Materials Science and Engineering Commons^™

Detection And Prediction Of Defects In Composite Materials Using Di-Electric Characterization And Neural Networks, Muthu Ram Prabhu Elenchezhian, Aishwarya Nandini, Vamsee Vadlamudi, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

The state of art non-destructive inspection techniques for composite materials detect the presence of defects in the composite material, but they do not identify what type of defect it is, and hence, further visual inspection of the details are needed. This visual classification is a costly and time-consuming process, and it’s difficult to distinguish all of the defects effectively. Broadband Dielectric Spectroscopy (BbDS), has been an established tool for dielectric material characterization in polymer industries for a long time. Dielectric spectra of heterogeneous materials are altered by constituent interfaces, with changes in morphological heterogeneity, electrical and structural interactions between particles, …

The Natural Aging Effect On Hardenability In Al-Mg-Si: A Complex Interaction Between Composition And Heat Treatment Parameters, Alex Poznak, Violet Thole, Paul G. Sanders

Michigan Tech Publications, Part 1

The technological relevance of Al-Mg-Si alloys has been rapidly growing over the last decade. Of particular interest to current and future applications is the problematic negative effect of prior natural aging on subsequent artificial age hardening. The influence of natural aging is dependent on both processing and compositional variables and has origins that are far from well-understood. This work examines the hardenability of 6000 series alloys under a wide range of conditions, paying particular attention to the natural aging effect. Experimental variables include alloy composition (Mg + Si, Mg/Si), cooling rate after solutionization, and duration of prior natural aging. Hardenability …

Peridynamic Modeling Of Dynamic Fracture In Bio-Inspired Structures For High Velocity Impacts, Sneha Akula

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Bio-inspired damage resistant models have distinct patterns like brick-mortar, Voronoi, helicoidal etc., which show exceptional damage mitigation against high-velocity impacts. These unique patterns increase damage resistance (in some cases up to 3000 times more than the constituent materials) by effectively dispersing the stress waves produced by the impact. Ability to mimic these structures on a larger scale can be ground-breaking and could be used in numerous applications. Advancements in 3D printing have now made possible fabrication of these patterns with ease and at a low cost. Research on dynamic fracture in bio-inspired structures is very limited but it is …

Design, Fabrication, And Characterization Of All-Inorganic Quantum Dot Light Emitting Diodes, Ramesh Vasan

Graduate Theses and Dissertations

Quantum dot light emitting diodes are investigated as a replacement to the existing organic light emitting diodes that are commonly used for thin film lighting and display applications. In this, all-inorganic quantum dot light emitting diodes with inorganic quantum dot emissive layer and inorganic charge transport layers are designed, fabricated, and characterized. Inorganic materials are more environmentally stable and can handle higher current densities than organic materials. The device consists of CdSe/ZnS alloyed core/shell quantum dots as the emissive layer and metal oxide charge transport layer. The charge transport in these devices is found to occur through resonant energy transfer …

Glucose Level Estimation Based On Invasive Electrochemical, And Non-Invasive Optical Sensing Methods, Sanghamitra Mandal

Graduate Theses and Dissertations

The purpose of this research is to design and fabricate sensors for glucose detection using inexpensive approaches. My first research approach is the fabrication of an amperometric electrochemical glucose sensor, by exploiting the optical properties of semiconductors and structural properties of nanostructures, to enhance the sensor sensitivity and response time. Enzymatic electrochemical sensors are fabricated using two different mechanisms: (1) the low-temperature hydrothermal synthesis of zinc oxide nanorods, and (2) the rapid metal-assisted chemical etching of silicon (Si) to synthesize Si nanowires. The concept of gold nano-electrode ensembles is then employed to the sensors in order to boost the current …

Fabrication And Characterization Of Graphene Based 2d Materials For Supercapacitors, Anishkumar Manoharan

Graduate Theses and Dissertations

Supercapacitors have attracted a lot attention due to their efficient energy storage. In comparison to batteries, supercapacitors have high capacitance, energy, and power densities per unit mass than conventional capacitors. Carbon based materials are most promising in supercapacitor application due to their outstanding physical and electrochemical behavior. In this work, a facile method to synthesize a nanocomposite electrode consisting of annealed carbon from carbon ink and MoS2 was demonstrated. Effects of various aqueous and solid electrolytes were studied. It was found that the nanocomposite electrode with 10% MoS2 and 1M Na2SO4 as the aqueous electrolyte tested using the three electrode …

Understanding The Evolution Of Surface Texture Under Boundary Lubrication, Salil T. Bapat

Graduate Theses and Dissertations

The objective of this research was to understand the evolution of surface texture under boundary/mixed lubrication (BL). Significant material/energy losses occur during BL because of direct contact between the two surfaces. Traditionally, tribofilms have been studied extensively for BL while textures have been used as a static engineering design parameter to enhance lubricant film properties. However, texture is dynamic at the tribological mating interface, where both physical and chemical interactions are continuously modulated. The evolution and the interplay between the tribofilm and texture is least studied in the literature, which is the focus of this research.

MoS2-based lubricants, known for …

Magnetic Studies Of Multiferroic Heterostructures, Ahmed Rayhan Mahbub

Graduate Theses/Dissertations

Multiferroic heterostructures (MHS) consisting of at least two materials with ferroic properties have been a major focus for researchers recently due to its immense potential in device applications. Almost all MHS use ferromagnetic layers making it a very important research area. In this thesis the magnetic properties of different ferromagnetic heterostructures have been investigated. Different bilayers of hard ferromagnet cobalt ferrite (CFO)-soft ferromagnet lanthanum strontium manganese oxide (LSMO) and hard ferromagnet CFO-antiferromagnet nickel oxide (NiO) were fabricated. Pulsed laser deposition technique was used to deposit the thin films on LAO and sapphire substrates. Purpose of using a hard ferromagnetic CFO …

Dielectric Property Investigation Of Degraded Pre-Preg And Performance Prediction Of The Final Composite Part, Aishwarya Nandini, Nina Shute, Muthu Ram Prabhu Elenchezhian, Vamsee Vadlamudi, Rassel Raihan, Kenneth Reifsnider

Institute of Predictive Performance Methodologies (IPPM-UTARI)-Archive

In recent years, fiber-reinforced (i.e., Glass, Carbon, Kevlar) epoxy composites are used widely in structural applications ranging from military and civil aircraft production to recreational consumer products. Most of the industries use pre-impregnated varieties of composite (prepregs) to make high-quality composite parts. Despite their various advantages, prepreg materials are unstable at ambient temperature. A realistic estimation of the shelf life of prepreg is therefore essential for maintaining quality while reducing wastage of resources. Prepregs are temperature and moisture sensitive material systems. To achieve prolonged shelf life, manufacturer and seller of the prepreg must store the materials at zero degrees Celsius …

Design, Fabrication, And Characterization Of Novel Optoelectronic Devices For Near-Infrared Detection, Ahmad Nusir

Graduate Theses and Dissertations

Investigating semiconductor materials and devices at the nanoscale has become crucial in order to maintain the exponential development in today’s technology. There is a critical need for making devices lower in power consumption and smaller in size. Nanoscale semiconductor materials provide a powerful platform for optoelectronic device engineers. They own interesting properties which include enhanced photoconductivity and size-tunable interband transitions.

In this research, different types of nanostructures were investigated for optoelectronic devices: nanocrystals, nanowires, and thin-films. First, lead selenide nanocrystals with narrow bandgap were synthesized, size-tailored, and functionalized with molecular ligands for the application of uncooled near-infrared photodetectors. The devices …

Optically Active Dye-Based Systems Templated By Dna Exhibiting Excitonic Delocalization, Brittany Lynn Cannon

Boise State University Theses and Dissertations

The concept of quantum computing was first developed in the early 1980’s. The attraction of quantum computers is their potential capacity to solve extremely complex problems, such as factorization, on a timescale far faster than that of classical computers. However, realization of quantum computation is currently in its infancy, and recent implementations possess serious drawbacks that reduce their appeal. Some challenges of current designs include the necessity to cool the systems using liquid helium to near absolute zero temperatures (15 mK) in order to maintain sufficiently long-lifetimes of the Qbits (i.e., unit of quantum information), difficulty with scaling up the …

Osteoprogenitor Cell Adhesion And Growth On The Bioactive Silicon Nitride Surface For Craniofacial Implants Applications, Kamal Awad

Material Science and Engineering Theses - Archive

As a novel biomaterial, silicon nitride (Si3N4) has been used for orthopedic and spinal fusion applications. Its ability to promote continuity for structural support of missing bone, by in/on bone growth, gives it advantageous properties and potential for mandibular and craniofacial reconstruction applications. Yet, the surface properties of this material and its effect on the osteogenic properties have not been fully realized. Thus, the aim of this study was to evidently investigate the surface properties of the bioactive Si3N4 that enhance the calvarial osteoblasts cell adhesion, growth, and differentiation when compared to conventional implant materials such as titanium (Ti) and …

Nature Inspired Technology: A New Process For Silicification Based On Marine Sponges, Ami Atul Shah

Material Science and Engineering Dissertations - Archive

Silica is used in various industries, ranging from automobile industry for tires to semiconductor industry, paints and coatings, biomedical devices & applications to food & drug industry. The current processing techniques for precipitated silica involve harsh conditions like high temperature and extreme pH conditions. Nature already has highly evolved production techniques for silica. They run at physiological conditions and exhibit intricate control over the synthesis, leading to very pure and ornate siliceous structures. These structures exhibit organized architecture at scales as small as nano-dimensions. The proposed research work is a step, towards development of new techniques that bio-mimic the silica …

Investigation Of The Processing-Structure-Property Relationship In Ta-Si-N Nanocomposite Coatings, Anna Zaman

Material Science and Engineering Dissertations - Archive

The present-day industry demands development of coatings for harsh environmental applications which can resist impact and oxidation at high temperatures. It is vitally important to develop new hard (>30 GPa) protective coatings which will be thermally stable at temperatures, T > 800 °C and simultaneously will ensure a good protection of the substrate against oxidation from an external atmosphere. The limitations of conventional coatings due to inferior hardness or poor oxidation stability can be overcome by nanocomposite coatings as they exhibit enhanced and completely new properties. To address this requirement of new enhanced protective systems, there is a need to …

Polymer Nanocomposites Containing High Aspect Ratio Particulates: Innovation In Co-Extruded Multilayer Barrier Films, Kevin Meyers

Dissertations

Delaminated montmorillonite (MMT) clay/ maleic anhydride grafted LLDPE nanocomposite multilayer films with alternating layers of LDPE were produced through multilayer co-extrusion. The MMT concentration within the nanocomposite layers was increased through annealing the films in the melt due to a mismatch in interdiffusion rates of the polymer layers. Analysis of the nanocomposite layers upon annealing revealed that the platelets impinged upon one another resulting in significant improvement in oxygen barrier in the multilayer system, exceeding the results of bulk nanocomposites.

Model analysis demonstrated that increasing the nanoplatelet aspect ratio or initial concentration in the filled layers would lead to even …

Antimicrobial Materials Via Thiol-Ene Chemistry, Dahlia Amato

Dissertations

With the increasing prevalence of antimicrobial resistance, the escalation of opportunistic/pathogenic infections is a looming global crisis. To avoid the pitfalls of conventional antibiotics, this dissertation focuses on developing macromolecular solutions to develop novel antimicrobial materials based on essential oils (thymol, carvacrol, and aldehydes). It is well established that essential oil derivatives exhibit high potency towards a wide range of pathogenic microbes. The rapid photopolymerization kinetics, limited by-products, and homogeneous network formation afforded by thiol-ene photopolymerization are utilized to either encapsulate essential oil derivatives or convert them into monomers which can subsequently be incorporated into new antimicrobial materials with new …

Molybdenum Sulfide Prepared By Atomic Layer Deposition: Synthesis And Characterization, Steven Payonk Letourneau

Boise State University Theses and Dissertations

Molybdenum disulfide (MoS₂) is the prototypical two-dimensional (2D) semiconductor. Like graphite, it has a layered structure containing weak van der Waals bonding between layers, while exhibiting strong covalent bonding within layers. The weak secondary bonding allows for isolation of these 2D materials to single layers, like graphene. While bulk MoS₂ is an indirect band gap semiconductor with a band gap of ~1.3 eV, monolayer MoS₂ exhibits a direct band gap of ~1.8 eV, which is an attractive property for many opto-electronic applications. Atomic layer deposition (ALD) has been used to grow amorphous films of MoS_{2 …}

Highly Flame Retardant And Bio-Based Rigid Polyurethane Foams Derived From Orange Peel Oil, Chunyang Zhang

Electronic Theses & Dissertations

Polyurethane is an important class of polymer which is being used for various industrial applications in the form of rigid foams, flexible foams, thermoplastic, elastomer, coating, and adhesive. Especially there is a huge market for rigid polyurethane foams for their applications as thermal insulating material in building and housing. In general, polyurethanes are prepared using polyols and diisocyanates. Most of the polyols used by industries are petrochemical based. In this project, a novel polyol from an orange peel oil-based derivative, limonene dimercaptan, was synthesized using one step photochemical thiol-ene reaction. The synthesized polyol was used to prepare flame retardant polyurethane …

Self-Assembly Of (111)-Oriented Tensile-Strained Quantum Dots By Molecular Beam Epitaxy, Christopher F. Schuck, Robin A. Mccown, Ashlie Hush, Austin Mello, Simon Roy, Joseph W. Spinuzzi, Paul J. Simmonds

Materials Science and Engineering Faculty Publications and Presentations

The authors report on a comprehensive study of the growth of coherently strained GaAs quantum dots (QDs) on (111) surfaces via the Stranski–Krastanov (SK) self-assembly mechanism. Recent reports indicate that the long-standing challenges, whereby the SK growth mechanism could not be used to synthesize QDs on (111) surfaces, or QDs under tensile strain, have been overcome. However, a systematic study of the SK growth of (111)-oriented, tensile-strained QDs (TSQDs) as a function of molecular beam epitaxy growth parameters is still needed. Here, the authors explore the effects of deposition amount, substrate temperature, growth rate, and V/III flux ratio on the …

Routine Million-Particle Simulations Of Epoxy Curing With Dissipative Particle Dynamics, Stephen Thomas, Monet Alberts, Michael M. Henry, Carla E. Estridge, Eric Jankowski

Materials Science and Engineering Faculty Publications and Presentations

Mesoscale simulation techniques have helped to bridge the length scales and time scales needed to predict the microstructures of cured epoxies, but gaps in computational cost and experimental relevance have limited their impact. In this work, we develop an open-source plugin epoxpy for HOOMD-Blue that enables epoxy crosslinking simulations of millions of particles to be routinely performed on a single modern graphics card. We demonstrate the first implementation of custom temperature-time curing profiles with dissipative particle dynamics and show that reaction kinetics depend sensitively on the stochastic bonding rates. We provide guidelines for modeling first-order reaction dynamics in a classic …

Surface Area And Electrocatalytic Properties Of Feni Nanoparticles For The Oxygen Evolution Reaction (Oer), James Burrow

Chemical Engineering Undergraduate Honors Theses

Iron-nickel bimetallic electrocatalysts have recently emerged as some of the best candidates for the oxygen evolution reaction (OER) in alkaline electrolyte. Understanding the effects of composition and morphology of iron-nickel nanoparticles is crucial for optimization and enhanced electrocatalyst performance. Both physical surface area and electrochemical surface area (ECSA) are functions of morphology. In this study, four different iron-nickel nanoparticle catalysts were synthesized. The catalysts were varied based on morphology (alloy versus core-shell) and composition (low, medium, and high stabilizer concentration). Brunauer-Emmett-Teller (BET) surface area analysis was conducted on three of the synthesized iron-nickel nanoparticles using a physisorption analyzer while electrochemical …

Ultrasonic Nondestructive Evaluation Of Metal Additive Manufacturing., Venkata Karthik Nadimpalli

Electronic Theses and Dissertations

Metal Additive Manufacturing (AM) is increasingly being used to make functional components. One of the barriers for AM components to become mainstream is the difficulty to certify them. AM components can have widely different properties based on process parameters. Improving an AM processes requires an understanding of process-structure-property correlations, which can be gathered in-situ and post-process through nondestructive and destructive methods. In this study, two metal AM processes were studied, the first is Ultrasonic Additive Manufacturing (UAM) and the second is Laser Powder Bed Fusion (L-PBF). The typical problems with UAM components are inter-layer and inter-track defects. To improve the …

Elucidating The Effect Of Water-To-Cement Ratio On The Hydration Mechanisms Of Cement, Aida Margarita Ley-Hernandez, Jonathan Lapeyre, Rachel Cook, Aditya Kumar, Dimitri Feys

Materials Science and Engineering Faculty Research & Creative Works

The hydration of cement is often modeled as a phase boundary nucleation and growth (pBNG) process. Classical pBNG models, based on the use of isotropic and constant growth rate of the main hydrate, that is, calcium-silicate-hydrate (C-S-H), are unable to explain the lack of any significant effect of the water-to-cement (w/c) ratio on the hydration kinetics of cement. This paper presents a modified form of the pBNG model, in which the anisotropic growth of C-S-H is allowed to vary in relation to the nonlinear evolution of its supersaturation in solution. Results show that once the supercritical C-S-H nuclei form, their …

Corrosion Resistance Of Pipeline Steel With Damaged Enamel Coating And Cathodic Protection, Liang Fan, Signo Tadeu Dos Reis, Genda Chen, Michael L. Koenigstein

Materials Science and Engineering Faculty Research & Creative Works

This paper presents the first report on the corrosion resistance of pipeline steel with damaged enamel coating and cathodic protection in 3.5 wt % NaCl solution. In particular, dual cells are set up to separate the solution in contact with the damaged and intact enamel coating areas, to produce a local corrosion resistance measurement for the first time. Enamel-coated steel samples, with two levels of cathodic protection, are tested to investigate their impedance by electrochemical impedance spectroscopy (EIS) and their cathodic current demand by a potentiostatic test. Due to its glass transition temperature, the enamel-coated pipeline can be operated on …

Real-Time Object Detection And Tracking On Drones, Tu Le

Maseeh Summer Undergraduate Research Experience

Unmanned aerial vehicles, also known as drones, have been more and more widely used in recent decades because of their mobility. They appear in many applications such as farming, search and rescue, entertainment, military, and so on. Such high demands for drones lead to the need of developments in drone technologies. Next generations of commercial and military drones are expected to be aware of surrounding objects while flying autonomously in different terrains and conditions. One of the biggest challenges to drone automation is the ability to detect and track objects of interest in real-time. While there are many robust machine …

Characterization And Analysis Of Ultrathin Cigs Films And Solar Cells Deposited By 3-Stage Process, Grace Rajan, Krishna Aryal, Shankar Karki, Puruswottam Aryal, Robert W. Collins, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

In view of the large-scale utilization of Cu(In,Ga)Se₂ (CIGS) solar cells for photovoltaic application, it is of interest not only to enhance the conversion efficiency but also to reduce the thickness of the CIGS absorber layer in order to reduce the cost and improve the solar cell manufacturing throughput. In situ and real-time spectroscopic ellipsometry (RTSE) has been used conjointly with ex situ characterizations to understand the properties of ultrathin CIGS films. This enables monitoring the growth process, analyzing the optical properties of the CIGS films during deposition, and extracting composition, film thickness, grain size, and surface roughness which …

Critical-Point Model Dielectric Function Analysis Of Wo3 Thin Films Deposited By Atomic Layer Deposition Techniques, Ufuk Kılıç, Derek Sekora, Alyssa Mock, Rafał Korlacki, Elena M. Echeverría, Natale J. Ianno, Eva Schubert, Mathias Schubert

Department of Electrical and Computer Engineering: Faculty Publications

WO₃ thin films were grown by atomic layer deposition and spectroscopic ellipsometry data gathered in the photon energy range of 0.72-8.5 eV and from multiple samples was utilized to determine the frequency dependent complex-valued isotropic dielectric function for WO₃. We employ a critical-point model dielectric function analysis and determine a parameterized set of oscillators and compare the observed critical-point contributions with the vertical transition energy distribution found within the band structure of WO₃ calculated by density functional theory. We investigate surface roughness with atomic force microscopy and compare to ellipsometric determined effective roughness layer thickness.

Reactive Lamination Of Perovskite Solar Cells., Lyndie Burns

Electronic Theses and Dissertations

Due to the growing demand for energy internationally and the environmental impact of other conventional energy technologies, solar power has been a growing area in the energy landscape. Perovskite research has increased substantially because of the high power conversion efficiencies, up to 22%, with many recent advances in the use of these organic-inorganic hybrid perovskites for photovoltaic cells. However, to bring perovskite solar cells into the industrial world, the overall cost of the manufacturing of the solar cell must be improved to compete with other well-developed photovoltaic technologies. Here is presented an alternative perovskite deposition method for methylammonium lead halide …

Investigation Of Nanomaterial Based Photovoltaic Panel Packaging Materials, Xingeng Yang

Graduate Theses and Dissertations

In this research, nanomaterial-based packaging materials for photovoltaic (PV) panels are investigated. A hydrophobic/anti-reflective surface coating which not only repels water from the top glass of a PV panel but at the same time reduces its light reflectance is investigated. COMSOL simulation results indicate that taller ellipsoid rod (aspect ratio = 5) reflects less light than shorter rod (aspect ratio = 0.5) in the desired spectrum for solar energy harvest from 400nm-700nm. The addition of a polymer layer on these ellipsoid rods broadens the light incident angle from 23° to 34°, from which light can be efficiently absorbed. Based on …

Near Bandgap Two-Photon Excited Luminescence Of Inas Quantum Dots, Xian Hu

Graduate Theses and Dissertations

Semiconductor quantum dots (QDs) confine carriers in three dimensions, resulting in atomic-like energy levels as well as size-dependent electrical and optical properties. Self-assembled III-V QD is one of the most studied semiconductor QDs thanks to their well-established fabrication techniques and versatile optical properties. This dissertation presents the photoluminescence (PL) study of the InAs/GaAs QDs with both above bandgap continuous-wave excitation (one-photon excitation) and below-bandgap pulse excitation (two-photon excitation). Samples of ensemble QDs, single QD (SQD), and QDs in a micro-cavity, all grown by molecular beam epitaxy, are used in this study. Morphology of these samples was examined using atomic force …