Materials Science and Engineering Commons^™

A Maximum Energy Release Rate Computational Framework For Fatigue Crack Trajectory And Life Prediction Under Mixed-Mode Proportional And Nonproportional Loading, Nahla Helmy Matar

Theses and Dissertations

The problem of mixed-mode fatigue crack growth has been a persistent research challenge. The determination of fatigue crack propagation direction directly impacts the safety and integrity of components and structures, making it crucial in various industrial applications, including welded drilling pipes, aerospace, and automotive engineering. Unlike uniaxial loading, mixed-mode cracks tend to change direction frequently (kinking), and nonproportional loading adds to the complexity of the problem. This research aims to estimate the crack propagation direction and fatigue crack life in linear elastic materials subjected to mixed-mode (I+II) loading conditions under proportional or non-proportional cyclic loading. Numerical software was developed based …

The Effect Of Mwcnt-Oil Impregnation Of Sintered Components On Their Wear And Corrosion Resistance, Maha Khaled Abdelfadeel

Theses and Dissertations

Powder Metallurgy (PM) offers an advantageous route for manufacturing complex and near net-shape components. Their inherent interconnected porosity that promotes the action of self lubrication compromises their structural integrity by creating pathways for corrosion and excessive wear. This research investigates the efficacy of Multi-Walled Carbon Nanotubes (MWCNTs) as a nano additive within the impregnating base oil (SN-150 base oil). An experimental matrix was designed to evaluate the influence of MWCNTs with different concentrations of 0.05, 0.1, and 0.2 wt.% and ultrasonic dispersion with varying sonication times of 30 and 60 minutes on the tribological and electrochemical performance of sintered steel …

Tuning Ion Mobility And Molecular Confinement In High-Performance Polymer Electrolytes For Energy Storage, Ezzeldien Yousef Muhammed Yousef

Theses and Dissertations

This research addresses the critical energy density limitations of aqueous supercapacitors, which are traditionally constrained by the narrow electrochemical stability window (ESW) of water 1.23 V. By employing two distinct molecular engineering strategies, this study developed high-performance electrolyte systems that significantly extend voltage stability and thermal resilience.

The first system, CsBr@PAM/HA, utilizes a polyacrylamide and hyaluronic acid hydrogel matrix. This system exploits the chaotropic nature of Cs⁺ ions to disrupt the aqueous hydrogen-bonding network, enhancing ionic conductivity to 104 mS cm^-1. Through systematic salt screening, CsBr was identified as the optimal electrolyte, enabling a stable 2.0 V …

Engineering Nanoelectrocatalytic Systems For Co2 And Nitrate Conversion Into Value-Added Chemicals, Abdelrahman Mohamed Abdelmohsen

Theses and Dissertations

The thesis addresses two major related environmental crises: nitrate pollution of water systems and the ever-increasing levels of atmospheric carbon dioxide. Both challenges are closely linked to anthropogenic disturbance of nitrogen and carbon cycles and require sustainable, energy efficient mitigation techniques. In this study, we investigate electrochemical conversion routes as a unified approach to convert these pollutants into value-added compounds: ammonia (NH3) via nitrate reduction (NO3-RR) and ethylene (C2H4) via carbon dioxide reduction (CO2RR). The first half of this work deals with the design and engineering of Cu-Zn alloy electrocatalysts for efficient NO3-RR. Tuning the alloy composition and surface nanostructure …

Moon Adaptive Technology For Extraterrestrial Architectural Robotics (Matear), Candela Noemi Solis Zampini

Theses and Dissertations

The Moon Adaptive Technology for Extraterrestrial Architectural Robotics (MATEAR) focuses on the development of an autonomous robotic system capable of providing structural building blocks directly from lunar regolith. As a sustained human presence on the Moon becomes a necessity, the costly and limited payload capacity associated with transporting construction goods from Earth creates a critical challenge. MATEAR addresses this problem through in-situ resource utilization (ISRU), integrating a regolith processing system onto a remote operated vehicle. The proposed system is designed to collect lunar dust, mechanically compact the material, and apply thermal treatment to enhance cohesion through sintering. These regolith-made bricks …

Development Of A Novel Innovative Umbrella Falsework System For Concrete Slabs, Abdelazem Hashim

Theses and Dissertations

Formwork is one of the major elements that contribute to the cost and duration of concrete building projects. This is why optimizing such an element can lead to huge savings to all parties involved in the construction projects. With contractors facing huge challenges in such a competitive industry and employers seeking the least price and least duration for their projects, contractors are constantly under the obligations of finding the best alternatives to deliver their projects in terms of both time and money. Therefore, the main aim of this research project is to develop a falsework system, where the falsework system …

Metal-Free Nitrogen-Enriched Graphitic Carbon Nitride Architectures For Advanced Supercapacitor Energy Storage: Design, Synthesis, And Electrochemical Performance Optimization, Loujain Gamal Mohamed

Theses and Dissertations

Abstract

This thesis addresses the urgent global requirement for efficient energy storage materials by developing and characterizing advanced graphitic carbon nitride (g-C3N4)-based electrode materials for supercapacitors. A facile, low-cost thermal polymerization method produces 2D nitrogen-rich GCN nanosheets exhibiting excellent electrochemical stability and wide voltage windows, enabling symmetric devices with 19.33 Wh/kg energy density and remarkable cycling stability over 21,000 cycles. To overcome intrinsic limitations of pristine GCN, a 3D/2D metal free composite with bio-derived carbon (Bio-Cx) is synthesized, delivering high capacitance, wide potential windows, and ultrahigh energy density of 53.72 Wh/kg in asymmetric configurations paired with mesoporous nitrogen-doped carbon (MPNDC). …

Fly Ash Proppant Developed For Hydraulic Fracturing, Raz Rzgar Haydar

Theses and Dissertations

Proppants are critical components in hydraulic fracturing, used to maintain fracture conductivity and enhance reservoir stimulation. In high-pressure and harsh reservoir environments, the use of high-strength proppants is essential to ensure well performance. Conventional proppants, being sand, ceramic, and sintered bauxite can be expensive, and their use often requires costly fracture fluids. This study investigates the possibility of utalizing fly ash geopolymers as a sustainable alternative that is also cost-effective for proppants manufacturing. Fly ash, a by-product from the combustion of coal and other materials, was explored as a base material for proppants, utilizing an alkaline solution as an activator …

Contours Of Duration: Movement Authored Through Form—A Behavior Archive, Jood Senussi Elbeshti

Theses and Dissertations

Insect anatomy offers an elegant example of motion derived from structure. Inspired by insect movement, Contours of Duration employs a cam-and-follower system consisting of moving, leg-like parts, designed to engage a series of rotating cams, such that the shape of each cam’s surface activates the legs in unique ways, generating repetitive movement, and demonstrating how geometry produces distinct motion behaviors over time. Through iterative experimentation and controlled variation, trace emerges as a central methodology, whereby movement, over time, creates a distinct pattern of marks, making motion legible and reflecting how subtle changes to surface and form generate different behavioral outcomes. …

Modeling Of Laser-Produced Plasma Plumes: Expansion, Chemistry, And Thin-Film Deposition, Edmund Tsiri Semaha, Edmund Tsiri Semaha

Theses and Dissertations

Abstract

Laser-assisted material processing involves coupled plasma expansion, chemical reactions, and particle transport that govern the quality of thin-film deposition. This dissertation presents a comprehensive computational investigation of these processes using the OpenFOAM framework. First, the performance of the twoPhaseEulerFoam (tPEF), rhoCentralFoam (rCF), and sonicFoam (sF) solvers is evaluated for modeling laser-produced plasma plume expansion under atmospheric conditions, demonstrating that tPEF accurately captures shock-wave propagation, hydrodynamic behavior, and multispecies interactions. Building on this validation, the reactingFoam (rF) solver is employed to investigate the chemistry of aluminum plasma expanding into an air environment (Al–N₂–O₂). The model incorporates appropriate thermodynamic, transport, and …

Nanomagnet Based Reservoir Computing And Quantum Control, Fahim F. Chowdhury

Theses and Dissertations

Conventional CMOS scaling has driven remarkable advances in computing but faces increasing physical and energy constraints, motivating alternative computing paradigms that integrate memory and computation while improving energy efficiency. Nanoscale magnetic systems offer a promising platform for such approaches because their intrinsic nonlinear dynamics and localized magnetic fields can support both classical and quantum information processing. This thesis investigates nanomagnetic systems for physical reservoir computing and, with primary emphasis, for localized quantum control of spin qubits.

The first part explores dipole-coupled nanomagnet arrays as physical reservoirs. Micromagnetic simulations demonstrate nonlinear dynamical behavior with high short-term memory and parity-check capacity, enabling …

Fused Filament Fabrication Additive Manufacturing Of 17-4 Ph Stainless Steel: Process–Structure–Property Relationships In Magnetic Materials, Maanav Patel

Theses and Dissertations

Additive manufacturing (AM) enables the fabrication of complex metallic components through layer-by-layer processing directly from digital models. Among AM techniques, material extrusion–based processes such as fused filament fabrication (FFF) provide an accessible method for producing metal parts using filament feedstocks composed of metal powders and polymer binders. When applied to precipitation-hardening stainless steels such as 17-4 PH, the processing route and heat treatments can influence the resulting microstructure and functional properties. This work investigates the magnetic behavior of 17-4 PH stainless steel fabricated using FFF and evaluates how heat treatment conditions influence measured magnetic properties. Samples were produced and analyzed …

Development And Testing Of A Prototype Erbium-Doped Lithium Tantalate Based Sensor For Infrastructure Crack Detection And Measurement, Alejandro Barrera

Theses and Dissertations

Ensuring the safety and longevity of infrastructure is crucial to safeguarding communities and preserving economic stability. In this study, the development of a novel sensor for detecting and characterizing cracks in infrastructure, particularly suited for deployment on Unmanned Aerial Vehicles (UAVs), is presented. The device utilizes a laser (operating at 980 nm) for excitation of erbium-doped lithium tantalate nanoparticles that emit 1550 nm wavelength, which stimulates a photodiode for data collection. The data was utilized to collect, process, and reconstruct topological information. The synthesized lithium tantalate nanoparticle samples vary in erbium doping percentages of 0.5%, 3%, and 10%. Experimental evaluation …

Tensile Creep Of A Hybrid Polymer-Matrix/Ceramic-Matrix Composite At Elevated Temperature, Waleed S. Alshehri

Theses and Dissertations

Advanced aerospace systems require structural materials that can perform reliably in high-temperature environments for long durations. The performance of standard polymer matrix composites (PMCs) in these conditions is often limited by their susceptibility to time-dependent deformation, such as creep. The objective of this research is to characterize the high-temperature creep behavior of a novel unitized material system comprising a polymer matrix composite (PMC) and a ceramic matrix composite (CMC) co-cured together. The PMC part consists of the polyimide matrix reinforced with laminated carbon fibers woven in an eight harness satin weave (8HSW). The CMC part consists of a zirconia-based ceramic …

Magnetic Molecularly Imprinted Polymers For Quercetin Adsorption: Fabrication, Characterization, And Application, Vinitha Ug

Theses and Dissertations

A highly selective Magnetic Molecularly Imprinted Polymer (MMIP) was developed for the detection and purification of Quercetin. The Density Functional Theory was utilized for the selection of suitable monomers based on binding energy interaction between quercetin and monomers (Acrylamide, Acrylonitrile, Methacrylic Acid). From computational studies, Acrylamide was selected as a suitable monomer for the synthesis of MMIP. Under ultrasound irradiation both quercetin and naringin imprinted materials MMIP-Q and MMIP-N were fabricated.

Compared to ultrasound-assisted synthesis, Microwave Synthesis provides uniform heat transfer throughout the reaction solution, which enables uniformity in the size of synthesised material, increases the yield of material and …

Fabrication Of Transparent Conducting Electrodes By Chemical Approaches & Their Application Towards Sensing And Energy Storage, Namuni Sneha

Theses and Dissertations

In the intelligent era, there is a growing demand for developing highly efficient and robust wearable electrodes through simple chemical approaches. We developed highperforming transparent electrodes using interconnected Au nanoparticle networks via a simple liquid-liquid interface approach that offers high conductivity, transparency (>85%), and mechanical durability. Additionally, the prepared electrodes exhibit tunable transmittance and sheet resistance, and the method was also adaptable to various substrates without harsh chemical or thermal treatments.

Furthermore, using Au 1L (1-layer) nanonetwork, a highly transparent breath sensor is fabricated with short response and recovery times (1.1 s and 1.3 s). The Au-1L sensor is …

Development Of Powder Activator From Agro-Industrial Waste And Its Application In The Preparation Of One-Part Alkali Activated Concrete, Anoop Kn

Theses and Dissertations

The environmental concerns associated with the traditional ordinary Portland cement (OPC) such as CO2 emission and high energy demand along with resource depletion as binder has led to the development of alkali activated binders (AABs). Even with the reduction in environmental issues, the implementation of AAB in practice is hindered by the handling issues of liquid activators. Hence, it is required to develop AAB with powdered activators to address the handling issues and to further reduce the environmental issues related to the production of activators. This research investigates the development of one-part alkali-activated concrete (OAAC) system utilising wastederived materials as …

Shape Memory Behavior In Medium To High Entropy Shape Memory Alloys: Design, Prediction, And Experimental Analysis, Hatim Raji

Theses and Dissertations

This dissertation provides a data-driven system integrating synthetic data generation and machine learning (ML) techniques to create multicomponent SMA compositions with specific transformation temperatures (TTs). Models were trained to represent the nonlinear dependencies influencing martensitic transformation behavior by using elemental, thermodynamic, and process-related aspects. The capacity of the ML models on medium entropy NiTiHfPd and high entropy NiTiHfZrCu systems accuracy was confirmed by experimental validation showing TTs closely matched with model outputs.

Development Of A Wearable Biosensor For Cortisol Detection In Human Sweat Utilizing Pani/Peo Polymer Blend And Nitrogen-Doped Graphene Quantum Dots, Cesar Sanchez

Theses and Dissertations

Since the development of the first biosensor in 1962, the evolution of commercially available wearable biosensors has been driven by an increasing consumer interest in real-time health tracking. However, challenges related to sensor sensitivity and cost have hindered progress. Deploying a novel approach, the biosensor integrates a blend of Polyaniline (PANi) and Polyethylene Oxide (PEO) along with Nitrogen-doped Graphene Quantum Dots (N-GQDs) to enhance sensitivity and electroactivity, crucial for cortisol detection. To optimize performance, three distinct synthesis methods for N-GQDs; hydrothermal, microwave, and hot plate synthesis were compared employing a bottom-up approach utilizing citric acid (CA) as the primary reactant …

Magnetically Impelled Arc Butt Welding And Straight Tube Butt Welding Analysis Of Boiler Grade Tube Joints, Santhosh Kumar S

Theses and Dissertations

Boiler-graded tubes of T11, T12, T91, and T92 materials with a thickness of 4.5 mm thick and 44.5 mm outer diameter were selected for the Straight Tube Butt Welding process using Hot Wire (STBW-HW) and Cold Wire (STBW-CW) conditions. Moreover, the research investigates and compares the welding characteristics of dissimilar T11 and T91 boiler-graded tubes using STBW - HW & Magnetically Impelled Arc Butt (MIAB) welding techniques. Similar and dissimilar welding was performed in STBW – HW & CW conditions.

In dissimilar welding, the tensile strength was higher in the T11-T91 STBWHW joints of 663 MPa than in the T12-T92 …

Biogenic Synthesis Of Metallic And Bimetallic Oxide Nanoparticles For Water Treatment Applications, Gunarani G.I

Theses and Dissertations

Access to clean water is a quality-of-life indicator. The availability of clean water apart from water scarcity is marred due to contamination by heavy metals and synthetic dyes, posing a grave environmental and public health challenge. This necessitates the implementation of advanced and sustainable treatment solutions towards water remediation. This research work focusses on the fabrication and application of biogenic and chemically synthesized metallic and bimetallic nanoparticles for the efficient removal of uranium, chromium, and toxic dyes from aqueous environments. The study particularly focuses on zero-valent (C-Fe and B-Fe) and bimetallic (C-NiFe and B-NiFe) nanoparticles, evaluating their adsorption capabilities and …

Porous Geopolymer Composite For Geotechnical Applications, Karla Viviana Sierra Flores

Theses and Dissertations

This research investigates the development of a porous geopolymer cement grout for soil grouting applications, aiming to reduce carbon emissions associated with Portland cement while maintaining critical performance characteristics such as strength and permeability. Class F fly ash and metakaolin were used as aluminosilicate precursors, activated by sodium silicate and sodium hydroxide solutions. The addition of hydrogen peroxide served as a foaming agent to introduce porosity by creating a thermodynamic reaction that releases oxygen gas during mixing. Compressive strength, porosity, and hydraulic conductivity were evaluated, with results showing that metakaolin significantly increased compressive strength due to its smaller particle size …

Development And Tribological Characterization Of Uhmwpe-Tin Composite Coatings Deposited By Electrostatic Spraying, Jarrod Keith Perez

Theses and Dissertations

The increasing demand for inert, wear-resistant, cost-efficient, environmentally friendly, and low-friction coatings has driven extensive research into polymer-based solutions. Among these, ultra-high-molecular-weight polyethylene (UHMWPE) has emerged as a strong candidate due to its low density, anticorrosion properties, self-lubricating nature, affordability, and ease of processing. However, its low load-bearing capacity limits its widespread use in high-stress tribological applications. To overcome this limitation, this project investigates the development and characterization of UHMWPE composite coatings reinforced with titanium nitride (TiN) particles at varying concentrations (2.5, 5, and 10 wt%) to enhance their mechanical properties and wear resistance.

Transfer Efficiencies Of Surface-To-Surface Transport Of Micron-Sized Actinide Surrogate Particles, Austin R. Powell

Theses and Dissertations

Particle effluent of varying sizes is released during routine activities within laboratory environments and these particles can come in contact with a wide range of surfaces. Particles of micron size or smaller can be especially pervasive and can transfer between multiple subsequent surfaces, leading to the progressive contamination of a laboratory. Understanding the transport dynamics of micron sized particles will help inform facility personnel of the possibility of contamination by these potentially hazardous materials of interest. In this research, the transfer efficiency of micron sized surrogate actinide particles (Europium-doped Gadolinium Oxysulfide (EGOS)) is measured for multiple materials, between two particle …

Improvement Of Microcracking And Mechanical Properties Of Tungsten Fabricated Via Laser Powder Bed Fusion Through Alloying With Reactive Secondary Constituents, William S. Mockel

Theses and Dissertations

Tungsten (W), a Group VI transition metal, possesses a number of advantageous properties, most notably its impressive mechanical performance at extreme temperatures. While tungsten's nature render traditional manufacturing methods difficult, additive manufacturing through laser powder bed fusion (LPBF) presents a promising avenue for fabricating tungsten components. However, the material’s high ductile-to-brittle transition temperature combined with the embrittling effect of impurities mean that the residual stresses imparted by LPBF result in microcracking in tungsten, degrading its usefulness. This study sought to improve the characteristics of LPBF-W through the removal of embrittling oxygen content via alloying with low concentrations of reactive elements, …

Material Classification With Spectropolarimetric Lidar, Alexander J. Watson

Theses and Dissertations

A method for characterizing unknown targets using a hyperspectral polarimetric light detection and ranging (LiDAR) system is presented. Light reflected from manmade objects tends to be more polarized than light reflected from objects in the natural world. As such, polarization measurements can be used in remote sensing applications to differentiate artificial and natural objects. Previous works have attempted to characterize objects through passive polarimetric imagery. Methods developed by Cain and Lemaster and Cunningham facilitate reconstruction of the Stokes Vector from returning light. Martin used multispectral polarimetry to classify targets when the angle of incidence (AOI) is close to 0º. Here, …

Fatigue Behaviour Of Al 6063 Alloy In Heat Treated, Deep Cryogenic Treated And Equal Channel Angular Pressing (Ecap) Processed Conditions, Sreearravind M

Theses and Dissertations

This research focuses on improving the Low Cycle Fatigue (LCF) life of Al6063 using three different processing techniques – Heat Treatment (HT), Deep Cryogenic Treatment (DCT), and Equal Channel Angular Pressing (ECAP). Al 6063, widely used in structural applications, has limited fatigue performance, necessitating the exploration of advanced processing techniques to enhance its LCF life.

In HT phase, Al 6063 T5 samples were subjected to solid solution HT followed by air and water quenching. The air-quenched (T6A) and water-quenched (T6W) samples were subjected to precipitation hardening. The Ultimate Tensile Strength (UTS) of the T6A sample increased to 188 MPa from …

Determining The Limitations Of Class F Fly Ash Compared To Class G Cement In Hydrocarbon Wells Application, Youssef Helmy

Theses and Dissertations

Cement is a material commonly used in multiple applications in different industries. Among the industries that uses cement is the oil and gas industry. API (American Petroleum Institute) Class G cement that is the most incorporated form of cement used in the cementation of oil and gas wells to provide several forms of protection and stabilization for the casings. However, Class G cement is contested in terms of efficiency, costs, and environmental awareness against Class F fly ash geopolymers by researchers. This research aims to explore the potential limitations that fly ash geopolymer might have for its use in the …

Partial Replacement Of Ordinary Portland Cement In Concrete By Limestone Calcined Clay (Lc2), Merna Abdelaziz

Theses and Dissertations

Limestone calcined clay (LC2) technique is a new approach that could address the environmental problem corelated with the construction industry due to its vital reliance on the ordinary Portland cement in its various applications. LC2 technique involves partial replacement of the OPC in concrete by limestone and calcined kaolinite clay with a ratio of 1:2 respectively. The main advantage of this technique is its high applicability due to its direct application on site. This study investigated the applicability of incorporating the LC2 technique in the construction industry. Three replacement percentages of OPC by LC2 in concrete were explored, which are …

A Fault-Tolerant Exchange-Coupled Spin-Ensemble Qubit At Elevated-Temperatures, Aniruddha Chakraborty

Theses and Dissertations

This thesis introduces a novel qubit architecture: the ferromagnetic exchange-coupled spin ensemble qubit (E-qubit), designed to address the noise-induced instability. In this work, the time evolution of the ensemble’s density matrix is studied using the Liouville–von Neumann equation. To benchmark against a single-spin qubit, the gate fidelity of an E-qubit is computed in the presence of thermal noise. Coherence time is also analyzed under identical thermal condition and a linear scaling is observed with qubit size . The results show that, at 6 K , the gate fidelity error (0.7 % ) of the seven- spin ensemble is an order …