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Materials Science and Engineering Faculty Research & Creative Works

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Full-Text Articles in Materials Science and Engineering

Electric Field-Induced Tetragonal To Orthorhombic Phase Transitions In [110]C-Oriented Batio₃ Single Crystals, D. J. Franzbach, Yijia Gu, Long-Qing Chen, K. G. Webber Dec 2012

Electric Field-Induced Tetragonal To Orthorhombic Phase Transitions In [110]C-Oriented Batio₃ Single Crystals, D. J. Franzbach, Yijia Gu, Long-Qing Chen, K. G. Webber

Materials Science and Engineering Faculty Research & Creative Works

Electric field-induced phase transitions in [110]c-oriented BaTiO3 single crystals were studied by macroscopic electrical measurements in the temperature range from 20 °C to 50 °C. Discontinuous, hysteretic jumps in the polarization and strain were observed, indicating a tetragonal ↔ orthorhombic phase transition. The critical electric field to induce the transition was found to shift to higher values with increasing temperature. The Landau-Devonshire theory was used to analyze the observed electric field-induced T ↔ O phase transitions.

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A Comparative Study On The Corrosion Resistance Of Cerium-Based Conversion Coatings On Az91d And Az31b Magnesium Alloys, C. E. Castano, Surender Maddela, Matthew J. O'Keefe, Y. M. Wang Dec 2012

A Comparative Study On The Corrosion Resistance Of Cerium-Based Conversion Coatings On Az91d And Az31b Magnesium Alloys, C. E. Castano, Surender Maddela, Matthew J. O'Keefe, Y. M. Wang

Materials Science and Engineering Faculty Research & Creative Works

In the present work a comparative study has been carried out on the surface morphology, electrochemical properties and corrosion performance of cerium-Based conversion coatings (CeCCs) on AZ91D and AZ31B magnesium alloys. the as-deposited coatings consisted of a two-layer structure: A continuous Mg/Al oxide transition layer of ∼ 50 nm thick and a CeCC layer of ∼ 400 nm thick. Potentiodynamic polarization and impedance spectroscopy results using a 0.6 wt.% NaCl and 0.6 wt.% (NH4)2SO4 electrolyte showed that cerium-Based conversion coatings enhanced the corrosion resistance of AZ91D and AZ31B magnesium alloys compared to polished uncoated samples. …

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Stress Corrosion Cracking Susceptibility Of Ultrafine Grained Az31, G. R. Argade, W. Yuan, K. Kandasamy, R. S. Mishra Oct 2012

Stress Corrosion Cracking Susceptibility Of Ultrafine Grained Az31, G. R. Argade, W. Yuan, K. Kandasamy, R. S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

In this study, stress corrosion cracking (SCC) behavior of AZ31 magnesium alloy was carried out using slow strain rate testing (SSRT) technique in 3.5 wt.% NaCl solution. the influence of microstructural scale on the stress corrosion behavior was investigated in AZ31 alloy with three different mean grain sizes. Single-pass and two-pass friction stir processing (FSP) was employed to obtain fine grain and ultrafine grain microstructures, respectively. for FSP, SSRT specimens were extracted from the processed region. SSRTs were carried out in air and solution at an initial strain rate of 10 -6/s. a significant decrease in the ultimate tensile strength …

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Nanostructured Dielectric Materials For High Energy Density Multi Layer Ceramic Capacitors, Fatih Dogan Sep 2012

Nanostructured Dielectric Materials For High Energy Density Multi Layer Ceramic Capacitors, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

A high energy density multilayer ceramic capacitor, having at least two electrode layers and at least one substantially dense polycrystalline dielectric layer positioned therebetween. The at polycrystalline dielectric layer has an average grain size of less than about 300 nanometers, a particle size distribution of between about 150 nanometers and about 3 micrometers, and a maximum porosity of about 1 percent. The dielectric layer is selected from the group including TiO2, BaTiO3, Al2O3, ZrO2, lead zirconium titanate, and combinations thereof and has a breakdown strength of at least about 1100 …

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Water Modeling Of Self-Braking Submerged Entry Nozzle Used For Steel Continuous Casting Mold, Yongfeng Chen, Lifeng Zhang, Shufeng Yang, Jingshe Li Sep 2012

Water Modeling Of Self-Braking Submerged Entry Nozzle Used For Steel Continuous Casting Mold, Yongfeng Chen, Lifeng Zhang, Shufeng Yang, Jingshe Li

Materials Science and Engineering Faculty Research & Creative Works

Slag entrainment in a continuous casting mold is one of the major causes of macro nonmetallic inclusions in continuous casting steel products. Stabilizing the level fluctuation is an important factor to improve steel quality. a new type of submerged entry nozzle (SEN) named self-braking SEN was designed. in the current study, water modeling experiments were performed to study the effect of self-braking SEN on level fluctuation in a continuous casting slab mold. the level position and the root mean square value of level fluctuation were analyzed through the online detection data. the results showed that the flow in the mold …

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Freeze-Form Extrusion Fabrication Of Functionally Graded Material Composites Using Zirconium Carbide And Tungsten, Ang Li, Aaron S. Thornton, Bradley K. Deuser, Jeremy Lee Watts, Ming-Chuan Leu, Greg Hilmas, Robert G. Landers Aug 2012

Freeze-Form Extrusion Fabrication Of Functionally Graded Material Composites Using Zirconium Carbide And Tungsten, Ang Li, Aaron S. Thornton, Bradley K. Deuser, Jeremy Lee Watts, Ming-Chuan Leu, Greg Hilmas, Robert G. Landers

Materials Science and Engineering Faculty Research & Creative Works

Ultra-high-temperature ceramics are being investigated for future use in aerospace applications due to their superior thermo-mechanical properties, as well as their oxidation resistance, at temperatures above 2000⁰C. However, their brittleness makes them susceptible to thermal shock failure. As graded composites, components fabricated as functionally-graded materials (FGMs) can combine the superior properties of ceramics with the toughness of an underlying refractory metal. This paper discusses the grading of two materials through the use of a Freeze-form Extrusion Fabrication (FEF) system to build FGM parts consisting of zirconium carbide (ZrC) and tungsten (W). Aqueous-based colloidal suspensions of ZrC and W were developed …

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Conductivity Of Twin-Domain-Wall/Surface Junctions In Ferroelastics: Interplay Of Deformation Potential, Octahedral Rotations, Improper Ferroelectricity, And Flexoelectric Coupling, Eugene A. Eliseev, Anna N. Morozovska, Yijia Gu, Albina Borisevich, Long-Qing Chen, For Full List Of Authors, See Publisher's Website. Aug 2012

Conductivity Of Twin-Domain-Wall/Surface Junctions In Ferroelastics: Interplay Of Deformation Potential, Octahedral Rotations, Improper Ferroelectricity, And Flexoelectric Coupling, Eugene A. Eliseev, Anna N. Morozovska, Yijia Gu, Albina Borisevich, Long-Qing Chen, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

Electronic and structural phenomena at the twin-domain-wall/surface junctions in the ferroelastic materials are analyzed. Carriers accumulation caused by the strain-induced band structure changes originated via the deformation potential mechanism, structural order parameter gradient, rotostriction, and flexoelectric coupling is explored. Approximate analytical results show that inhomogeneous elastic strains, which exist in the vicinity of the twin-domain-wall/surface junctions due to the rotostriction coupling, decrease the local band gap via the deformation potential and flexoelectric coupling mechanisms. This is the direct mechanism of the twin-wall static conductivity in ferroelastics and, by extension, in multiferroics and ferroelectrics. On the other hand, flexoelectric and rotostriction …

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Transition Of Deformation Behavior In An Ultrafine Grained Magnesium Alloy, S. K. Panigrahi, K. Kumar, N. Kumar, W. Yuan, R. S. Mishra, R. Delorme, B. Davis, R. A. Howell, K. Cho Jul 2012

Transition Of Deformation Behavior In An Ultrafine Grained Magnesium Alloy, S. K. Panigrahi, K. Kumar, N. Kumar, W. Yuan, R. S. Mishra, R. Delorme, B. Davis, R. A. Howell, K. Cho

Materials Science and Engineering Faculty Research & Creative Works

The deformation behavior of friction stirs processed magnesium alloy with average grain size ranging from 25 μm to 240 nm was studied. an evaluation of critical grain size for transition of deformation mode from twinning to slip was carried out by employing tensile and compressive tests. the role of critical grain size in transition of deformation behavior from strain hardening to softening was established. Inhomogeneous yielding was observed during tensile test of ultrafine-grained magnesium alloy below the critical grain size. © 2012 Elsevier B.V.

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Method For Producing Pressurelessly Sintered Zirconium Diboride/Silicon Carbide Composite Bodies, Shi C. Zhang, Greg Hilmas, William Fahrenholtz Jul 2012

Method For Producing Pressurelessly Sintered Zirconium Diboride/Silicon Carbide Composite Bodies, Shi C. Zhang, Greg Hilmas, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

A method of sintering a ZrB2-SiC composite body at ambient pressures, including blending a first predetermined amount of ZrB2 powder with a second predetermined amount of SiC powder, wherein both powders are characterized by the presence of surface oxide impurities. Next the blended powders are mixed to yield a substantially homogeneous powder mixture and a portion of the substantially homogeneous powder mixture is formed into a green body. The body is fired to a first temperature, wherein substantially all surface oxide impurities are reduced and/or volatilized to substantially eliminate oxides from the green body, and the body …

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Spin Diffusion In Bulk Gan Measured With Mnas Spin Injector, Shafat Jahangir, Fatih Dogan, Hyun Kum, Aurelien Manchon, Pallab Bhattacharya Jul 2012

Spin Diffusion In Bulk Gan Measured With Mnas Spin Injector, Shafat Jahangir, Fatih Dogan, Hyun Kum, Aurelien Manchon, Pallab Bhattacharya

Materials Science and Engineering Faculty Research & Creative Works

Spin injection and precession in bulk wurtzite n-GaN with different doping densities are demonstrated with a ferromagnetic MnAs contact using the three-terminal Hanle measurement technique. Theoretical analysis using minimum fitting parameters indicates that the spin accumulation is primarily in the n-GaN channel rather than at the ferromagnet (FM)/semiconductor (SC) interface states. Spin relaxation in GaN is interpreted in terms of the D'yakonov-Perel mechanism, yielding a maximum spin lifetime of 44 ps and a spin diffusion length of 175 nm at room temperature. Our results indicate that epitaxial ferromagnetic MnAs is a suitable high-temperature spin injector for GaN.

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Effects Of Rare-Earth Doping On Femtosecond Laser Waveguide Writing In Zinc Polyphosphate Glass, Luke B. Fletcher, Jon J. Witcher, Neil Troy, Signo Tadeu Dos Reis, Richard K. Brow, Denise M. Krol Jul 2012

Effects Of Rare-Earth Doping On Femtosecond Laser Waveguide Writing In Zinc Polyphosphate Glass, Luke B. Fletcher, Jon J. Witcher, Neil Troy, Signo Tadeu Dos Reis, Richard K. Brow, Denise M. Krol

Materials Science and Engineering Faculty Research & Creative Works

We have investigated waveguide writing in Er-Yb doped zinc polyphosphate glass using a femtosecond laser with a repetition rate of 1 KHz. We find that fabrication of good waveguides requires a glass composition with an O/P ratio of 3.25. The dependence on laser writing parameters including laser fluence, focusing conditions, and scan speed is reported. Waveguide properties together with absorption and emission data indicate that these glasses can be used for the fabrication of compact, high gain amplifying devices.

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Process Optimization For Friction-Stir-Welded Martensitic Steel, M. Ghosh, K. Kumar, R. S. Mishra Jun 2012

Process Optimization For Friction-Stir-Welded Martensitic Steel, M. Ghosh, K. Kumar, R. S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Advanced high-strength M190 steel sheets were joined by friction-stir welding under different tool rotational and traversing speeds. the optical microstructure of the joints exhibited complete martensite and partial martensite at the weld nugget depending on the cooling rate during welding. the first heat-affected zone outside of the weld nugget revealed ferrite-pearlite phase aggregate, and the second heat-affected zone showed a tempered martensitic structure. the interplay of process variables in terms of peak temperature and cooling rate was studied to observe their effect on joint efficiency under shear testing. the peak hardness at weld nugget was close to the parent alloy …

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Glasses For Radiotherapy, Delbert E. Day May 2012

Glasses For Radiotherapy, Delbert E. Day

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

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Effective Dielectric Constant Of Two Phase Dielectric Systems, Vladimir Petrovsky, Piotr Jasinski, Fatih Dogan May 2012

Effective Dielectric Constant Of Two Phase Dielectric Systems, Vladimir Petrovsky, Piotr Jasinski, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Various theoretical approaches are implemented for electrical characterization of two-phase material systems. Most of these approaches do not include possibility of percolation of the dispersed material. In this article brick wall model is extended on the systems exhibiting percolation. Transition from brick wall geometry to corresponding equivalent circuits provides final equations for effective dielectric constant. Comparison of theoretical results with experimental data shows that developed equations provide good fitting of effective dielectric constant to experimental values. Dielectric constants of both phases and percolation threshold calculated from the fitting match the corresponding experimental values of the phases.

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Material Flow And Microstructural Evolution During Friction Stir Spot Welding Of Az31 Magnesium Alloy, W. Yuan, Rajiv S. Mishra, B. Carlson, R. Verma, R. K. Mishra May 2012

Material Flow And Microstructural Evolution During Friction Stir Spot Welding Of Az31 Magnesium Alloy, W. Yuan, Rajiv S. Mishra, B. Carlson, R. Verma, R. K. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Material flow and local texture evolution during friction stir spot welding (FSSW) of AZ31 magnesium alloy was characterized by varying tool rotation rates. Texture at various locations of the welded region was measured using electron backscatter diffraction (EBSD). Material flow is significantly influenced by tool rotation rate with a conical step spiral pin tool, and FSSW introduces a unique basal fiber texture in the welded region. Results indicate that local texture evolution is dominated by shear deformation through material flow. the tool shoulder applies both shear and compressive deformation to the upper region material; however, the rotating pin introduces only …

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The Flow And Fracture Of Advanced Glasses - An Overview, Tanguy Rouxel, Richard K. Brow Mar 2012

The Flow And Fracture Of Advanced Glasses - An Overview, Tanguy Rouxel, Richard K. Brow

Materials Science and Engineering Faculty Research & Creative Works

Editors' note on appropriate occasions, the International Journal of Applied Glass Science will engage the services of Guest Editors to help focus on topics of special interest to the international glass community. in this inaugural issue of this initiative, Professors Tanguy Rouxel and Richard Brow have accomplished just that in their overview of the subject "Flow and Fracture of Advanced Glasses." an introduction to this material and brief biographical sketch are given below. Our sincere thanks are extended to them for their help and cooperation throughout this undertaking, and especially the authors who contributed so much of their time, energy, …

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Phenomenological Thermodynamic Potential For Catio₃ Single Crystals, Yijia Gu, Karin Rabe, Eric Bousquet, Venkatraman Gopalan, Long-Qing Chen Feb 2012

Phenomenological Thermodynamic Potential For Catio₃ Single Crystals, Yijia Gu, Karin Rabe, Eric Bousquet, Venkatraman Gopalan, Long-Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

The antiferrodistortive (AFD) structural transitions of calcium titanate (CaTiO3) at ambient pressure have been extensively studied during the last few years. It has been found that none of the AFD polymorphs is polar or ferroelectric. However, it was recently shown theoretically and later experimentally confirmed that a ferroelectric transition in CaTiO3 can be induced by tensile strains. The ferroelectric instability is believed to be strongly coupled to the AFD soft modes. In this paper, we present a complete thermodynamic potential for describing the coupling between the AFD and ferroelectric phase transitions. We analyzed the dependence of transition …

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Hot Deformation Behavior Of Friction-Stir Processed Strip-Cast 5083 Aluminum Alloys With Different Mn Contents, M. A. García-Bernal, Rajiv S. Mishra, R. Verma, D. Hernández-Silva Feb 2012

Hot Deformation Behavior Of Friction-Stir Processed Strip-Cast 5083 Aluminum Alloys With Different Mn Contents, M. A. García-Bernal, Rajiv S. Mishra, R. Verma, D. Hernández-Silva

Materials Science and Engineering Faculty Research & Creative Works

Fine grained 5083 aluminum alloy is the most common Al-Mg alloy for superplastic forming (SPF) of lightweight sheet metal parts in the automotive and aerospace industries. the fine-grained sheet is industrially produced by massive cold rolling of conventionally rolled sheet stock at high cost. Friction stir processing (FSP) as a thermomechanical process is very effective in refining the microstructure of as-cast alloys such as that produced by continuous strip casting (CC). in this work, the effect of friction stirs processing on the superplastic properties of three CC 5083 aluminum alloys, with different Mn content, has been investigated. the three alloys …

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High-Density Pressurelessly Sintered Zirconium Diboride/Silicon Carbide Composite Bodies And A Method For Producing The Same, Shi C. Zhang, Greg Hilmas, William Fahrenholtz Jan 2012

High-Density Pressurelessly Sintered Zirconium Diboride/Silicon Carbide Composite Bodies And A Method For Producing The Same, Shi C. Zhang, Greg Hilmas, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

A method of sintering a ZrB2-SiC composite body at ambient pressures, including blending a first predetermined amount of ZrB2 powder with a second predetermined amount of SiC powder, wherein both powders are characterized by the presence of surface oxide impurities. Next the blended powders are mixed to yield a substantially homogeneous powder mixture and a portion of the substantially homogeneous powder mixture is formed into a green body. The body is fired to a first temperature, wherein substantially all surface oxide impurities are reduced and/or volatilized to substantially eliminate oxides from the green body, and the body …

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Deposition Of Cerium-Based Conversion Coatings On Aluminum Alloy 380, Ci Lin, Surender Maddela, William Fahrenholtz, Matthew O'Keefe Jan 2012

Deposition Of Cerium-Based Conversion Coatings On Aluminum Alloy 380, Ci Lin, Surender Maddela, William Fahrenholtz, Matthew O'Keefe

Materials Science and Engineering Faculty Research & Creative Works

Cerium-based conversion coatings were deposited on as-cast aluminum alloy 380 substrates by a spontaneous immersion process. In this study, the effects of rinsing temperature prior to immersion in the coating deposition solution were studied with respect to the surface morphology, electrochemical response, and corrosion resistance of the coatings. Panels rinsed at 25 degrees celsius prior to coating had large cracks and holes in the coating. In contrast, panels rinsed at 100 degrees celsius prior to coating had a uniform coating morphology with fewer, smaller cracks. Electrochemical testing revealed that coatings deposited on substrates rinsed at 100 degrees celsius had higher …

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Effective Dielectric Constant Of Two Phase Systems, Vladimir Petrovsky, Piotr Z. Jasinski, Fatih Dogan Jan 2012

Effective Dielectric Constant Of Two Phase Systems, Vladimir Petrovsky, Piotr Z. Jasinski, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Theoretical approaches to electrical characterization of two phase systems are mostly limited to the systems where the individual components exhibit the same type of conductivity (pure dielectric or pure conductive systems). In this article, the brick wall geometry is extended to the mixed conductive systems with percolation. Impedance spectroscopy techniques were used for experimental investigation of slurries. Various metal oxide powders and host liquids were analyzed using a wide range of solids loadings. Comparison of experimental results with theoretical predictions shows good fitting of the experimental data. Parameters (the values of permittivity for both phases and percolation threshold) calculated from …

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Directional Anisotropy In The Mechanical Behavior Of Friction Stir Processed And Aged Az91 Alloy, Vipin Jain, Wei Yuan, R. S. Mishra, Gouthama, Anil K. Gupta Jan 2012

Directional Anisotropy In The Mechanical Behavior Of Friction Stir Processed And Aged Az91 Alloy, Vipin Jain, Wei Yuan, R. S. Mishra, Gouthama, Anil K. Gupta

Materials Science and Engineering Faculty Research & Creative Works

Friction stir processing (FSP) is an emerging grain refinement technique for magnesium alloys. in this study, a cast AZ91 alloy was processed by a single-pass FSP to achieve an average grain size of ∼6 μm in the nugget zone. the FSP is found to introduce texture in the alloy due to preferred alignment of basal poles in the processing direction. the mechanical behavior is significantly influenced by texture. after FSP, the alloy was aged at different temperatures and times for continuous and discontinuous precipitation of β-Mg17Al12. a high anisotropy in yield stress is observed in the processing and transverse direction …

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Grain Boundary Behavior In An Ultrafine-Grained Aluminum Alloy, P. S. De, R. S. Mishra Dec 2011

Grain Boundary Behavior In An Ultrafine-Grained Aluminum Alloy, P. S. De, R. S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

The low-angle grain boundary (LAGB) stability in an ultrafine-grained (UFG) Al alloy during monotonic loading was investigated by orientation imaging microscopy (OIM). the experiments show that boundaries with misorientation below ∼2.5 deg are stable, while boundaries with misorientation between 2.5 and 15 deg are unstable. Similar results were observed during cyclic loading of UFG Al alloy. This behavior was rationalized using the nonequilibrium thermodynamics concept. on the other hand, it is postulated that the grain boundary behavior in microcrystalline alloy is different because of the larger dislocation mean free path. © 2011 the Minerals, Metals & Materials Society and ASM …

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Fluid Flow-Related Transport Phenomena In Steel Slab Continuous Casting Strands Under Electromagnetic Brake, Yufeng Wang, Lifeng Zhang Dec 2011

Fluid Flow-Related Transport Phenomena In Steel Slab Continuous Casting Strands Under Electromagnetic Brake, Yufeng Wang, Lifeng Zhang

Materials Science and Engineering Faculty Research & Creative Works

In the current study, a three-dimensional (3D) numerical model is built to investigate the effect of a local-type electromagnetic brake (EMBr) on the fluid flow, heat transfer, and inclusion motion in slab continuous casting strands. the results indicate that the magnetic force affects the jet characteristics, including jet angle, turbulent kinetic energy, and its dissipation rate. to reduce the top surface velocity and stabilize the top surface, the magnetic flux intensity should be larger than a critical value. with a 0.39 T magnetic flux intensity, the top surface velocity and its fluctuation can be well controlled, and less slag is …

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Influence Of Grain Size And Texture On Hall-Petch Relationship For A Magnesium Alloy, W. Yuan, S. K. Panigrahi, J. Q. Su, R. S. Mishra Dec 2011

Influence Of Grain Size And Texture On Hall-Petch Relationship For A Magnesium Alloy, W. Yuan, S. K. Panigrahi, J. Q. Su, R. S. Mishra

Materials Science and Engineering Faculty Research & Creative Works

Friction stir processing was applied to a magnesium alloy to generate various grain sizes with the same intense basal texture. Subsequent tensile deformation along two orthogonal directions by easy activation or inhibition of basal slip follows the Hall-Petch relationship between yield stress and grain size in both directions. the Hall-Petch parameters are texture dependent. Easy activation of basal slip introduces lower values, while inhibition of basal slip leads to higher values. the Hall-Petch parameters are interpreted by texture and microstructural factors. © 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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Processing And Dielectric Properties Of Tio2 Thick Films For High-Energy Density Capacitor Applications, Sheng Chao, Fatih Dogan Nov 2011

Processing And Dielectric Properties Of Tio2 Thick Films For High-Energy Density Capacitor Applications, Sheng Chao, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Nanosized titanium dioxide (TiO2) powders (∼40 nm) were used for preparation of tape-casting slurries. Effect of various solvents and dispersants on the dispersibility of TiO2 slurries was studied by sedimentation tests and rheology measurements. TiO2 green tapes were prepared by tape-casting method and densified at 1000°C with a sintered density >95%. Dielectric properties of TiO2 tapes were studied by measuring of dielectric constant, loss factor and dielectric breakdown strength (BDS) with respect to their microstructural development. BDS values as high as ∼1400 kV/cm were obtained for sintered tapes so that energy densities up to 14 …

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Simulation Of The Fluid Flow-Related Phenomena In The Electrolyte Of An Aluminum Electrolysis Cell, Yufeng Wang, Lifeng Zhang, Xiangjun Zuo Oct 2011

Simulation Of The Fluid Flow-Related Phenomena In The Electrolyte Of An Aluminum Electrolysis Cell, Yufeng Wang, Lifeng Zhang, Xiangjun Zuo

Materials Science and Engineering Faculty Research & Creative Works

A full-scale water model and mathematical simulation were used to study the fluid flow-related phenomena in a water model of an aluminum electrolysis cell. the time-dependent, multiphase fluid flow model was developed to represent the complex transient flow in the electrolysis bath. the accuracy of the mathematical model was validated by the ink dispersion and laser doppler velocimetry measurements in the water model. the shape, motion, release frequency of large-size bubbles, the fluid flow pattern, and the electrolyte-metal interface were predicted by the mathematical simulation. the design and operation of the anode were discussed, including the effect of the anode …

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Kinetic Analysis Of The Thermal Degradation Of Printed Wiring Boards, Alex Luyima, Lifeng Zhang, Lucas Nana Wiredu Damoah Aug 2011

Kinetic Analysis Of The Thermal Degradation Of Printed Wiring Boards, Alex Luyima, Lifeng Zhang, Lucas Nana Wiredu Damoah

Materials Science and Engineering Faculty Research & Creative Works

The non-isothermal pyrolysis of printed wiring boards (PWBs) was investigated by simultaneous thermogravimetric and differential thermal analysis (TG-DTA) in the temperature range of 300-1200 K. Pyrolysis experiments were carried out on PWBs samples at three different heating rates of 10, 20, and 30°C/min. in this study, the kinetic parameters of PWBs pyrolysis have been estimated using model free and model fitted methods. © 2011 TMS.

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Large Kinetic Asymmetry In The Metal-Insulator Transition Nucleated At Localized And Extended Defects, W. Fan, Jinbo Cao, J. Seidel, Yijia Gu, J. W. Yim, For Full List Of Authors, See Publisher's Website. Jun 2011

Large Kinetic Asymmetry In The Metal-Insulator Transition Nucleated At Localized And Extended Defects, W. Fan, Jinbo Cao, J. Seidel, Yijia Gu, J. W. Yim, For Full List Of Authors, See Publisher's Website.

Materials Science and Engineering Faculty Research & Creative Works

Superheating and supercooling effects are characteristic kinetic processes in first-order phase transitions, and asymmetry between them is widely observed. In materials where electronic and structural degrees of freedom are coupled, a wide, asymmetric hysteresis may occur in the transition between electronic phases. Structural defects are known to seed heterogeneous nucleation of the phase transition, hence reduce the degree of superheating and supercooling. Here we show that in the metal-insulator transition of single-crystal VO 2, a large kinetic asymmetry arises from the distinct spatial extension and distribution of two basic types of crystal defects: point defects and twin walls. Nanometer-thick twin …

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Effect Of Slide Gate And Embr On The Transport Of Inclusions And Bubbles In Slab Continuous Casting Strands, Yufeng Wang, Anping Dong, Lifeng Zhang Apr 2011

Effect Of Slide Gate And Embr On The Transport Of Inclusions And Bubbles In Slab Continuous Casting Strands, Yufeng Wang, Anping Dong, Lifeng Zhang

Materials Science and Engineering Faculty Research & Creative Works

This study is to investigate the effect of electromagnetic brake (EMBr) on fluid flow and particle motion in steel slab continuous casting strands. the effect of slide gate moving on fluid flow pattern was discussed. a strong swirl and asymmetrical flow at the outports and, subsequently, inside the slab mold, was induced by slide gate. the application of EMBr would be a remedy to the swirl flow in the casting mold. Flow pattern has great influence on the trajectories of injected bubbles and nonmetallic inclusions. More bubbles tend to release from the top surface near the wide face opposite to …

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