Advanced Sustainable Concrete Materials For Infrastructure Applications, Kaylea Ann Smith

Masters Theses

"This study was performed to examine the effects of cement replaced by high volumes of Class C fly-ash on durability characteristics of concrete up to 120 days. Specifically, this study investigates possibility of amending American Society for Testing and Materials (ASTM) to allow High Volume Fly-ash (HVFA) concrete to cure until later ages prior to testing instead of 28 days. Five mix designs were compared with varying fly-ash percentages from 0 to 70% (by total cementitious mass). No other additives were present in any of the five mix designs. Water-to-cementitious ratio (w/cm) and total cementitious material remained constant as 0.40 …

Factors Affecting The Heat Transfer During The Dip Testing Of Potential Third Generation Advanced High Strength Steels, Kramer Michael Pursell

Masters Theses

"A dip tester was designed and built at Missouri University of Science and Technology to test the effects of the primary alloying elements (Mn, Si, and Al) of Fe-Mn-Al-Si-C type 3rd generation advanced high strength steel (AHSS) alloys, dipping superheat, and dipping speed on the heat transfer during rapid solidification. The difficulties associated with casting 3rd generation AHSS were compiled as well to serve as a best-practices guide. An extensive list of potential 3rd generation AHSS alloys was developed and tested, and the effects of various dip testing parameters were examined.

Manganese was found to increase the heat flux by …

Determination Of Setting Times By Shear Wave Velocity Evolution In Fresh Mortar Using Bender Element Method, Jianfeng Zhu

Masters Theses

This study aims at using modified bender element (BE) method to monitor the shear wave velocity (V_s) of mortar at early-age and determine initial and final setting times with the V_s method. Modifications of the traditional BE method have been made to overcome the aggressive cementitious environment and eliminate electromagnetic coupling. BE has been successfully employed in mortar samples with and without admixtures to evaluate the evolution of V_s during the early age (first 24 hrs) of hydration. An energy approach method of determining the first arrival time of S-wave has been proposed. Pulse wave velocity …

Understanding Impurities In Copper Electrometallurgy, Paul Laforest

Masters Theses

"This work involves examining two industrial reports of methods to handle impurities in copper electrowinning and electrorefining. The first part evaluates the addition of Hydrostar, Cyquest N-900, DXG-F7, and Guartec EW to copper electrowinning electrolyte to affect MnO₂ deposition on coated titanium anodes (CTAs). The second part examines the effects of anode chemistry and thiourea addition on the ductility of electrorefined copper starter sheet.

In part one, a laboratory cell was used to simulate a short cycle electrowinning cell via chronopotentiometric operation with an IrO₂-Ta₂O₅ CTA at 40⁰C. A cyclic voltammetric sweep was applied …

Developing A Novel Methodolgy And Testbed For Fatigue Analysis Of Metal Specimens, Sai Aravind Palepu

Masters Theses

"A prototype of fatigue testing machine was built to determine the fatigue strength of materials. Proposed testing prototype was displacement controlled magnetic type bend fatigue testing machine. Designed prototype was tuned to operate at or near resonance of the specimen in order to amplify excitation displacement. Low maintenance i.e. zero wear of the parts was achieved, there were no moving components in the prototype machine. Crucial components used to build were: DC power supply, solenoid, Arduino UNO, supports and laser displacement sensor. DC source used to pass current through solenoid producing magnetic field; mosfet and Arduino generated square waves of …

Development Of Two Color Imaging Pyrometer For Studying Thermal History Of Laser Metal Deposition, Niroop Matta

Masters Theses

"The laser aided manufacturing process is a process in which parts are built by adding material into the melt pool created by a laser. This process involves a complex thermal history which is important in determining the quality of the parts built. The objective of this study is to develop a high resolution two color imaging pyrometer which can measure the temperature of an object without the dependence of spectral emissivity of the material at an economical price. An 8.8 MP CMOS sensor is used as an imaging sensor. The visible spectrum of light is used for temperature measurement. The …

Hybrid Manufacturing Process Of SicF/Sic Composite Using Preceramic Polymer, Robert Raymond Meinders

Masters Theses

"Continuous fiber-reinforced silicon carbide (SiC_f/SiC) ceramic composites have been increasingly used due to their high temperature strength and graceful failure mechanisms. A disadvantage is the high cost and lengthy production processes that are required to develop these materials. Polymer infiltration and pyrolysis (PIP) is one of the most attractive fabrication processes for composites due to shape flexibility, mass production and relatively low cost; however, the quality of material obtained by this method has been considered insufficient due to the microstructure defects of the material obtained. This study investigated a hybrid of multiple polymer manufacturing processes to maximize quality …

Deforming Diamond, Ciprian Borcea, Ileana Streinu

Computer Science: Faculty Publications

For materials science, diamond crystals are almost unrivaled for hardness and a range of other properties. Yet, when simply abstracting the carbon bonding structure as a geometric bar-and-joint periodic framework, it is far from rigid. We study the geometric deformations of this type of framework in arbitrary dimension d, with particular regard to the volume variation of a unit cell.

3d Printing, Open-Source Technology And Their Applications In Research, Chenlong Zhang

Dissertations, Master's Theses and Master's Reports

Open-source software received tremendous success as it drives down the cost of software and expand the distribution. Open-source hardware, as part of the open-source movement, has just risen into public attention for its potential to further drive down the cost of all kinds of manufacturing goods and reshape the manufacture chain. In this report we explores the history, development and the future of open-source hardware project, summarizing the opportunities, challenges and possible solutions. 3D printing is demonstrated as a booster to assist open-source hardware’s development. Low-cost 3D printer enables at-home and in-time fabrication, the download-print-use-improve-distribute cycle is established to encourage …

Computational Study Of Microstructure-Propertymechanism Relations In Ferroic Composites, Fengde D. Ma

Dissertations, Master's Theses and Master's Reports - Open

Ferroic materials, as notable members of smart materials, have been widely used in applications that perform sensing, actuation and control. The macroscopic property change of ferroic materials may become remarkably large during ferroic phase transition, leading to the fact that the macroscopic properties can be tuned by carefully applying a suitable external field (electric, magnetic, stress). To obtain an enhancement in physical and/or mechanical properties, different kinds of ferroic composites have been fabricated. The properties of a ferroic composite are determined not only by the properties and relative amounts of the constituent phases, but also by the microstructure of individual …

Modeling And Simulation Of Microstructures, Mechanisms, And Diffraction Effects In Energy Materials: Ferroelectrics And Lithium Ion Battery Cathode Materials, Jie Zhou

Dissertations, Master's Theses and Master's Reports - Open

Ferroelectric materials, as a large family exploited for the application of sensors, transducers and random access memories, open up a remarkable ground both for fundamental science and industry. Dielectric and piezoelectric properties are of the most interest in ferroelectric materials, which motivate research to enhance ferroelectric properties based on various application purposes. Among the multitudinous candidates in ferroelectric family, pseudo binary solid solutions with ABO₃ lattice structure attract special attention in virtue of their large strain response when applying external loading. Furthermore, existence of morphological phase boundary (MPB) on their phase diagrams shed light on tuning material compositions to …

Structures, Properties And Functionalities Of Magnetic Domain Walls In Thin Films, Nanowires And Atomic Chains: Micromagnetic And Ab Initio Studies, Liwei D. Geng

Dissertations, Master's Theses and Master's Reports - Open

Structures, properties and functionalities of magnetic domain walls in thin film, nanowires and atomic chains are studied by micromagnetic simulations and ab initio calculations in this dissertation. For magnetic domain walls in thin films, we computationally investigated the dynamics of one-dimensional domain wall line in ultrathin ferromagnetic film, and the exponent α = 1.24 ± 0.05 is obtained in the creep regime near depinning force, indicating the washboard potential model is supported by our simulations. Furthermore, the roughness, creep, depinning and flow of domain wall line with commonly existed substructures driven by magnetic field are also studied. Our simulation results …

Failure Modes For I-Section Gfrp Beams, Mamadou Konate, Zia Razzaq

Civil & Environmental Engineering Faculty Publications

This paper presents calculations for the failure modes for I-section Glass Fiber Reinforced Polymer (GFRP) beams with single mid-span web brace. Theoretical predictions are made using ASCE-LFRD Pre-Standard for FRP structures. For the member length considered, it is found that for small and medium I-sections the failure mode is governed by lateral-torsional buckling and for bigger I-sections the failure mode is governed by material rupture. The outcome of the predicted lateral-torsional buckling mode is compared with that observed experimentally.

Tunable Optical Nanocavity Of Iron-Garnet With A Buried Metal Layer, Alexey N. Kuz'michev, Lars E. Kreilkamp, Mohammed Nur-E-Alam, Evgeni Bezus, Mikhail Vasilev, Iliya A. Akimov, Kamal Alameh, Manfred Bayer, Vladimir I. Belotelov

Research outputs 2014 to 2021

We report on the fabrication and characterization of a novel magnetophotonic structure designed as iron garnet based magneto-optical nanoresonator cavity constrained by two noble metal mirrors. Since the iron garnet layer requires annealing at high temperatures, the fabrication process can be rather challenging. Special approaches for the protection of metal layers against oxidation and morphological changes along with a special plasma-assisted polishing of the iron garnet layer surface were used to achieve a 10-fold enhancement of the Faraday rotation angle (up to 10.8°=μm) within a special resonance peak of 12 nm (FWHM) linewidth at a wavelength of 772 nm, in …

Reaction Of Liquid Aluminium- Samarium Alloys With B4c At Ultra High Temperatures, Sanjay Shantha-Kumar

Open Access Theses & Dissertations

Reactive studies between a packed bed of B4C and Al-Sm-Me (Me = Ti, Zr, Hf) alloy melts were carried out under a pseudo-isopiestic thermodynamic system. A graphite enclosure isolated the system under a temperature gradient with one end reaching temperatures greater than 1800 K and the opposite end of the graphite enclosure contains liquid Al with temperatures approximating 950 K. The liquid Al establishes an oxygen potential to control oxidation of very reactive elements (i.e., Al, Sm and Ti). The Al-Sm-Me alloy infuses into a packed bed of B4C reacting exothermically to form borides and carbides depending on the thermodynamic …

High Temperature Oxidation Of Nb-Cr-Mo-Si-B Alloys, Kathryn S. Thomas

Open Access Theses & Dissertations

It has been the trend to use nickel based superalloys in high temperature applications, however higher temperatures are required in the effort to enhance the efficiency of such components as jet turbine engines. The melting temperature of the nickel based superalloy limits the extent to which temperature can be raised as these materials are typically used at temperatures within 200 degrees of their melting point. Refractory metal based systems are attractive due to their high melting points, low densities, and good high temperature strength. However, in such cases as niobium, poor oxidation resistance limits the widespread use of such alloys. …

Defeating Anisotropy In Material Extrusion 3d Printing Via Materials Development, Ángel Ramón Torrado Pérez

Open Access Theses & Dissertations

Additive Manufacturing technologies has been in continuous development for more than 35 years. Specifically, the later denominated Material Extrusion Additive Manufacturing (MEAM), was first developed by S. Scott Crump around 1988 and trademarked later as Fused Deposition Modeling (FDM). Although all of these technologies have been around for a while, it was not until recently that they have been more accessible to everyone. Today, the market of 3D printers covers all ranges of price, from very specialized, heavy and expensive machines, to desktop printers of only a few cubic inches in volume. Until recently, FDM technology had remained somewhat stagnant …

Design And Analysis Of A Novel Latch System Implementing Fiber-Reinforced Composite Materials, Francisco Guevara

Open Access Theses & Dissertations

The use of fiber-reinforced composite materials have increased in the last four decades in high technology applications due to their exceptional mechanical properties and low weight. In the automotive industry carbon fiber have become popular exclusively in luxury cars because of its high cost. However, Carbon-glass hybrid composites offer an effective alternative to designers to implement fiber-reinforced composites into several conventional applications without a considerable price increase maintaining most of their mechanical properties. A door latch system is a complex mechanism that is under high loading conditions during car accidents such as side impacts and rollovers. Therefore, the Department of …

Novel Engineered Nanomaterials For Water Remediation And Gas Adsorption: Graphene Oxide And Carbon Nanotubes Decorated With Metal-Organic Frameworks And Magnetic Nanoparticles, Vahid Jabbari

Open Access Theses & Dissertations

In the current study, a series of novel magnetic and non-magnetic hybrid nanocomposites based on metal-organic frameworks (MOFs) of M3(BTC)2 (M: Ni, Cu, Zn, and Cd), graphene oxide (GrO), and carbon nanotubes (CNTs), and Fe3O4 magnetic nanoparticles (MNPs) were developed via a green, simple and versatile solvothermal method at which GrO and CNT were used as platform to grow the MOFs and Fe3O4 MNPs over them. The as-synthesized nanocomposites were characterized by XRD, SEM, TEM, XPS, IR, Raman, TGA, and N2 adsorption/desorption isotherms. Morphological analysis confirmed successful growth of nano-size Fe3O4 MNPs and M3(BTC)2 MOFs over GrO and CNT platforms. …

A Methodology For Use Of Digital Image Correlation For Hot Mix Asphalt Testing, Estefany Ramos

Open Access Theses & Dissertations

Digital Image Correlation (DIC) is a relatively new technology which aids in the measurement of material properties without the need for installation of sensors. DIC is a noncontact measuring technique that requires the specimen to be marked with a random speckled pattern and to be photographed during the test. The photographs are then post-processed based on the location of the pattern throughout the test. DIC can aid in calculating properties that would otherwise be too difficult even with other measuring instruments.

The objective of this Thesis is to discuss the methodology and validate the use of DIC in different hot …

Acoustic Emission Characteristics Of Damage Accumulation In Kevlar® 49 Composites, Eduardo Andrade

Open Access Theses & Dissertations

Acoustic emission (AE) data attained during tensile testing of epoxy impregnated Kevlar® 49 (K/Ep) composite strands were reduced and analyzed to monitor progressive damage accumulation during the approach to tensile failure. The K/Ep material tested in this study was chosen due to its similarity to the material-of-construction used in composite overwrapped pressure vessels (COPVs) used on the NASA Space Shuttle Orbiter. Insight into the progressive microstructural degradation of K/Ep strands was gained by monitoring AE event rate and energy. Source location based on energy attenuation and arrival time data was used to differentiate between significant AE attributable to microstructural damage …

Effect Of Nanofiber Morphology On Pvdf Air Filter Performance, Andrew W. Marton

Williams Honors College, Honors Research Projects

Poly(vinylidene fluoride) (PVDF) can be formed into small nanofibers by electrospinning that are useful for a variety of applications. Air filters produced with PVDF are known to capture ionic particles with high efficiency. Existing studies have focused on the effects of electrospinning conditions on nanofiber morphology. In this study fibers were generated with varying morphologies. Air filters were then made from each sample and then characterized by TSI. Air filters were found to have increased resistances relative to their capture efficiencies according to particle diameter. Capture efficiencies did not correlate strongly with particle diameter, and the presence of beads in …

Design Of The University Of Akron's 2015 Fsae Electric Vehicle Braking System, Nicholas D. Galbincea

Williams Honors College, Honors Research Projects

The following report encompasses the design of the 2015 University of Akron’s FSAE formula electric braking system. The system is one based on hydraulic braking and designed for a one man performance racing vehicle. The objective of the system is to convert the kinetic energy of the vehicle into thermal energy, allowing the vehicle to decelerate optimally and safely. The design includes three major categories: calculation and evaluation of the hydraulic system in order to select calipers and master cylinders, the design of the pedal box, and the design of the rotors.

The results and findings of the proceeding report …

Reusable Adhesive Tapes From Electrospun Polymer Fibers, Vishal K. Chaurasia

Williams Honors College, Honors Research Projects

Many emerging applications demand an adhesive that has reusable properties. The adhesive must exhibit high adhesion strength to various surfaces and be able to be removed easily and then reapplied with minimal to no loss in adhesion strength. This work aims to tackle this problem by creating an adhesive tape fabricated by electrospinning polymer solutions onto a substrate. Electrospun adhesive nano/micro fibers have the ability to display the reusable characteristics desired. Several adhesive custom formulations were first developed and optimized for electrospinning. Then these formulations were successfully electrospun on to various substrates after much fine tuning of electrospinning parameters. The …

Nylon-6 Fabric Nanocomposite Resistance Temperature Detectors - Effects Of Oxidant, Mwcnt, And Nylon-6 Concentration, Rebecca Howdyshell

Williams Honors College, Honors Research Projects

Abstract

The purpose of this honors project is to construct and test temperature detectors, which can be used for the advancement of exercise devices, prosthetic sockets, or medical applications. Resistance Temperature Detectors (RTDs) are an effective way to measure temperature due to the dependence of the RTD material’s resistance on temperature. The focus of this project was to develop an RTD for prosthetic socket or exercise applications, where the RTD is in close contact with the skin of the user. Generally, RTDs are constructed from platinum, copper, or nickel. However, metal RTDs have a tendency to be large and rigid, …

The Examination Of Stress Corrosion Cracking In High Strength Carbon Steel Through Combined Mechanical-Electrochemical Testing, Jacob Sines

Williams Honors College, Honors Research Projects

Through the analysis of materials and environments seen in industry a better understanding of the fundamentals behind degradation mechanisms can be observed. The scope of this project was to better understand the fundamentals behind the degradation of high strength pipeline steels in a lab setting to simulate an environment seen in industry. Specifically the degradation mechanisms of high and nearly neutral pH stress corrosion cracking were examined in environments that simulated oil and gas pipelines buried in soil. Experimentation was carried out utilizing X65 carbon steel specimen, a Gamry potentiostat, a CORTEST proof ring, a CORTEST slow strain rate machine, …

Rheology Of Cross-Linked Polymers And Polymer Foams: Theory And Experimental Results, John Herman

Wayne State University Dissertations

Typical polymers have a time-dependent response to loading which results in stress relaxation or creep. Models using springs/dashpots or Volterra integrals are capable of predicting the material response, but place little or no emphasis on the reasoning behind the response. This research proposes a microscopic reasoning behind polymer chain movement, while developing a model to predict the creep and stress relaxation of a polymer foam. Based on the theorized slip/stick of polymer chains as they slide past each other, this model successfully predicts the behavior of a PMI polymer foam under tensile loads. This model lends insights into polymer microscopic …

Assessing Coupled Mechanical Behavior And Environmental Degradation At Submicron Scales, Samantha K Lawrence

Open Access Dissertations

Mechanical and electromechanical properties, deformation and fracture mechanisms, and environmental resistance of materials at submicron scales have been investigated through the combination of nanomechanical testing, high resolution microscopy, diffraction, and electrochemical testing. Nanomechanical techniques were used to isolate environmental, orientation, and size effects. Material evaluation focuses on metals, both model and engineering alloys, in bulk and thin-film form as well as oxide-substrate systems. Yield behavior of Ni 200, a model material, depends on sampled volume size, orientation, and surface preparation. Exposure to high-pressure hydrogen gas is also found to impact incipient plasticity and mechanical properties of commercially pure Ni 201. …

Kesterite Thin-Film Solar Cell Absorbers Derived Using Inhomogeneous Czts Nanoparticles, Wei-Chang D. Yang

Open Access Dissertations

My doctoral research focuses on understanding the structure-property-processing relationship of the kesterite materials to improve their device performance. It is recognized in both my own work and the recent literature that the structural and compositional integrities of CZTSSe are crucial to derive the solar cell grade kesterite thin-films. Analytical electron microscopy (AEM) allows me to demonstrate the structural and compositional inhomogeneity of the CZTS nanoparticles and CZTSSe thin-films at the nanoscale. For example, the observed forbidden reflections in TED patterns and FFT diffractograms corresponding to HRTEM images indicate that cation disorder leads to stacking faults in CZTS nanoparticles. Probe-corrected STEM …

Characterization And Mechanical Properties Of Solar Grade Silicon In Granular And Nanopowder Form, Mohamad Bilal Zbib

Open Access Dissertations

Polycrystalline silicon is mainly used for solar cell applications, structures in micro-electromechanical systems, and production of single crystal Si. One of the relatively new methods for producing large quantities of polysilicon is fluidized bed reactor (FBR), where two main morphologies are produced, granular solid (1-3 mm) and nanopowders (30-300 nm). Grinding and fracture occurs in the granular solid during shipping and handling which can affect the final product properties and create safety issues. The microstructure and the morphology of both the granular and the nanopowder forms of Si were examined using scanning and transmission electron microscopes (SEM and TEM). The …