Materials Science and Engineering Commons^™

Spectrally-Resolved Imaging Of The Transverse Modes In Multimode Vcsels, Stephan A. Misak, Dan G. Dugmore, Kirsten A. Middleton, Evan R. Hale, Kelly R. Farner, Kent D. Choquette, Paul O. Leisher

Rose-Hulman Undergraduate Research Publications

Vertical-cavity surface-emitting lasers (VCSELs) enable a range of applications such as data transmission, trace sensing, atomic clocks, and optical mice. For many of these applications, the output power and beam quality are both critical (i.e. high output power with good beam quality is desired). Multi-mode VCSELs offer much higher power than single-mode devices, but this comes at the expense of lower beam quality. Directly observing the resolved mode structure of multi-mode VCSELs would enable engineers to better understand the underlying physics and help them to develop multi-mode devices with improved beam quality. In this work, a low-cost, high-resolution (<3 >pm) …

Temperature Dependent Surface Reconstruction Of Freely Suspended Films Of 4-N-Heptyloxybenzylidene-4-N-Heptylaniline, Daniel E. Martinez Zambrano

Lawrence University Honors Projects

Surfaces of freely suspended thick films of 4-n-heptyloxybenzylidene-4-n-heptylaniline (7O.7) in the crystalline-B phase have been imaged using non-contact mode atomic force microscopy. Steps are observed on the surface of the film with a height of 3.0 +/- 0.1 nm corresponding to the upright molecular length of 7O.7. In addition, we find that the step width varies with temperature between 56 and 59 degrees C. The steps are many times wider than the molecular length, suggesting that the steps are not on the surface but instead originate from edge dislocations in the interior. Using a strain model for liquid crystalline layers …

Characterization Of Pressure-Driven And Electro-Kinetically Driven Flow In A Micro-Fluidic Chip Using Particle Imaging Velocimetry, Alexis Weckel

Master's Theses

The flow profiles of pressure-driven and electro-kinetic driven flows were compared for a microfluidic chip. It was found that the pressure-driven flow had a parabolic profile while the electro-kinetic flow had a plug shaped flow profile. The measured velocities were similar to those determined by the Poiseuille flow model and the Helmholtz-Smoltchowski equation. Flow uniformity is very important for control in microfluidic mixers. Parabolic flow profiles lead to inconsistent reactions while the more uniform plug shape flow allow for a more steady reaction across the channel. Previous work had been performed to measure the flow of a solution of fluorescent …

An Investigation Of Incipient Melting During Solution Heat Treatment Of 7050 Aluminum Forgings And Its Effect On Corrosion Properties, Thomas Kilkenny

Materials Engineering

7050 alloy (6.2Zn-2.3Mg-2.3Cu-0.12Zr) is a structural aluminum alloy commonly used in the aerospace industry. Its rich chemistry makes it susceptible to incipient melting. Incipient melting is a phenomenon where areas with high local alloy content melt before the rest of the material. This can cause a degradation of mechanical and corrosion properties. A six by four factor solution heat treatment trial was conducted. Six solution heat treatment temperatures, 890- 940°F in 10°F increments, and four times, 1, 2, 4, and 6 hours, were used. Incipient melting was observed in the 910°F, 6 hour solution heat treatment and all 920-940°F solution …

Analysis Of Shear Strength Variance Of Ph 15-7 Mo Blind Rivet Stems For Aerospace Applications, Miles Macarthur, Kent C. Majewski

Materials Engineering

This project attempts to reduce manufacturing costs incurred to Cherry Aerospace by variance in material properties. To track and predict the shear strength of PH 15-7 Mo stainless steel rivet stems throughout the heat treatment process, samples were taken from several steps in the manufacturing process and experimental heat treatments were performed across a range of temperatures. The supplied rivet stems were heat treated for four hours at temperatures from 520°C to 560°C, in increments of 10°C. Double shear testing in accordance with ASTM 1312-13A revealed that there is no apparent correlation between the strength of the supplied wire and …

Effect Of Heat Treatment On The Mechanical Properties In Natural Bamboo, Austin Levy, Mackenzie Kirkpatrick

Materials Engineering

Previous studies have shown that heat treatments have the ability to improve mechanical strength and stiffness in hardwood species. Compared to structural hardwoods, bamboo is a more sustainable and globally viable renewable resource. Therefore, Bambusoides vivax (timber bamboo) culms were fabricated into flat, rectangular cross-section samples with varying cellulose content to be heat treated and tested for mechanical properties. All samples were heat treated (HT) twice. The first HT was a normalization of all samples at 103 +/- 3 °C. The second HT was performed at various times and temperatures ranging from 130°C to 170°C for 0.5 to 3 hours. …

Minimizing Sheet Resistance Of Organic Photovoltaic Cell Top Contact Electrode Layer: Silver Nanowire Concentration Vs. Conductive Polymer Doping Concentration, Caitlyn Cook

Materials Engineering

The top contact electrode layers of nine organic photovoltaic cells were prepared with two varying factors: three Silver nanowire (AgNW) densities deposited on a conductive polymer doped with three concentrations. Silver’s low sheet resistance of 20-Ω/sq is hypothesized to lower the sheet resistance of the anode layer and thus enhance the overall efficiency of the cell. Four-point probe measurements indicated that increasing AgNW density in the top contact electrode layer of an organic photovoltaic cell significantly reduces sheet resistance from 52.2k-Ω/sq to 18.0 Ω/sq. Although an increase in doping concentration of the conductive polymer reduced sheet resistance in low AgNW …

Tensile Test Design To Measure Interlayer Adhesion In Investment Casting Shells For Spalling Mitigation, Shelby Boyd, Alex Miller, Jameson Senger

Materials Engineering

We designed a tensile test fixture for a 112 lbf capacity Instron load frame that imparts a normal force on the face of a button epoxied to an investment casting shell sample, delaminating the shell area attached to the button. Using a green standard shell (Group 1), a partially fired standard shell (Group 2), and a green shell with a different third coat (Group 3), we verified that the fixture can measure differences in strength between sample groups. We attached steel buttons to leveled samples with 0.05 mL of Hysol-Loctite 9340 epoxy, let it cure for 48 hours, and tested …

Effect Of Time Delay Between Etching And Adhesive Bonding (“Outlife” Time) On Lap-Shear Strength Of Aluminum Alloys Using Environmentally-Friendly P2 Etch, Josh Barkhimer, Matthew Erich, Gokul Nair

Materials Engineering

Raytheon Company currently uses a Forest Products Laboratory (FPL) paste etchant for preparing aluminum surfaces for adhesive bonding, and FPL is a source of hazardous hexavalent chromium. The goal of this study was to evaluate a less-toxic P2 paste etchant as a possible replacement. Coupons of 2024-T3, 6061-T6, and 7075-T6 grades of aluminum alloy were solvent-degreased, abrasively cleaned, and etched at room temperature using P2 paste following a strict protocol adopted from Raytheon. Coupons were then left exposed to air for assigned time intervals (or “outlife” times) of 0, 1, 4, 8, 16, and 63 or 72 hours. The aluminum …

Effects Of Composition And Solid Solution Strengthening On The Compression Strength Of Iron-Based Hardfacing Alloys, Tyler Wiggins, Samuel Garrison-Terry

Materials Engineering

Three iron-based hardfacing alloys were fabricated to have a tungsten strengthened matrix with varying compositions of 10-15, 20, and 30 wt% tungsten/chrome boride content. The fourth sample was fabricated to have a molybdenum solid solution strengthened matrix with 10-15 wt% W/Cr Boride content. This project focuses on the compressive strength of iron-based hardfacing alloys. Preliminary compression tests with Scoperta iron-based hardfacing alloys showed a need for sample dimension reduction due to compressive loads that could not be met by a 50 kN maximum capacity mechanical testing system. The preliminary tests showed compressive strengths exceeding 2340 MPa. Samples of the current …

Electrochemical Testing Of Aluminum-Lithium Alloys 2050, 2195, And The Current Aerospace Industry Standard 7075 To Measure The Galvanic Corrosion Behavior With Ti-6al-4v, Trent Duncan, Kevin Knight

Materials Engineering

This project aimed to characterize the electrochemical behavior of four different aluminum alloys, and determine how much galvanic corrosion would occur when each alloy was coupled to Ti-6Al-4V. The particular alloys tested were 2050-T3, 2050-T852, 2195-T852, and 7075-T7352. These alloys were tested to determine the effects of aging, and adding lithium, to the corrosion behavior of aluminum alloys. Potentiodynamic polarization curves were generated using the Parstat 2273 potentiostat in accordance with ASTM standard G5, and corrosion analysis software was used to produce Tafel fit lines, which determined the open circuit potential (E_corr) of each sample. Nine tests were …

Measuring And Increasing The Suspension Time Of Lanthanide Oxysulfide Particles With Modifiers Via Fluorescence For Use In Anti-Counterfeiting Applications, Joe Dei Rossi, Tyler Dinslage, Tyler Schelling

Materials Engineering

No abstract provided.

Mechanical Testing Of Multi-Construction Composite Tubes For Use In Fly Fishing Rods, Macormik Hopen

Materials Engineering

A testing protocol was established for measuring the flexure properties of thin-walled tubes constructed of a composite mixture of glass and carbon fibers and epoxy resin for use in Fly Fishing rods. Standard three point bend tests were conducted in accordance with ASTM standard D7329-13 with a span length of six inches. All samples were of the sample length and diameter, allowing direct comparison of the maximum loads reached before failure, which are directly indicative of the Modulus of Rupture (MOR). Two constructions were tested both containing the same unidirectional fiber but with different support structure. These tubes were tested …

Molecular Dynamics Investigation Of The Arabinan-Cellulose Interface For Cellulose Nanocomposite Applications, Luke Thornley

Materials Engineering

Atom level computer simulations of the arabinan and cellulose interface were performed to better understand the mechanisms that give arabinan-cellulose composites (ArCCs) their strength with the goal to improve man-made ArCCs. The molecular dynamics (MD) software LAMMPS was used in conjunction with the ReaxFF/c force field to model the bond between cellulose and arabinan. A cellulose nanocrystal with dimensions 51 x 32 x 8 Å was minimized with various weight percent of water, 0%, 3%, 5%, 8%, 10%, and 12%. After the system was equilibrated for at least 100,000 femtoseconds, an arabinan molecule composed of 8 arabinose rings was added …

Characterization Of Laser Deposited Ti-6al-4v To Nb Gradient Alloys, Clincy Cheung

Materials Engineering

An alloy was fabricated with Ti-6Al-4V and Nb powder using laser deposition (LD) to form a compositional gradient. The gradient was deposited, starting with Ti-6Al-4V powder, onto a forged Ti-6Al-4V substrate in an Argon environment. Niobium (Nb) composition increased by 4-at.% with each layer deposited until the composition reached 100-at.% Nb. This process yielded steep thermal gradients and affected the microstructure and mechanical properties across the compositional gradient. To observe the microstructural changes in the alloy, an etched gradient was viewed with optical microscopy at 1000x, where the grain structure was observed to be an acicular α phase at 100-at.% …

Investigating The Cause Of Unique Mechanical Behavior In Platinum Alloy Guidewire Tips, Evan Borgeson, Alfred Rosen

Materials Engineering

The platinum alloy used by Abbott Vascular in guidewire tips exhibits a yielding behavior characterized by an abrupt transition from elastic to plastic zones and high ductility. This yielding behavior was hypothesized to be a result of one of three structural phenomena: ordering, solute strain aging, or interstitial strain aging. To test for these strengthening mechanisms in the wire, X-ray diffraction analysis, heat treatments, and tensile testing were completed. The wire has a diameter of 0.0025 inches and was supplied in two forms, the final stress relieved state, and as-drawn from the production line. Heat treatments were performed at 130 …

Forest Sign Maker, Victor Espinosa Iii, Kevin Ly, Lisa Yip

Mechanical Engineering

Executive Summary:

The Inyo National Forest is arguably one of the most beautiful locations in California, containing natural masterpieces such as Mount Whitney and the Ancient Bristlecone Pine Forest. Despite its magnificence, the Inyo National Forest can be a treacherous region. The Friends of the Inyo take pride in being able to facilitate the viewing experience for all outdoorsmen by maintaining the mountain trails, which includes providing adequate trail signage.

Unfortunately, there is a fundamental issue with the recent state of trail signage in the Inyo National Forest: the rate at which signs are being vandalized or naturally destroyed is …

Effect Of Surfactant Architecture On Conformational Transitions Of Conjugated Polyelectrolytes, Greg A. Braggin

Master's Theses

Water soluble conjugated polyelectrolytes (CPEs), which fall under the category of conductive polymers, possess numerous advantages over other conductive materials for the fabrication of electronic devices. Namely, the processing of water soluble conjugated polyelectrolytes into thin film electronic devices is much less costly as compared to the processing of inorganic materials. Moreover, the handling of conjugated polyelectrolytes can be performed in a much more environmentally friendly manner than in the processing of other conjugated polymers because conjugated polyelectrolytes are water soluble, whereas other polymers will only dissolve in toxic organic solvents. The processing of electronic devices containing inorganic constituents such …

Impact Of Stoichiometry On Structural And Optical Properties Of Sputter Deposited Multicomponent Tellurite Glass Films, Okechukwu Ogbuu, Qingyang Du, Hongtao Lin, Lan Li, Yi Zou, Erick Koontz, Charmayne Smith (Lonergan), Sylvain Danto, Kathleen Richardson, Juejun Hu

Materials Science and Engineering Faculty Research & Creative Works

Multicomponent TeO₂-Bi₂O₃-ZnO (TBZ) glass thin films were prepared using RF magnetron sputtering under different oxygen flow rates. The influences of oxygen flow rate on the structural and optical properties of the resulting thin films were investigated. We observed that thin films sputtered in an oxygen-rich environment are optically transparent while those sputtered in an oxygen-deficient environment exhibit broadband absorption. The structural origin of the optical property variation was studied using X-ray diffraction, X-ray photoelectron spectroscopy, Raman Spectroscopy, and transmission electron microscopy which revealed that the presence of under-coordinated Te leads to the observed optical …

Chemical Oxidative Polymerization, Optical, Electrochemical And Kinetic Studies Of 8-Amino-2-Naphthol, Fatih Dogan, Ismet Kaya, Ali Bilici, Mehmet Yildirim

Materials Science and Engineering Faculty Research & Creative Works

Here the polymerization of 8-amino-2-naphthol (AN) is reported without use of an additional external template, surfactants or functional dopants. For this, NaOCl and hydrochloride acid solution (1.0 M) were used as oxidant and reaction medium, respectively. The structure of oligomer was elucidated by FT-IR, UV–vis and 1 H-NMR techniques. The number average molecular weight of oligomer was found to be 2200Da with a polydispersity index of 1.4 by size exclusion chromatography. This oligomer exhibited a multicolor emission behavior as it was excited at different wavelengths. Redox states were clarified by cyclic voltammetry (CV) technique and the relationship between anodic/cathodic peak …

Electrolytic Recovery Of Bismuth And Copper As A Powder From Acidic Sulfate Effluents Using An Emew® Cell, Wei Jin, Paul I. Laforest, Alex Luyima, Weldon Read, Luis M. Navarro, Michael S. Moats

Materials Science and Engineering Faculty Research & Creative Works

Effective removal of bismuth is a primary concern during copper electrorefining. A novel electrowinning process using an emew® cell was developed to recover bismuth and copper from a copper electrorefining waste stream. Significant removal and co-deposition of copper and bismuth were achieved from a highly acidic sulfate industrial effluent using a current density of 350 A m^-2, but the current efficiency was low (27%). Operating at a lower current density (75 A m^-2) facilitated the preferred removal of Cu, while increasing current efficiency to 67.4% due to the decrease of aside-reaction. Consequently, a two-stage process was …

Capillary Channel Flow (Ccf) Eu2-02 On The International Space Station (Iss): An Experimental Investigation Of Passive Bubble Separations In An Open Capillary Channel, Mark M. Weislogel, Andrew P. Wollman, Ryan M. Jenson, John T. Geile, John F. Tucker, Brentley M. Wiles, Andy L. Trattner, Claire Devoe, Lauren M. Sharp, Peter J. Canfield, Jörg Klatte, Michael E. Dreyer

Mechanical and Materials Engineering Faculty Publications and Presentations

It would be signicantly easier to design fluid systems for spacecraft if the fluid phases behaved similarly to those on earth. In this research an open 15:8 degree wedge-sectioned channel is employed to separate bubbles from a two-phase flow in a microgravity environment. The bubbles appear to rise in the channel and coalesce with the free surface in much the same way as would bubbles in a terrestrial environment, only the combined effects of surface tension, wetting, and conduit geometry replace the role of buoyancy. The host liquid is drawn along the channel by a pump and noncondensible gas bubbles …

Analysis Of Compression Creep Deformation Of 7050 Aluminum Large Scale Open Die Forgings During The Solution Heat Treatment Process, Ashley Lopez, Elysha Cole

Materials Engineering

A stress, ranging from 104.17 to 166.67 psi, was applied to 0.5 in diameter cylindrical samples of 7050 aluminum using a manufactured fixture that applies stress using an indenter with a diameter of 0.127 in. The stress range used replicates the stresses produced on large scale forgings weighing up to 4000 lbs. We chose a maximum, medium and low stress as our stress parameters. The samples were placed into the fixture for stability then placed in a furnace heated to 890°F which is the solution heat treatment temperature for 7050 aluminum. The heat treatment times varied between 4 and 24 …

Effects Of Initial Forging Temperature, Cooling Rates, And Carbon Content On Primary Alpha Formation In Ti-6al-4v, James Tillman, Hui Wei

Materials Engineering

Ti-6Al-4V is an alpha-beta titanium alloy system, which contains both alpha and beta phases at room temperature. Both alpha and beta phases provide Ti-6Al-4V a range of different properties for a range of applications. In order to improve the energy efficiency and better satisfy customers’ requirements of less than 52% primary alpha phase, Weber Metals sponsored this project to study the effects of carbon content, forging temperature, and cooling rates on primary alpha formation in Ti-6Al-4V alloys. There has been a lot of discussion as to whether or not carbon, a known alpha stabilizer, will affect the microstructure in small …

Improving Product Design By Predicting Flexural Strength Of A Honeycomb Core Sandwich Panel Composite Using Ply Tensile Strength, Justin Lui, Javal Patel

Materials Engineering

The use of composite sandwich panels has increased in the aerospace industry. Prediction of a theoretical composite construction's flexural properties is important for efficient composite product designs. Utilizing the four point flexure geometry defined by Zodiac Aerospace, Santa Maria, CA, a mechanical model was derived to predict the flexural behavior of a theoretical honeycomb core sandwich composite using laminate tensile properties. The most common failure mode of Zodiac Aerospace’s four point bend test is a failure in tension of the bottom laminate. Given this information, ASTM D3039 (Standard Test Method for Tensile Properties of Polymer Matrix Composite Materials) was chosen …

Elevated Temperature Effects On The Mechanical Properties Of Age Hardened 6xxx Series Aluminum Alloy Extrusions, Rachael Donovan, Rose Fortune, Robert Trout

Materials Engineering

The purpose of this project is to determine if over-aging of aluminum causes the yield or tensile strength to fall below the minimum strength values set by the aluminum industry. Extruded aluminum alloys, 6061-T6, 6063-T6, and two proprietary alloys, HS6X-T6 and RX82-T6, were exposed to reheating treatments at extended times and temperatures. The three temperatures were 350°F, 390°F, and 425°F. The times of reheat increased logarithmically from 30 minutes to 64 hours. The samples were tensile tested to determine the tensile strength and yield strength. Statistical methods helped model the behavior of yield and tensile strength as a function of …

Measuring Performance Of Paint Coating Via Laboratory And Field Testing, Eugene Leung, Rocco Lattanzio

Materials Engineering

No abstract provided.

Self-Contained Breathing Apparatus For Firefighter With A Permanent Stoma, Jason Delgadillo, Aaron Wheeler, Zachary Wishbow

Biomedical Engineering

The purpose of this project was to create a unique SCBA (self-contained breathing apparatus) for a firefighter named Chris Gauer. This prototype consists of a SCBA headgear connected to a polycarbonate-formed stoma mask with a medical-grade sanitary silicone hose.

New Screening Methodology For Selection Of Polymeric Materials For Transdermal Drug Delivery Devices, Roberto P. Falcone

Dissertations

As medical advances extend the human lifespan, the level of chronic illnesses will increase and thus straining the needs of the health care system that, as a result, governments will need to balance expenses without upsetting national budgets.

Therefore, the selection of a precise and affordable drug delivery technology is seen as the most practical solution for governments, health care professionals, and consumers.

Transdermal drug delivery patches (TDDP) are one of the best economical technologies that are favored by pharmaceutical companies and physicians alike because it offers fewer complications when compared to other delivery technologies. TDDP provides increased efficiency, safety …

Computational Studies Of Electronic Structure Of Doped Graphene, Yan Chu

Theses

In the literature, extensive studies have been performed to study the electronic properties of doped graphene. This is due to the potentially large number of applications of graphene in p-n junctions, transistors, photodiodes and lasers. By utilizing single heteroatom chemical doping method or electric field-induced method, one can introduce a band gap, ranging from 0.1eV to 0.5eV, in graphene. A tunable bandgap is highly desirable because it would allow significant flexibility in the design and optimization of such devices, particularly if it could be tuned by adjusting the doping configurations. Here, we demonstrate the realization of a widely tunable electronic …