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Air Force Institute of Technology

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Articles 121 - 150 of 329

Full-Text Articles in Materials Science and Engineering

Degradation Of Carbon Fiber Reinforced Polymer And Graphite By Laser Heating, Nicholas C. Herr Sep 2016

Degradation Of Carbon Fiber Reinforced Polymer And Graphite By Laser Heating, Nicholas C. Herr

Theses and Dissertations

The availability of high power, diode pumped solid state and fiber lasers at powers 10 kW and shorter wavelengths (1.07 micrometer) has invigorated the development of tactical laser weapons. This shift to tactical missions greatly increases the variety of potential targets including carbon fiber reinforced polymers and related materials. The complexity of laser-material interactions has driven a historical reliance on live-fire testing and empirical models, but this becomes more difficult as the number of target materials grow. This dissertation combines thermal imagery and existing thermal models of the fire response of composite materials to develop a hybrid modeling approach of …

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Effect Of Stress Ratio On Fatigue Crack Growth Rate At Notched Hole In 7075-T6 Aluminum Alloy Under Biaxial Fatigue, Reja Alshahrani Sep 2016

Effect Of Stress Ratio On Fatigue Crack Growth Rate At Notched Hole In 7075-T6 Aluminum Alloy Under Biaxial Fatigue, Reja Alshahrani

Theses and Dissertations

This research investigates the behavior of fatigue crack growth rate in both laboratory air and saltwater (3.5% NaCl) environments for notched cruciform specimen made from 7075-T6 aluminum alloy sheet at different stress ratios. With biaxility ratio of 1, and frequency of applied load of 10 Hz, the crack growth behavior was investigated under in-plane biaxial tension-tension fatigue with 0.1, 0.5, 0.7 stress ratios and then compared them to study the effect of stress ratio on the crack growth rate. Finite Element Analysis (FEA) was used to calculate cyclic variation of stress intensity factors (delta K) at the crack tips. The …

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Fusion Of Renewable Ring Resonator Lasers And Ultrafast Laser Inscribed Photonic Waveguides, Hengky Chandrahalim, Stephen C. Rand, Xudong Fan Sep 2016

Fusion Of Renewable Ring Resonator Lasers And Ultrafast Laser Inscribed Photonic Waveguides, Hengky Chandrahalim, Stephen C. Rand, Xudong Fan

Faculty Publications

We demonstrated the monolithic integration of reusable and wavelength reconfigurable ring resonator lasers and waveguides of arbitrary shapes to out-couple and guide laser emission on the same fused-silica chip. The ring resonator hosts were patterned by a single-mask standard lithography, whereas the waveguides were inscribed in the proximity of the ring resonator by using 3-dimensional femtosecond laser inscription technology. Reusability of the integrated ring resonator – waveguide system was examined by depositing, removing, and re-depositing dye-doped SU-8 solid polymer, SU-8 liquid polymer, and liquid solvent (toluene). The wavelength reconfigurability was validated by employing Rhodamine 6G (R6G) and 3,3′-Diethyloxacarbocyanine iodide (CY3) …

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Reconfigurable Liquid Attenuated Collimator, Larry W. Burggraf, Benjamin R. Kowash, Jack G. M. Fitzgerald Aug 2016

Reconfigurable Liquid Attenuated Collimator, Larry W. Burggraf, Benjamin R. Kowash, Jack G. M. Fitzgerald

AFIT Patents

A reconfigurable radiographic aperture mask collimator apparatus includes a body portion configured to receive an attenuating liquid having a first attenuation value per unit volume. The apparatus further includes a grid portion mated to a face of the body portion and a plurality of passageways each having a cross sectional area and a length. The plurality of passageways is disposed within the grid portion. A plurality of plugs is slidably disposed within the plurality of passageways, and each of the plurality of plugs has a second attenuation value per unit volume less than the first attenuation value. One of the …

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The Effects Of Ionizing Radiation And Oxidizing Species On Strains Of Deinococcus Radiodurans Lacking Endogenous Oxidative Protection Methods, Dylan L. Klawuhn Jun 2016

The Effects Of Ionizing Radiation And Oxidizing Species On Strains Of Deinococcus Radiodurans Lacking Endogenous Oxidative Protection Methods, Dylan L. Klawuhn

Theses and Dissertations

Multiple strains of Deinococcus radiodurans were transformed, creating knockout mutations in genes responsible for manganese ion transport, manganese and copper/zinc super-oxide dismutase, and bacillithiol synthesis. These mutated strains were then irradiated with ~20,000 Gys. The results showed that the mutated strains had a higher sensitivity to ionizing radiation, those responsible for bacillithiol synthesis having an increase in sensitivity 3000 times more than wild type Deinococcus radiodurans. In addition to radiation the mutated strains were also exposed to paraquat, an oxidizing herbicide. Strains missing manganese super-oxide dismutase showed increased sensitivity.

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Microfacet Wavelength Scaling Of The Brdf, Samuel E. Freda Jun 2016

Microfacet Wavelength Scaling Of The Brdf, Samuel E. Freda

Theses and Dissertations

The bidirectional reflectance distribution function (BRDF) describes realistic scattering of light off materials by relating incident irradiance to outbound radiance. One popular class of BRDF models assumes a surface is comprised of tiny microfacets. The drawback of microfacet BRDFs is that they often no not contain specific material parameters and neglect wavelength effects. Wave optics BRDF expressions, however, can describe wavelength effects at the expense of being more computationally cumbersome. Previous work of following a Beckmann-Kirchhoff derivation of BRDF, then relating wave optics BRDF coordinates to microfacet coordinates led to a complicated, but versatile, BRDF. In this work, the infinite …

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Identification Of The Zinc-Oxygen Divacancy In Zno Crystals, Maurio S. Holston, Eric M. Golden, Brant E. Kananen, John W. Mcclory, Nancy C. Giles, Larry E. Halliburton Apr 2016

Identification Of The Zinc-Oxygen Divacancy In Zno Crystals, Maurio S. Holston, Eric M. Golden, Brant E. Kananen, John W. Mcclory, Nancy C. Giles, Larry E. Halliburton

Faculty Publications

An electron paramagnetic resonance (EPR) spectrum in neutron-irradiated ZnO crystals is assigned to the zinc-oxygen divacancy. These divacancies are observed in the bulk of both hydrothermally grown and seeded-chemical-vapor-transport-grown crystals after irradiations with fast neutrons. Neutral nonparamagnetic complexes consisting of adjacent zinc and oxygen vacancies are formed during the irradiation. Subsequent illumination below ∼150 K with 442 nm laser light converts these (V2−Zn − V2+O)0 defects to their EPR-active state (V−Zn − V2+O)+ as electrons are transferred to donors. The resulting photoinduced S = 1/2 spectrum of the …

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Radiation Effects On An Active Ytterbium-Doped Fiber Laser, Adam C. Poulin Mar 2016

Radiation Effects On An Active Ytterbium-Doped Fiber Laser, Adam C. Poulin

Theses and Dissertations

This is the first published research focused on the impact of gamma and mixed gamma/neutron radiation on an actively lasing ytterbium-doped fiber laser. While the gain medium of the ytterbium-doped fiber laser was irradiated, the power was measured in-situ and the spectrum was recorded intermittently. Two radiation sources were used, a 60Co cell and a reactor. Three irradiation experiments were conducted per radiation source; pristine fibers were used for the first two experiments, and fibers from the second experiment were re-irradiated for the third experiment. The results indicate that as the total dose increased linearly with time, the laser …

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Radiation Effects In Thin Film Hexagonal Boron Nitride, Nathaniel M. Kaminski Mar 2016

Radiation Effects In Thin Film Hexagonal Boron Nitride, Nathaniel M. Kaminski

Theses and Dissertations

The radiation response of 2 nm and 12 nm hexagonal boron nitride (hBN) thin film insulators was studied using metal insulator semiconductor (MIS) devices. Current-voltage, capacitance-voltage, and impedance spectroscopy measurements were compared to quantify changes in hBN resistance due to radiation damage. MIS devices exposed to a gamma total dose deposition of 3.1 Mrad(Si) from a Co- 60 source exhibited a small increase in hBN resistance and no observable C-V shift associated with charge trapping. MIS devices irradiated with 4.5 MeV silicon ions showed no significant resistivity decrease to a threshold fluence of 1 ×1012 for the 2 nm …

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Characterization Of 2d Jammed Granular Memristive Copper Arrays, Len L. Kedrow Mar 2016

Characterization Of 2d Jammed Granular Memristive Copper Arrays, Len L. Kedrow

Theses and Dissertations

A novel sensor made of jammed granular memristive copper spheres was explored in an effort to develop a protection technology that could be used in non-proliferation treaty monitoring. The micro-copper spheres were annealed for various times at a constant temperature. SEM, EDS, and XPS were used to characterize the growth of the oxide coating. Electrical characterization of the device was done by confining the granular copper spheres to a two-dimensional plane using a unique test fixture capable of measuring I-V curves at the boundary of the circuit board using tungsten pillar electrodes. Electroforming of the copper spheres produced soft dielectric …

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Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 700°C In Air And In Silicic Acid-Saturated Steam, Matthew W. Piper Mar 2016

Creep Of Hi-Nicalon™ S Ceramic Fiber Tows At 700°C In Air And In Silicic Acid-Saturated Steam, Matthew W. Piper

Theses and Dissertations

Aircraft structural and engine components are subjected to elevated temperature and steam environments during operation. Turbine blades experience particularly harsh conditions that are approaching the operating temperature limits of current Nickel-based superalloys even with active cooling. Ceramic matrix composites (CMCs), which demonstrate high specific strength and specific stiffness and maintain these properties at elevated temperatures such that active cooling is not required, are prime candidates to replace superalloys as the materials for turbine blades. Ceramic matrix composites are composite materials that consist of a ceramic matrix with fiber reinforcement. This research investigated a silicon carbide (SiC) fiber, Hi-Nicalon™ S, which …

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System And Method For Identifying Electrical Properties Of Integrate Circuits, Mary Y. Lanzerotti Jan 2016

System And Method For Identifying Electrical Properties Of Integrate Circuits, Mary Y. Lanzerotti

AFIT Patents

A new method for displaying electrical properties for integrated circuit (IC) layout designs provides for improved human visualization of those properties and comparison of as designed layout design parameters to as specified layout design parameters and to as manufactured layout parameters. The method starts with a circuitry as designed layout in a first digital format, extracts values for electrical properties from that circuitry as designed layout then annotates those values back into the first digital format. The annotated circuitry as designed layout is then converted from the first digital format to a second digital format that can be converted to …

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Creep And Oxidation Of Hafnium Diboride-Based Ultra High Temperature Ceramics At 1500°C, Anthony J. Degregoria Dec 2015

Creep And Oxidation Of Hafnium Diboride-Based Ultra High Temperature Ceramics At 1500°C, Anthony J. Degregoria

Theses and Dissertations

Ultra high temperature ceramics (UHTCs) are leading candidates for aerospace structural applications in high temperature environments, including the leading edges of hypersonic aircraft and thermal protection systems for atmospheric re-entry vehicles. Before UHTCs can be used in such applications, their structural integrity and environmental durability must be assured, which requires a thorough understanding and characterization of their creep and oxidation behavior at relevant service temperatures.

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Creep Behavior In Interlaminar Shear Of A Hi-Nicalon™/Sic-B4c Composite At 1200°C In Air And In Steam, Marina B. Ruggles-Wrenn, Matthew T. Pope Nov 2015

Creep Behavior In Interlaminar Shear Of A Hi-Nicalon™/Sic-B4c Composite At 1200°C In Air And In Steam, Marina B. Ruggles-Wrenn, Matthew T. Pope

Faculty Publications

Creep behavior in interlaminar shear of a non-oxide ceramic composite with a multilayered matrix was investigated at 1200∘C in laboratory air and in steam environment. The composite was produced via chemical vapor infiltration (CVI). The composite had an oxidation inhibited matrix, which consisted of alternating layers of silicon carbide and boron carbide and was reinforced with laminated Hi-NicalonTM fibers woven in a five-harness-satin weave. Fiber preforms had pyrolytic carbon fiber coating with boron carbon overlay applied. The interlaminar shear properties were measured. The creep behavior was examined for interlaminar shear stresses in the 16–22 MPa range. Primary …

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Environmental Degradation Of Nickel-Based Superalloys Due To Gypsiferous Desert Dusts, Matthew B. Krisak Sep 2015

Environmental Degradation Of Nickel-Based Superalloys Due To Gypsiferous Desert Dusts, Matthew B. Krisak

Theses and Dissertations

More than twenty-five years of continuous operation in the dusty environments of Southwest Asia have shown that degradation of gas turbine engine components due to particle ingestion is a serious threat to operations. In particular, the continued push for higher engine operating temperatures has brought a new emphasis to the damage mechanisms (for example CMAS glass formation and hot corrosion) caused by ingested particles forming molten deposits on engine components. Despite decades of research little progress has been made to mitigate the effects of CMAS and hot corrosion degradation to engine components. This research focused on hot corrosion specifically. A …

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Characterization Of Point Defects In Lithium Aluminate (Lialo2) Single Crystals, Maurio S. Holston Sep 2015

Characterization Of Point Defects In Lithium Aluminate (Lialo2) Single Crystals, Maurio S. Holston

Theses and Dissertations

Lithium aluminate (LiAlO2) is an insulating wide-band gap material currently under development for tritium breeding and radiation detection and dosimetry applications. Point defects are imperfections in a crystal lattice localized over a few atomic lengths that can alter the electrical, mechanical, or optical properties of materials. An understanding of point defect behavior is a necessary precursor for optimizing lithium aluminate for nuclear applications. This dissertation has identified and characterized the major point defects created and induced through x-ray and neutron radiation using electron paramagnetic resonance and fluorescence spectroscopy, thermoluminescence, and optical absorption. This dissertation explains for the first …

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Corrosion Fatigue Crack Growth Behavior At Notched Hole In 7075-T6 Under Biaxial And Uniaxial Fatigue With Different Phases, Ali Khawagi Aug 2015

Corrosion Fatigue Crack Growth Behavior At Notched Hole In 7075-T6 Under Biaxial And Uniaxial Fatigue With Different Phases, Ali Khawagi

Theses and Dissertations

This research investigates fatigue crack propagation behavior in both air and saltwater (3.5% NaCl) environments from pre-cracked notched circular hole in a 7075-T6 cruciform specimen. With stress ratio of 0.5, biaxility stress ratio of unity, and frequency of applied load of 10 Hz, the crack growth behavior was investigated under in-plane biaxial tension-tension fatigue with 45⁰, 90⁰ and 180⁰ phase difference conditions and then compared to previous fatigue tests with no phase difference to study the effect of changing the phase differences between the applied loads on the crack growth rate. Finite Element Analysis (FEA) was used to calculate cyclic …

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Improved Terahertz Modulation Using Germanium Telluride (Gete) Chalcogenide Thin Films, Alexander H. Gwin, Christopher H. Kodama, Tod V. Laurvick, Ronald Coutu Jr., Philip F. Taday Jul 2015

Improved Terahertz Modulation Using Germanium Telluride (Gete) Chalcogenide Thin Films, Alexander H. Gwin, Christopher H. Kodama, Tod V. Laurvick, Ronald Coutu Jr., Philip F. Taday

Faculty Publications

We demonstrate improved terahertz (THz) modulation using thermally crystallized germanium telluride (GeTe) thin films. GeTe is a chalcogenide material that exhibits a nonvolatile, amorphous to crystalline phase change at approximately 200 °C, as well as six orders of magnitude decreased electrical resistivity. In this study, amorphous GeTe thin films were sputtered on sapphire substrates and then tested using THz time-domain spectroscopy (THz-TDS). The test samples, heated in-situ while collecting THz-TDS measurements, exhibited a gradual absorbance increase, an abrupt nonvolatile reduction at the transition temperature, followed by another gradual increase in absorbance. The transition temperature was verified by conducting similar thermal …

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Interstitial Silicon Ions In Rutile Tio2 Crystals, Eric M. Golden, Nancy C. Giles, Shan Yang, Larry E. Halliburton Apr 2015

Interstitial Silicon Ions In Rutile Tio2 Crystals, Eric M. Golden, Nancy C. Giles, Shan Yang, Larry E. Halliburton

Faculty Publications

Electron paramagnetic resonance (EPR) is used to identify a new and unique photoactive silicon-related point defect in single crystals of rutile TiO2. The importance of this defect lies in its assignment to interstitial silicon ions and the unexpected establishment of silicon impurities as a major hole trap in TiO2. Principal g values of this new S=1/2 center are 1.9159, 1.9377, and 1.9668 with principal axes along the [¯110],[001], and [110] directions, respectively. Hyperfine structure in the EPR spectrum shows the unpaired spin interacting equally with two Ti nuclei and unequally with two Si nuclei. These silicon …

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Fatigue Behavior Of Im7/Bmi 5250-4 Composite At Room And Elevated Temperatures, James T. Tipton Mar 2015

Fatigue Behavior Of Im7/Bmi 5250-4 Composite At Room And Elevated Temperatures, James T. Tipton

Theses and Dissertations

The tension-tension fatigue and tension-compression fatigue behaviors of the IM7/BMI 5250-4 composite were investigated. The tension-tension fatigue of the composite with 0/90 and ±45 fiber orientations was studied at 23, 170, and 190°C. The tension-compression fatigue of the composite with 0/90 fiber orientation was examined at 23°C. The tensile and compressive properties of the composite were also evaluated at room and elevated temperatures for both 0/90 and ±45 fiber orientations. Elevated temperature had little effect on the tensile properties of the 0/90 fiber orientation, but strongly influenced the ±45 tensile properties as well as the compressive properties of both fiber …

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Theoretical Investigation Of Stabilities And Optical Properties Of Si12C12 Clusters, Xiaofeng F. Duan, Larry W. Burggraf Jan 2015

Theoretical Investigation Of Stabilities And Optical Properties Of Si12C12 Clusters, Xiaofeng F. Duan, Larry W. Burggraf

Faculty Publications

By sorting through hundreds of globally stable Si12C12 isomers using a potential surface search and using simulated annealing, we have identified low-energy structures. Unlike isomers knit together by Si–C bonds, the lowest energy isomers have segregated carbon and silicon regions that maximize stronger C–C bonding. Positing that charge separation between the carbon and silicon regions would produce interesting optical absorption in these cluster molecules, we used time-dependent density functional theory to compare the calculated optical properties of four isomers representing structural classes having different types of silicon and carbon segregation regions. Absorptions involving charge transfer between segregated …

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Reconfigurable Solid-State Dye-Doped Polymer Ring Resonator Lasers, Hengky Chandrahalim, Xudong Fan Jan 2015

Reconfigurable Solid-State Dye-Doped Polymer Ring Resonator Lasers, Hengky Chandrahalim, Xudong Fan

Faculty Publications

This paper presents wavelength configurable on-chip solid-state ring lasers fabricated by a single-mask standard lithography. The single- and coupled-ring resonator hosts were fabricated on a fused-silica wafer and filled with 3,3′-Diethyloxacarbocyanine iodide (CY3), Rhodamine 6G (R6G) and 3,3′-Diethylthiadicarbocyanine iodide (CY5)-doped polymer as the reconfigurable gain media. The recorded lasing threshold was ~220 nJ/mm2 per pulse for the single-ring resonator laser with R6G, marking the lowest threshold shown by solid-state dye-doped polymer lasers fabricated with a standard lithography process on a chip. A single-mode lasing from a coupled-ring resonator system with the lasing threshold of ~360 nJ/mm2 per pulse …

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Monolithic Optofluidic Ring Resonator Lasers Created By Femtosecond Laser Nanofabrication, Hengky Chandrahalim, Qiushu Chen, Ali A. Said, Mark Dugan, Xudong Fan Jan 2015

Monolithic Optofluidic Ring Resonator Lasers Created By Femtosecond Laser Nanofabrication, Hengky Chandrahalim, Qiushu Chen, Ali A. Said, Mark Dugan, Xudong Fan

Faculty Publications

We designed, fabricated, and characterized a monolithically integrated optofluidic ring resonator laser that is mechanically, thermally, and chemically robust. The entire device, including the ring resonator channel and sample delivery microfluidics, was created in a block of fused-silica glass using a 3-dimensional femtosecond laser writing process. The gain medium, composed of Rhodamine 6G (R6G) dissolved in quinoline, was flowed through the ring resonator. Lasing was achieved at a pump threshold of approximately 15 μJ/mm2. Detailed analysis shows that the Q-factor of the optofluidic ring resonator is 3.3 × 104, which is limited by both solvent …

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Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton Dec 2014

Sulfur Vacancies In Photorefractive Sn2P2S6 Crystals, Eric M. Golden, Sergey A. Basun, A. A. Grabar, I. M. Stoika, Nancy C. Giles, D. R. Evans, Larry E. Halliburton

Faculty Publications

A photoinduced electron paramagnetic resonance (EPR) spectrum in single crystals of Sn2P2S6 (SPS) is assigned to an electron trapped at a sulfur vacancy. These vacancies are unintentionally present in undoped SPS crystals and are expected to play an important role in the photorefractive behavior of the material. Nonparamagnetic sulfur vacancies are formed during the initial growth of the crystal. Subsequent illumination below 100 K with 442 nm laser light easily converts these vacancies to EPR-active defects. The resulting S = 1/2 spectrum shows well-resolved and nearly isotropic hyperfine interactions with two P ions and two Sn ions. Partially resolved interactions …

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Polycrystalline Iii-Nitrides, Michael J. Callahan, Buguo Wang, John S. Bailey Oct 2014

Polycrystalline Iii-Nitrides, Michael J. Callahan, Buguo Wang, John S. Bailey

AFIT Patents

This invention provides a process for producing high-purity dense polycrystalline III-nitride slabs. A vessel which contains a group III-metal such as gallium or an alloy of group III-metals of shallow depth is placed in a reactor. The group III-metal or alloy is heated until a molten state is reached after which a halide-containing source mixed with a carrier gas and a nitrogen-containing source is flowed through the reactor vessel. An initial porous crust of III-nitride forms on the surface of the molten III-metal or alloy which reacts with the nitrogen-containing source and the halide-containing source. The flow rate of the …

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Copper Doping Of Zno Crystals By Transmutation Of 64Zn To 65Cu: An Electron Paramagnetic Resonance And Gamma Spectroscopy Study, Matthew C. Recker, John W. Mcclory, Maurio S. Holston, Eric M. Golden, Nancy C. Giles, Larry E. Halliburton Jun 2014

Copper Doping Of Zno Crystals By Transmutation Of 64Zn To 65Cu: An Electron Paramagnetic Resonance And Gamma Spectroscopy Study, Matthew C. Recker, John W. Mcclory, Maurio S. Holston, Eric M. Golden, Nancy C. Giles, Larry E. Halliburton

Faculty Publications

Transmutation of 64Zn to 65Cu has been observed in a ZnO crystal irradiated with neutrons. The crystal was characterized with electron paramagnetic resonance (EPR) before and after the irradiation and with gamma spectroscopy after the irradiation. Major features in the gamma spectrum of the neutron-irradiated crystal included the primary 1115.5 keV gamma ray from the 65Zn decay and the positron annihilation peak at 511 keV. Their presence confirmed the successful transmutation of 64Zn nuclei to 65Cu. Additional direct evidence for transmutation was obtained from the EPR of Cu2+ ions (where 63Cu and 65 …

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Functionalization Of Carbon Nanotube Yarn By Acid Treatment, Heath E. Misak, Ramazan Asmatulu, Mat O'Malley, Emil Jurak, Shankar Mall Apr 2014

Functionalization Of Carbon Nanotube Yarn By Acid Treatment, Heath E. Misak, Ramazan Asmatulu, Mat O'Malley, Emil Jurak, Shankar Mall

Faculty Publications

Carbon nanotube (CNT) yarn was functionalized using sulfuric and nitric acid solutions in 3:1 volumetric ratio. Successful functionalization of CNT yarn with carboxyl and hydroxyl groups (e.g., COOH, COO–, OH, etc.) was confirmed by attenuated total reflectance spectroscopy. X-ray diffraction revealed no significant change to the atomic in-plane alignment in the CNTs; however, the coherent length along the diameter was significantly reduced during functionalization. A morphology change of wavy extensions protruding from the surface was observed after the functionalization treatment. The force required to fracture the yarn remained the same after the functionalization process; however, the linear density was increased …

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Carbon Allotrope Dependence On Temperature And Pressure During Thermal Decomposition Of Silicon Carbide, Munson J. Anderson Mar 2014

Carbon Allotrope Dependence On Temperature And Pressure During Thermal Decomposition Of Silicon Carbide, Munson J. Anderson

Theses and Dissertations

Bulk CNT and graphene films form on SiC using a metal-catalyst-free thermal decomposition approach. In this work, the background vacuum pressure and temperature used in the decomposition process are varied to investigate their impact on the type and quality of carbon allotrope formed on the SiC substrate. The carbon nanostructure growth is performed using two approaches, both of which involve intense heating (1400-1700°C) of SiC under moderate vacuum conditions (0.01 - 0.00001 Torr). The first growth method uses a conventional graphite resistance furnace capable of annealing waferscale samples over 1700°C under vacuum. Using this approach, post-growth characterization is performed using …

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Experimental Investigation Of Mechanical Behavior Of An Oxide/Oxide Ceramic Composite In Interlaminar Shear And Under Combined Tension-Torsion Loading, Skyler R. Hilburn Mar 2014

Experimental Investigation Of Mechanical Behavior Of An Oxide/Oxide Ceramic Composite In Interlaminar Shear And Under Combined Tension-Torsion Loading, Skyler R. Hilburn

Theses and Dissertations

Creep behavior in interlaminar shear of an oxide-oxide ceramic composite, Nextel 720™/aluminosilicate (N720/AS), was investigated at 1100°C in laboratory air and in steam. The interlaminar shear strength (ILSS) was determined as 7.65 MPa. The creep behavior was examined for interlaminar shear stresses in the 2-6 MPa range. Primary and secondary creep regimes were observed in all tests conducted in air and in steam. Tertiary creep was noted in the tests performed at 6 MPa. Larger creep strains and higher creep strain rates were produced in steam. Surprisingly, the presence of steam had a beneficial effect on creep lifetimes. It appears …

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Hydrothermal Crystal Growth Of Lithium Tetraborate And Lithium 𝛾-Metaborate, Jeffrey J. Graham Mar 2014

Hydrothermal Crystal Growth Of Lithium Tetraborate And Lithium 𝛾-Metaborate, Jeffrey J. Graham

Theses and Dissertations

Growth of lithium tetraborate by the hydrothermal method was attempted in 10-6 M LiOH, both by spontaneous nucleation and transport growth. Tetraborate grew out of the first spontaneous nucleation reaction, while the seed dissolved and lithium gamma-metaborate formed during the transport growth reactions. A species thermodynamic stability study showed gamma-metaborate formed exclusively from 350°C to 550°C, and Li3B5O8(OH)2 was observed at 250°C; tetraborate was not observed. A solubility study on lithium tetraborate did not achieve equilibrium conditions, but did demonstrate that gamma-metaborate is significantly more thermodynamically stable than tetraborate under the tested …

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