Materials Science and Engineering Commons^™

Mechanical Testing Of Fused Filament 3-D Printed Components For Distributed Manufacturing, Nagendra Gautam Tanikella

Dissertations, Master's Theses and Master's Reports

Fused filament fabrication (FFF)-based open-source 3-D printers offer the potential of decentralized manufacturing both in developing and developed countries. Unfortunately, a severe lack of data and standards relating to material properties and printed components limit this potential. This thesis first investigates the mechanical properties of a wide-range of FFF materials and provides a database of mechanical strength of the materials tested. The results demonstrate that the tensile strength of a 3-D printed specimen depends largely on the mass of the specimen, which provides a means to estimate the strength of 3-D printed components. Then this information is used to evaluate …

Thermomechanical Processing Of Aluminum Micro-Alloyed With Sc, Zr, Ti, B, And C, Cameron Mcnamara

Dissertations, Master's Theses and Master's Reports

Critical exploration of the minimalistic high strength low alloy aluminum (HSLA-Al) paradigm is necessary for the continued development of advanced aluminum alloys. In this study, scandium (Sc) and zirconium (Zr) are examined as the main precipitation strengthening additions, while magnesium (Mg) is added to probe the synergistic effects of solution and precipitation hardening, as well as the grain refinement during solidification afforded by a moderate growth restriction factor. Further, pathways of recrystallization are explored in several potential HSLA-Al systems sans Sc. Aluminum-titanium-boron (Al-Ti-B) and aluminum-titanium-carbon (Al-Ti-C) grain refining master alloys are added to a series of Al-Zr alloys to examine …

Nd2fe14b: (Nd1-X Dyx)2 Fe14b Core-Shell Structure Formation By Hot Press Liquid Phase Sintering, Li Chen

Dissertations, Master's Theses and Master's Reports

The purpose of this project is to produce Nd rich core-Dy rich shell grain structure in liquid phase sintered alloys by consolidating Dy rich powder mixed with powder. The technical barrier to producing the core-shell microstructure is that the Dy composition variations will homogenize during the consolidation process. This dissertation is based on the hypothesis that compositional homogenization of the core-shell structure can be minimized if consolidation occurs under applied pressure (hot press liquid phase sintering). The hypothesis is tested by comparing the homogenization of the Dy composition to the degree of consolidation with and without applied pressure. It is …

Investigation Of The Resistance To Demagnetization In Bulk Rare-Earth Magnets Comprised Of Crystallographically-Aligned, Single-Domain Crystallites With Modified Intergranular Phase, Jie Li

Dissertations, Master's Theses and Master's Reports

The research presented in this dissertation investigates whether an increased coercivity of Neodymium-Iron-Boron (Nd2Fe14B) based bulk magnets at elevated temperature (160°C), which is now only obtainable by substituting ~7wt% dysprosium (Dy) for a portion of neodymium (Nd), can be achieved through specific microstructural modifications with decreased Dy concentrations. The approach is to reduce the size of individual crystallographically-aligned grains in the magnet so that each grain can only support a single magnetic domain and to simultaneously dilute the Nd-Fe inter-granular phase present in conventional magnets with a non-Fe-containing, Nd-rich phase (Nd-Cu alloy) in an attempt to partially magnetically isolate the …

The Effect Of Solidification Rate And Solutionizing Quench Rate On The Mechanical Properties And Hardening Response Of Aluminum Alloys: A Quantitative Comparison, Rafael Gil-Figueroa

Dissertations, Master's Theses and Master's Reports

A comparative study of five aluminum alloys was performed to characterize the effect of solidification rate and quench rate on casting microstructure and properties. The alloys were cast in the geometry for Jominy End Quench (JEQ) testing, so as to take advantage of the JEQ test’s ability to give data on multiple quench rates in a single sample and illustrate the quench sensitivity of an alloy. While the Jominy End Quench test has been used in aluminum alloys, the effects of solidification rates have not been assessed in depth. The work done by other studies has either focused on a …

Experimental Investigations Of Fused Filament Fabrication For Applications To Affordable Scientific Hardware, Bas Wijnen

Dissertations, Master's Theses and Master's Reports

This research aims to make science more accessible through the use of open source 3-D printers.

A new control system for CNC machines in general and 3-D printers specifically, is developed and presented that enables web-based control of 3-D tools from any Internet connected device. The system can be set up and controlled entirely from a web interface.

A tool was designed to help apply science to the developing world. The developing world remains plagued by lack of access to safe drinking water. A methodology is provided for the design, development, and technical validation of a low-cost open-source water testing …

Nanosphere Lithography And Its Application In Rapid And Economic Fabrication Of Plasmonic Hydrogenated Amorphous Silicon Photovoltaic Devices, Chenlong Zhang

Dissertations, Master's Theses and Master's Reports

Solar photovoltaic (PV) devices harvest energy from solar radiation and convert it to electricity. PV technologies, as an alternative to traditional fossil fuels, use clean and renewable energy while minimizing pollution. For decades researchers have been developing thin film solar cells as an important alternatives to the relatively expensive bulk crystal solar cell technology. Among those, hydrogenated amorphous silicon (a-Si:H) solar cells prevails for good efficiency, non-toxic and materially abundant nature. However, a-Si:H thickness must be minimized to prevent light induced degradation, so optical enhancement is necessary. Light manipulation has to be applied and carefully engineered to trap light within …

Dynamic Atomistic Study Of Tunnel Functions In Nanostructured Transitional Metal Oxides, Yifei Yuan

Dissertations, Master's Theses and Master's Reports

Alpha (α-) MnO₂ is a well know transitional metal oxide possessing one dimensional 2×2 (4.6 × 4.6 Ų) tunnels for accommodation of various ions. Such a characteristic tunneled structure has enabled the wide applications of α-MnO₂ in the fields of ion exchange, molecular sieves, biosensor, catalysis and energy storage. This PhD dissertation focuses on the dynamic study of ion transport functionality of α-MnO₂ at atomic level using an aberration corrected scanning transmission electron microscopy equipped with a special holder with a scanning tunneling microscopy probe.

The wide application of in situ TEM studying the dynamic …

Methodology For Analyzing Epoxy-Cnt Phononic Crystals For Wave Attenuation And Guiding, Madhu Kolati

Dissertations, Master's Theses and Master's Reports

Phononic crystals (PhnCs) control, direct and manipulate sound waves to achieve wave guiding and attenuation. This dissertation presents methodology for analyzing nanotube materials based phononic crystals to achieve control over sound, vibration and stress mitigation. Much of the analytical work presented is in identifying frequency band gaps in which sound or vibration cannot propagate through these PhnCs. Wave attenuation and mitigation analysis is demonstrated using finite element simulation. Engineering principles from current research areas of solid mechanics, solid-state physics, elasto-dynamics, mechanical vibrations and acoustics are employed for the methodology. A considerable effort is put to show that these PhnCs can …

Inhibition Of Bacterial Growth And Prevention Of Bacterial Adhesion With Localized Nitric Oxide Delivery, Julia Osborne

Dissertations, Master's Theses and Master's Reports

Bacterial infections continue to be a problem at the site of an indwelling medical device, and over the years, various bacterial strains have become more resistant to current antibiotic treatments. Bacterial infection at an indwelling medical device can be dangerous and affect the performance of the medical device which can ultimately lead to the failure of the device due to bacterial resistance to treatment.

Nitric Oxide (NO) has been shown to possess antibacterial properties to prevent and inhibit bacterial growth. NO releasing coatings on indwelling medical devices could provide a reduction in bacterial infections that occur at the device site …

Investigation And Modeling Of Al3(Sc, Zr) Precipitation Strengthening In The Presence Of Enhanced Supersaturation And Within Al-Cu Binary Alloys, Kyle Deane

Dissertations, Master's Theses and Master's Reports

Diffuse Al-Sc and Al-Zr alloys have been demonstrated in literature to be relatively coarsening resistant at higher temperatures when compared with commonly used precipitation strengthening alloys (e.g. 2000 series, 6000 series). However, because of a limited strengthening due to the low solubility of scandium and zirconium in aluminum, and owing to the scarcity and therefore sizeable price tag attached to scandium, little research has been done in the way of optimizing these alloys for commercial applications.

With this in mind, this dissertation describes research which aims to tackle several important areas of Al-Sc-Zr research that have been yet unresolved. In …

Mse Annual Report 2016, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• Faculty and Staff News
• Faculty Research
• Student News
• Senior Design Teams
• Graduate Student News
• Outreach
• Alumni News
• MSE by the Numbers
• Scholarships

Integrated Voltage—Current Monitoring And Control Of Gas Metal Arc Weld Magnetic Ball-Jointed Open Source 3-D Printer, Yuenyong Nilsiam, Amberlee S. Haselhuhn, Bas Wijnen, Paul G. Sanders, Joshua M. Pearce

Department of Materials Science and Engineering Publications

To provide process optimization of metal fabricating self-replicating rapid prototyper (RepRap) 3-D printers requires a low-cost sensor and data logger system to measure current (I) and voltage (V) of the gas metal arc welders (GMAW). This paper builds on previous open-source hardware development to provide a real-time measurement of welder I-V where the measuring circuit is connected to two analog inputs of the Arduino that is used to control the 3-D printer itself. Franklin firmware accessed through a web interface that is used to control the printer allows storing the measured values and downloading those stored readings to the user’s …

Controlling Optical Absorption In Metamaterial Absorbers For Plasmonic Solar Cells, Wyatt Adams, Ankit Vora, Jephias Gwamuri, Joshua M. Pearce, Durdo O. Guney

Department of Materials Science and Engineering Publications

Metals in the plasmonic metamaterial absorbers for photovoltaics constitute undesired resistive heating. However, tailoring the geometric skin depth of metals can minimize resistive losses while maximizing the optical absorbance in the active semiconductors of the photovoltaic device. Considering experimental permittivity data for InxGa1-xN, absorbance in the semiconductor layers of the photovoltaic device can reach above 90%. The results here also provides guidance to compare the performance of different semiconductor materials. This skin depth engineering approach can also be applied to other optoelectronic devices, where optimizing the device performance demands minimizing resistive losses and power consumption, such as photodetectors, laser diodes, …

Open-Source Photometric System For Enzymatic Nitrate Quantification, Ben T. Wittbrodt, D. A. Squires, J. Walbeck, E. Campbell, W. H. Campbell, Joshua M. Pearce

Department of Materials Science and Engineering Publications

Nitrate, the most oxidized form of nitrogen, is regulated to protect people and animals from harmful levels as there is a large over abundance due to anthropogenic factors. Widespread field testing for nitrate could begin to address the nitrate pollution problem, however, the Cadmium Reduction Method, the leading certified method to detect and quantify nitrate, demands the use of a toxic heavy metal. An alternative, the recently proposed Environmental Protection Agency Nitrate Reductase Nitrate-Nitrogen Analysis Method, eliminates this problem but requires an expensive proprietary spectrophotometer. The development of an inexpensive portable, handheld photometer will greatly expedite field nitrate analysis to …

Low-Cost Open-Source Voltage And Current Monitor For Gas Metal Arc Weld 3d Printing, Anthony Pinar, Bas Wijnen, Gerald C. Anzalone, Timothy C. Havens, Paul G. Sanders, Joshua M. Pearce

Department of Materials Science and Engineering Publications

Arduino open-source microcontrollers are well known in sensor applications for scientific equipment and for controlling RepRap 3D printers. Recently low-cost open-source gas metal arc weld (GMAW) RepRap 3D printers have been developed. The entry-level welders used have minimal controls and therefore lack any real-time measurement of welder voltage or current. The preliminary work on process optimization of GMAW 3D printers requires a low-cost sensor and data logger system to measure welder current and voltage. This paper reports on the development of a low-cost open-source power measurement sensor system based on Arduino architecture. The sensor system was designed, built, and tested …

Mse Annual Report 2015, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• Faculty and Staff News
• Faculty Research
• Student News
• Senior Design Teams
• Outreach
• Alumni News
• MSE by the Numbers
• Endowed Professorships

A Field Investigation Of Composite Mud Brick Compressive Strength, Kevin D. Hale

Dissertations, Master's Theses and Master's Reports - Open

It has been highlighted in numerous publications that in the field of earth construction there is a strong disconnect between experimental work in the laboratory and its application in the field. The current study attempts to help bridge this gap with a field test conducted in Nampula, Mozambique. Mud bricks were made with a simple hand mold and reinforced with bamboo and straw fibers. Fibers were cut into lengths of 3 cm and 6 cm while being mixed in fractions of 0.125%, 0.25% and 0.50% by weight and compressive strength was measured using an application of the 3-point bending test. …

Beautiful Forms And Compositions Are Not Made By Chance: Exploring The Efficacy Of Portable X-Ray Fluorescence To Sort And Source English Lead Glazed Ceramics, Steven J. Sarich

Dissertations, Master's Theses and Master's Reports - Open

Advances in portable X-ray fluorescence (pXRF) technology have made it a viable option for the non-destructive exploration of the underlying chemical composition of ceramic artifacts for the purposes of classification. However, because the literature regarding the use of this instrument on historic artifacts is limited, it is necessary to begin with a broad scale exploratory assessment that might act as a jumping off point for future studies on this topic. Toward that end, this research uses a collection of British and Continental European ceramics ranging from 1650-1920, owned and curated by the Chipstone Foundation in Fox Point, WI, to explore …

Biocorrosion Rate And Mechanism Of Metallic Magnesium In Model Arterial Environments, Patrick Bowen

Dissertations, Master's Theses and Master's Reports

A new paradigm in biomedical engineering calls for biologically active implants that are absorbed by the body over time. One popular application for this concept is in the engineering of endovascular stents that are delivered concurrently with balloon angioplasty. These devices enable the injured vessels to remain patent during healing, but are not needed for more than a few months after the procedure. Early studies of iron- and magnesium-based stents have concluded that magnesium is a potentially suitable base material for such a device; alloys can achieve acceptable mechanical properties and do not seem to harm the artery during degradation. …

Systematic Study Of The Biological Effects Of Nitric Oxide (No) Using Innovative No Measurement And Delivery Systems, Weilue He

Dissertations, Master's Theses and Master's Reports

Nitric oxide (NO) is recognized as the most important small signaling molecule in the human body. An imbalance of NO is closely associated with many serious diseases such as neurological disorders, cardiovascular diseases, chronic inflammations and cancers. Herein two chemiluminescence-based devices (a real-time NO measurement device and a controllable NO delivery device) were developed to facilitate the NO quantitative study and obtain information for NO related drug design.

The first device used for real-time measuring NO(g) flux from living cells was developed and validated. The principle was to use a two-chamber design, with a cell culture chamber and a gaseous …

3d Printing, Open-Source Technology And Their Applications In Research, Chenlong Zhang

Dissertations, Master's Theses and Master's Reports

Open-source software received tremendous success as it drives down the cost of software and expand the distribution. Open-source hardware, as part of the open-source movement, has just risen into public attention for its potential to further drive down the cost of all kinds of manufacturing goods and reshape the manufacture chain. In this report we explores the history, development and the future of open-source hardware project, summarizing the opportunities, challenges and possible solutions. 3D printing is demonstrated as a booster to assist open-source hardware’s development. Low-cost 3D printer enables at-home and in-time fabrication, the download-print-use-improve-distribute cycle is established to encourage …

Computational Study Of Microstructure-Propertymechanism Relations In Ferroic Composites, Fengde D. Ma

Dissertations, Master's Theses and Master's Reports - Open

Ferroic materials, as notable members of smart materials, have been widely used in applications that perform sensing, actuation and control. The macroscopic property change of ferroic materials may become remarkably large during ferroic phase transition, leading to the fact that the macroscopic properties can be tuned by carefully applying a suitable external field (electric, magnetic, stress). To obtain an enhancement in physical and/or mechanical properties, different kinds of ferroic composites have been fabricated. The properties of a ferroic composite are determined not only by the properties and relative amounts of the constituent phases, but also by the microstructure of individual …

Modeling And Simulation Of Microstructures, Mechanisms, And Diffraction Effects In Energy Materials: Ferroelectrics And Lithium Ion Battery Cathode Materials, Jie Zhou

Dissertations, Master's Theses and Master's Reports - Open

Ferroelectric materials, as a large family exploited for the application of sensors, transducers and random access memories, open up a remarkable ground both for fundamental science and industry. Dielectric and piezoelectric properties are of the most interest in ferroelectric materials, which motivate research to enhance ferroelectric properties based on various application purposes. Among the multitudinous candidates in ferroelectric family, pseudo binary solid solutions with ABO₃ lattice structure attract special attention in virtue of their large strain response when applying external loading. Furthermore, existence of morphological phase boundary (MPB) on their phase diagrams shed light on tuning material compositions to …

Structures, Properties And Functionalities Of Magnetic Domain Walls In Thin Films, Nanowires And Atomic Chains: Micromagnetic And Ab Initio Studies, Liwei D. Geng

Dissertations, Master's Theses and Master's Reports - Open

Structures, properties and functionalities of magnetic domain walls in thin film, nanowires and atomic chains are studied by micromagnetic simulations and ab initio calculations in this dissertation. For magnetic domain walls in thin films, we computationally investigated the dynamics of one-dimensional domain wall line in ultrathin ferromagnetic film, and the exponent α = 1.24 ± 0.05 is obtained in the creep regime near depinning force, indicating the washboard potential model is supported by our simulations. Furthermore, the roughness, creep, depinning and flow of domain wall line with commonly existed substructures driven by magnetic field are also studied. Our simulation results …

Biological Materials: Part A. Temperature-Responsive Polymers And Drug Delivery And Part B. Polymer Modification Of Fish Scale And Their Nano-Mechanical Properties, Xu Xiang

Dissertations, Master's Theses and Master's Reports - Open

This research has three parts. Two parts deal with novel nanoparticle assemblies for drug delivery, and are described in Part A, while the third part looks at properties of fish scales, an abundant and little-used waste resource, that can be modified to have value in medical and other areas.

Part A describes fundamental research into the affects of block sequence of amphiphilic block copolymers prepared from on a new and versatile class of monomers, oligo(ethylene glycol) methyl ether acrylate (OEGA) and the more hydrophobic di(ethylene glycol) methyl ether methacrylate (DEGMA). Polymers from these monomers are biologically safe and give polymers …

Open-Source Syringe Pump Library, Bas Wijnen, Emily J. Hunt, Gerald C. Anzalone, Joshua M. Pearce

Department of Materials Science and Engineering Publications

This article explores a new open-source method for developing and manufacturing high-quality scientific equipment suitable for use in virtually any laboratory. A syringe pump was designed using freely available open-source computer aided design (CAD) software and manufactured using an open-source RepRap 3-D printer and readily available parts. The design, bill of materials and assembly instructions are globally available to anyone wishing to use them. Details are provided covering the use of the CAD software and the RepRap 3-D printer. The use of an open-source Rasberry Pi computer as a wireless control device is also illustrated. Performance of the syringe pump …

Mechanical Properties Of Components Fabricated With Open-Source 3-D Printers Under Realistic Environmental Conditions, B. M. Tymrak, M Kreiger, Joshua M. Pearce

Department of Materials Science and Engineering Publications

he recent development of the RepRap, an open-source self-replicating rapid prototyper, has made 3-D polymer-based printers readily available to the public at low costs ( < $500). The resultant uptake of 3-D printing technology enables for the first time mass-scale distributed digital manufacturing. RepRap variants currently fabricate objects primarily from acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA), which have melting temperatures low enough to use in melt extrusion outside of a dedicated facility, while high enough for prints to retain their shape at average use temperatures. In order for RepRap printed parts to be useful for engineering applications the mechanical properties of printed parts must be known. This study quantifies the basic tensile strength and elastic modulus of printed components using realistic environmental conditions for standard users of a selection of open-source 3-D printers. The results find average tensile strengths of 28.5 MPa for ABS and 56.6 MPa for PLA with average elastic moduli of 1807 MPa for ABS and 3368 MPa for PLA. It is clear from these results that parts printed from tuned, low-cost, open-source RepRap 3-D printers can be considered as mechanically functional in tensile applications as those from commercial vendors.

Development Of Precipitation Hardenable Al-Sc-Zr-Hf Quaternary Alloys Through Thermodynamic Modeling, And Room-Temperature And Elevated Temperature Hardness, Matthew J. Wong

Dissertations, Master's Theses and Master's Reports - Open

Aluminum alloyed with small atomic fractions of Sc, Zr, and Hf has been shown to exhibit high temperature microstructural stability that may improve high temperature mechanical behavior. These quaternary alloys were designed using thermodynamic modeling to increase the volume fraction of precipitated tri-aluminide phases to improve thermal stability. When aged during a multi-step, isochronal heat treatment, two compositions showed a secondary room-temperature hardness peak up to 700 MPa at 450°C. Elevated temperature hardness profiles also indicated an increase in hardness from 200-300°C, attributed to the precipitation of Al₃Sc, however, no secondary hardness response was observed from the Al …

Design, Synthesis And Applications Of Fluorescent And Electrochemical Probes, Giri K. Vegesna

Dissertations, Master's Theses and Master's Reports - Open

“Seeing is believing” the proverb well suits for fluorescent imaging probes. Since we can selectively and sensitively visualize small biomolecules, organelles such as lysosomes, neutral molecules, metal ions, anions through cellular imaging, fluorescent probes can help shed light on the physiological and pathophysiological path ways. Since these biomolecules are produced in low concentrations in the biochemical pathways, general analytical techniques either fail to detect or are not sensitive enough to differentiate the relative concentrations. During my Ph.D. study, I exploited synthetic organic techniques to design and synthesize fluorescent probes with desirable properties such as high water solubility, high sensitivity and …