To accomplish this goal, we focused on three specific objectives: (i) accurately measure the diffusivities of a solute – AOT reverse micelles – …

An Updated Analytical Method For Predicting The Bracing Behavior Of Z-Purlin Supported Standing Seam Diaphragm Systems, Michael W. Seek

Engineering Technology Faculty Publications

Roof systems utilizing Z-purlins as a secondary member supporting a standing seam panel system are used extensively by the metal building industry. The Z-purlins rely on the diaphragm action in the standing seam panel system to provide lateral support and transfer forces to anchorages. The behavior of the standing seam system is highly nonlinear making prediction of the interaction between the Z-purlin and the standing seam system difficult. To better understand the behavior of the interaction between the purlins and the panel system, a series of non-linear shell finite element models were developed based on the test results of simple …

Cold-Formed Steel Strength Predictions For Combined Bending And Torsion, Yu Xia, Robert S. Glauz, Benjamin W. Schafer, Michael Seek, Hannah B. Blum

Engineering Technology Faculty Publications

Locally slender cross-section members, such as cold-formed steel Cee and Zee sections, are susceptible to significant twisting and high warping torsion stresses. Torsion considerations are complicated by whether it is derived as a first-order effect from loading or a second-order effect from instability. The current design for combined bending and torsion interaction has some limitations, including only considering the first yield in torsion and ignoring the cross-section slenderness in torsion. Previous work has derived a simple uniform equation to predict the bimoment capacity and two bimoment strength curves for local and distortional buckling under torsion only. This work is extended …

Recycling Metal Chips Into Usable Materials, Alex Mortensen, Ben Mortensen

Williams Honors College, Honors Research Projects

This report entails the scope, design considerations, and plans for creating a metal chip converter into metal briquettes. The construction is a set of machines with multiple processes to make the conversion happen. The process includes washing fine metal chips, drying them off, compressing them, and melting them down into usable briquettes. This project is intended to make a simple process to recycle metal chips into usable material for reuse. The project's objective is to reduce the costs of storage and recycling waste by offering a solution to recycle it into materials the shop can reuse.

Beeswax Wraps As An Alternative To Single-Use Plastics, Sarah Skiver

Williams Honors College, Honors Research Projects

The project goal was to compare the food storage efficacy of sustainable beeswax wraps verses the single-use plastic methods of resealable plastic sandwich bags and plastic cling wrap. The goal was also to test the reusability of the beeswax wraps, as it is a key advantage of beeswax wraps that is advertised. The project purpose was to explore sustainable and eco-friendly alternatives to single use plastics, which are harmful to the environment in both their production and their disposal. Food spoilage was compared in beeswax wrap, plastic sandwich bags, and plastic cling wrap, and spoilage was also observed in a …

Structural Design And Application Of Polymeric Silicon Elastomers, Jacob Wyant

Williams Honors College, Honors Research Projects

The purpose of this project was to determine how the polymeric structure and mechanical properties of this elastomer are affected by the ratio between the polydimethylsiloxane macromolecular chains and the crosslinkers. These were determined via tensile and compression testing. Then, spiropyran was added to observe how this fluorescence and crosslinking agent affected the elastomer. Also, the elastomer’s fluorescent and icephobic nature were tested. The elastomers with a higher ratio of crosslinker to macromolecular chain could withstand higher tensile and compressive strains but failed at lower stresses than their counterparts with lower concentrations of crosslinkers. The elastomers were also found to …

Intergranular And Pitting Corrosion Mechanisms Of Sensitized Aluminum Alloy Aa5083, Clayton Egleston

Williams Honors College, Honors Research Projects

The motivation and objectives of this project is to examine the mechanisms of intergranular corrosion (IGC) and pitting corrosion of sensitized AA5083. In this regard, different characterization techniques were used, including optical analysis of microstructure, cyclic potentiodynamic polarization with Tafel fitting, electrochemical impedance spectroscopy with electrical equivalent circuit (EEC) fitting, and potentiostatic current transient monitoring. The transition from IGC to pitting corrosion occurs when the grain boundaries become saturated with the β-phase (Mg₂Al₃). It was found that AA5083 becomes more vulnerable to pitting corrosion as the degree of sensitization increases.

Investigation Of Fiber Orientation And Mechanical Properties Of Pyrolysis Recycled Carbon-Fiber Reinforced Thermoset Composite, Reva N. Simmons, Harry Lee, Garam Kim

Discovery Undergraduate Interdisciplinary Research Internship

With increasing demand of carbon fiber reinforced fiber thermoset composites, establishing a sustainable cycle for these materials becomes crucial. Pyrolysis is a process of reclaiming carbon fiber from thermoset composites by thermally degrading the polymer at high temperatures allowing the fibers to be extracted. Carbon fiber reclaimed through current pyrolysis processes for thermoset composites typically loses its original shape and orientation, making it difficult to reorganize the fibers. This study investigated the feasibility of maintaining the fiber orientations for continuous fiber reinforced thermoset composite during pyrolysis by stitching the carbon fiber layup to a conformable copper mesh during the manufacturing …

Study Of Bounds For Effective Moduli Of Polycrystals And Composites Using Variational Principle For Probabilistic Measures, Md. Tofiqul Islam

Wayne State University Dissertations

Tensors that are invariant with respect to subgroups of 3D group of rotations were constructed first by Lokhin and Sedov (J. Appl. Math. Mech. (PMM), 1963, 27, 597-629). In this paper we do one more step and derive formulas for the elastic modulus tensors for all symmetry groups from the Lokhin-Sedov results. The tensor basis obtained in this way has an advantage of being built upon the same tensors that are used in construction of nonlinear tensor functions. One consequence of the formulas derived is that the number of types of anisotropic elastic behaviors is ten. There is a long- …

Dome Tester, Clark Bates, Nikolas M. Kulin

Williams Honors College, Honors Research Projects

We are reconfiguring and modifying the previously built dome tester to be more user friendly and mechanically applicable. This has a long-term goal of being a usable teaching tool for manufacturing education within the college of engineering and polymer sciences. The dome tester pushes a metal dome into a clamped sheet of metal to test its forming limits and where necking occurs. We have implemented a better method of viewing the sheet sample as it is being deformed, and improved measuring methods for the distance a sample is deformed. By introducing these changes in conjunction with improved documentation of the …

Wetting Transition Of Texturized Surfaces, Jenna Stephens

Williams Honors College, Honors Research Projects

Building on previous research, this project aims to continue the investigation of the wettability of various liquids on a uniform, texturized surface. Different surface energies can impact the wettability of a surface. The surface can be hydrophilic, hydrophobic, or in between. The goal of this project is to research how features of texturized surfaces affect the wetting transition of water, oil, and a mixture of both. Additionally, this project aims to improve the quality of the 3D printed surfaces. The surfaces that will be studied are constructed using UV cured resin 3D printing and are made up of an array …

Coolant Capability Study, Christina Grassi

Williams Honors College, Honors Research Projects

The scope of my project is a capability study on different coolants used in manufacturing plants. From this study, the coolant qualities and impact on the manufacturing process will be evaluated in that process and will be documented as a changed standard at the Timken company. Since coolants are sometimes the only fluid on the surface of the parts being manufactured, the rust preventative capabilities will also be studied and evaluated through humidity cabinet testing with and without spiking the coolant with chlorides and sulfates. This project will be carried out on my co-op rotation with the Timken company so …

Defining The Proper Operating Time For The Septa Extractor, Abigail Jones

Williams Honors College, Honors Research Projects

Anionic polymerizations are a common type of reaction used to produce synthetic rubber. During these reactions, it is necessary to charge initiators, modifiers, and other substances, through pressurized containers that are sealed with rubber septa. These septa prevent oxygen and moisture from entering the pressurized container, and the reactor, though they need to be cleaned before use to remove other impurities. Currently a glass Soxhlet Extractor is used to remove such impurities, and though effective, it has a limited capacity, so it has to run frequently. This limitation led to the commissioning of the Septa Extractor, which is an automated …

Anti-Freeze Double Network Hydrogels, William Gross

Williams Honors College, Honors Research Projects

Three polyethylene glycol (PEG) based crosslinkers with repeat unit nominal weights of 62.1, 200, and 400 g/mol in agar/PAM double network (DN) hydrogels were used to study the effect of different crosslinkers on thermal and mechanical properties. Using the one-pot synthesis method, hydrogels with the PEG crosslinkers or methylene-bis-acrylamide (MBAA) were made via sol-gel transition for formation of agar network, and photopolymerization of the PAM network using Irgacure 2959 as photo initiator. Tensile and compression tests were performed on as prepared, swollen, and swollen & cooled specimens of each hydrogel. Freezing time and thermal imaging were performed in -20 °C …

Hdd Dataset: Optimising Retrofitted Insulation For Irish Residential Building Walls, Rakshit D. Muddu, Aimee Byrne, Anthony James Robinson

Datasets

In this study, a thermal-economic analysis was conducted to determine the optimum insulation thickness of retrofitted insulation walls in different regions in Ireland. This was based on the Heating Degree Day method (HDD). This dataset contains optimum insulation thickness, payback period, cost savings and carbon emission for all 25 counties in the Republic of Ireland