Materials Science and Engineering Commons^™

Cathodic Behavior Of Co, Co-Fe Alloys And Some Other Metals In Acids In A Cathodic Protection Arrangement, Ram Bajaj

Masters Theses

"During cathodic protection of a corroding metal, electrons are forced into the metal by a sacrificial anode, a battery or a rectifier. These electrons, which constitute the suppressing or external current, are discharged (by H⁺ of the corrosive liquid) on the local cathode of the corroding metal decreasing the emf of the local cells, and, thus, reducing the cell current or the rate of corrosion of the metal. This process was studied in detail by finding out the relationship existing between the cell and suppressing currents. The study was made using two circuits: the cell circuit (representing the local current) …

Thermal-Fatigue Of Type 304 Stainless Steel, Gajinder Bir Singh Arora

Masters Theses

"Thermal fatigue resistance of unrestrained samples of type 304 stainless steel has been investigated under different test conditions. The following studies are reported: (a) effects of heating and cooling rates on the initiation of cracks, (b) effects of upper and lower cycle temperatures on the initiation of cracks, (c) effect of water quenching and (d) the manner in which cracks initiated and propagated. It is shown that under cyclic conditions involving maximum temperatures up to 1000°C, the thermal fatigue life of the material decreases rapidly with rise in the maximum temperature of the cycle. The increase in the lower cycle …

The Effect Of Thermal-Mechanical Processing Of The Exfoliation Corrosion Resistance Of An Aluminum-Zinc-Magnesium-Copper Alloy, James Lawrence Spehr

Masters Theses

"The objective of this investigation was to evaluate the effect of thermal-mechanical processing on the exfoliation corrosion resistance of an aluminum-zinc-magnesium-copper alloy. the aluminum alloy used was commercially available 7178 alloy in two thicknesses, 0.390 inch thick and 0.250 inch thick. this material was reduced 10, 25 and 40% in thickness in both the annealed and solution heat treated conditions. The material was then aged to a high strength condition, T6, or T8, in the case of the material reduced in the solution heat treated condition. The effect of the thermal-mechanical processing on the exfoliation corrosion resistance was then evaluated …

Effect Of Hydrostatic Pressure On Anelastic Stress Relaxation In A Mixed-Alkali Silicate Glass, Young-Gil (Gilbert Y.) Kim

Masters Theses

"The effect of hydrostatic pressure on the anelastic stress relaxation of a mixed-alkali silicate glass (0.05 Na₂O, 0.95 K₂O, 3 SiO₂) was studied at 75°C between ambient pressure and 6 kbar. The activation volume of diffusion was found to be - 4.2 cm³/mole. It is proposed that a reequilibration of the defect population at pressure gives rise to the negative activation volume of diffusion"--Abstract, page ii.

Anodic Oxidation Of Pure And D.S. (Dispersion Hardened) Lead In Sulfuric Acid Solutions, Rafael San Martin Aldazabal

Masters Theses

"The anodic oxidation of pure and dispersion hardened lead in 1 N H₂SO₄ was studied potentiostatically in the range - 0.28 to 2.0 volts (SHE). The anode surfaces were observed at various stages on a scanning electron microscope and x-ray diffraction techniques were used to determine the phases present. It was established that by oxidation up to 0.25 v only PbSO₄ is obtained. At potentials between 0.25 and 1.57 v, PbO (tetragonal) is formed beneath the lead sulfate layer. At potentials above 1.57 up to 2.0 v, a layer of ßPbO₂ forms in the outermost part of the anode underlying …

Precipitation Hardening Of A Mg - 3.5 Wt. % Th - 1. Wt. % Mn Alloy, Adolf Chun-Chiung Huang

Masters Theses

"The precipitation process in a Mg - 3.5 wt. % Th - 1. wt. % Mn alloy during aging at 260⁰, 350⁰ and 400⁰C was determined principally by transmission electron microscopy. At 350⁰ and 400⁰C, general precipitation of the equilibrium Mg₄Th phase moderately hardens the alloy. No transition lattice of this phase was seen. The Mg₄Th precipitate forms initially as disc shaped plates parallel either to the prism or basal plane of the matrix...During prolonged aging at 400⁰C the plates lengthen into long laths on either of the above planes in the close packed direction...At 260⁰C an unidentified G. P. …

Establishment Of A Torsion Pendulum And Its Evaluation, Ashwin Kantilal Ghatalia

Masters Theses

"A torsion pendulum apparatus has been constructed. The pendulum has been evaluated by studying the Zener relaxation in α brass. Three wire specimens of commercial alloy of Cu-Zn were used and the value of log decrement has been obtained by the method of free decay of the oscillations. The known Zener peak was observed"--Abstract, page ii.

Thermal Fatigue Testing Of Die Casting Die Steels, Kulwant Singh Sabharwal

Masters Theses

"Thermal fatigue is a form of surface failure produced by repeated thermal stresses and is the main cause of die retirement in the die casting industry. A general review of the fundamental and practical aspects of thermal fatigue as encountered in the dies, based on earlier published work, is given and preliminary experiments in an effort to set up a suitable method of testing to study this phenomenon are then described. In the present technique developed to create the thermal conditions experienced by a die steel in aluminum die casting, a small portion of one face of a cylindrical test-piece …

The Effect Of Aging On The Exfoliation Corrosion Characteristics Of 7178 Aluminum Alloy, J. James Slavick

Masters Theses

"The objective of this investigation was twofold: 1) to determine the effect of the quench-to-artificial aging delay period on the exfoliation corrosion of 7178 aluminum alloy subsequently aged at 250F for 24 hours and 2) to determine the effect of an initial aging treatment at 212F on the tensile properties and exfoliation of 7178 aluminum subsequently aged at 250F. Testing was conducted on 0.125 inch thick sheet. Quench-to-aging delay periods of 0 to 28 days, and initial artificial aging treatments at 212F for 24 and 48 hours were investigated. In addition, the effect of overaging T6 material at 320F for …

Internal Friction Of Phase Separated Glasses, Scot Walter Taylor

Masters Theses

"The large internal friction peak observed in a 10Li₂O·10Na₂O·80SiO₂ glass was studied as a function of the degree of phase separation. Transmission electron microscopy was used to evaluate the type and degree of phase separation. No observable changes in the temperature position or height of the internal friction peak were observed at successive stages of phase separation. Phase separation of a mixed alkali borosilicate glass also produced no changes in the internal friction peaks. Phase separation is not considered responsible for the large internal friction peak observed in mixed alkali glasses"--Abstract, page ii.

The Effect Of Small Additions Of Niobium Upon The Corrosion Rates And Electrochemical Potentials Of Iron In Hcl, Hf, And H₂So₄, Richard Lee Jones

Masters Theses

"The valence of niobium ions going into solution was determined by dissolving the metal in hot HF and measuring the volume of hydrogen evolved. The corrosion rates of Nb, NbH_x, Fe and Fe - Nb alloys were determined in various concentrations of NCl, H₂SO₄ and HF. The Fe and Fe - Nb alloy samples were made by using powder metallurgy techniques. It was found that a metal skin was produced on the surface of iron corrosion samples if the carbon content of the surface layer was lower than that of the core of the sample. The lower carbon …

A Continuous Method For Determination Of The Evaporation Rate Of Zinc, Paul Alan O'Neill

Masters Theses

"A method for determination of the evaporation rate of zinc using a continuous recording balance has been devised. Tests were carried out under an inert gas over the range 600°C to 750°C with a total pressure of 1 atmosphere. It was found that the rate of evaporation doubled with an increase of 50°C in this range. Scanning electron microscope photographs show the crystalline nature of the condensate and the presence of a thin oxide layer on some solidified test samples. This oxide layer reduced the rate of evaporation by retarding the zinc vapor escape from the evaporating surface"--Abstract, Page iii.

The Electrodeposition Of Zinc; Changes In Current Efficiency And Surface Structure Resulting From Various Addition Agents, Haruhisa Fukubayashi

Masters Theses

"An examination of the surface structure of zinc electrodeposited from an acid-sulfate solution was made by scanning electron microscopy techniques. The current efficiencies were also determined, to a lesser extent, in order to correlate the results with the surface structures. Commercial and pure zinc oxide were used to prepare the neutral zinc sulfate solutions. The starting solutions were in a range of acid and zinc concentrations commonly used in commercial practice. Changes in morphology resulting from addition agents such as animal glue, gum arabic, and sodium silicate are compared"--Abstract, page ii.

Isotope Effect Of Interstitial Diffusion Of Carbon In A Dilute Fe-Si Alloy, Edward T. Yen

Masters Theses

"The isotope effect of carbon interstitial diffusion in a Fe-2.75at%Si alloy has been measured at -3.10°C using the disaccommodation technique. The disaccommodation has been analyzed in terms of two relaxation processes which are discussed on the basis of the reorientation mechanism of carbon interstitials at Fe-Fe sites and Fe-Si sites respectively. The ratios of the relaxation times [tau]₁₃/[tau]₁₂ are 1.0382 for the former and 1.0072 for the latter relaxation process. This result is discussed on the basis of many-body reaction rate theory"--Abstract, page ii.

Pressure Welding Of Continuously Cast Nodular Iron, Gerald W. Wille

Masters Theses

"The objective of this study was to determine the feasibility of using pressure welding as a joining technique for swaged nodular iron.

Test pressure welds were produced with swaged continuous cast nodular iron at temperatures between 1750⁰F and 2050⁰F with welding pressures between 15,900 psi and 51,400 psi using an induction coil to heat the weld zone.

Pressure welds of greater strength than the as-received nodular iron were produced by swaging the material before welding. The optimum welding parameters were a temperature of 2050⁰F with a welding pressure of 46,700 psi.

On the basis of these tests it is concluded …

Compressive Creep Of Basic Refractories, Maurice E. Green

Masters Theses

"The microstructure and mineralogical composition of direct bonded, 50 wt.% magnesia - 50 wt.% chrome ore refractory compositions containing controlled additions of silica were correlated with their compressive creep behavior in the temperature range 1450⁰ to 1550⁰C under stresses of 100 to 175 psi. Steady state creep rates were determined from the linear regression of the steady state regions of deformation on time. Apparent activation energies and deformation flow characteristics were determined from the temperature and stress dependence of the steady state creep rates. Silica contents up to 3.5 wt.% increased the amount of direct intergranular bonding which decreased the …

Kinetics Of The Formation Of Strontium Zirconate, W. H. Parker

Masters Theses

"The decomposition rate of strontium carbonate (SrC0₃) was measured using a TGA apparatus. It was found to deviate slightly from zero order classical reaction. The rate of formation of strontium zirconate (SrZr0₃) from zirconium oxide (ZrO₂) and strontium oxide (SrO) in the form of the decomposition product of SrCO₃ was measured using quantitative x-ray diffraction for mineralogical analysis. It was found to most nearly follow the Zhuravlev-Lesokhin-Tempel' man rate equation. The rate of decomposition of strontium carbonate was found to be more rapid than the rate of formation of strontium zirconate such that for the most part strontium oxide is …

The Effect Of Prior Cold Work On The Pressure Welding Of Ferritic Nodular Iron, Ronald Morris Ledbetter

Masters Theses

"The purpose of this investigation was to determine the effect of prior cold work by swaging on the pressure welding of ferritic nodular iron. Test pressure welds were produced from continuously cast ferritic nodular iron in the as cast condition and with prior cold work of 20, 30, 40, and 50 per cent reductions in area. Welding pressures of 23,500 psi, 35,300 psi, and 47,100 psi were employed. All welds were made at interface temperatures of 2000°F. Welds made with the as cast material at high welding pressures possessed relatively low tensile strengths due to the creation of planes of …

Lattice Parameters, Coefficients Of Thermal Expansion, Densities, And Lattice Perfection Of The Copper-Indium Primary Solid Solutions, Lin Sheng Yu

Masters Theses

"Precise measurements of lattice parameters and densities of the alpha-phase Cu-In solid solutions were made at temperatures of 25°C. The thermal expansion coefficients between 15 and 65°C, the solid solubility of In in Cu at 650°C, and the soundness of crystal structure resulting from alloying were determined. The Cu-In alloys were prepared from high purity (99.999%) Cu and In by melting both metals inside evacuated quartz tubes. The solidified alloys were annealed and then examined by X-ray for homogeneity...The slowly solidified alpha-phase alloys gave densities lower than the theoretical (X-ray) values due to the presence of shrinkage microporosity. This density …

The Inert Gas Effect On The Rate Of Evaporation Of Zinc And Cadmium, Chu Sheng Wu

Masters Theses

"An experimental study has been made to investigate the effect of argon and helium on the rate of evaporation of zinc and cadmium under one atmosphere pressure at temperatures ranging from 500⁰C to 850⁰C. The experimental results were compared with the maximum rates calculated using the effusion formula as well as with values obtained using three different types of equations based on kinetic theory, diffusion theory, and empirical data. The rate of evaporation in this study appeared to be diffusion controlled. Equations have been derived for expressing the rate of evaporation of zinc and cadmium in both argon and helium …

A Mechanical Metallurgical Method Of Predicting The Springback Tendencies Of A Bent Metal Strip, Jerrold Myles Alyea

Masters Theses

"Attempted substitution of new solid materials and composite metal strips for those materials presently being used in many applications now being pursued vigorously in industry. A serious problem was created because the newly proposed materials do not exhibit the same springback after bending as did the previously used materials in a particular bend angle and radius situation. Elementary bend theory and mechanical metallurgical techniques have been incorporated into a method which can be used to accurately predict the .2% offset yield strength of any proposed rolled-temper solid metal strip and some composite strips when they must exhibit the same springback …

Corrosion Rates And Electrokinetics Of Cobalt And Cobalt-Rich Cobalt-Iron Alloys In Sulfuric And Hydrochloric Acids, Cheng Tzong Horng

Masters Theses

"Corrosion rates for Co and Co-rich Co-Fe alloys were determined in sulfuric and hydrochloric acids under both deaerated and oxygenated conditions. For the purpose of comparison, corrosion rates of Co cut from metal sheet were also determined in the same environments as those of sintered alloys. Sintered alloys were inferior to solid Co as corrosion resistant materials. It was found that the surface was more corrosion resistant than the interior. Thus after long exposure to the corrosive acid, the samples became porous inside while the surfaces remained substantially intact. Oxygen had a pronounced effect in accelerating the corrosion of Co …

Influence Of Nobler Metal Salt Additions Upon The Dissolution Rate Of Aluminum In Hydrofluoric Acid, Barry L. Basden

Masters Theses

"The rate of dissolution of aluminum in 2N HF upon the addition of nobler metallic salts was studied. Aluminum corrodes in HF due to the acid's ability to dissolve the protective oxide present on the surface. Rates were measured by the hydrogen evolution method. Salt additions of AgN0₃, CuSO₄, HAuC₄, and PtCl₄ to aluminum dissolving in 2N HF resulted in the electroless deposition of more or less coherent metals (from the salts mentioned) on the aluminum surface. The dissolution rate initially decreased in all of the cases and was attributed to the "blanketing effect" of the deposits. Ensuing increases of …

Relationships Among The Metallurgical Condition, Hardness, And The Electrical Conductivity Of Aluminum Alloys, Richard A. Mueller

Masters Theses

"Electrical conductivity measurements (eddy current determined) combined with indentation hardness measurements are now being used throughout the aerospace industry for nondestructive evaluation of the metallurgical condition of commercial precipitation hardenable aluminum alloys. The review of literature and experiments with two aluminum alloys, 7178 and a 5% Zn-Al binary, have shown that skilled interpretation of hardness-conductivity data depends not only upon a qualitative understanding of the modern wave mechanical theories of electron conduction, but also upon some knowledge of the precipitation reaction kinetics. In particular, the effects of "quenched-in" vacancies and retrogression upon the reaction kinetics must be considered. Studies of …

A Determination Of The Rate Of Evaporation Of Zinc At Atmospheric Pressure., Yu Ming Su

Masters Theses

"Measurements of evaporation rates of zinc in three different residual gases, e.g., argon, carbon monoxide, and hydrogen at one atmosphere pressure, were made. It was found that the rate of evaporation of zinc in one atmosphere of argon was almost the same as that in carbon monoxide, while the rate in hydrogen was almost twice the rate in argon or carbon monoxide. Measurements of evaporation rate of zinc in one atmosphere of argon-oxygen mixtures were also made. The evaporation rate was considerably reduced because the formation of the oxide film retards the zinc vapor escaping from the evaporating surface"--Abstract, page …

A Comparison Of Strength Properties Of Heat Treated Aisi 1065 Steels At High Strength Levels, Robert Lowell Hollenbeck

Masters Theses

"Six AISI C 1065 steels were heat treated and tensile tested in order to evaluate their ductility at high strength levels. Heat treating and tensile testing procedures were developed for use working with these steels at tensile strengths of 300,000 psi and higher. The austenitizing procedure in the hardening operation was found to affect the strength and ductility of the high strength samples. Rapidly heating to the austenitizing temperature followed by an immediate quench produced better properties than slow heating followed by a soaking period before the quench. However, it was concluded that the carbon contents of the steels studied …

A Transmission Electron Microscopy Study Of Some High Strength Plain Carbon Steels, George Joseph Vytanovych

Masters Theses

"Methods of preparing foils of high strength, heat treated, plain carbon steels for examination in the electron microscope by the transmission technique were perfected and are described. Two processes for the initial thinning of a bulk sample were successful. A chemical process was found to be more rapid but not satisfactory for small samples. A mechanical process was slower, but was applicable to the smaller specimens. Electro-polishing the thinned material yielded acceptable foils from which photomicrographs of good quality were obtained. The microstructure of the high strength steel samples showed typical tempered martensite. No reasons for the differences in ductility …

Lattice Constants, Thermal Expansion Coefficients, Densities, And Imperfections In Gold And The Alpha-Phase Of The Gold-Indium System, Vinayak Keshavlal Patel

Masters Theses

"An investigation of structure insensitive properties (lattice parameters, thermal expansion coefficients, densities, and imperfection) of gold and the alpha-phase of the gold-indium system was made. The gold-indium alloys were prepared from high purity (99.999%) gold and indium by melting both metals inside sealed quartz glass tubes which were first evacuated and then filled with helium gas. The solidified alloys were annealed and then examined by x-ray for homogeneity. The lattice constant of 99.999% pure gold at 25⁰C was found to be 4.07894 ł 0.00005 (corrected for refraction) Å. The coefficient of thermal expansion was 13.4 x 10⁻⁶⁰C⁻¹ between 15 and …

Compressive Creep Of High Alumina Refractories, Vernon Lee Burdick

Masters Theses

"The deformation of refractory materials consisting of 90% sintered or fused alumina plus 10% silica was measured at temperatures from 1450 to 1515⁰C and a compressive stress of 100 psi. Creep rates and activation energies were determined from the steady state portion of deformation vs. time data and correlated with the mineralogical composition. Supplemental measurements included x-ray diffraction, electron probe microanalysis, apparent porosity and tensile strength. conditions having an important effect upon the mineralolgical composition were: (1) duration of heat treatment, (2) amount of sodium oxide impurity, and (3) reactivity of the alumina grain. Prolonged heat treatment and sodium oxide …

Relationship Of Feldspar Properties To Surface And Volume Defects In Porcelains, Macy Wiiliam Vance

Masters Theses

"Four levels of particle size distribution and four compositions of feldspar ranging from high-potash to high-soda content were evaluated in their effect on body and surface defects and selected engineering properties of an electrical porcelain. It was found that surface blistering defects occurred at a high incidence in porcelain specimens slightly overfired at 1225⁰C in a body composition containing 33% albite (soda), 67% high-potash feldspar blend and a relatively coarse, 140 mesh grind, of the feldspar. The occurrence of surface and volume blisters was correlated with the formation of a microscopic bleb structure in the porcelain matrix. It was also …