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Full-Text Articles in Materials Science and Engineering

Review Of P-Type Doped Perovskite Materials For Sofc And Other Applications, Harlan U. Anderson Jan 1992

Review Of P-Type Doped Perovskite Materials For Sofc And Other Applications, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

p-type perovskite-type oxides are candidates for use as components of high temperature fuel cells and as oxygen separation membranes. The particular properties that these applications require are reviewed. The characteristics that these oxides have which allow them to satisfy many of these requirements are discussed and a defect model presented. The status of the utilization of these oxides and of the areas which need to be addressed such as thermal expansion and sintering characteristics are reviewed. © 1992.

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Effect Of Cation Substitution On The Thermal Expansion Coefficient Of Lacro3, R. Koc, Harlan U. Anderson Jan 1992

Effect Of Cation Substitution On The Thermal Expansion Coefficient Of Lacro3, R. Koc, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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Tensile Fatigue Behaviour Of Tightly Woven Carbon/Carbon Composites, A. Ozturk, Robert E. Moore Jan 1992

Tensile Fatigue Behaviour Of Tightly Woven Carbon/Carbon Composites, A. Ozturk, Robert E. Moore

Materials Science and Engineering Faculty Research & Creative Works

The tensile fatigue behavior of a tightly woven carbon/carbon composite was investigated as a function of stress level. Load-controlled fatigue tests were performed in tension-tension mode with a stress ratio, R, of 0.1 under ambient laboratory conditions. Results of composite behavior are discussed in terms of the relationship of the stress/strain behavior to the fatigue life of these composites as well as the effects of applied stress levels. It is shown that these composites exhibit good resistance to cyclic loading. No fatigue failures were obtained after 106 cycles when the maximum tensile load in the fatigue cycle is less than …

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Electrical Conductivity And Seebeck Coefficient Of (La, Ca) (Cr, Co)O3, R. Koc, Harlan U. Anderson Jan 1992

Electrical Conductivity And Seebeck Coefficient Of (La, Ca) (Cr, Co)O3, R. Koc, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

Electrical conductivity and Seebeck coefficients of (La, Ca) (Cr, Co)O3 were measured as a function of temperature. The electrical conductivity as measured in air from 100 to 1100 °C increased with increasing Co and Ca content. The Seebeck coefficients were positive, indicating p-type conductivity. The substitution of Co for Cr significantly decreased the Seebeck coefficients, indicating that the substitution resulted in an increase in site occupancy, associated with the Co. The additional Ca substitution for La resulted in further decrease in the Seebeck coefficients, then exhibited a temperature-independent behaviour, indicating that the carrier mobility, rather than carrier concentration, was …

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Grain Size Effect On The Induced Piezoelectric Properties Of 0.9pmn-0.1pt Ceramic, U. Kumar, Wayne Huebner, P. Marsh, H. Kankul, S. F. Wang, Clyde G. Oakley Jan 1992

Grain Size Effect On The Induced Piezoelectric Properties Of 0.9pmn-0.1pt Ceramic, U. Kumar, Wayne Huebner, P. Marsh, H. Kankul, S. F. Wang, Clyde G. Oakley

Materials Science and Engineering Faculty Research & Creative Works

Lead magnesium niobate-lead titanate (Pb(Mg1/3Nb2/3)O3 - PbTiO3 (PT) solid solutions have been widely researched to produce devices that can be used in low- and high-electric-field applications. For some applications, such as medical ultrasonic transducers, it is necessary to prepare the ceramic with high density and small average grain size. The effect of grain size on the low- and high-field properties of 0.9-PMN-0.10-PT ceramics is described in the present work. To prepare highly dense ceramic, vibratory and attrition milled powders were sintered between 1000 and 1250 ⁰C. The average grain sizes of the sintered ceramics …

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Method Of Making Highly Sinterable Lanthanum Chromite Powder, Von Richards, Subhash C. Singhal Jan 1992

Method Of Making Highly Sinterable Lanthanum Chromite Powder, Von Richards, Subhash C. Singhal

Materials Science and Engineering Faculty Research & Creative Works

A highly sinterable powder consisting essentially of LaCrO.sub.3, containing from 5 weight % to 20 weight % of a chromite of dopant Ca, Sr, Co, Ba, or Mg and a coating of a chromate of dopant Ca, Sr, Co, Ba, or Mg; is made by (1) forming a solution of La, Cr, and dopant; (2) heating their solutions; (3) forming a combined solution having a desired ratio of La, Cr, and dopant and heating to reduce solvent; (4) forming a foamed mass under vacuum; (5) burning off organic components and forming a charred material; (6) grinding the charred material; (7) …

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Solvent Extraction Reagent Entrainment Effects On Zinc Electrowinning From Waste Oxide Leach Solutions, M. Neira, Thomas J. O'Keefe, Johh L. Watson Jan 1992

Solvent Extraction Reagent Entrainment Effects On Zinc Electrowinning From Waste Oxide Leach Solutions, M. Neira, Thomas J. O'Keefe, Johh L. Watson

Materials Science and Engineering Faculty Research & Creative Works

A considerable quantity of metal-containing waste oxide is generated by the primary metal industry, and under increased environmental regulation, treatment of these wastes has become viable. Hydrometallurgical processing is often appropriate and one potential treatment process for zinc oxide wastes involves leaching the oxide with an acid, purifying by a solvent extraction operation, and recovering metallic zinc by electrowinning the purified leach solution. The purification stage is frequently critical and the introduction of a solvent extraction organic reagent into the flowsheet can be detrimental to downstream processes. The object of this study was to determine the effect of organics, entrained …

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Sol-Gel Derived, Air-Baked Indium And Tin Oxide Films, Douglas M. Mattox Sep 1991

Sol-Gel Derived, Air-Baked Indium And Tin Oxide Films, Douglas M. Mattox

Materials Science and Engineering Faculty Research & Creative Works

A sol-gel derived, transparent, electrically conducting tin-doped In2O3 film system has been developed which only requires air baking. The films approximate the properties of sputtered and hot-sprayed films but are simpler and less expensive to apply by dipping and spinning procedures. Substrate sodium interference was seen to be minimal. © 1991.

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Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt Aug 1991

Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

A method for preparing nonradioactive microspheres adapted for radiation synovectomy of arthritic joints in a mammal involves forming the microspheres by doping a biodegradable glass material which may be lithium or potassium silicate, lithium or potassium aluminosilicate, lithium or potassium aluminoborate, lithium or potassium germanate or lithium or potassium alumino- germanate with an isotope which may be samarium, holmium, erbium, dysprosium, rhemium or yttrium so that the isotope is chemcially dissolved in and distributed uniformly throughout the glass material. The doped glass material is then treated with an acid wash to produce a thin layer on the surface thereof and …

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Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt Apr 1991

Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

Radioactive microspheres for radiation synovectomy of arthritic joints in a mammal comprises a biodegradable glass material and a beta radiation emitting radioisotope chemically dissolved in and distributed substantially uniformly throughout the glass material. The biodegradable glass material may be lithium silicate, lithium aluminosilicate, lithium aluminoborate, lithium germa- nate, lithium aluminogermanate, potassium silicate, potassium aluminosilicate, potassium aluminoborate, potassium germanate or potassium aluminogermanate and the beta radiation emitting radioisotope may be samarium-153, holmium-166, erbium-169, dysprosium-165, rhenium-186, rhenium-188 or yttrium-90. Method for preparing such microspheres and for carrying out radiation synovectomy of arthritic joints utilizing such microspheres are also disclosed.

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Radioactive Glass Microspheres, D. E. Day, Gary J. Ehrhardt Apr 1991

Radioactive Glass Microspheres, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

A radioactive microsphere for radiation therapy of a mammal comprising a biologically compatible glass material containing a beta or gamma emitting radioisotope distributed substantially uniformly throughout the glass. Advantageously, the radioisotope is produced by irradiation of the microsphere.

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Phase Separation In Glasses, N. J. Kreidl Mar 1991

Phase Separation In Glasses, N. J. Kreidl

Materials Science and Engineering Faculty Research & Creative Works

The detection, acceptance and further investigation of glass-glass phase separation was closely connected with the development of methods making detection possible, such as electron microscope technique pioneered and exploited by Werner Vogel, to whom this paper is dedicated on the occasion of his 65th birthday. Structures are not always found in agreement with rules derived from thermodynamic principles, and also depend on thermal history, as well as mode of preparation. The phenomenon is exemplified in many glass-forming systems. Among more recent applications are the control of crystallization by preceding phase separation as in glass-ceramics and semiconductor-doped glasses for non-linear optics. …

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Compensation Modes In Counterdoped Rutile, M. M. Nasrallah, Harlan U. Anderson Jan 1991

Compensation Modes In Counterdoped Rutile, M. M. Nasrallah, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

Thermogravimetric measurements were conducted on undoped, Nb5+ or Ta5+ donor-doped, and Al3+ acceptor doped rutile at 1000°C and 105-10-7 Pa oxygen activity. Nb5+ or Ta5+ doped rutile was counter doped by Al3+ in order to identify the role of Al3+ acceptor and its effect on donor doped rutile. Our results show that both dopants enter the lattice substitutionally for Ti4+, that Al3+ is as effective an acceptor as Nb5+ or that Ta5+ is effective as a donor, and the compensation occurs on a one-to-one basis. Earlier reports indicate …

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Synthesis And Characterization Of Barium Lanthanum Titanates, Jyoti P. Guha Jan 1991

Synthesis And Characterization Of Barium Lanthanum Titanates, Jyoti P. Guha

Materials Science and Engineering Faculty Research & Creative Works

Ternary compounds in the system BaO—TiO2—La2O3 were prepared by the solid‐state reaction technique at temperatures between 1300° and 1400°C using precursor oxides as the starting materials. In an alternative processing technique, BaTiO3 was reacted with appropriate proportions of prefabricated lanthanum titanates at 1350°C to obtain the compounds. Two compounds were identified in the TiO2‐rich region of the system. The X‐ray powder diffraction pattern of a compound with a chemical composition BaLa2Ti3O10 (BaO·La2O3·3TiO2) is indexed on the basis of an orthorhombic unit …

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Defect Structure, Nonstoichiometry, And Phase Stability Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, M. M. Nasrallah, Don M. Sparlin Jan 1991

Defect Structure, Nonstoichiometry, And Phase Stability Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, M. M. Nasrallah, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

The dependence of the defect structure of Ca-doped YCrO3 on oxygen activity and temperature was investigated by high temperature thermogravimetric measurements. Defect models developed from electrical conductivity data obtained in a previous study were used to interpret the thermogravimetric data. A correlation was found between the electrical conductivity and the thermogravimetric data which suggested that these data were concomitantly dependent on the acceptor dopant and oxygen vacancy dependance of the thermodynamic parameters. Kröger-Vink type diagrams showing the regions of stability with respect to oxygen activity and temperature were constructed. The TGA data show that Ca-doped YCrO3 is even …

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Positron Study Of Defects And Diffusion Induced Grain Boundary Migration In A Pb-Sn System, A. Belaidi, Hollis P. Leighly, H. Aourag, B. Khelifa, M. Oubadi, A. Elias Jan 1991

Positron Study Of Defects And Diffusion Induced Grain Boundary Migration In A Pb-Sn System, A. Belaidi, Hollis P. Leighly, H. Aourag, B. Khelifa, M. Oubadi, A. Elias

Materials Science and Engineering Faculty Research & Creative Works

The Pb-Sn system discloses a remarkable effect at the intermediate α → α + β phase boundary. The observation of the sharp transient peak in the S-parameter curve which is analogous to those found in thermal capacity curves is, as far as the authors are aware, unique in such positron measurements. This effect is interpreted in terms of positron trapping in defects associated with the strains accompanying the initial stage of transformation. This short note offers a new approach to the underlying phenomenon published in J. Phys. F. Met. Phys., 12 (1982) 813 by A. Belaidi, H. P. Leighly Jr. …

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Electrical Conductivity, Seebeck Coefficient And Defect Chemistry Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, Don M. Sparlin, M. M. Nasrallah Jan 1991

Electrical Conductivity, Seebeck Coefficient And Defect Chemistry Of Ca-Doped Ycro3, G. F. Carini, Harlan U. Anderson, Don M. Sparlin, M. M. Nasrallah

Materials Science and Engineering Faculty Research & Creative Works

The electrical transport behavior and defect structure of Ca-doped YCrO3 were studied using electrical conductivity and Seebeck coefficient measurements as a function of oxygen activity and temperature. Defect models derived from the electrical conductivity data were found to adequately relate the concentration of charge carriers to the acceptor dopant and oxygen vacancy concentrations. Thermodynamic properties were calculated and found to be consistent with the model. Activation energy and carrier mobility data were also obtained. The analysis of the electrical conductivity, Seebeck and mobility data suggest that the conduction process in Ca-doped YCrO3 occurs via the small polaron hopping …

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Fracture Toughening Of High Pressure Sintered Diamond And Carbide Ceramics, P. D. Ownby Nov 1990

Fracture Toughening Of High Pressure Sintered Diamond And Carbide Ceramics, P. D. Ownby

Materials Science and Engineering Faculty Research & Creative Works

High pressure sintered bodies of polycrystalline diamond or carbide ceramics are rendered more resistant to cracking by establishing dispersed, localized "stress centers" of submicron size particles of lonsdaleite, diamond, or other form of metastable, high density carbon which has the capability of transforming crystallographically to graphite in situ in the body. When an incipient crack in the body approaches entrapped metastable particles along its path, the crack promotes or permits transformation of the metastable particles to graphite particles, with concomitant increase in their size, thereby resisting further propagation of the crack.

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Recent Applications Of Glass Science, Norbert J. Kreidl Aug 1990

Recent Applications Of Glass Science, Norbert J. Kreidl

Materials Science and Engineering Faculty Research & Creative Works

Recent, often exciting, applications of glass science include solid state batteries, electronic switches and memories, electrophotography, solar cells, microspheres for optical strengthening and medical uses, novel glass ceramics such as machinable and bioactive materials, solder glasses, composites, sol-gel glasses, gradient index optics, communication fibers, sensors, non-linear and active optics, and, perhaps, digital optics. The large field of special coatings is not covered in this review. © 1990.

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Electrochemical Evaluation Of Copper Deposition With Gas Sparging, D. A. Uceda, Thomas J. O'Keefe Mar 1990

Electrochemical Evaluation Of Copper Deposition With Gas Sparging, D. A. Uceda, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

The influence of gas sparging during copper electrolysis was studied using standard electrochemical techniques. The polarization behavior of acid copper electrolytes was determined in the presence and absence of gas sparging on vertical electrodes. Tracer ion techniques were employed to determine the effect of gas sparging and forced circulation of the electrolyte on the mass transfer characteristics of the system. In addition to the potentiodynamic scans, 3-h copper deposits were produced for morphology and orientation studies. The effect of current density and temperature on deposition were also studied. The polarization experiments have shown that a mass transfer component becomes evident …

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The Effects Of Lead On The Electrochemical And Adhesion Behavior Of Zinc Electrodeposits, Vijay Srinivasan, J. Sami Cuzmar, Thomas J. O'Keefe Feb 1990

The Effects Of Lead On The Electrochemical And Adhesion Behavior Of Zinc Electrodeposits, Vijay Srinivasan, J. Sami Cuzmar, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

The presence of excessive lead in zinc sulfate electrolytes can lead to problems related to both processing efficiency and the properties of the metal produced. For example, poor adhesion can occur in electrogalvanized steel when it is heated in the temperature range of 215 °C to 280 °C if lead is present in the deposit. The duration of heating necessary to induce the peeling of the zinc was found to be dependent on the temperature, time, and concentration of lead in the electrolyte and the plating parameters. The presence of lead slowed the formation of the intermetallic, and the peeling …

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Comments On The Papers By Kê And Su, Hollis P. Leighly Jan 1990

Comments On The Papers By Kê And Su, Hollis P. Leighly

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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Mass-Transfer Measurements Of Copper Deposition In A Fluosilicate Electrolyte, D. Uceda, Thomas J. O'Keefe, E. Cole Jan 1990

Mass-Transfer Measurements Of Copper Deposition In A Fluosilicate Electrolyte, D. Uceda, Thomas J. O'Keefe, E. Cole

Materials Science and Engineering Faculty Research & Creative Works

The electrodeposition of copper from a fluosilicate electrolyte has been investigated by electrochemical techniques, x-ray diffraction, and scanning electron microscopy. The diffusion coefficient of cupric ion in a fluosilicate solution has been determined with the aid of a rotating disk electrode using the mixed control Levich equation. Gold (Au+3) was used as a tracer to evaluate the mass transport properties of the system. The polarization behavior of the electrolyte was measured in the presence and absence of gas sparging on a vertical stationary electrode to study the effect of the mass transport contribution. Sound copper deposits were obtained …

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Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3: Defect Structure, Electrical Conductivity, And Thermoelectric Power, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin Jan 1990

Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3: Defect Structure, Electrical Conductivity, And Thermoelectric Power, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Seebeck coefficient and electrical conductivity measurements were performed for undoped and Sr-doped LaMnO3 as a function of temperature and oxygen partial pressure. The results of electrical conductivity showed typical p-type behavior. As reduction proceeded, the electrical conductivity of these LaMnO3-based perovskites decreased with P 1 4O2. The analysis of the electrical conductivity data was performed by extending the defect model from a previous thermogravimetric (TG) study. The measured Seebeck coefficients were found to be positive except for the most reducing conditions when the decomposition into multiple phases occurred. The Heikes formula was adopted to interpret …

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Design Considerations For 1-3 Composites Used In Transducers For Medical Ultrasonic Imaging, Wayne Huebner, Kuiming Liang, Clyde G. Oakley Jan 1990

Design Considerations For 1-3 Composites Used In Transducers For Medical Ultrasonic Imaging, Wayne Huebner, Kuiming Liang, Clyde G. Oakley

Materials Science and Engineering Faculty Research & Creative Works

Ceramic polymer piezoelectric composites with 1-3 connectivity have become an important tool in the design and manufacture of thickness-mode transducers for medical diagnostic ultrasonic imaging. The authors compare annular array transducers made from ceramics alone to those made with these composites to demonstrate the advantages of composites. They examine some of the trade-offs involved in optimizing composite designs for this application. The effects of varying Young's modulus and Poisson's ratio of the polymer phase on the coupling coefficient and high-frequency lateral resonances of the composite are presented

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Production Of Thin Copper Foils On Microporous Titanium Oxide Substrates, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand Jan 1990

Production Of Thin Copper Foils On Microporous Titanium Oxide Substrates, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand

Materials Science and Engineering Faculty Research & Creative Works

This study deals with the electrochemical production of thin (35 μm) copper films on anodized titanium substrates. The formation of a microporous oxide layer on the titanium electrodes greatly enhances the surface density of copper nuclei during a potentiostatic experiment so that a complete coverage of the cathode surfaces may be obtained after short term (20 s) polarization. Moreover, the oxide film may act as a parting agent and the copper films may be easily stripped from their substrates. The higher the pore density of the oxide film, the higher the surface density of nuclei and the easier the foil's …

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Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt Dec 1989

Composition And Method For Radiation Synovectomy Of Arthritic Joints, D. E. Day, Gary J. Ehrhardt

Materials Science and Engineering Faculty Research & Creative Works

Radioactive microspheres for radiation synovectomy of arithmetic joints in a mammal comprise a biodegradable glass material and a beta radiation emitting radioisotope chemically dissolved in and distributed substantially uniformly throughout the glass material. The biodegradable glass material may be lithium silicate, lithium aluminosilicate, lithium aluminoborate, lithium germa- nate, lithium aluminogermanate, potassium silicate, potassium aluminosilicate, potassium, aluminoborate, potassium germanate or potassium aluminogermanate and the beta radiation emitting radioisotope may be samarium-153, holmium-166, erbium-169, dysprosium-165, rhenium-186, rhenium-188 or yttrium-90. Methods for preparing such microspheres and for carrying out radiation synovectomy of arthritic joints utilizing such microspheres are also disclosed.

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Structural Characteristics Of Sr1-Xlaxti 3+Δ As A Function Of Oxygen Partial Pressure At 1400°C, S. A. Howard, J. K. Yau, Harlan U. Anderson Dec 1989

Structural Characteristics Of Sr1-Xlaxti 3+Δ As A Function Of Oxygen Partial Pressure At 1400°C, S. A. Howard, J. K. Yau, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The structural characteristics of Sr1-x Lax TiO3+δ (0≤x≤0.4) at 1400°C have been investigated as a function of ambient oxygen partial pressure. A modified Rietveld pattern-fitting structure-refinement program [H. M. Rietveld, J. Appl. Crystallogr. 2, 65 (1969)] was used to determine the nature of the distortions of the fundamental perovskite unit cell, the degree of lattice perfection, and the cation vacancy concentrations. Specimens equilibrated in forming gas displayed a linear relation between x, the lattice parameters, and the degree of lattice perfection while those samples annealed in air and oxygen deviated significantly from linearity. A monoclinic distortion of …

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Evaluation Of Mass Transport In Copper And Zinc Electrodeposition Using Tracer Methods, H. M. Wang, S. F. Chen, Thomas J. O'Keefe, M. Degrez, R. Winand Mar 1989

Evaluation Of Mass Transport In Copper And Zinc Electrodeposition Using Tracer Methods, H. M. Wang, S. F. Chen, Thomas J. O'Keefe, M. Degrez, R. Winand

Materials Science and Engineering Faculty Research & Creative Works

Control of the electro crystallization process is essential in the deposition of metals from aqueous electrolytes. A knowledge of the influence of mass transfer on the metal ion reduction is a critical element in any number of electrolytic processes, particularly where relatively high current densities are desired. The use of more positive ion tracer techniques as a means of experimentally determining some of the mass transport properties of interest are described. Examples for copper, zinc and zinc alloys electrolysis are included. © 1989 Chapman and Hall Ltd.

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Nucleation Of Electrodeposited Copper On Anodized Titanium, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand Jan 1989

Nucleation Of Electrodeposited Copper On Anodized Titanium, J. L. Delplancke, M. Sun, Thomas J. O'Keefe, R. Winand

Materials Science and Engineering Faculty Research & Creative Works

A study has been made to determine the effect of an electrochemically produced titanium-oxide film on the nucleation of copper. The oxide films were made galvanostatically at 25°C in 1 M sulphuric acid on pure titanium metal. Potentiodynamic, potential step and current step experiments were performed in an additive-free copper sulphate-sulphuric acid electrolyte at 25°C. It was found that the oxide film played an important role during nucleation. By increasing the thickness of the anodic film, it was possible to decrease the diameter and to increase the surface density of copper nuclei. The kinetics of nucleation and growth of the …

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