Materials Science and Engineering Commons^™

Sputter Deposition Of Thin-Film Capacitors Onto Low Temperature Co-Fired Ceramic Substrates, Jack Murray

Masters Theses

"Single layer thin film capacitor structures were fabricated on the surface of low temperature co-fired ceramic (LTCC) substrates using sputter deposition. The capacitor structures had areas between ~10⁴ µm² to ~10⁶ µm² and featured ~200 nm Al or Pt electrodes with 150-1500 nm Al₂O₃ dielectric layers. Impedance analysis and current-voltage testing were carried out to determine the effect of electrode material and dielectric thickness upon capacitor performance. Capacitance values for devices with Al electrodes ranged from ~10 to ~700 pF, depending on capacitor area and dielectric thickness, and the fit to expected values was better than devices with Pt or …

Plastic Strain Accommodation And Acoustic Emission During Melting Of Embedded Indium Particles In Aluminum, Michael M. Kuba

Masters Theses

"Melting of micron-sized (0.2 to 3 µm diameter) indium particles embedded in an aluminum matrix was discovered to produce acoustic emission. Melting of embedded immiscible particles produces a pure dilation during the phase transformation and has no long-range diffusion field to control the speed of transformation. It was found that acoustic emission can no longer be considered as a criterion of displacive transformations and that melting of micron-sized embedded particles is strain energy controlled. Acoustic emission was confirmed to result from the rapid relaxation of aluminum around indium particles embedded on grain boundaries. Prismatic punching of dislocation loops is proposed …

Cerium-Based Conversion Coatings On Cast Aluminum 380 And 413 Alloys, Ci Lin

Masters Theses

"This investigation focused on the deposition and characterization of cerium-based conversion coatings (CeCCs) on cast aluminum alloys. Previous research has shown that CeCCs are viable alternatives to chromate conversion on high strength alloys such as 2024-T3 and 7075-T6. For the casting alloys such as 380 and 413, the presence of Si affects the composition and stability of the native oxide, which means that pretreatment plays an important role for the coating deposition. This thesis consists of two papers that describe the results of the study.

The first paper reports the effect of the final rinsing temperature before coating deposition on …

The Quantification Of The Fly Ash Adsorption Capacity For The Purpose Of Characterization And Use In Concrete, Zeyad Tareq Ahmed

Dissertations, Master's Theses and Master's Reports - Open

Fly ash has been shown to be an effective replacement for portland cement in concrete mixtures. However, many fly ash materials contain unburned carbon from the combustion process. Unburned carbon in fly ash adsorbs air entraining admixtures (AEAs) reducing their effectiveness in providing a specified air void system in concrete materials. Measurement tools and methods for characterization of the adsorption properties of fly ash materials are necessary for beneficial use of fly ash materials in concrete. In this research, two methods were developed to measure and quantify the adsorption capacity AEAs on fly ash materials. The first method is the …

Electric-Field-Induced Interfacial Instabilities Of A Soft Elastic Membrane Confined Between Viscous Layers, Mohar Dey, Dipankar Bandyopadhyay, Ashutosh Sharma, Shizhi Qian, Sang Woo Joo

Mechanical & Aerospace Engineering Faculty Publications

We explore the electric-field-induced interfacial instabilities of a trilayer composed of a thin elastic film confined between two viscous layers. A linear stability analysis (LSA) is performed to uncover the growth rate and length scale of the different unstable modes. Application of a normal external electric field on such a configuration can deform the two coupled elastic-viscous interfaces either by an in-phase bending or an antiphase squeezing mode. The bending mode has a long-wave nature, and is present even at a vanishingly small destabilizing field. In contrast, the squeezing mode has finite wave-number characteristics and originates only beyond a threshold …

Multi-Wavelength Laser Sensor For Intruder Detection And Discrimination, Kavitha Venkataraayan, Sreten Askraba, Kamal E. Alameh, Clifton L. Smith

Research outputs 2011

An intruder detection and discrimination sensor with improved optical design is developed using lasers of different wavelengths to demonstrate the concept of discrimination over a distance of 6 m. A distinctive feature of optics is used to provide additional transverse laser beam scanning. The sample objects used to demonstrate the concept of discrimination over a distance of 6 m are leaf, bark, black fabric, PVC, wood and camouflage material. A camouflage material is chosen to illustrate the discrimination capability of the sensor. The sensor utilizes a five-wavelength laser combination module, which sequentially emits identically-polarized laser light beams along one optical …

Technical Feasibility Of Storage On Large Dish Stirling Systems, Charles E. Andraka, K Scott Rawlinson, Nathan P. Siegel

Faculty Journal Articles

Dish-Stirling systems have been demonstrated to provide high-efficiency solar-only electrical generation, holding the world record at 31.25%. This high efficiency results in a system with a high possibility of meeting the DOE SunShot goal of $0.06/kWh. Current dish-Stirling systems do not incorporate thermal storage. For the next generation of non-intermittent and cost-competitive solar power plants, we propose a thermal energy storage system that combines latent (phase-change) energy transport and latent energy storage in order to match the isothermal input requirements of Stirling engines while also maximizing the exergetic efficiency of the entire system. This report takes an initial look at …

High Pressure Synchrotron X-Ray Diffraction Studies Of Superprotonic Transitions In Phosphate Based Solid Acids, Juan Daniel Hermosillo

Open Access Theses & Dissertations

Certain phosphate based solid acids, such as CsH2PO4 and RbH2PO4, have been shown to exhibit an abrupt, several-order-of-magnitude increase in their proton conductivity when heated above a temperature threshold. This so called superprotonic behavior allows the above-mentioned materials to function as fuel cell electrolytes at temperatures between 150C and 300C, a remarkable application that attracted significant interest especially from the automobile industry. Yet, the microscopic structures and dynamic mechanisms responsible for this behavior are not fully understood. In fact, until very recently, the very nature of the superprotonic behavior has been debate, with some groups attributing the steep proton enhancement …

Development Of Advanced Polymer Nanocomposite Capacitors, Miguel Mendoza

Open Access Theses & Dissertations

The current development of modern electronics has driven the need for new series of energy storage devices with higher energy density and faster charge/discharge rate. Batteries and capacitors are two of the most widely used energy storage devices. Compared with batteries, capacitors have higher power density and significant higher charge/discharge rate. Therefore, high energy density capacitors play a significant role in modern electronic devices, power applications, space flight technologies, hybrid electric vehicles, portable defibrillators, and pulse power applications. Dielectric film capacitors represent an exceptional alternative for developing high energy density capacitors due to their high dielectric constants, outstanding breakdown voltages, …

Hafnia-Based Nanostructured Thermal Barrier Coatings For Next Generation Gas Turbine Technology, Mohammed Noor-A-Alam

Open Access Theses & Dissertations

Extensive efforts have been directed in the last several decades towards improving thermodynamic efficiency of industrial gas turbines for power generation plants. The central theme of the efforts is to increase the turbine operating temperature and, thus, allowing higher efficiency. Thermal barrier coatings (TBC) constitute an advanced technology to protect the metallic surface from high temperature exposure for long time operation. The TBCs protect the gas turbine components from high temperature and allows further increase in engine operating temperature which subsequently increases the efficiency of the gas turbine power plant. However, the current TBC materials are capable of allowing the …

Applications Of Density Functional Theory In Materials Science And Engineering, Manuel Alvarado

Open Access Theses & Dissertations

Density Functional Theory (DFT) is a powerful tool that can be used to model various systems in materials science. Our research applies DFT to two problems of interest. First, an organic/inorganic complex dye system known as a Mayan pigment is modeled to determine chemical binding sites, verifying each model with physical data such as UV/Vis spectra. Preliminary studies on palygorskite-based mayan pigments (mayacrom blue, mayacrom purple) show excellent agreement with experimental studies when using a dimer dye geometry binding with tetrahedrally-coordinated aluminum impurity sites in palygorksite. This approach is applied to a sepiolite-based organic/inorganic dye system using thioindigo attached to …

Raman And Infrared Study Of Electrospun Plla/Pcl Nanofiber Blends For Use In Tissue Engineering, Jose Luis Enriquez Carrejo

Open Access Theses & Dissertations

Recently, the biomedical engineering field has developed at a very fast pace as improved techniques and materials become available to promote its growth. Consequently, the research in polymeric biomaterials has been highly stimulated by this trend. The goal of the current research is to demonstrate the usefulness of the Raman scattering, Raman mapping, and infrared absorption spectroscopies to tissue engineering, by spectroscopically characterizing blends of PLLA and PCL polymers, which were prepared by electrospinning with and without cell addition. The proposed use of these blends is as primary biomaterials in biodegradable scaffolds used in tissue engineering. Both Raman and infrared …

Development Of A Multi-Material, Multi-Technology Fdm System For Process Improvement Experimentation, David Espalin

Open Access Theses & Dissertations

Over the last three decades, developments within the area of Additive Manufacturing (AM) have resulted in novel technologies capable of producing highly customized, complex part geometries in a fraction of the lead time required by traditional manufacturing methods (e.g., injection molding, metal casting). In particular, fused deposition modeling (FDM), a material extrusion AM process, can produce parts using production-grade thermoplastics like acrylonitrile butadiene styrene, polycarbonate, and polyetherimide. Additionally, non-commercial materials (e.g., polycaprolactone, ceramic loaded polymers, carbon nanotube loaded polymers) have been processed using FDM in part to demonstrate the potential diversity in material selection.

Recently, a myriad of personal 3D …

The Effect Of Al And B Additions On The Oxidation Behavior Of Alloys From The Nb-Cr-Si System, Nydia Judit Esparza

Open Access Theses & Dissertations

Nickel based superalloys have been developed to perform substantially in industry however as technology develops, the need and desire to increase service temperatures to improve efficiency and performance is pushing the capabilities of these alloys. These aspired requirements entail the research and development of new structural materials that surpass the abilities of nickel alloys. Research in Nb-based alloys is underway as Nb alloys have shown to be a promising alternative with similar density but higher melting temperatures than the Ni alloys. However, because Nb has poor oxidation properties extensive studies are necessary to develop an alloy that can perform as …

A Study Of Wo3 And W0.95ti0.05o3 Thin Films Using Comparative Spectroscopy, James Heyward Howard

Open Access Theses & Dissertations

Tungsten oxide (WO3) is important and well-studied in materials science, particularly for sensor applications. In this research work, we consider the innovation of adding Ti to thin films of this material. Since the characteristics of any such material are strongly dependent on the conditions and methods used in its deposition, the main objective of this project is to provide a detailed spectroscopic characterization by Raman scattering, infrared absorption, and X-ray photoelectron spectroscopy (XPS) of WO3 and of W0.95Ti0.05O3. This characterization will be based on comparison of the morphology and composition of WO3-based thin films, grown by radio frequency magnetron reactive …

Development Of Nanocomposites For Energy Storage Devices, Md Ashiqur Rahaman Khan

Open Access Theses & Dissertations

With the ever-increasing need in improving the performance and operation life of future mobile devices, developing higher power density energy storage devices has been receiving more attention. Lithium ion battery (LIB) and capacitor are two of the most widely used energy storage devices and have attracted increasing interest from both industrial and academic fields. Batteries have higher power density than capacitor but significantly longer charge/discharge rates. In order to further improve the performance of these energy storage devices, one of the approaches is to use high specific surface area nano-materials. Among all the nano-materials developed so far, one-dimensional nanowires are …

Nanoprobe I-V Characterization Of Cdte/Cds Micro And Nano-Patterned Solar Cells, Heber Prieto

Open Access Theses & Dissertations

This thesis presents a novel way to characterize micro and nano patterned cadmium telluride thin film solar cells via a nano-probe system. A historical review of CdTe-based solar cells is presented first followed by review of the technology developed to produce the patterned CdTe cells. A detailed presentation is then provided on the use of a Zyvex nanoprobing system to characterize the patterned solar cells. The I-V response of micro- and nano-patterned solar cells stimulated under different e-beam conditions is presented and analyzed. Suggestions of how to improve the technique are provided. This work documents, for the first time, the …

The Influence Of Build Parameters On The Microstructure During Electron Beam Melting Of Ti6al4v, Karina Puebla

Open Access Theses & Dissertations

With the demand of devices to replace or improve areas, such as: electronic, biomedical and aerospace industries. Improvements in these areas of engineering have been in need due to the customer’s needs for product properties requirements. The design of components must exhibit better material properties (mechanical or biocompatible) close to those of any given product. Rapid prototyping (RP) technologies that were originally designed to build prototypes may now be required to build functional end-use products. To carry out the transition, from RP to rapid manufacturing (RM), the available materials utilized in RP must provide the performance required for RM. The …

Oxidation Of Borides And Carbides With Y2o3 And Ta Additions, Salvador Manuel Rodriguez

Open Access Theses & Dissertations

The study presented here describes an investigation of an oxidation scale of a fully-sintered Y2O3-ZrB2-TiC composite exposed in air at 1173K. Upon oxidation of the boride/carbide, a ZrO2-TiO2 was expected to form similar to the ZrO2-SiO2 dual scale of an oxidized ZrB2-SiC. The 47wt% Y2O3-38wt%ZrB2-16wt%TiC composite formed a dual scale consisting primarily of an Y2O3-ZrO2-TiC inner scale with an outer scale of ZrO2-TiO2-Y2O3.

The samples oxidized with a parabolic layer growth allowing the calculation of the effective diffusion coefficient indicating that the oxidation was controlled by oxygen ingress through primarily the ZrO2-Y2O3 phase. The oxygen potential between the inner layer …

Extreme Strain Localization And Sliding Friction In Physically Associating Polymer Gels, Kendra Erk, Jeffrey D. Martin, Y. Thomas Hu, Kenneth R. Shull

School of Materials Engineering Faculty Publications

Model physically associating gels deformed in shear over a wide range of reduced rates displayed evidence of strain localization. The non-linear stress responses and inhomogeneous velocity profiles observed during shear rheometry coupled with particle tracking velocimetry were associated with the occurrence of rate-dependent, banding and fracture-like responses in the gel. Scaling law analysis from traditional sliding friction studies suggests that at the molecular level, deformation is confined to a shear zone with thickness comparable to the gel’s mesh size, the smallest structurally relevant length scale in the gel.

Shear And Dilational Interfacial Rheology Of Surfactant-Stabilized Droplets, Kendra Erk, Jeffrey D. Martin, Jonathan T. Schwalbe, Frederick R. Phelan Jr., Steven D. Hudson

School of Materials Engineering Faculty Publications

A new measurement method is suggested that is capable of probing the shear and dilational interfacial rheological responses of small droplets, those of size comparable to real emulsion applications. Freely suspended aqueous droplets containing surfactant and non-surface-active tracer particles are transported through a rectangular microchannel by the plane Poiseuille flow of the continuous oil phase. Optical microscopy and high-speed imaging record the shape and internal circulation dynamics of the droplets. Measured circulation velocities are coupled with theoretical descriptions of the droplet dynamics in order to determine the viscous (Boussinesq) and elastic (Marangoni) interfacial effects. A new Marangoni-induced stagnation point is …

Multiscale Simulation Of Laser Ablation And Processing Of Semiconductor Materials, Lalit Shokeen

Electronic Theses and Dissertations

We present a model of laser-solid interactions in silicon based on an empirical potential developed under conditions of strong electronic excitations. The parameters of the interatomic potential depends on the temperature of the electronic subsystem Te, which is directly related to the density of the electron-hole pairs and hence the number of broken bonds. We analyze the dynamics of this potential as a function of electronic temperature Te and lattice temperature Tion. The potential predicts phonon spectra in good agreement with finite-temperature densityfunctional theory, including the lattice instability induced by the high electronic excitations. For 25fs pulse, a wide range …

Microstructure And Mechanical Properties Of Cold Drawn Steel Wires, Ning Liu

Theses: Doctorates and Masters

Cold drawn eutectoid steel wires have been widely used for a variety of applications, such as suspension bridges, steel cords for automobile tires, and springs. Much research has been done to increase their mechanical strength. With advances in modern production technology, both the drawing speed and the quality of drawn steels have been enhanced. After a careful literature survey, it is obvious that some issues are still controversial. As Y.S. Yang, J.G. Bae and C.G. Park mentioned, the lamellar spacing, thickness and volume fraction of cementites have all reached the nanometer regime, and the conventional theory is not enough to …

Novel Design Of Functionalized Carbon Nanotube Electrodes And Membranes For Fuel Cells And Energy Storage, Xin Su

Theses and Dissertations--Chemical and Materials Engineering

A novel electrochemical method to generate nm-scale bubbles at the tips of CNTs can temporarily block the membrane. A 92% blocking efficiency is achieved when the bubbles are stabilized in 30-60 nm diameter „wells‟ at the tips of CNTs. This well is formed by the electrochemical oxidation of the conductive CNTs partially into the polymer matrix of the membrane. Meanwhile, the nanoscale bubbles can be removed with 0.004 atm pressure to recover the transport through the CNT membrane. The CNT membrane with nanoscale bubble valve system was used to demonstrate electrochemical energy storage.

Uniform ultrathin Pt films were electrodeposited onto …

Nanoparticle Additives For Multiphase Systems: Synthesis, Formulation And Characterization, Vinod Kanniah

Theses and Dissertations--Chemical and Materials Engineering

Study on nanoparticle additives in multiphase systems (liquid, polymer) are of immense interest in developing new product applications. Critical challenges for nanoparticle additives include their synthesis, formulation and characterization. These challenges are addressed in three application areas: nanofluids for engine lubrication, ultrathin nanocomposites for optical devices, and nanoparticle size distribution characterization.

Nanoparticle additives in oligomer mixtures can be used to develop extended temperature range motor oils. A model system includes poly(α-olefin) based oligomers with a modest fraction of poly(dimethylsiloxane) oligomers along with graphite as nanoparticle additive. Partition coefficients of each oligomer are determined since the oligomer mixture phase separated at …

Understanding Degradation And Lithium Diffusion In Lithium Ion Battery Electrodes, Juchuan Li

Theses and Dissertations--Chemical and Materials Engineering

Lithium-ion batteries with higher capacity and longer cycle life than that available today are required as secondary energy sources for a wide range of emerging applications. In particular, the cycling performance of several candidate materials for lithium-ion battery electrodes is insufficient because of the fast capacity fading and short cycle life, which is mainly a result of mechanical degradation.

This dissertation mainly focuses on the issue of mechanical degradation in advanced lithium-ion battery electrodes. Thin films of tin electrodes were studied where we observed whisker growth as a result of electrochemical cycling. These whiskers bring safety concerns because they may …

Finite Element Analysis Of The Contact Deformation Of Piezoelectric Materials, Ming Liu

Theses and Dissertations--Chemical and Materials Engineering

Piezoelectric materials in the forms of both bulk and thin-film have been widely used as actuators and sensors due to their electromechanical coupling. The characterization of piezoelectric materials plays an important role in determining device performance and reliability. Instrumented indentation is a promising method for probing mechanical as well as electrical properties of piezoelectric materials.

The use of instrumented indentation to characterize the properties of piezoelectric materials requires analytical relations. Finite element methods are used to analyze the indentation of piezoelectric materials under different mechanical and electrical boundary conditions.

For indentation of a piezoelectric half space, a three-dimensional finite element …

Investigation Into The Usability Of Micromechanical Models To Predict The Behavior Of A Nanocomposite Polymer, Jason Handlogten

All Graduate Theses, Dissertations, and Other Capstone Projects

The purpose of this thesis was to determine the acceptability of a set of existing nanocomposite test specimens for tensile testing and then to determine the Young's and shear modulus of these test specimens. If the test specimens were found to be acceptable, the accuracy of three micromechanical models was to be evaluated by comparing their predictions to the mechanical properties determined from testing the specimens. The set of existing nanocomposite test specimens had a distinct concave shape on two surfaces that were believed to be intended as flat. In order to determine if they adhered to the Type I …

Role Of Alloy Additions On Strengthening In 17-4 Ph Stainless Steel, Arpana S. Murthy

Doctoral Dissertations

"Alloy modifications by addition of niobium (Nb ), vanadium (V), nitrogen (N) and cobalt (Co) to cast 17-4 PH steel were investigated to determine the effect on mechanical properties. Additions of Nb, V, and N increased the yield strength from 1120 MPa to 1310 MPa while decreased the room temperature charpy V notch (CVN) toughness from 20 J to four Joules. The addition of Co to cast 17-4 PH steel enhanced the yield strength and CVN toughness from 1140 MPa to 1290 MPa and from 3.7 J to 5.5 J, respectively. In the base 17-4 PH steel, an increase in …

Hollow Hydroxyapatite Microspheres As Devices For Controlled Delivery Of Proteins And As Scaffolds For Tissue Engineering, Hailuo Fu

Doctoral Dissertations

"Hollow HA microspheres were prepared by converting Li₂O-CaO-B₂O₃ glass microspheres in a K₂HPO₄ solution. Process parameters, such as reaction temperature (25°C-60°C) and concentration of the phosphate solution (0.02-0.25 M) significantly influenced the microstructure of the hollow HA microspheres. Microspheres with the largest hollow core size were obtained at lower temperature or with low K₂HPO₄ concentration. In comparison, microspheres with high surface area (~140 m²/g) were obtained at higher K₂HPO₄ concentration (0.25 M). Upon heat treatment (up to 900°C), the surface area of the hollow HA microspheres decreased (from ~100 m²/g to ~2 m²/g), and the rupture strength increased (from ~11 …