Materials Science and Engineering Commons^™

Development Of Graphene Synthesis And Characterization Techniques Toward Cmos Applications And Beyond, Otto Kno Zietz

Dissertations and Theses

Graphene exhibits mechanical and electrical properties which, coupled with its two dimensional (2D) morphology, make it an attractive material component for inclusion in a wide range of industries. Since the discovery of graphene in 2004, industry adoption has been limited due to the demanding synthesis requirements for high quality and connected graphene as well as the difficulties associated with direct incorporation. Chemical vapor deposition (CVD) has emerged as the most cost efficient method for producing high quality graphene at scales suitable for mass production. However, the 1000°C temperatures and micrometer thick catalysts required for this process preclude direct inclusion in …

N-Type Charge Transport In Heavily P-Doped Polymers, Zhiming Liang, Hyun Ho Choi, Xuyi Luo, Tuo Liu, Ashkan Abtahi, Uma Shantini Ramasamy, J. Andrew Hitron, Kyle N. Baustert, Jacob L. Hempel, Alex M. Boehm, Armin Ansary, Douglas R. Strachan, Jianguo Mei, Chad Risko, Vitaly Podzorov, Kenneth R. Graham

Chemistry Faculty Publications

It is commonly assumed that charge-carrier transport in doped π-conjugated polymers is dominated by one type of charge carrier, either holes or electrons, as determined by the chemistry of the dopant. Here, through Seebeck coefficient and Hall effect measurements, we show that mobile electrons contribute substantially to charge-carrier transport in π-conjugated polymers that are heavily p-doped with strong electron acceptors. Specifically, the Seebeck coefficient of several p-doped polymers changes sign from positive to negative as the concentration of the oxidizing agents FeCl3 or NOBF4 increase, and Hall effect measurements for the same p-doped polymers reveal that …

Wetting And Brazing Of Yig Ceramics Using Ag–Cuo–Tio2 Metal Filler, Wanqi Zhao, Shuye Zhang, Jian Yang, Tiesong Lin, Dusan P. Sekulic, Peng He

Mechanical Engineering Faculty Publications

The wetting and brazing of Y₃Fe₅O₁₂ (YIG) ceramics with a Ag–8CuO–2TiO₂ filler was investigated for the first time. For comparison, the wettability of a Ag–10CuO filler on YIG ceramics was similarly investigated. The Ag–8CuO–2TiO₂ filler has an equilibrium contact angle of approximately 31 °C on the YIG substrate at 1000 °C; thus, its wettability is excellent. Moreover, its wettability exceeds that of Ag–10CuO. The microstructure and the interfacial structure between the filler and the substrate were determined using scanning electron microscopy, X-ray diffraction, EPMA and transmission electron microscopy. The liquid Ag–8CuO–2TiO₂ filler …

Quantifying Charge Transport In Chemically Doped Semiconducting Polymers, Shawn Gregory

Link Foundation Energy Fellowship Reports

This report is for the Link Foundation, which generously provided me a graduate research fellowship. In this report, I outline a segment of the organic electronics and organic thermoelectrics fields, then detail the contributions I have made, and finally conclude with a perspective on these fields. Subsequently, in accordance with the fellowship reporting requirements, I list all articles that I have published or will publish whose funding originated (in part) from the Link Foundation. Lastly, I share some personal notes on how this fellowship impacted my PhD experience and career.

Jcati Base Plate, Jacob Atamian

All Undergraduate Projects

Students of the Mechanical Engineering Technology (MET) program at Central Washington University have contributed to an ongoing Carbon Fiber Recycler project funded by the Joint Center for Aerospace Technology Innovation (JCATI). The goal of this project was to modify the existing recycling system to produce a higher success rate of recycled carbon composite material. This report focuses on increasing the rigidity of the crushing gears so that the deflection occurring among the components during operation was below 0.005 inches to ensure proper operating conditions. The operating speed of the crushing gears was 2.5 rpm with a crushing load of 10,500 …

Jcati Carbon Fiber Recycling Shredder, Benjamin Cooley

All Undergraduate Projects

Once carbon fibers are cast into a resin and used in a composite material, retrieving those fibers can be a difficult task. However, it is beneficial to recycle and reuse the fibers from old unneeded components rather than pay the cost of acquiring new ones. The Joint Center for Aerospace Technology Innovation (JCATI) carbon fiber recycling device condenses the multistep process of extracting the fibers by integrating all steps into one automated device. In the previous version of the device, the cutting blades turned the long composite strips into thin fingers but did not sever them across the width.

The …

Surface Acoustic Waves Increase Magnetic Domain Wall Velocity, Anil Adhikari, Shireen Adenwalla

Shireen Adenwalla Papers

Domain walls in magnetic thin films are being explored for memory applications and the speed at which they move has acquired increasing importance. Magnetic fields and currents have been shown to drive domain walls with speeds exceeding 500 m/s. We investigate another approach to increase domain wall velocities, using high frequency surface acoustic waves to create standing strain waves in a 3 micron wide strip of magnetic film with perpendicular anisotropy. Our measurements, at a resonant frequency of 248.8 MHz, indicate that domain wall velocities increase substantially, even at relatively low applied voltages. Our findings suggest that the strain wave …

Aps March Meeting 2021 (Online) Updates On Scientific Research During Pandemic Times, Vianney Gimenez-Pinto

Title III Professional Development Reports

While the ongoing global pandemic continues to affect our everyday lives, researchers in Science, Technology, Engineering and Math found a way to come together at the American Physical Society (APS) March Meeting 2021. The conference was online-only and had more than 11,000 registered attendants who actively participated in the program during March 14- 19, 2021.

Jcati Pyrolysis System, Jack Dutton

All Undergraduate Projects

The Joint Center for Aerospace Technology Innovation (JCATI) project is designed to recycle carbon fiber pieces for use in manufacturing. Part of the system requires the removal of resin from the carbon fibers to facilitate the recycling of carbon fiber. To accomplish this task the pyrolysis process is implemented using a commercial grade oven with a conveyor system. Argon gas is injected into the shroud and over the oven to purge the interior of oxygen. The conveyor system enables this to be a batch process. A ramp is used to allow simple addition of material to the conveyor system and …

Balsa Wood Bridge, Andrew Harris

All Undergraduate Projects

Faculty at Central Washington University proposed a challenge to mechanical engineering students that could be accomplished in an in-home setting. The goal was to create a balsa wood bridge, weighing no more than 85 grams, that can support a load over an open span and raise above its resting position by means of a mechanical system. To produce a successful solution to the problem, a vertical lift bridge was created consisting of two lifting towers and a load bearing bridge. Using equations of static equilibrium and strength of materials, the required width for each member was determined. Project requirements were …

Observation Of New Particle Formation In The Northern Hemisphere At Altitude From 4 To 20 Km, Mohamed Saad

Electronic Theses and Dissertations

New particle formation (NPF) is investigated using measurements of aerosol size distributions and meteorological variables made in two continents, including USA and Europe. Despite the considerably different aerosol particle abundances among the sites, a common relationship was found between the characteristics of NPF events and the air mass convective and/or advective transport. CO and O3 act as tracers of tropospheric and stratospheric air, respectively, their statistical relationship can be used to quantify air mass characteristics and origins. The mixing ratio values of CO increased within the upper troposphere layer before/during NPF events, which may serve as an indicator of occurring …

Mini Rc Baja Car, Jason Schindler

All Undergraduate Projects

Incorporating each aspect of engineering incorporated into a senior project is difficult. That is why an RC Baja car is a great senior project for Mechanical Engineering students. The approach that students must take to design, construct, and test the car is to set parameters, and to make overall goals that can be easily measured. These goals include, but not limited to things like a $700 budget and the ability to withstand a 1-foot drop to a flat surface on all four wheels simultaneously. First, the design must meet the specifications and rules that are set previously. This ensures that …

Big Data Analysis Of Nanoscience Bibliometrics, Patent, And Funding Data (2000-2019), Yuliang Zhao, Zhixiang Wei, Qing Dai, Hongwei Dong, Hongjun Xiao, Shuxian Wu, Xingxing He, Beverley Mitchell, Thomas A. Collins, Sarah Huggett, John Van Orden, Christiane Barranguet, Basak Candemir

Public Reports

Given the strategic significance of Nanoscience and nanotechnology, it is essential to evaluate and predict its developmental trends. This report is based on the largest abstract and citation database of peer-reviewed literature, Elsevier's Scopus, along with the research evaluation platform SciVal. The funding and patent analysis data for the report is from Funding Institutional and PatentSight, respectively. This report provides an evaluation of Nanoscience's scientific output, role, contribution, and impact through bibliometric analysis, combined with big data indicators of Nanoscience scientific results and patents from 2000 to 2019.

Optimisation Of Retrofit Wall Insulation: An Irish Case Study, Rakshit D. Muddu, D M. Gowda, Anthony James Robinson, Aimee Byrne

Articles

Ireland has one of the highest rates of emissions per capita in the world and its residential sector is responsible for approximately 10% of total national CO2 emissions. Therefore, reducing the CO2 emissions in this sector will play a decisive role in achieving EU targets of reducing emissions by 40% by 2030. To better inform decisions regarding retrofit of the existing building stock, this study proposes Optimum Insulation Thicknesses (OIT) for typical walls in 25 regions in Ireland. The calculation of OIT includes annual heat energy expenditure, CO2 emissions, and material payback period. The approach taken is based on Heating …

Recycling Of Fiber Polymer Matrix Composites In Cementitious Materials, Edward Patton Clark

Electronic Theses and Dissertations

Recycling options for fiber polymer matrix composite waste materials are limited because they typically cannot be reused, reprocessed for down-cycling, and are generally environmentally unfriendly. The utility industry, specifically electrical distribution, has been increasingly using hybrid carbon, glass fiber, and epoxy resin composite rods for high-voltage (HV) conductor transmission lines. The high-voltage conductor core (HVCC) used in the transmission line can have an optimal in-service-life of roughly several decades, in which the material is then retired to a waste landfill. Currently, there is limited research and recycling methodology for these hybrid composite rods. In this research, powder carbon fiber, glass …

Effects Of Resin Chemistries On The Selective Removal Of Industrially Relevant Metal Ions Using Wafer-Enhanced Electrodeionization, Humeyra B. Ulusoy Erol, Christa N. Hestekin, Jamie A. Hestekin

Chemical Engineering Faculty Publications and Presentations

Wafer-enhanced electrodeionization (WE-EDI) is an electrically driven separations technology that occurs under the influence of an applied electric field and heavily depends on ion exchange resin chemistry. Unlike filtration processes, WE-EDI can be used to selectively remove ions even from high concentration systems. Because every excess ion transported increases the operating costs, the selective separation offered by WE-EDI can provide a more energy-efficient and cost-effective process, especially for highly concentrated salt solutions. This work reports the performance comparison of four commonly used cation exchange resins (Amberlite IR120 Na⁺, Amberlite IRP 69, Dowex MAC 3 H⁺, and …

Real-Time Voluntary Motion Prediction And Parkinson's Tremor Reduction Using Deep Neural Networks, Anas Ibrahim, Yue Zhou, Mary E. Jenkins, Ana Luisa Trejos, Michael D. Naish

Mechanical and Materials Engineering Publications

Wearable tremor suppression devices (WTSD) have been considered as a viable solution to manage parkinsonian tremor. WTSDs showed their ability to improve the quality of life of individuals suffering from parkinsonian tremor, by helping them to perform activities of daily living (ADL). Since parkinsonian tremor has been shown to be nonstationary, nonlinear, and stochastic in nature, the performance of the tremor models used by WTSDs is affected by their inability to adapt to the nonlinear behaviour of tremor. Another drawback that the models have is their limitation to estimate or predict one step ahead, which introduces delay when used in …

Inventions Of Scientists, Engineers And Specialists From Different Countries In The Area Of Nanotechnologies. Part Ii, Leonid A. Ivanov, Li Da Xu, Zhanna V. Pisarenko, Qiang Wang, Petr S. Prokopiev

Information Technology & Decision Sciences Faculty Publications

The article provides an abstract review of patents. The results of creative activity of scientists, engineers and specialists, including inventions in the field of nanotechnology and nanomaterials, being implemented, allow achieving a significant effect in construction, housing and community services, and related sectors of the economy. For example, the invention «Method for liquidphase synthesis of nanostructured ceramic material in the CeO2–Sm2O3 system to create a solid oxide fuel cell» can contribute to the active development of alternative, hydrogen energy. Fuel cells have a wide range of applications – from batteries in portable electronic devices to large-scale power generation and autonomous …

Material Analysis Of 3d Welded 5356 Aluminum Alloy, Ryan Fouts

Electronic Theses and Dissertations

Metal 3D printing has been reserved for aerospace and high-end automotive industries because of its cost. A gas metal arc welder (GMAW) on a rugged 3D printer frame could make metal additive manufacturing an option for more industries and consumers. 3D welded aluminum has not been examined in depth as an option for additive manufacturing (AM). Extensive tests are necessary to determine the correct settings to use a metal inert gas (MIG) welder for AM. Porosity within the welded material must be evaluated to better understand the additive process. The material properties of 3D welded aluminum will be tested and …

Monitoring Of Overhead Polymer Core Composite Conductors Under Excessive Mechanical Loads Using Fiber Bragg Grating Sensors, Daniel H. Waters

Electronic Theses and Dissertations

This combined experimental and numerical study addresses mechanical effects associated with static and dynamic loading of novel High Temperature Low Sag (HTLS) transmission line polymer core composite conductors. The developed methodology was successfully applied to ACCC® to explain the complex failure mechanisms associated with combined bending and tension loading. Furthermore, the use of Fiber Bragg Grating (FBG) sensors was investigated for the first time to monitor the ACCC® design during installation and in-service.

Transverse low-velocity impacts to the ACCC® conductor having either free or constrained end conditions and large axial tensile loads were performed. It was identified that the most …

Hydraulic Balsa Wood Rising Bridge, Kaitlyn Greenfield

All Undergraduate Projects

What is the solution to allowing tall vessels to navigate past a vehicle bridge that is less than 10 [ft] above the water? To answer this question, a balsa wood bridge was designed, constructed, and tested. The bridge needed to articulate by mechanical means, allow for travel through the bridge, and be able to withstand ample force while the main structure only being constructed of balsa wood and glue. The project was analyzed in sections. These sections include: the bridge structure and its members, the hydraulic lift, and the pins needed for the bridge and hydraulic lift to operate. The …

Molecular To Macroscopic Understanding Of Chloroaluminate Anion Intercalation In Rechargeable Aluminum-Graphite Batteries, Jeffrey Xu

Dissertations and Theses

Today’s global energy challenges pose an urgent need to electrify transportation and better store intermittent renewable energy sources (e.g., solar and wind energy). For such large-scale battery applications, aluminum batteries are a promising “beyond lithium-ion” technology due to the high volumetric capacity, earth abundance, low-cost, and inherent safety of aluminum metal. However, there are very few compatible positive electrode materials that exhibit high energy density and cycling stability, in part due to the challenges of electrochemically intercalating highly charged Al³⁺ cations. Recently, graphite has been demonstrated as a promising positive electrode material in non-aqueous rechargeable aluminum batteries, which store …

Development Of Light Actuated Chemical Delivery Platform On A 2-D Array Of Micropore Structure, Hojjat Rostami Azmand, Hojjat Rostami Azmand

Dissertations and Theses

Localized chemical delivery plays an essential role in the fundamental information transfers within biological systems. Thus, the ability to mimic the natural chemical signal modulation would provide significant contributions to understand the functional signaling pathway of biological cells and develop new prosthetic devices for neurological disorders. In this paper, we demonstrate a light-controlled hydrogel platform that can be used for localized chemical delivery in a high spatial resolution. By utilizing the photothermal behavior of graphene-hydrogel composites confined within micron-sized fluidic channels, patterned light illumination creates the parallel and independent actuation of chemical release in a group of fluidic ports. The …

Atomic-Scale Simulation Of Dissipation And Adhesion During Interactions Between Mineral Surfaces, Baochi Doan

Electronic Theses and Dissertations, 2020-2023

Adhesion and dissipation during surface interactions are important phenomena with wide applications in materials science, including cold-spray technology for additive manufacturing and stiction in MEMS (Mircro ElectroMechanical Systems). In planet formation theories, energy dissipation in collisions between mineral grains is important to the formation of dust-grain aggregates and planetesimals. Early contact mechanics theories such as Hertz and Johnson-Kendall-Roberts have laid theoretical foundations for understanding these phenomena. Recently, there are breakthroughs in using non-equilibrium thermodynamics methods to elucidate dissipation. For example, the Green-Kubo method can calculate transport coefficients based on the Fluctuation-Dissipation theorem, and Jarzynski equality can be used to determine …

Processing Of 3d Porous Biomaterial Scaffolds To Enhance The In Vitro Breast Cancer Tumor Microenvironment, Zi Wang

Electronic Theses and Dissertations, 2020-2023

Tumors contain heterogeneous cell populations within the tumor microenvironment (TME). TME supports tumor progression and development via the function of multiple cell types and cell-extracellular matrix (ECM) interactions. 3D porous biomaterial scaffolds can be a type of in vitro tumor models to mimic TME ECM. Current tumor models lack structural complexity replicating tumor ECM, tunable mechanical properties, and have limited mass exchange between cells and their microenvironment. In this work, we firstly developed scaffolds with a hierarchical pore structure via the Freeze-FRESH(FF) fabrication technique that combines 3D printing and freeze-casting. Later, we studied the effect of varying processing parameters and …

Microstructural Development Of Inconel 625 Nickel-Based Superalloy As Function Of Laser Powder Bed Fusion Parameters, Sofia Nucci

Electronic Theses and Dissertations, 2020-2023

Additive manufacturing (AM) allows fabrication of complex components with features that are impractical or impossible to achieve through conventional methods. Selective laser melting (SLM) powder bed fusion AM technology was selected for this study on Inconel 625, a widely utilized high-temperature alloy that is hard to machine. The present work investigates impact of laser power and scanning speed variations on the resulting characteristics of fabricated IN625 samples. Gas atomized metallic alloy powders were acquired and analyzed through laser diffraction to verify acceptable size distribution. Cubic samples were built with a range of laser scan speeds in 200 mm/s intervals for …

Lightning Strike Response Of Composite Structures: A Review, Akhileshwar Pandey, Ashutosh Kumar Upadhyay, Karunesh Kumar Shukla

Journal of Metals, Materials and Minerals

Wind turbines and aircraft are generally made of less conductive carbon/glass composites. Significant damages may occur to these materials if they are struck by high energy lightning strikes. Damage and structural response of composites is essentially a multiphysics domain, involving thermal, electrical, magnetic and structural analysis. In this article, the fundamental physics of lightning, multiphysics analysis, numerical implementation and experimental studies about composite materials are reviewed. The relevant international standards and possible characterization methods of lightning strike damage are also reproduced in this article. In addition to this, the current and prospective technologies, to protect composite from lightning strikes are …

Wear Behavior Of Aluminium 6061 Alloy Reinforced With Coated/Uncoated Multiwalled Carbon Nanotube And Graphene, Vijee Kumar, Kempaiah Ujjaini Nagegowda, Satish Babu Boppana, Ramesh Sengottuvelu, Palanikumar Kayaroganam

Journal of Metals, Materials and Minerals

The current study deals with the fabrication and investigation of wear characteristics of Aluminium 6061(Al6061) hybrid metal matrix composites (MMCs) processed through powder metallurgy technique. Al6061 hybrid MMCs involving fixed 2 wt% of coated/uncoated multiwalled carbon nanotubes (MWCNTs) and varying weight percentages of graphene were fabricated through ball milling procedure. To enhance the scattering of MWCNTs in the matrix, MWCNTs were coated by means of copper through electroless deposition method. Dry sliding wear conduct of Al6061 MMCs was investigated using a pin-on-disc wear testing machine. It was found that at lower load, composites exhibited lower wear resistance than base alloy …

Improvement On Cost-Performance Ratio Of Fiberglass/Carbon Fiber Hybrid Composite, Nathawat Poopakdee, Warut Thammawichai

Journal of Metals, Materials and Minerals

Fiberglass composite (FG) is widely used as a metal substitute in general applications due to its corrosion and chemical resistance, relatively high strength, and low cost. Still, the FG is deficient in performance and relatively heavy for airframes. Carbon fiber composite (CF) is utilized instead as it has greater performance and lower weight. However, the CF is brittle and expensive. Thus, in this work, we combine FG and CF into two types of hybrid composites to achieve a cost-effective solution with greater or comparable mechanical properties to those of CF. The first one uses FG as core and CF as …

Efficiency Of Tri-N-Octylamine For The Liquid-Liquid Extraction Of Co (Ii) From Acidic Chloride Medium, Aishwarya Mishra, Nilam Swain, Sanghamitra Pradhan, Sujata Mishra

Journal of Metals, Materials and Minerals

Cobalt criticality is increasing as a function of time and this concern has impelled researchers to ascertain efficient recovery schemes of cobalt. In this paper, an extraction strategy for cobalt utilizing tri-n-octyl amine (TOA) in kerosene from acidic chloride media has been developed. The extraction percentage was found to be 76.7 using 1.5M TOA. The extracted species has been formulated as (R3NH) CoCl3 based on the findings of slope analysis. Influence of various salting out agents like NH4Cl, KCl, and NaCl on the percentage extraction has been analysed and KCl emerged as beneficial for extraction. The estimated values of enthalpy …