Open Access. Powered by Scholars. Published by Universities.®

Materials Science and Engineering Commons™

Open Access. Powered by Scholars. Published by Universities.®

2011

Discipline
Institution
Keyword
Publication
Publication Type
File Type

Articles 241 - 270 of 373

Full-Text Articles in Materials Science and Engineering

Research On Coupled Human And Natural Systems (Chans): Approach, Challenges, And Strategies, Marina Alberti, Heidi Asbjornsen, Lawrence A. Baker, Nicholas Brozović, Laurie E. Drinkwater, Scott A. Drzyzga, Claire A. Jantz, José Fragoso, Daniel S. Holland, Timothy A. Kohler, Jianguo Liu, William J. Mcconnell, Herbert D. G. Maschner, James D. A. Millington, Michael Monticino, Guillermo Podestá, Robert Gilmore Pontius Jr., Charles L. Redman, Nicholas J. Reo, David J. Sailor, Gerald Urquhart Apr 2011

Research On Coupled Human And Natural Systems (Chans): Approach, Challenges, And Strategies, Marina Alberti, Heidi Asbjornsen, Lawrence A. Baker, Nicholas Brozović, Laurie E. Drinkwater, Scott A. Drzyzga, Claire A. Jantz, José Fragoso, Daniel S. Holland, Timothy A. Kohler, Jianguo Liu, William J. Mcconnell, Herbert D. G. Maschner, James D. A. Millington, Michael Monticino, Guillermo Podestá, Robert Gilmore Pontius Jr., Charles L. Redman, Nicholas J. Reo, David J. Sailor, Gerald Urquhart

Mechanical and Materials Engineering Faculty Publications and Presentations

Understanding the complexity of human–nature interactions is central to the quest for both human well-being and global sustainability. To build an understanding of these interactions, scientists, planners, resource managers, policy makers, and communities increasingly are collaborating across wide-ranging disciplines and knowledge domains. Scientists and others are generating new integrated knowledge on top of their requisite specialized knowledge to understand complex systems in order to solve pressing environmental and social problems (e.g., Carpenter et al. 2009). One approach to this sort of integration, bringing together detailed knowledge of various disciplines (e.g., social, economic, biological, and geophysical), has become known as the …

Go to article

Experimental Investigation Of Natural Fiber Reinforced Composite, Irene Samy Fahim Apr 2011

Experimental Investigation Of Natural Fiber Reinforced Composite, Irene Samy Fahim

Theses and Dissertations

There is a growing use of polymers in different applications worldwide. This phenomenon resulted in an enormous increase in the amount of plastic waste. These wastes have significant impacts on the environment including pollution and depletion of resources. Recycling plastic waste and reusing it helps in alleviating environmental degradation. The amount of recycled plastics all over the world not utilized is huge. U.S.A recycled 5.7% of the total plastics generated and Western Europe recycled 39% of total amount of plastics consumed [1]. This research studies the potential usage of virgin and recycled polymer reinforced with natural fiber such as rice …

Go to article

Circuit Design For Sensor Detection Signal Conditioner Nitrate Content, Robeth Viktoria Manurung, Aminuddin Debataraja, Hiskia Hiskia Apr 2011

Circuit Design For Sensor Detection Signal Conditioner Nitrate Content, Robeth Viktoria Manurung, Aminuddin Debataraja, Hiskia Hiskia

Makara Journal of Technology

Circuit Design for Sensor Detection Signal Conditioner Nitrate Content. Nitrate is one of macro nutrients very important for agriculture. The availability of nitrate in soil is limited because it is very easy to leaching by rain, therefore nitrate could be contaminated ground water by over-process of fertilizer. This process could also produce inefficiency in agriculture if it happened continuesly without pre-analysis of farm field. The answer those problems, it is need to develop the ion sensor system to measure concentrations of nitrat in soil. The system is consist of nitrate ion sensor device, signal conditioning and data acquisition circuit. The …

Go to article

Production Of Lovastatin And Sulochrin By Aspergillus Terreus Using Solid State Fermentation, Rizna Triana Dewi, Nina Artanti, Hani Mulyani, Puspa Dewi Narrij Lotulung, Minarti Minarti Apr 2011

Production Of Lovastatin And Sulochrin By Aspergillus Terreus Using Solid State Fermentation, Rizna Triana Dewi, Nina Artanti, Hani Mulyani, Puspa Dewi Narrij Lotulung, Minarti Minarti

Makara Journal of Technology

Lovastatin is an anti-cholesterol agent that was produced by Aspergillus terreus using solid state fermentation (SSF). During this fermentation process, sulochrin is also produced as an unwanted co-metabolite. However, our previous result showed that sulochrin had potential as antidiabetes because it is an inhibitor agent of α-glucosidase. In this paper, we reported our observation on lovastatin and sulochrin production pattern in relation with inhibitor α-glucosidase activity during eleven days fermentation of A. terreus koji (SSF) ethyl acetate extract. Koji obtained from solid state fermentation with rice as the substrate and incubated at room temperature, sample is taken daily for eleven …

Go to article

The Zonation Of Abration Speed Characteristics And Its Handling Technique Of Jalinbar Of North Bengkulu As Vital Band Transportation, Suwarsono Suwarsono, Supiyati Supiyati, Suwardi Suwardi Apr 2011

The Zonation Of Abration Speed Characteristics And Its Handling Technique Of Jalinbar Of North Bengkulu As Vital Band Transportation, Suwarsono Suwarsono, Supiyati Supiyati, Suwardi Suwardi

Makara Journal of Technology

The Zonation of Abration Speed Characteristics and its Handling Technique of Jalinbar of North Bengkulu as Vital Band Transportation. Jalinbar Bengkulu is a vital infrastructure for traffic service, goods, agriculture products, mining, plantation and oils distribution. Abration due to scour of seawater often make these roads jammed and discrupts the peoples economy movement. The aims of this research was to investigate the abration speed of all segment of Jalinbar. The research method was a combination of two methods: A determination of swash energy of sea water using photometer and determination of rocks binding energy using douche method. The result shows …

Go to article

The Formation Design Of Noise Reducers From Plywood, Foam, Tray, Dan Coconut Fiber For Static Sources, Melati Ferianita Fachrul, Wisnu Eka Yulyanto, Asharani Merya Apr 2011

The Formation Design Of Noise Reducers From Plywood, Foam, Tray, Dan Coconut Fiber For Static Sources, Melati Ferianita Fachrul, Wisnu Eka Yulyanto, Asharani Merya

Makara Journal of Technology

The Formation Design of Noise Reducers from Plywood, Foam, Tray, dan Coconut Fiber for Static Sources. Research was conducted in a semi-anechoic room using a method referring to the ISO 3745. The design used is the Hemisphere in which the source of noise is analogous to engines in an industry. The value reduction in the rate of sound power is obtained by comparing the sound power level before and after control is given. The noise control test materials used consist of layers of plywood, foam, fiber and tray (egg box). The effectiveness of these materials is tested by measuring the …

Go to article

A Least Squares Closure Approximation For Liquid Crystalline Polymers, Traci Ann Sievenpiper Apr 2011

A Least Squares Closure Approximation For Liquid Crystalline Polymers, Traci Ann Sievenpiper

Mathematics & Statistics Theses & Dissertations

An introduction to existing closure schemes for the Doi-Hess kinetic theory of liquid crystalline polymers is provided. A new closure scheme is devised based on a least squares fit of a linear combination of the Doi, Tsuji-Rey, Hinch-Leal I, and Hinch-Leal II closure schemes. The orientation tensor and rate-of-strain tensor are fit separately using data generated from the kinetic solution of the Smoluchowski equation. The known behavior of the kinetic solution and existing closure schemes at equilibrium is compared with that of the new closure scheme. The performance of the proposed closure scheme in simple shear flow for a variety …

Go to article

Natural Gas As Petroleum Fuel Substitution: Analysis Of Supply-Demand Projections, Infrastructures, Investments And End-User Prices, Abdul Qoyum Tjandranegara, Arsegianto Arsegianto, Widodo Wahyu Purwanto Apr 2011

Natural Gas As Petroleum Fuel Substitution: Analysis Of Supply-Demand Projections, Infrastructures, Investments And End-User Prices, Abdul Qoyum Tjandranegara, Arsegianto Arsegianto, Widodo Wahyu Purwanto

Makara Journal of Technology

The petroleum fuels (PF) subsidy has long burdens the government spending, and discourages less expensive energy usage such as natural gas (NG). Exporting NG and importing the more expensive PF products cause financial losses to Indonesia. The lack of NG infrastructure is the main hurdle in maximizing domestic NG usage and so does the perception of its high investment costs burdening government spending and pushing the NG transportation cost up. This study calculates the required NG infrastructure and its investments for several levels of PF substitutions up to 2030. To balance the NG demands, the supply from each field and …

Go to article

The Synergy Of Recombinant Xylanolytic Enzyme On Xylan Hydrolysis, One Asmarani, Bambang Prajogo Eko Wardojo, Ni Nyoman Tri Puspaningsih Apr 2011

The Synergy Of Recombinant Xylanolytic Enzyme On Xylan Hydrolysis, One Asmarani, Bambang Prajogo Eko Wardojo, Ni Nyoman Tri Puspaningsih

Makara Journal of Technology

Microbial xylanases or xylanolytic enzyme have received considerable attention over the last years owing to a multitude of possible applications. These enzymes have potential in the biodegradation of lignocellulosic biomass to fuels, chemicals, fruit juice, animal feed and in improving rumen digestion. More recently, the use of xylanases as bleaching agent in the pulp and paper industry has been suggested to replace of some of the chemicals presently used for this purpose. Such applications could have an important positive impact on the environment. The purpose of this research was determining the synergy of 3 recombinant xylanolytic enzymes (β-xylosidase, exo-xylanase and …

Go to article

Cradle To Gate Simple Life Cycle Assessment Of Biodiesel Production In Indonesi, Akhmad Hidayatno, Teuku Yuri M. Zagloel, Widodo Wahyu Purwanto, Carissa Carissa, Lindi Anggraini Apr 2011

Cradle To Gate Simple Life Cycle Assessment Of Biodiesel Production In Indonesi, Akhmad Hidayatno, Teuku Yuri M. Zagloel, Widodo Wahyu Purwanto, Carissa Carissa, Lindi Anggraini

Makara Journal of Technology

The focus of this research is to analyze potential environmental impact in the supply chain of palm oil biodiesel industries. Simple Life Cycle Assessment (LCA) is applied to analyze impacts, produced by the three main units in the supply chain of Palm-Oil-based Biodiesel, which are Palm Plantation, CPO mill, and Biodiesel Plant. We developed LCA calculation model using spreadsheet software, used to assess a number of input scenarios to evaluate the best scenario, in variation of: land quality, land area and the rate of clearing, land clearing technique and type of the original land. The biggest potential environmental impact is …

Go to article

Characterization Of Surface Active Shell Charcoal Nyamplung Seeds (Calophyllum Inophyllum Linn), Santiyo Wibowo, Wasrin Syafi, Gustan Pari Apr 2011

Characterization Of Surface Active Shell Charcoal Nyamplung Seeds (Calophyllum Inophyllum Linn), Santiyo Wibowo, Wasrin Syafi, Gustan Pari

Makara Journal of Technology

Characterization of Surface Active Shell Charcoal Nyamplung Seeds (Calophyllum inophyllum Linn). Chemical and physical activation of nyamplung shell with 0%, 5%, and 10% H3PO4 for 60 and 120 minutes has been carried out to prepare activated charcoal. The purpose of this experiment was to look into the characteristic of nyamplung shell activated charcoal surface. Nyamplung shell was carbonized into charcoal, then activated by immersion in H3PO4 solution using 0%, 5% and 10%, for 24 hours, and heated in retort at two temperatures (700 and 800 oC) and two duration (60 and 120 minutes). The material were characterized by fourier transform …

Go to article

An Investigation Into The Resistance/Powering And Seakeeping Characteristics Of River Catamaran And Trimarana, Murdijanto Murdijanto, I Ketut Aria Pria Utama, Andi Jamaluddin Apr 2011

An Investigation Into The Resistance/Powering And Seakeeping Characteristics Of River Catamaran And Trimarana, Murdijanto Murdijanto, I Ketut Aria Pria Utama, Andi Jamaluddin

Makara Journal of Technology

The increase of fuel price has caused fleet operational and shipping business to be in danger situation. The fuel consumption of a ship is influenced by ship volume or wetted area which contributes directly to the increase of ship resistance and the size of main engine. In order to find out the appropriate answers, a series of investigation into river transportation using monohull, catamaran and trimaran types of vessel was carried out. The work focused on the estimation of total resistance and powering as well as seakeeping characteristics and carried out experimentally using tank test and numerically using a ship …

Go to article

Determining The Standard Value Of The Oily Distortion Of Acquisition The Fingerprint Images, Rahmat Syam, Mochamad Hariadi, Mauridhi Hery Purnomo Apr 2011

Determining The Standard Value Of The Oily Distortion Of Acquisition The Fingerprint Images, Rahmat Syam, Mochamad Hariadi, Mauridhi Hery Purnomo

Makara Journal of Technology

Determining the Standard Value of the Oily Distortion of Acquisition the Fingerprint Images. This research describes a novel procedure for determining the standard value of the oily distortion of acquisition the fingerprint images based on the score of clarity and ridge-valley thickness ratio. The fingerprint image is quantized into blocks size 32 x 32 pixels. Inside each block, an orientation line, which perpendicular to the ridge direction, is computed. The center of the block along the ridge direction, a two-dimension (2-D) vector V1 (slanted square) with the pixel size 32 x 13 pixels can be extracted and transformed to a …

Go to article

Are Ieee 754 32-Bit And 64-Bit Binary Floating-Point Accurate Enough?, Bernaridho Hutabarat, I Ketut Eddy Purnama, Mochamad Hariadi, Mauridhi Hery Purnomo Apr 2011

Are Ieee 754 32-Bit And 64-Bit Binary Floating-Point Accurate Enough?, Bernaridho Hutabarat, I Ketut Eddy Purnama, Mochamad Hariadi, Mauridhi Hery Purnomo

Makara Journal of Technology

This paper describes a research toward the accuracy of floating-point values, and effort to reveal the real accuracy. The methods used in this research paper are assignment of values, assignment of value of arithmetic expressions, and output the values using floating-point value format that helps reveal the accuracy. The programming-tool used are Visual C# 9, Visual C++ 9, Java 5, and Visual BASIC 9. These tools run on top of Intel 80 x 86 hardware. The results show that 1*10-x cannot be accurately represented, and the approximate accuracy ranges only from 7 to 16 decimal digits.

Go to article

Ergonomic Analysis Of Garment Industry Using Posture Evaluation Index (Pei) In Virtual Environment, Erlinda Muslim, Boy Nurtjahyo, Romadhani Ardi Apr 2011

Ergonomic Analysis Of Garment Industry Using Posture Evaluation Index (Pei) In Virtual Environment, Erlinda Muslim, Boy Nurtjahyo, Romadhani Ardi

Makara Journal of Technology

Ergonomic Analysis of Garment Industry using Posture Evaluation Index (PEI) in Virtual Environment. This research tried to study, in a virtual environment, the ergonomics of four divisions in garment industry: cutting division, sewing division, button division, and finishing division. Variables that influence the working conditions in each division are different; depend on the real situations that happened. The purpose is to assess the real working conditions based on ergonomics study using Posture Evaluation Index (PEI). PEI integrates the scores of low back analysis (LBA), ovako working posture (OWAS), and rapid upper limb assessment (RULA). Analysis phase was done using digital …

Go to article

Formation Of Caco3 Particle And Conductivity Of Na2co3 And Cacl2 Solution Under Magnetic Field On Dynamic Fluid System, Nelson Saksono, Setijo Bismo, Roekmijati Widaningroem, Azwar Manaf Apr 2011

Formation Of Caco3 Particle And Conductivity Of Na2co3 And Cacl2 Solution Under Magnetic Field On Dynamic Fluid System, Nelson Saksono, Setijo Bismo, Roekmijati Widaningroem, Azwar Manaf

Makara Journal of Technology

Hard water causes the CaCO3 scale formation on the pipe walls and heat exchanger equipments in industrial or domestic water processes. A great number of experimental researches on the prevention of the CaCO3 precipitation process by magnetic field have been carried out. In this research, Na2CO3 and CaCl2 solutions was magnetized in the circulated flow condition (dynamic fluid system). The velocity of fluid and the circulation time was modified to examine its influences to the magnetization process. CaCO3 content was measured by titration method of EDTA complexometry. Conductivity test was conducted to find out hydrate ion bonding. The results showed …

Go to article

Two-Class Classification With Various Characteristics Based On Kernel Principal Component Analysis And Support Vector Machines, Ivanna Kristianti Timotius, Iwan Setyawan, Andreas Ardian Febrianto Apr 2011

Two-Class Classification With Various Characteristics Based On Kernel Principal Component Analysis And Support Vector Machines, Ivanna Kristianti Timotius, Iwan Setyawan, Andreas Ardian Febrianto

Makara Journal of Technology

Two class pattern classification problems appeared in many applications. In some applications, the characteristic of the members in a class is dissimilar. This paper proposed a classification system for this problem. The proposed system was developed based on the combination of kernel principal component analysis (KPCA) and support vector machines (SVMs). This system has been implemented in a two class face recognition problem. The average of the classification rate in this face image classification is 82.5%.

Go to article

Batio3–Srtio3 Layered Dielectrics For Energy Storage, Sheng Chao, Fatih Dogan Mar 2011

Batio3–Srtio3 Layered Dielectrics For Energy Storage, Sheng Chao, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

BaTiO3–SrTiO3 (BST) thick films (~ 250–390 μm) with layered structures were fabricated by tape-casting and lamination process. Layered composites with various Ba/Sr ratios were obtained by lamination of BaTiO3 (BT) and SrTiO3 (ST) tapes in different spatial configurations (2–2). As-prepared BST ceramics showed much improved sinterability over the laminates of pure BT or pure ST tapes. Dielectric properties of materials were measured in the temperature range of 25 °C to 200 °C. The method of utilizing of layered structures offered flexibility to maximize the energy storage capability at specific operating conditions: (temperature and electric field) …

Go to article

Interfacial Effects On Droplet Dynamics In Poiseuille Flow, Kendra Erk, Jonathan T. Schwalbe, Frederick R. Phelan Jr., Petia M. Vlahovska, Steven D. Hudson Mar 2011

Interfacial Effects On Droplet Dynamics In Poiseuille Flow, Kendra Erk, Jonathan T. Schwalbe, Frederick R. Phelan Jr., Petia M. Vlahovska, Steven D. Hudson

School of Materials Engineering Faculty Publications

Many properties of emulsions arise from interfacial rheology, but a theoretical understanding of the effect of interfacial viscosities on droplet dynamics is lacking. Here we report such a theory, relating to isolated spherical drops in a Poiseuille flow. Stokes flow is assumed in the bulk phases, and a jump in hydrodynamic stress at the interface is balanced by Marangoni and surface viscous forces according to the Boussinesq–Scriven constitutive law. Our model employs a linear equation of state for the surfactant. Our analysis predicts slip, cross-stream migration and droplet-circulation velocities. These results and the corresponding interfacial parameters are separable: e.g., cross-stream …

Go to article

Memristive Properties Of Thin Film Cuprous Oxide, Brett C. Castle Mar 2011

Memristive Properties Of Thin Film Cuprous Oxide, Brett C. Castle

Theses and Dissertations

Memristive properties of thin film copper oxides with different grain sizes were characterized using tunneling atomic force microscopy (TUNA) and optical reflection measurements. The thin films containing copper ions of different chemical states were prepared by thermal oxidation of metallic copper thin films, deposited via magnetron sputtering onto silicon wafer substrates at an elevated temperature for various lengths of time. The TUNA measurements showed a memristive hysteresis in the I-V curves under an applied bias profile with an initial bias of -3.5V, a ramp up to 3.5V, and subsequent return to -3.5V. Histogram analysis of the barrier height distribution for …

Go to article

Electromagnetic Modeling And Measurement Of Adaptive Metamaterial Structural Elements, Matthew E. Jussaume Mar 2011

Electromagnetic Modeling And Measurement Of Adaptive Metamaterial Structural Elements, Matthew E. Jussaume

Theses and Dissertations

This document addresses two major obstacles facing metamaterial development: uncertainty in the characterization of electromagnetic field behavior in metamaterial structures and the relatively small operational bandwidth of metamaterial structures. To address the first obstacle, a method of prediction aided measurement is developed and exploited to examine the field interactions within metamaterial devices. The fusion of simulation and measurement techniques enhances the understanding of the physical interactions of fields in the presence of metamaterials. To address the second obstacle, this document characterizes the effectiveness of an adaptive metamaterial design that incorporates a microelectromechanical systems (MEMS) variable capacitor. Applying voltages to the …

Go to article

An Analytical Model Of Nanometer Scale Viscoelastic Properties Of Polymer Surfaces Measured Using An Atomic Force Microscope, Jacob B. Goldberg Mar 2011

An Analytical Model Of Nanometer Scale Viscoelastic Properties Of Polymer Surfaces Measured Using An Atomic Force Microscope, Jacob B. Goldberg

Theses and Dissertations

The United States Air Force and the Department of Defense is increasingly interested in nanomaterials. To study these materials, one needs to measure the mechanics of materials on the nanoscale. Over the past few decades the atomic force microscope (AFM) has been used in various methods to establish local surface properties at the nanoscale. In particular, surface elasticity measurements are crucial to understanding nanoscale surface properties. Problems arise, however, when measuring soft surfaces such as polymers and biological specimens, because these materials have a more complex viscoelastic response. This research focuses on modeling an AFM dynamic nanoindentation experiment intended to …

Go to article

Rheological Characteristics Of Solvent Free Nanofluids: Thermal Transitions And Reactive Curing, Daniel Chojnowski Mar 2011

Rheological Characteristics Of Solvent Free Nanofluids: Thermal Transitions And Reactive Curing, Daniel Chojnowski

Master's Theses and Doctoral Dissertations

Solvent-free nanofluids are a new and exciting class of material that evolved to address the limitations of their predecessors, nanocomposites. One of the most exciting aspects of solvent-free nanofluids is the wide range of tools chemists have to build and study them. Understanding how the structure manipulations impact the rheology of the resulting solvent-free nanofluids is essential if solvent-free nanofluids are truly the technology of the future. This work documents the basic rheological parameters, thermal transitions, and curing kinetics of various solvent-free nanofluids synthesized by Zhiming Qiu and Kejian Bian at the Coating Research Institute at Eastern Michigan University.

Go to article

Corrosion-Resistant Glasses For Steel Enamels, Richard K. Brow, Signo Tadeu Dos Reis, Michael L. Koenigstein, Genda Chen Mar 2011

Corrosion-Resistant Glasses For Steel Enamels, Richard K. Brow, Signo Tadeu Dos Reis, Michael L. Koenigstein, Genda Chen

Materials Science and Engineering Faculty Research & Creative Works

A cementitious composite material wherein glass-coated steel rods are positioned in a cementitious matrix. The glass composition for coating the steel reinforcing rods includes between about 33-45 weight percent SiO2, 13.5-19.5 weight percent B2O3, 3.5-4.6 weight percent Al2O3, 4.0-13.5 weight percent K2O, 5.5-15.5 weight percent ZrO2, 8.6-15.9 weight percent Na2O, 4.6-5.1 weight percent CaO, 0.6-0.7 weight percent MnO2, 1.0-1.0 weight percent NiO, and 1.0-1.1 weight percent CoO. The glass composition is typically in compression on the rods at ambient temperatures, has a …

Go to article

Analysis Of Interband, Intraband, And Plasmon Polariton Transitions In Silver Nanoparticle Films Via In Situ Real-Time Spectroscopic Ellipsometry, S. A. Little, R. W. Collins, S. Marsillac Mar 2011

Analysis Of Interband, Intraband, And Plasmon Polariton Transitions In Silver Nanoparticle Films Via In Situ Real-Time Spectroscopic Ellipsometry, S. A. Little, R. W. Collins, S. Marsillac

Electrical & Computer Engineering Faculty Publications

The dielectric function of Ag nanoparticle films, deduced from an analysis of in situ real-time spectroscopic ellipsometry (RTSE) measurements, is found to evolve with time during deposition in close consistency with the film structure, deduced in the same RTSE analysis. In the nucleation regime, the intraband dielectric function component is absent and plasmon polariton behavior dominates. Only at nuclei contact, does the intraband amplitude appear, increasing above zero. Both intraband and plasmon amplitudes coexist during surface smoothening associated with coalescence. The intraband relaxation time increases rapidly after surface smoothening is complete, also in consistency with the thin film structural evolution.

Go to article

Influence Of Electric Field On The Adsorption And Bioactivity Of Hemoglobin On A Macroporous Gold Electrode, Cui-Hong Wang, Yi-Bing Kong, Xing-Hua Xia Feb 2011

Influence Of Electric Field On The Adsorption And Bioactivity Of Hemoglobin On A Macroporous Gold Electrode, Cui-Hong Wang, Yi-Bing Kong, Xing-Hua Xia

Journal of Electrochemistry

The adsorption and bioactivity of proteins at interfaces have been widely studied due to their important role in the construction of biosensors,bioelectronics and biofuel cells.Interfacial electric field is one of the important factors which could affect the adsorption and bioactivity of proteins at materials surfaces.It could dramatically change the adsorption density,molecular conformation and orientation at material surfaces.In this paper,the influence of interfacial electric field on the adsorption kinetics and bioactivity of hemoglobin(Hb) on a three-dimensional(3D) macroporous gold electrode surface has been studied using electrochemical methods and infrared spectroscopy.It was found that the interfacial electric field created excess surface charge which …

Go to article

Prepartion And Characterization Of Spr Au Substrate Using Wet Chemical Plating, You-Chen Zhou, Yan-Yan Wang, Zhi-Fang Ma, Yan-Xia Jiang, Jin Qiu, Shi-Gang Sun Feb 2011

Prepartion And Characterization Of Spr Au Substrate Using Wet Chemical Plating, You-Chen Zhou, Yan-Yan Wang, Zhi-Fang Ma, Yan-Xia Jiang, Jin Qiu, Shi-Gang Sun

Journal of Electrochemistry

The present study developed a preparation method of SPR gold substrate based on water phase operation.Firstly,on the glass modified by APTMS we self-assembed a gold colloid monolayer as the catalyst bed;Secondly,using the chemical plating technique,we made the gold film increase equably within the namometer range to obtain the proper shape and thinkness of the gold film required by the SPR.The analysis results of UV-vis and TEM demonstrated that the diameter of the monolayer formed from gold nanoparticles was 2.5 nm.Moreover,SEM showed that the nanoparticle prepared by electroless gold plating was uniformly distributed,whose diameter was 40 nm.The SPR flow injection experiment …

Go to article

Preparation And Electrochemical Properties Of Sn Thin Film As Anode Materials For Lithium-Ion Batteries, Hong-Mei Bai, Zhan-Liang Tao, Fang-Yi Cheng, Jun Chen Feb 2011

Preparation And Electrochemical Properties Of Sn Thin Film As Anode Materials For Lithium-Ion Batteries, Hong-Mei Bai, Zhan-Liang Tao, Fang-Yi Cheng, Jun Chen

Journal of Electrochemistry

Sn thin films as the anode materials of Li-ion batteries were prepared by vacuum-evaporation method on the copper foam substrate. The phase structure,surface morphology and electrochemical property of the as-prepared films were characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM), and galvanostatic cycling. The results showed that three-dimensional structure of copper foam substrate enhanced the adhesion strength between the active material and the substrate, under the same substrate temperature, the particles became bigger with the increasing of evaporation time, while their electrochemical property decreased, under the same evaporation time, the particles didn′t changed obviously with the increasing of substrate temperature,while their cycle …

Go to article

Synthesis Of Mesoporous Nickel Oxide For Supercapacitor Application, Xuan-Xuan Chen, Zhen-Zhen Zhao, Deng-Chao Wang, Zhong-Jie Huang, Wen-Bin Ni, Li Yu, Jian-Wei Zhao Feb 2011

Synthesis Of Mesoporous Nickel Oxide For Supercapacitor Application, Xuan-Xuan Chen, Zhen-Zhen Zhao, Deng-Chao Wang, Zhong-Jie Huang, Wen-Bin Ni, Li Yu, Jian-Wei Zhao

Journal of Electrochemistry

Mesoporous nickel oxide has been synthesized by calcining metal-organic coordination precursor.Transmission electron microscopy and BET test showed that the prepared NiO had a regular morphology and displayed a narrow size distribution.Electrochemical tests revealed that such mesoporous NiO had a specific capacity of 72 F·g-1 at the current of 2.0 A·g-1.Futhermore,the material showed excellent cycle-life stability.There was no degradation of capacitance after 1000 cycles.

Go to article

A Titanium-Supported Nanoporous Pd Electrocatalyst For Methanol Oxidation, Feng-Juan Niu, Qing-Feng Yi Feb 2011

A Titanium-Supported Nanoporous Pd Electrocatalyst For Methanol Oxidation, Feng-Juan Niu, Qing-Feng Yi

Journal of Electrochemistry

Titanium-supported nanoporous palladium electrode(nanoPd /Ti) was prepared by a hydrothermal process in the presence of the ligand EDTA and using formaldehyde as reducing agent.SEM images showed that the size of Pd particles was about 60 nm and the Pd particles were connected with each other to form a three-dimensional network structure.Cyclic voltammetry(CV) and electrochemical impedance spectroscopy(EIS) were applied to evaluate the electrocatalytic activity of the nanoPd/Ti electrode towards methanol oxidation in alkaline solution.CV results showed that the nanoPd /Ti electrode presented high anodic peak densities and a low onset potential for methanol oxidation.Also nanoPd /Ti electrode showed excellent CO tolerance …

Go to article

First Prev Next Last