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Materials Science and Engineering Faculty Research & Creative Works

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Full-Text Articles in Materials Science and Engineering

Method Of Making Highly Sinterable Lanthanum Chromite Powder, Von Richards, Subhash C. Singhal Jan 1992

Method Of Making Highly Sinterable Lanthanum Chromite Powder, Von Richards, Subhash C. Singhal

Materials Science and Engineering Faculty Research & Creative Works

A highly sinterable powder consisting essentially of LaCrO.sub.3, containing from 5 weight % to 20 weight % of a chromite of dopant Ca, Sr, Co, Ba, or Mg and a coating of a chromate of dopant Ca, Sr, Co, Ba, or Mg; is made by (1) forming a solution of La, Cr, and dopant; (2) heating their solutions; (3) forming a combined solution having a desired ratio of La, Cr, and dopant and heating to reduce solvent; (4) forming a foamed mass under vacuum; (5) burning off organic components and forming a charred material; (6) grinding the charred material; (7) …

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Sol-Gel Derived, Air-Baked Indium And Tin Oxide Films, Douglas M. Mattox Sep 1991

Sol-Gel Derived, Air-Baked Indium And Tin Oxide Films, Douglas M. Mattox

Materials Science and Engineering Faculty Research & Creative Works

A sol-gel derived, transparent, electrically conducting tin-doped In2O3 film system has been developed which only requires air baking. The films approximate the properties of sputtered and hot-sprayed films but are simpler and less expensive to apply by dipping and spinning procedures. Substrate sodium interference was seen to be minimal. © 1991.

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Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt Aug 1991

Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

A method for preparing nonradioactive microspheres adapted for radiation synovectomy of arthritic joints in a mammal involves forming the microspheres by doping a biodegradable glass material which may be lithium or potassium silicate, lithium or potassium aluminosilicate, lithium or potassium aluminoborate, lithium or potassium germanate or lithium or potassium alumino- germanate with an isotope which may be samarium, holmium, erbium, dysprosium, rhemium or yttrium so that the isotope is chemcially dissolved in and distributed uniformly throughout the glass material. The doped glass material is then treated with an acid wash to produce a thin layer on the surface thereof and …

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Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt Apr 1991

Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

Radioactive microspheres for radiation synovectomy of arthritic joints in a mammal comprises a biodegradable glass material and a beta radiation emitting radioisotope chemically dissolved in and distributed substantially uniformly throughout the glass material. The biodegradable glass material may be lithium silicate, lithium aluminosilicate, lithium aluminoborate, lithium germa- nate, lithium aluminogermanate, potassium silicate, potassium aluminosilicate, potassium aluminoborate, potassium germanate or potassium aluminogermanate and the beta radiation emitting radioisotope may be samarium-153, holmium-166, erbium-169, dysprosium-165, rhenium-186, rhenium-188 or yttrium-90. Method for preparing such microspheres and for carrying out radiation synovectomy of arthritic joints utilizing such microspheres are also disclosed.

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Radioactive Glass Microspheres, D. E. Day, Gary J. Ehrhardt Apr 1991

Radioactive Glass Microspheres, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

A radioactive microsphere for radiation therapy of a mammal comprising a biologically compatible glass material containing a beta or gamma emitting radioisotope distributed substantially uniformly throughout the glass. Advantageously, the radioisotope is produced by irradiation of the microsphere.

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Phase Separation In Glasses, N. J. Kreidl Mar 1991

Phase Separation In Glasses, N. J. Kreidl

Materials Science and Engineering Faculty Research & Creative Works

The detection, acceptance and further investigation of glass-glass phase separation was closely connected with the development of methods making detection possible, such as electron microscope technique pioneered and exploited by Werner Vogel, to whom this paper is dedicated on the occasion of his 65th birthday. Structures are not always found in agreement with rules derived from thermodynamic principles, and also depend on thermal history, as well as mode of preparation. The phenomenon is exemplified in many glass-forming systems. Among more recent applications are the control of crystallization by preceding phase separation as in glass-ceramics and semiconductor-doped glasses for non-linear optics. …

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Compensation Modes In Counterdoped Rutile, M. M. Nasrallah, Harlan U. Anderson Jan 1991

Compensation Modes In Counterdoped Rutile, M. M. Nasrallah, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

Thermogravimetric measurements were conducted on undoped, Nb5+ or Ta5+ donor-doped, and Al3+ acceptor doped rutile at 1000°C and 105-10-7 Pa oxygen activity. Nb5+ or Ta5+ doped rutile was counter doped by Al3+ in order to identify the role of Al3+ acceptor and its effect on donor doped rutile. Our results show that both dopants enter the lattice substitutionally for Ti4+, that Al3+ is as effective an acceptor as Nb5+ or that Ta5+ is effective as a donor, and the compensation occurs on a one-to-one basis. Earlier reports indicate …

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Electrical Conductivity, Seebeck Coefficient And Defect Chemistry Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, Don M. Sparlin, M. M. Nasrallah Jan 1991

Electrical Conductivity, Seebeck Coefficient And Defect Chemistry Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, Don M. Sparlin, M. M. Nasrallah

Materials Science and Engineering Faculty Research & Creative Works

The electrical transport behavior and defect structure of Ca-doped YCrO3 were studied using electrical conductivity and Seebeck coefficient measurements as a function of oxygen activity and temperature. Defect models derived from the electrical conductivity data were found to adequately relate the concentration of charge carriers to the acceptor dopant and oxygen vacancy concentrations. Thermodynamic properties were calculated and found to be consistent with the model. Activation energy and carrier mobility data were also obtained. The analysis of the electrical conductivity, Seebeck and mobility data suggest that the conduction process in Ca-doped YCrO3 occurs via the small polaron hopping …

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Synthesis And Characterization Of Barium Lanthanum Titanates, Jyoti P. Guha Jan 1991

Synthesis And Characterization Of Barium Lanthanum Titanates, Jyoti P. Guha

Materials Science and Engineering Faculty Research & Creative Works

Ternary compounds in the system BaO—TiO2—La2O3 were prepared by the solid‐state reaction technique at temperatures between 1300° and 1400°C using precursor oxides as the starting materials. In an alternative processing technique, BaTiO3 was reacted with appropriate proportions of prefabricated lanthanum titanates at 1350°C to obtain the compounds. Two compounds were identified in the TiO2‐rich region of the system. The X‐ray powder diffraction pattern of a compound with a chemical composition BaLa2Ti3O10 (BaO·La2O3·3TiO2) is indexed on the basis of an orthorhombic unit …

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Positron Study Of Defects And Diffusion Induced Grain Boundary Migration In A Pb-Sn System, A. Belaidi, Hollis P. Leighly, H. Aourag, B. Khelifa, M. Oubadi, A. Elias Jan 1991

Positron Study Of Defects And Diffusion Induced Grain Boundary Migration In A Pb-Sn System, A. Belaidi, Hollis P. Leighly, H. Aourag, B. Khelifa, M. Oubadi, A. Elias

Materials Science and Engineering Faculty Research & Creative Works

The Pb-Sn system discloses a remarkable effect at the intermediate α → α + β phase boundary. The observation of the sharp transient peak in the S-parameter curve which is analogous to those found in thermal capacity curves is, as far as the authors are aware, unique in such positron measurements. This effect is interpreted in terms of positron trapping in defects associated with the strains accompanying the initial stage of transformation. This short note offers a new approach to the underlying phenomenon published in J. Phys. F. Met. Phys., 12 (1982) 813 by A. Belaidi, H. P. Leighly Jr. …

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Defect Structure, Nonstoichiometry, And Phase Stability Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, M. M. Nasrallah, Don M. Sparlin Jan 1991

Defect Structure, Nonstoichiometry, And Phase Stability Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, M. M. Nasrallah, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

The dependence of the defect structure of Ca-doped YCrO3 on oxygen activity and temperature was investigated by high temperature thermogravimetric measurements. Defect models developed from electrical conductivity data obtained in a previous study were used to interpret the thermogravimetric data. A correlation was found between the electrical conductivity and the thermogravimetric data which suggested that these data were concomitantly dependent on the acceptor dopant and oxygen vacancy dependance of the thermodynamic parameters. Kröger-Vink type diagrams showing the regions of stability with respect to oxygen activity and temperature were constructed. The TGA data show that Ca-doped YCrO3 is even …

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Fracture Toughening Of High Pressure Sintered Diamond And Carbide Ceramics, P. D. Ownby Nov 1990

Fracture Toughening Of High Pressure Sintered Diamond And Carbide Ceramics, P. D. Ownby

Materials Science and Engineering Faculty Research & Creative Works

High pressure sintered bodies of polycrystalline diamond or carbide ceramics are rendered more resistant to cracking by establishing dispersed, localized "stress centers" of submicron size particles of lonsdaleite, diamond, or other form of metastable, high density carbon which has the capability of transforming crystallographically to graphite in situ in the body. When an incipient crack in the body approaches entrapped metastable particles along its path, the crack promotes or permits transformation of the metastable particles to graphite particles, with concomitant increase in their size, thereby resisting further propagation of the crack.

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Recent Applications Of Glass Science, Norbert J. Kreidl Aug 1990

Recent Applications Of Glass Science, Norbert J. Kreidl

Materials Science and Engineering Faculty Research & Creative Works

Recent, often exciting, applications of glass science include solid state batteries, electronic switches and memories, electrophotography, solar cells, microspheres for optical strengthening and medical uses, novel glass ceramics such as machinable and bioactive materials, solder glasses, composites, sol-gel glasses, gradient index optics, communication fibers, sensors, non-linear and active optics, and, perhaps, digital optics. The large field of special coatings is not covered in this review. © 1990.

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Electrochemical Evaluation Of Copper Deposition With Gas Sparging, D. A. Uceda, Thomas J. O'Keefe Mar 1990

Electrochemical Evaluation Of Copper Deposition With Gas Sparging, D. A. Uceda, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

The influence of gas sparging during copper electrolysis was studied using standard electrochemical techniques. The polarization behavior of acid copper electrolytes was determined in the presence and absence of gas sparging on vertical electrodes. Tracer ion techniques were employed to determine the effect of gas sparging and forced circulation of the electrolyte on the mass transfer characteristics of the system. In addition to the potentiodynamic scans, 3-h copper deposits were produced for morphology and orientation studies. The effect of current density and temperature on deposition were also studied. The polarization experiments have shown that a mass transfer component becomes evident …

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The Effects Of Lead On The Electrochemical And Adhesion Behavior Of Zinc Electrodeposits, Vijay Srinivasan, J. Sami Cuzmar, Thomas J. O'Keefe Feb 1990

The Effects Of Lead On The Electrochemical And Adhesion Behavior Of Zinc Electrodeposits, Vijay Srinivasan, J. Sami Cuzmar, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

The presence of excessive lead in zinc sulfate electrolytes can lead to problems related to both processing efficiency and the properties of the metal produced. For example, poor adhesion can occur in electrogalvanized steel when it is heated in the temperature range of 215 °C to 280 °C if lead is present in the deposit. The duration of heating necessary to induce the peeling of the zinc was found to be dependent on the temperature, time, and concentration of lead in the electrolyte and the plating parameters. The presence of lead slowed the formation of the intermetallic, and the peeling …

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Design Considerations For 1-3 Composites Used In Transducers For Medical Ultrasonic Imaging, Wayne Huebner, Kuiming Liang, Clyde G. Oakley Jan 1990

Design Considerations For 1-3 Composites Used In Transducers For Medical Ultrasonic Imaging, Wayne Huebner, Kuiming Liang, Clyde G. Oakley

Materials Science and Engineering Faculty Research & Creative Works

Ceramic polymer piezoelectric composites with 1-3 connectivity have become an important tool in the design and manufacture of thickness-mode transducers for medical diagnostic ultrasonic imaging. The authors compare annular array transducers made from ceramics alone to those made with these composites to demonstrate the advantages of composites. They examine some of the trade-offs involved in optimizing composite designs for this application. The effects of varying Young's modulus and Poisson's ratio of the polymer phase on the coupling coefficient and high-frequency lateral resonances of the composite are presented

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Comments On The Papers By Kê And Su, Hollis P. Leighly Jan 1990

Comments On The Papers By Kê And Su, Hollis P. Leighly

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3: Defect Structure, Electrical Conductivity, And Thermoelectric Power, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin Jan 1990

Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3: Defect Structure, Electrical Conductivity, And Thermoelectric Power, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Seebeck coefficient and electrical conductivity measurements were performed for undoped and Sr-doped LaMnO3 as a function of temperature and oxygen partial pressure. The results of electrical conductivity showed typical p-type behavior. As reduction proceeded, the electrical conductivity of these LaMnO3-based perovskites decreased with P 1 4O2. The analysis of the electrical conductivity data was performed by extending the defect model from a previous thermogravimetric (TG) study. The measured Seebeck coefficients were found to be positive except for the most reducing conditions when the decomposition into multiple phases occurred. The Heikes formula was adopted to interpret …

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Mass-Transfer Measurements Of Copper Deposition In A Fluosilicate Electrolyte, D. Uceda, Thomas J. O'Keefe, E. Cole Jan 1990

Mass-Transfer Measurements Of Copper Deposition In A Fluosilicate Electrolyte, D. Uceda, Thomas J. O'Keefe, E. Cole

Materials Science and Engineering Faculty Research & Creative Works

The electrodeposition of copper from a fluosilicate electrolyte has been investigated by electrochemical techniques, x-ray diffraction, and scanning electron microscopy. The diffusion coefficient of cupric ion in a fluosilicate solution has been determined with the aid of a rotating disk electrode using the mixed control Levich equation. Gold (Au+3) was used as a tracer to evaluate the mass transport properties of the system. The polarization behavior of the electrolyte was measured in the presence and absence of gas sparging on a vertical stationary electrode to study the effect of the mass transport contribution. Sound copper deposits were obtained …

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Production Of Thin Copper Foils On Microporous Titanium Oxide Substrates, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand Jan 1990

Production Of Thin Copper Foils On Microporous Titanium Oxide Substrates, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand

Materials Science and Engineering Faculty Research & Creative Works

This study deals with the electrochemical production of thin (35 μm) copper films on anodized titanium substrates. The formation of a microporous oxide layer on the titanium electrodes greatly enhances the surface density of copper nuclei during a potentiostatic experiment so that a complete coverage of the cathode surfaces may be obtained after short term (20 s) polarization. Moreover, the oxide film may act as a parting agent and the copper films may be easily stripped from their substrates. The higher the pore density of the oxide film, the higher the surface density of nuclei and the easier the foil's …

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Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt Dec 1989

Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

Radioactive microspheres for radiation synovectomy of arithmetic joints in a mammal comprise a biodegradable glass material and a beta radiation emitting radioisotope chemically dissolved in and distributed substantially uniformly throughout the glass material. The biodegradable glass material may be lithium silicate, lithium aluminosilicate, lithium aluminoborate, lithium germa- nate, lithium aluminogermanate, potassium silicate, potassium aluminosilicate, potassium, aluminoborate, potassium germanate or potassium aluminogermanate and the beta radiation emitting radioisotope may be samarium-153, holmium-166, erbium-169, dysprosium-165, rhenium-186, rhenium-188 or yttrium-90. Methods for preparing such microspheres and for carrying out radiation synovectomy of arthritic joints utilizing such microspheres are also disclosed.

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Structural Characteristics Of Sr1-Xlaxti 3+Δ As A Function Of Oxygen Partial Pressure At 1400°C, S. A. Howard, J. K. Yau, Harlan U. Anderson Dec 1989

Structural Characteristics Of Sr1-Xlaxti 3+Δ As A Function Of Oxygen Partial Pressure At 1400°C, S. A. Howard, J. K. Yau, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The structural characteristics of Sr1-x Lax TiO3+δ (0≤x≤0.4) at 1400°C have been investigated as a function of ambient oxygen partial pressure. A modified Rietveld pattern-fitting structure-refinement program [H. M. Rietveld, J. Appl. Crystallogr. 2, 65 (1969)] was used to determine the nature of the distortions of the fundamental perovskite unit cell, the degree of lattice perfection, and the cation vacancy concentrations. Specimens equilibrated in forming gas displayed a linear relation between x, the lattice parameters, and the degree of lattice perfection while those samples annealed in air and oxygen deviated significantly from linearity. A monoclinic distortion of …

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Evaluation Of Mass Transport In Copper And Zinc Electrodeposition Using Tracer Methods, H. M. Wang, S. F. Chen, Thomas J. O'Keefe, M. Degrez, R. Winand Mar 1989

Evaluation Of Mass Transport In Copper And Zinc Electrodeposition Using Tracer Methods, H. M. Wang, S. F. Chen, Thomas J. O'Keefe, M. Degrez, R. Winand

Materials Science and Engineering Faculty Research & Creative Works

Control of the electro crystallization process is essential in the deposition of metals from aqueous electrolytes. A knowledge of the influence of mass transfer on the metal ion reduction is a critical element in any number of electrolytic processes, particularly where relatively high current densities are desired. The use of more positive ion tracer techniques as a means of experimentally determining some of the mass transport properties of interest are described. Examples for copper, zinc and zinc alloys electrolysis are included. © 1989 Chapman and Hall Ltd.

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Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3 Nonstoichiometry And Defect Structure, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin Jan 1989

Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3 Nonstoichiometry And Defect Structure, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Undoped and Sr-doped LaMnO3 showed reversible oxidation-reduction behavior. These perovskites can be excess, stoichiometric or deficient in oxygen content depending on the specific conditions. Under very reducing conditions decomposition into new phases occurs. Phase stabilities for these oxides were determined. The results showed that Sr doping caused the LaMnO3 to dissociate at higher oxygen activities than those necessary for undoped LaMnO3. Defect models are proposed to interpret the thermogravimetric results in which metal vacancies are assumed for the oxygen excess condition and oxygen vacancies are assumed for the oxygen deficient condition. Thermodynamic properties were calculated which …

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Nucleation Of Electrodeposited Copper On Anodized Titanium, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand Jan 1989

Nucleation Of Electrodeposited Copper On Anodized Titanium, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand

Materials Science and Engineering Faculty Research & Creative Works

A study has been made to determine the effect of an electrochemically produced titanium-oxide film on the nucleation of copper. The oxide films were made galvanostatically at 25°C in 1 M sulphuric acid on pure titanium metal. Potentiodynamic, potential step and current step experiments were performed in an additive-free copper sulphate-sulphuric acid electrolyte at 25°C. It was found that the oxide film played an important role during nucleation. By increasing the thickness of the anodic film, it was possible to decrease the diameter and to increase the surface density of copper nuclei. The kinetics of nucleation and growth of the …

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Effect Of Volatilization On The Conduction Behavior Of Acceptor‐Doped Chromium Oxide, Rong‐Fong ‐F Huang, Harlan U. Anderson Jan 1989

Effect Of Volatilization On The Conduction Behavior Of Acceptor‐Doped Chromium Oxide, Rong‐Fong ‐F Huang, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The effect of volatilization on the conduction behavior of Li‐ or Mg‐doped Cr2O3 was studied. The Po2 dependence on conduction changed from 1/4 to 3/8 when volatilization occurred. The high‐temperature conduction mechanism of Cr2O3 may be dominated by the formation of Cr vacancies due to the volatilization effect. Copyright © 1989, Wiley Blackwell. All rights reserved

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High-Temperature Defect Structure Of Nb-Doped Lacro3, Chikung J. Yu, Harlan U. Anderson, Don M. Sparlin Jan 1989

High-Temperature Defect Structure Of Nb-Doped Lacro3, Chikung J. Yu, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Electrical conductivity and Seebeck measurements on LaCr0.98Nb0.02CrO3 show that the defect structure of the material is mainly controlled by the extrinsic electrons formed by the Nb donors through the electronic compensation process. The experimental results also indicate that this material conducts electricity via a small polaron mechanism with an electron mobility around 0.004-0.01 cm2/V sec between 1100 and 1300°C. © 1989.

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Glass Microspheres, D. E. Day, Gary J. Ehrhardt Dec 1988

Glass Microspheres, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

A radioactive microsphere for radiation therapy of a mammal comprising a biologically compatible glass material containing a beta or gamma emitting radioisotope distributed substantially uniformly throughout the glass. Advantageously, the radioisotope is produced by irradiation of the microsphere.

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Anomalous Temperature Dependence Of The Electric Field Gradient At The Y Site In In₀.₁Y₀.₉Ba₂Cu₃O9- Δ, Gary L. Catchen, Michael Blaszkiewicz, Anthony Baratta, Wayne Huebner Aug 1988

Anomalous Temperature Dependence Of The Electric Field Gradient At The Y Site In In₀.₁Y₀.₉Ba₂Cu₃O9- Δ, Gary L. Catchen, Michael Blaszkiewicz, Anthony Baratta, Wayne Huebner

Materials Science and Engineering Faculty Research & Creative Works

Perturbed angular correlation (PAC) spectroscopy has been used to measure a well-defined static electric quadrupole interaction in a superconducting ceramic, In0.1Y0.9Ba2Cu3O9-δ. Perturbation functions, Fourier transforms, and the derived PAC parameters are given for data taken at temperatures ranging from 77 to 1070 K. Indirect evidence is presented for the occupation of the Y site by the 111In-111Cd PAC probe. The derived electric field gradients were found to increase linearly with temperature. This result suggests the presence of soft, anisotropic vibrations in the structure. Additional evidence is presented …

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Structural Characterization Of A High-Temperature, Ionic Conducting Ceramic Using Perturbed Angular Correlation Spectroscopy, Gary L. Catchen, Michael Blaszkiewicz, Khalid Jamil, Dinesh K. Agrawal, Wayne Huebner, Herbert A. Mckinstry, Lorenz H. Menke Jr. Apr 1988

Structural Characterization Of A High-Temperature, Ionic Conducting Ceramic Using Perturbed Angular Correlation Spectroscopy, Gary L. Catchen, Michael Blaszkiewicz, Khalid Jamil, Dinesh K. Agrawal, Wayne Huebner, Herbert A. Mckinstry, Lorenz H. Menke Jr.

Materials Science and Engineering Faculty Research & Creative Works

Perturbed angular correlation (PAC) spectroscopy has been used to characterize several structural aspects of a high-temperature, ionic conducting ceramic, CaZr3.95Hf0.05P6O24. Hafnium was introduced into the material to provide the PAC probe nuclei, 181Hf/181Ta, which were located primarily at Zr sites. PAC measurements were made over a range of temperatures from 77 to 1180 K, and they have been analyzed and interpreted using several simple models. The distorted octahedral crystal field at the Zr site produced a (low-frequency) static electric quadrupole interaction which can be accurately described by the point-charge model. But, the temperature dependence of the associated electric field gradient …

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