Open Access. Powered by Scholars. Published by Universities.®

Materials Science and Engineering Commons™

Open Access. Powered by Scholars. Published by Universities.®

Materials Science and Engineering Faculty Research & Creative Works

Discipline
Keyword
Publication Year

Articles 601 - 630 of 1011

Full-Text Articles in Materials Science and Engineering

Method For Preparation Of Nanometer Cerium-Based Oxide Particles, X.-D. Zhou, Wayne Huebner, Harlan U. Anderson Apr 2006

Method For Preparation Of Nanometer Cerium-Based Oxide Particles, X.-D. Zhou, Wayne Huebner, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

The invention comprises novel undoped and doped nanometer-scale CeO2 particles as well as a novel semi-batch reactor method for directly synthesizing the novel particles at room temperature. The powders exhibited a surface area of approximately 170 m2/g with a particle size of about 3-5 nm, and are formed of single crystal particles that are of uniform size and shape. The particles’ surface area could be decreased down to 5 m2/g, which corresponds to a particle size of 100 nm, by thermal annealing at temperatures up to 1000° C. Control over the particle size, size distribution …

Go to article

The Phase Stability Of Cerium Species In Aqueous Systems Iii. The Ce(Iii/Iv)-H2o-H2o2/O2 System Dimeric Ce(Iv) Species, Pu Yu, Thomas J. O'Keefe Apr 2006

The Phase Stability Of Cerium Species In Aqueous Systems Iii. The Ce(Iii/Iv)-H2o-H2o2/O2 System Dimeric Ce(Iv) Species, Pu Yu, Thomas J. O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Equilibria and thermodynamic data for cerium dimer species were calculated for both the Ce-H2O-O2 and Ce-H2O-H2O2 systems. It was found that Ce (IV) has a tendency to form dimers, especially when the total cerium concentration is higher than 0.001 M. There are three major soluble dimer forms considered in this paper: (CeOCe)6+,(CeOCe)(OH)5+, and (CeOCe)(OH)24+, all having very similar standard potentials (E0 Ce(IV)dimer/Ce(III)01.66∀0.02V). When they coexist in solution, the concentration ratio of the Ce (IV) dimer to Ce3+ depends on the total cerium concentrations, the …

Go to article

Freeze-Spray Processing Of Layered Ceramic Composites (Preprint), Oratai Jongprateep, Q. Fu, A. Abbott, Fatih Dogan Apr 2006

Freeze-Spray Processing Of Layered Ceramic Composites (Preprint), Oratai Jongprateep, Q. Fu, A. Abbott, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Thermal gradients and associated stresses are critical in designing with ceramic composites having low thermal conductivity. In order to reduce the stresses from thermal gradients, compositional gradients are employed in designing of composite structures. This study addresses development of freeze-spray process to fabricate layered ceramic structures with controlled layer thickness and microstructural development. The composites were processed by spraying of ceramic slurries with low binder content and relatively high solids loadings up to 40 vol on a cooled substrate. The frozen parts were freeze-dried and sintered at elevated temperatures. The relationship between microstructural development and thermal expansion behavior of Al …

Go to article

Structural And Magnetic Properties Of La Mn₁₋ₓfeₓo₃ (0 < X < 1.0), X.-D. Zhou, L. R. Pederson, Qingsheng Cai, Jinbo Yang, B. J. Scarfino, M. Kim, William B. Yelon, William Joseph James, Harlan U. Anderson, C. Wang Apr 2006

Structural And Magnetic Properties Of La Mn₁₋ₓfeₓo₃ (0 < X < 1.0), X.-D. Zhou, L. R. Pederson, Qingsheng Cai, Jinbo Yang, B. J. Scarfino, M. Kim, William B. Yelon, William Joseph James, Harlan U. Anderson, C. Wang

Materials Science and Engineering Faculty Research & Creative Works

Electronic, structural, and magnetic properties of Mn-doped lanthanum ferrites were studied by neutron diffraction, superconducting quantum interference device, and impedance spectroscopy. Neutron diffraction refinements were performed with the constraint of full La occupancy, which showed the presence of excess oxygen when x < 0.4. Mixed valent Mn cations and cation vacancies, therefore, exist in all the samples. The samples with x > 0.7 are magnetically ordered at room temperature with orthorhombic symmetry (Pbnm). When x < 0.3 the structure is rhombohedral and magnetically disordered above 16 K. The majority carriers, electron holes, correspond to high oxidation states of Mn. The carrier concentration is determined from the Seebeck coefficients, and is a function of temperature and Fe concentration. The measurements of conductivity and Seebeck coefficients show polaron hopping at elevated temperatures.

Go to article

Decreasing Electrical Energy Consumption Through Sic Additions, Kent D. Peaslee, Semen Naumovich Lekakh, Von Richards, John Carpenter, Chen Wang Jan 2006

Decreasing Electrical Energy Consumption Through Sic Additions, Kent D. Peaslee, Semen Naumovich Lekakh, Von Richards, John Carpenter, Chen Wang

Materials Science and Engineering Faculty Research & Creative Works

This paper summarizes results of industrial experiments investigating the introduction of supplemental chemical energy in Electric Arc Furnaces (EAF). Specifically, this research evaluates the effects of adding 0.4-0.6% of the scrap charge weight as SiC (10 lbs per scrap ton charged) in the EAF. SiC additions increase the available exothermic reactions during oxygen boiling in an attempt to reduce the electrical energy requirements. Results from 180 trial heats at two different steel foundries are highlighted and statistically evaluated. In both cases, the SiC additions had a measurable effect on decreasing the electrical energy consumption.

Go to article

Improving Melting Efficiency Through The Application Of New Refractory Materials, Kent D. Peaslee, Semen Naumovich Lekakh, Von Richards, Todd P. Sander, Jeffrey D. Smith, Mangesh Vibhandik Jan 2006

Improving Melting Efficiency Through The Application Of New Refractory Materials, Kent D. Peaslee, Semen Naumovich Lekakh, Von Richards, Todd P. Sander, Jeffrey D. Smith, Mangesh Vibhandik

Materials Science and Engineering Faculty Research & Creative Works

Ladle design and ladle practices have a significant effect on a foundry operation and product quality. Large steel temperature losses or instabilities in the pouring temperature are frequently compensated by tapping at higher temperatures dramatically increasing furnace and ladle lining wear, oxidation of the steel, alloying element losses, and energy consumption in steel melting. Ladle lining materials need to satisfy a complex array of often conflicting requirements. For example, ceramic materials for linings must possess a high strength at liquid steel temperatures to prevent erosion and crack formation. However, linings need to also have a low thermal conductivity which typically …

Go to article

Vibration Testing Of Repaired Lead-Tin/Lead-Free Solder Joints, Matthew O'Keefe, S. Vetter, D. Murry, J. Smith, P. Amick, Martin G. Perez, D. W. Kleine, Richard S. Colfax Jan 2006

Vibration Testing Of Repaired Lead-Tin/Lead-Free Solder Joints, Matthew O'Keefe, S. Vetter, D. Murry, J. Smith, P. Amick, Martin G. Perez, D. W. Kleine, Richard S. Colfax

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Crystal And Electronic Structures Of Linh₂, Jinbo Yang, X.-D. Zhou, Qingsheng Cai, William Joseph James, William B. Yelon Jan 2006

Crystal And Electronic Structures Of Linh₂, Jinbo Yang, X.-D. Zhou, Qingsheng Cai, William Joseph James, William B. Yelon

Materials Science and Engineering Faculty Research & Creative Works

The crystal structure of LiNH2 was reinvestigated using powder neutron diffraction with high sensitivity. The compound crystallizes in the tetragonal space group I4 with lattice parameters α = b= 5.034 42 (24) Å, c = 10.255 58 (52) Å. It is found that H atoms occupy 8g1(0.2429, 0.1285, 0.1910) and 8g2 (0.3840, 0.3512, 0.1278) sites. The bond lengths between the nearest nitrogen and hydrogen atoms are 0.986 and 0.942 Å, respectively. The bond angle between H-N-H is about 99.97°. These results are significantly different from those of previous experiments. The electronic structure was calculated according to the revised structural …

Go to article

Effect Of Nozzle Base Material On The Rate Of Clogging During The Continuous Casting Of Aluminum-Killed Steels, Luis Trueba, Kent D. Peaslee, Jeffrey D. Smith, Musa Karakus Jan 2006

Effect Of Nozzle Base Material On The Rate Of Clogging During The Continuous Casting Of Aluminum-Killed Steels, Luis Trueba, Kent D. Peaslee, Jeffrey D. Smith, Musa Karakus

Materials Science and Engineering Faculty Research & Creative Works

One approach to solving the problem of nozzle clogging during the continuous casting of aluminum-killed steels is through careful selection of nozzle materials. in this study, the rate of clogging was measured while casting steel through simulated nozzles produced from alumina, zirconia, magnesia, zirconia-graphite, and alumina-graphite - three common base materials and two common carbon-containing nozzle materials. Spent nozzles were characterized using optical and cathodoluminescence microscopy. Interactions between the nozzles and steel were not observed in the alumina, zirconia, and zirconia-graphite nozzles. Slight interactions were observed in the magnesia nozzles as alumina inclusions within the steel interacted with the nozzle …

Go to article

Effect Of Welding Parameters On Properties Of 5052 Al Friction Stir Spot Welds, T. A. Freeney, S. R. Sharma, Rajiv S. Mishra Jan 2006

Effect Of Welding Parameters On Properties Of 5052 Al Friction Stir Spot Welds, T. A. Freeney, S. R. Sharma, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Effect of process parameters on friction stir spot welding (FSSW) of 5052 Al alloy has been evaluated. a plunge type FSSW machine was used for this study. Sheet thicknesses of 1 and 1.6mm were used. the tool rotation rate was varied between 1000 and 3000 rpm. the tool plunge rate and dwell time was varied to give weld cycle of 1-4 seconds. Shear tests were performed in 2 sheet and 3 sheet configurations to determine the influence of processing parameters on the mechanical properties of lap joint FSSWs. Higher joint strengths were observed at lower tool rotation rates. Copyright © …

Go to article

Redox Stable Electrodes For Hydrogen Producing Solid Oxide Electrolyzer, Yong Wook Sin, Vladimir Petrovsky, Harlan U. Anderson Jan 2006

Redox Stable Electrodes For Hydrogen Producing Solid Oxide Electrolyzer, Yong Wook Sin, Vladimir Petrovsky, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

This report focuses on a study which measured the electrical conductivity of LSCrM, LSCr and LSM as a function of oxygen activity and temperature to evaluate the chemical and mechanical stability of the materials as an electrode in a solid oxide fuel-fed electrolyzer cell (SOFEC). the LSCrM symmetrical cell was fabricated using La0.75Sr0.25Cr0.5Mn0.5O3 (LSCrM) powder and evaluated using electrical conductivity, impedance spectroscopy, current density and power density as a function of temperature. during the evaluation, symmetrical cell tests and fuel cell tests were performed as a function of temperature. Silver (Ag) …

Go to article

Effect Of Baceo3 And Basno3 Additives On Microstructural Development And Critical Current Density Of Melt Textured Yba2cu3o7-X, Oratai Jongprateep, Fatih Dogan, Michael Strasik, Kevin E. Mccrary Sep 2005

Effect Of Baceo3 And Basno3 Additives On Microstructural Development And Critical Current Density Of Melt Textured Yba2cu3o7-X, Oratai Jongprateep, Fatih Dogan, Michael Strasik, Kevin E. Mccrary

Materials Science and Engineering Faculty Research & Creative Works

Improvement of superconducting properties, such as critical current density Jc and trapped magnetic field, of melt textured YBa2Cu3O7-x (Y123) require introducing of effective pinning sites, e.g., nonsuperconducting inclusions, twin boundaries and other defects. It has been shown that addition of small quantities of BaCeO3 (< 0.5 wt.%) into Y123 results in an increase of the J/sub c/. However, higher cerium concentrations affect the solidification process and inhibit the growth of melt textured Y123 single crystals. In this study, the effect of BaCeO/sub 3/ additions on the growth and microstructural development of melt textured Y123 single crystals were investigated. The relationship between the solidification kinetics, microstructural development and superconducting properties of Y123 melt textured single crystals with cerium additives is discussed.

Go to article

Freeze-Form Extrusion Fabrication Of Ceramics, Tieshu Huang, Michael S. Mason, Greg Hilmas, Ming-Chuan Leu Aug 2005

Freeze-Form Extrusion Fabrication Of Ceramics, Tieshu Huang, Michael S. Mason, Greg Hilmas, Ming-Chuan Leu

Materials Science and Engineering Faculty Research & Creative Works

A novel, environmentally friendly solid freeform fabrication method called Freeze-form Extrusion Fabrication (FEF) has been developed for the fabrication of ceramic-based components. The method is based on deposition of ceramic pastes using water as the media. The ceramic solids loading can be 50 vol. % or higher and initial studies have focused on the use of aluminum oxide (Al2O3). The FEF system components and their interaction are examined, and the main process parameters affecting part geometry defined. 3-D shaped components have been fabricated by extrusion deposition of the ceramic paste in a layer-by-layer fashion. The feasibility …

Go to article

Integral Channels In Metal Components And Fabrication Thereof, Rajiv S. Mishra Aug 2005

Integral Channels In Metal Components And Fabrication Thereof, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

An internal channel in a metal body for use in applications where internal fluid flow within a metal body is desired, as in a heat exchanger. The internal channel is formed in the metal body by frictionally stirring with a pin plunged into the metal body, and traversing the metal body with the pin.

Go to article

Journal Of Materials Engineering And Performance: Editorial, C. Suryanarayana, Leon L. Shaw, Rajiv S. Mishra Aug 2005

Journal Of Materials Engineering And Performance: Editorial, C. Suryanarayana, Leon L. Shaw, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Method And Sealant For Weld Joints, David C. Van Aken, John A. Baumann, Richard J. Lederich, Rajesh Talwar Jun 2005

Method And Sealant For Weld Joints, David C. Van Aken, John A. Baumann, Richard J. Lederich, Rajesh Talwar

Materials Science and Engineering Faculty Research & Creative Works

A sealant for a weld joint and an associated weld joint and method are provided. The sealant includes aluminum and germanium and is characterized by a melting temperature that is lower than the melting temperature of the structural member that is joined. The sealant, which is disposed between faying surfaces of the structural members, can fill the spaces between the structural members to prevent the entry of chemicals, moisture, debris, and other substances, thereby reducing the likelihood of corrosion of the joint or structural members at the interface. Further, the sealant can be diffusion bonded to the faying surfaces, for …

Go to article

Nanocomposite Nickel Ceria Cermet With Low Nickel Content For Anode-Supported Sofcs, Piotr Z. Jasinski, Toshio Suzuki, Vladimir Petrovsky, Harlan U. Anderson May 2005

Nanocomposite Nickel Ceria Cermet With Low Nickel Content For Anode-Supported Sofcs, Piotr Z. Jasinski, Toshio Suzuki, Vladimir Petrovsky, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

Ni-ceria cermet's with 7.5, 11, and 14 vol % of Ni manufactured by a novel method, called net-shape technology, are presented and evaluated. the method is a combination of conventional ceramic sintering and a polymer precursor impregnation technique. Ceria powder with a carbon pore former is sintered, constructing a rigid and stable oxide skeleton, which is next backfilled with Ni polymer precursor. the electrical conductivity of the cermet's as a function of Ni content has been investigated. © 2005 the Electrochemical Society. All rights reserved.

Go to article

The Wettability Of Titanium Diboride By Molten Aluminum Drops, D. A. Weirauch, W. J. Krafick, G. Ackart, P. D. Ownby May 2005

The Wettability Of Titanium Diboride By Molten Aluminum Drops, D. A. Weirauch, W. J. Krafick, G. Ackart, P. D. Ownby

Materials Science and Engineering Faculty Research & Creative Works

Titanium diboride is widely accepted to be completely wet by liquid aluminum, yet few published wetting studies demonstrate this behavior, and reported contact angles vary widely. Sessile drop substrates from four different sources were selected and their microstructures and chemistries characterized. the results of sessile drop experiments using four techniques to modify oxide film behavior were compared. the Al-TiB2 interfaces were examined in metallographic sections or after chemical removal of the Al drop. Al wets a material containing 5.5 wt% Ni in vacuum experiments before the hold temperature of 1025°C is reached. the other TiB2 substrates are completely wet by …

Go to article

Thermochemistry Of La 1-Sr Xfeo 3-Δ Solid Solutions (0.0 ≤ X ≤ 1.0, 0.0 ≤ Δ ≤ 0.5), Jihong Cheng, Alexandra Navrotsky, Xiao Dong Zhou, Harlan U. Anderson Apr 2005

Thermochemistry Of La 1-Sr Xfeo 3-Δ Solid Solutions (0.0 ≤ X ≤ 1.0, 0.0 ≤ Δ ≤ 0.5), Jihong Cheng, Alexandra Navrotsky, Xiao Dong Zhou, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

A series of compounds with the general formula La1-xSrxFeO3-δ have been synthesized in the complete solid solution range 0.0 ≤ x ≤ 1.0 and 0.0 ≤ δ ≤ 0.5 with a variety of heat treatments. High temperature drops solution calorimetry in molten 2PbO·B2O3 at 702 °C was performed to determine their enthalpies of formation from oxides at room temperature. the enthalpy of oxidation involved in the reaction 2FeXFe + V O•• + 0.5O 2(g) = 2Fe Fe• + O OX is independent of oxygen nonstoichiometry in each …

Go to article

An Exafs Investigation Of Rare-Earth Local Environment In Ultraphosphate Glasses, M. Karabulut, E. Metwalli, A. K. Wittenauer, Richard K. Brow, G. K. Marasinghe, C. H. Booth, J. J. Bucher, D. K. Shuh Apr 2005

An Exafs Investigation Of Rare-Earth Local Environment In Ultraphosphate Glasses, M. Karabulut, E. Metwalli, A. K. Wittenauer, Richard K. Brow, G. K. Marasinghe, C. H. Booth, J. J. Bucher, D. K. Shuh

Materials Science and Engineering Faculty Research & Creative Works

The local structures around rare-earth ions in rare-earth ultra phosphate glasses (nominally 15RE2O3-85P2O5, mol%, RE = Nd, Sm, Gd, Ho, and Er) and metaphosphate glasses (nominally 25RE2O3-75P2O5, mol%, RE = Nd, Gd, and Er) have been studied by extended X-ray absorption fine structure spectroscopy (EXAFS) at the respective rare-earth LIII edges. the RE-O distance decreases with increasing atomic number of the rare-earth ion for both ultra and metaphosphate glasses. on average, RE-O distances for metaphosphate glasses are shorter than those for ultra phosphate glasses …

Go to article

Study Of The Electronic Structure Of Cafeo₃, Jinbo Yang, M. S. Kim, Qingsheng Cai, X.-D. Zhou, Harlan U. Anderson, William Joseph James, William B. Yelon Jan 2005

Study Of The Electronic Structure Of Cafeo₃, Jinbo Yang, M. S. Kim, Qingsheng Cai, X.-D. Zhou, Harlan U. Anderson, William Joseph James, William B. Yelon

Materials Science and Engineering Faculty Research & Creative Works

We have studied the charge disproportionation phenomenon in CaFeO3 using the local-spin density approximation with the on-site Coulomb interaction parameter U and exchange parameter J. The calculation reveals that the total number of the 3d electrons is about 5.1 for both Fe(1)(Fe5+) and Fe(2)(Fe3+) atoms, and that there are about 0.25 electron holes in the O-2p band. Therefore, the charge disproportionation can be more accurately described as 2d5L(Fe4+)=d5L2(Fe5+)+d5(Fe3+), where L denotes a hole in the oxygen 2p band, instead of 2d4(Fe4+)=d3(Fe5+)+d5(Fe3+). The hybridization between the Fe-3d and O-2p orbitals is stronger for Fe(1) than for Fe(2) due to the shorter …

Go to article

Approaches Toward Integrating Functionality Into Structural Materials, Rajiv S. Mishra Jan 2005

Approaches Toward Integrating Functionality Into Structural Materials, Rajiv S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Go to article

Coupled Electrical And Magnetic Properties In (La,Sr)Feo3-Δ, X.-D. Zhou, Qingsheng Cai, Jinbo Yang, M. S. Kim, William B. Yelon, William Joseph James, Y.-W. Shin, B. J. Scarfino, Harlan U. Anderson Jan 2005

Coupled Electrical And Magnetic Properties In (La,Sr)Feo3-Δ, X.-D. Zhou, Qingsheng Cai, Jinbo Yang, M. S. Kim, William B. Yelon, William Joseph James, Y.-W. Shin, B. J. Scarfino, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

This article is aimed at studying the temperature dependence oxygen nonstoichiometry, magnetic moments, Fe3+ fraction, Néel temperature and conductivity of (La,Sr)FeO3-δ. It is found that the magnetic properties in La0.60 Sr0.40 Fe3-δ is determined by Fe3+ and its concentration, and the conductance is resulted from Fe4+ ions, which act as electron holes. Both of magnetic and electrical properties were directly governed by oxygen nonstoichiometry (δ). when δ=0.2, the compound has maximum Fe3+, the saturation magnetic moments and Néel temperature are 3.8 µB and 410 °C, both at the highest level, …

Go to article

Alloy Recovery And Control In Steel Melting, Kent D. Peaslee, Darryl S. Webber, Semen Naumovich Lekakh, Bradley Randall Jan 2005

Alloy Recovery And Control In Steel Melting, Kent D. Peaslee, Darryl S. Webber, Semen Naumovich Lekakh, Bradley Randall

Materials Science and Engineering Faculty Research & Creative Works

Alloy recovery plays an important role in steel melting economics because the cost of alloying additives such as ferroalloys and pure non-ferrous metals is significantly higher than the cost of steel scrap. Recovery of alloying additives also influences the reproducibility of steel properties from heat to heat. This paper reviews alloy recovery and final chemistry distributions at seven steel foundries and preliminary laboratory studies of alloy dissolution in ladles. Melting and alloy practices were observed for several plant trial heats in each of the foundries. Alloying and chemistry data were collected for an additional 20 - 155 heats at each …

Go to article

Efficiency In Steel Melting: Ladle Development, Kent D. Peaslee, Semen Naumovich Lekakh, Todd P. Sander, Jeffrey D. Smith Jan 2005

Efficiency In Steel Melting: Ladle Development, Kent D. Peaslee, Semen Naumovich Lekakh, Todd P. Sander, Jeffrey D. Smith

Materials Science and Engineering Faculty Research & Creative Works

Effective ladle design and use is important for steel casting production. In foundry operations, the ladle temperature of the liquid steel is typically 150 to 250°F above the steel's melting point to compensate for the heat losses in small ladles and the associated high cooling rates from the large surface area to volume ratios. Higher superheat is also necessary to provide sufficient steel fluidity to properly fill the mold cavity. In spite of the relatively short time that the steel is in contact with the ladle lining, the huge thermal gradients in the lining drive high values of heat flow …

Go to article

Efficiency In Steel Melting: Opportunities And Progress, Kent D. Peaslee, Semen Naumovich Lekakh, Von Richards, Jay Triplett Jan 2005

Efficiency In Steel Melting: Opportunities And Progress, Kent D. Peaslee, Semen Naumovich Lekakh, Von Richards, Jay Triplett

Materials Science and Engineering Faculty Research & Creative Works

This paper summarizes the findings from a study of melting efficiency in steel foundries and provides examples of material and energy savings from improvements in technology and melting practices. This study is based on information gathered at 19 Steel Founders Society of America member foundries and includes a combination of historical data and industrial measurements by the research team. Information and data were collected on the type of melting equipment, melting practices, energy use and ladle practices. The data was statistically analyzed using STATGRAPHICS commercial software. A multiple regression analysis allowed evaluation of the influence of the melting furnace (type, …

Go to article

Elevated Temperature Deformation Behavior Of Nanostructured Al-Ni-Gd-Fe Alloys, X. L. Shi, Rajiv S. Mishra, T. J. Watson Jan 2005

Elevated Temperature Deformation Behavior Of Nanostructured Al-Ni-Gd-Fe Alloys, X. L. Shi, Rajiv S. Mishra, T. J. Watson

Materials Science and Engineering Faculty Research & Creative Works

The elevated temperature deformation behavior of nanostructured Al89Ni3Gd7Fe1 alloy was characterized. Tensile strength was 760 MPa at 373 K. Ductility of the alloy increases with increasing strain rate at 573 K. At high temperatures (623-673 K), the operative deformation mechanism is dislocation-climb controlled.

Go to article

Continuous Solidification Of Yba2cu3o7−X By Isothermal Undercooling, Fatih Dogan Jan 2005

Continuous Solidification Of Yba2cu3o7−X By Isothermal Undercooling, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Growth kinetics and microstructural development of single crystal YBa2Cu3O7−x (Y123) superconductors, prepared by a melt texturing method under isothermal undercooling conditions, were investigated. At small undercooling, ΔT = 6 K, the initial growth of Y123 crystal was terminated at a size of ∼8 mm × 8 mm in the semisolid phase before the entire sample was fully solidified through the peritectic reaction. With incremental increase of ΔT, the growth of the crystal continued so that the whole sample (22 mm diameter and 8 mm thickness) solidified as a single crystal. Termination of the crystal growth …

Go to article

Single Chamber Electrolyte Supported Sofc Module, Toshio Suzuki, Piotr Jasinski, Harlan U. Anderson, Fatih Dogan Nov 2004

Single Chamber Electrolyte Supported Sofc Module, Toshio Suzuki, Piotr Jasinski, Harlan U. Anderson, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

An electrolyte supported single chamber solid oxide fuel cell (SOFC) module consisting of two cells has been proposed. The module consists of one Sm-doped CeO2 (SDC) electrolyte substrate (0.5 mm thick with the size of 5 3 10 mm), two Ni-SDC anodes on one side, and two SDC-(La,Sr)(Co,Fe)O3 cathodes on the other side. Two modules with different electrode areas were prepared and tested using an air-propane mixture. The electrode area had a strong influence on the performance of the module. It was shown that the two-cell module generated 1.5 V open-circuit voltage and about 17 mW maximum power …

Go to article

Rare Earth-Aluminum Oxide Glasses For Optical Applications, Richard Weber, Jean A. Tangeman, Paul C. Nordine, Richard N. Scheunemann, Kirsten J. Hiera, Chandra S. Ray Oct 2004

Rare Earth-Aluminum Oxide Glasses For Optical Applications, Richard Weber, Jean A. Tangeman, Paul C. Nordine, Richard N. Scheunemann, Kirsten J. Hiera, Chandra S. Ray

Materials Science and Engineering Faculty Research & Creative Works

Glasses based on rare earth oxides and aluminum oxide with 0-20 mol% SiO2 provide a combination of optical properties, mechanical and chemical stability, and process characteristics not available in other oxide materials. Properties of the glasses include: refractive index 1.7-1.8, low dispersion (Abbe number ∼40), high solubility of optically active dopants, homogeneous chemical composition, long fluorescence lifetimes at dopant concentrations up to 5 mol%, broad fluorescence bandwidth, and infra-red transmission to ≈5000nm. the glasses are hard, strong and resist chemical attack and they can be cast in sections 5-10mm thick. This paper briefly describes glass processing and presents bulk …

Go to article

First Prev Next Last