Materials Science and Engineering Commons^™

Dielectric Properties Of A Ferroelectric Copolymer Langmuir–Blodgett Film, Mahantappa S. Jogad, Stephen Ducharme

Stephen Ducharme Publications

We report measurements of the real (epsilon prime) and imaginary (epsilon double-prime) parts of the relative complex permittivity of a Langmuir–Blodgett film of ferroelectric copolymer of vinylidene fluoride (70%) with trifluoroethylene (30%). The measurements were made in the temperature range of 35 to 125° C, and frequency range of 19 Hz to 5 MHz. The results indicate low frequency loss due to conduction and dielectric loss peak near the ferroelectric–paraelectric phase transition.

A Direct Correlation Function For Mesomorphic Polymers And Its Application To The ‘Smectic’ Phase Of Isotactic Polypropylene, Y Cohen, Ravi F. Saraf

Papers in Materials Science

A general model to calculate the structure of a smectic to nematic-like order in polymer systems is proposed. The model is limited to well-aligned molecules with respect to each other. It is especially suited for systems where the packing between neighboring chains is described by liquid-like disorder with axial registration in the chain-axis direction. In such a case the diffraction pattern from the oriented structure exhibits broad liquid-like reflections on the equatorial but sharper reflections on the layer lines. An Ornstein-Zernike approach is adopted to calculate the inter-chain packing and inter-chain registration, where the direct correlation function of packing and …

Two-Dimensional Ferroelectric Films, Alexander V. Bune, Vladimir M. Fridkin, Stephen Ducharme, Lev M. Blinov, Serguei P. Palto, Alexander V. Sorokin, S. G. Yudin, A. Zlatkin

Stephen Ducharme Publications

Ultrathin crystalline films offer the possibility of exploring phase transitions in the crossover region between two and three dimensions. Second- order ferromagnetic phase transitions have been observed in monolayer magnetic films [1,2], where surface anisotropy energy stabilizes the two-dimensional ferromagnetic state at finite temperature [3]. Similarly, a number of magnetic materials have magnetic surface layers that show a second-order ferromagnetic–paramagnetic phase transition with an increased Curie temperature [4]. Ferroelectricity is in many ways analogous to ferromagnetism, and bulk-like ferroelectricity and finite-size modifications of it have been seen in nanocrystals as small as 250 Å in diameter [5], in perovskite films …

Simulation Of The Growth Of Cvd Films, Jacob J. Thiart, Vladimir Hlavacek, Hendrik J. Viljoen

Papers in Materials Science

Chemical vapor deposition (CVD) is the preferred method of manufacture for solid films used in many industrially important thin and thick film applications. Requirements for the physical, mechanical and electrical properties of these films are becoming increasingly difficult to achieve, and deposition morphology plays an important role in this regard. Recently, we proposed a continuum model describing the evolution of a gassolid interface during atmospheric pressure CVD (Viljoen er al., 1994). A linear stability analysis (LSA) was used to determine the effect of reactor conditions on planar growth stability. The present paper discusses numerical solution of this model, and uses …

Characterization Of Piezoceramic Crosses With Large Range Scanning Capability And Applications For Low Temperature Scanning Tunneling Microscopy, J. A. Helfrich, Shireen Adenwalla, J. B. Ketterson, G. A. Zhitomirsky

Shireen Adenwalla Papers

We have developed a large amplitude piezoceramic scanner which should have numerous applications. Scanning tunneling microscopy (STM) and other scanning probe microscopies predominantly use piezoceramics for the scanning elements. Similarly adaptive optics, high resolution lithography, and micromanipulators are other examples of research which regularly utilize piezoceramic scanners. We present a new geometry for a piezoceramic scanner which allows for both high resolution (~nanometers) and large amplitude (~400 µm) displacements. The cross-shaped geometry makes it possible to produce extremely long pieces with very high tolerances. We have shown its effectiveness by using it as the major component of a low temperature …

Analysis Of Transport Phenomena In The Coating Of Fibers By Cvd, J H. Scholtz, J E. Gatica, Hendrik J. Viljoen

Papers in Materials Science

Inorganic coated fibres produced by chemical vapour deposition find several technological applications. In this CVD process, a filler core is mounted in a reactor between two electrodes. Reactive gases flow over the substrate and react near or on the fibre surface to form the desired coating. Experience has showed that, quality deposition can only be obtained over a small range of the governing parameters: these parameters are, however, difficult to control. In the present, study a mathematical model is developed for the reactor configuration under consideration. The different mass and energy transport mechanisms are compared and their influence on the …

Aircraft Quality Casting Standards, Robert Katz, Robert Bolin , Depositor

Robert Katz Publications

These standards are to be used in connection with the Handbook for Instructions for Aircraft Designers, 8^th Edition …

In the radiography of aircraft castings, markings appearing on the film may be attributed to either the condition of the castings examined, or to some details of the radiographic process entirely unrelated to the quality of the castings, These latter patterns must be recognized and related to the radiographic process so that sound castings will not be unnecessarily rejected. Radiographs must be carefully compared with the surface irregularities of the casting they represent before an attempt is made to …