Materials Science and Engineering Commons^™

Rbd2po4: Room Temprature Synthesis, Chemical And Structural Stablity Upon Heating, Masoud Mollaee

Open Access Theses & Dissertations

Monoclinic RbD2PO4 polycrystals were synthesized via the room temperature crystallization of RbH2PO4 dissolved in D2O. Powder x-ray diffraction (XRD) data collected at T=25 ºC indicate that this deuterated compound crystallizes in space group P21/m with unit cell parameters a=7.688í?, b=6.192í?, c=4.781í? and β=109.02°, and is isomorphic with the intermediate-temperature phase of its hydrogenated counterpart rubidium dihydrogen phosphate (RDP). We found no evidence of previously reported [Phase Transitions 80, 17 (2007)] polymorphic phase transition in rubidium dideuterium phosphate (DRDP) upon heating from room temperature to 210 ºC. All lattice parameters vary smoothly within this temperature range, demonstrating that the P21/m phase …

Applications Of High Throughput (Combinatorial) Methodologies To Electronic, Magnetic, Optical, And Energy-Related Materials, Martin L. Green, Ichiro Takeuchi, Jason R. Hattrick-Simpers

Faculty Publications

High throughput (combinatorial) materials science methodology is a relatively new research paradigm that offers the promise of rapid and efficient materials screening, optimization, and discovery. The paradigm started in the pharmaceutical industry but was rapidly adopted to accelerate materials research in a wide variety of areas. High throughput experiments are characterized by synthesis of a “library” sample that contains the materials variation of interest (typically composition), and rapid and localized measurement schemes that result in massive data sets. Because the data are collected at the same time on the same “library” sample, they can be highly uniform with respect to …

Effect Of Vortex Hotspots On The Radio-Frequency Surface Resistance Of Superconductors, A. Gurevich, G. Ciovati

Physics Faculty Publications

We present detailed experimental and theoretical investigations of hotspots produced by trapped vortex bundles and their effect on the radio-frequency (rf) surface resistance Rs of superconductors at low temperatures. Our measurements of Rs, combined with the temperature mapping and laser scanning of a 2.36-mm-thick Nb plate incorporated into a 3.3-GHz Nb resonator cavity cooled by the superfluid He at 2 K, revealed spatial scales and temperature distributions of hotspots and showed that they can be moved or split by thermal gradients produced by the scanning laser beam. These results, along with the observed hysteretic field dependence of Rs which can …

Synthesis And Investigations Of Type I And Ii Clathrates Of Group 14, Michael Blosser

USF Tampa Graduate Theses and Dissertations

Clathrates are a class of new materials that have an open-framework structure that allows guest atoms or molecules to be enclosed inside of their polyhedral framework. Varying the number, weight, and size of the guest species in a particular framework allows one to alter the physical properties of the clathrate. This relationship enables one to further the fundamental understanding of the physics and chemistry of the clathrate structure and use this knowledge to "tune" certain properties. This "tunability" of inorganic clathrates is of great interest as it allows one to optimize their physical properties; making them promising candidates for a …

Non-Equilibrium Melting And Sublimation Of Graphene Simulated With Two Interatomic Potentials, Brad Steele

USF Tampa Graduate Theses and Dissertations

The mechanisms of the sublimation of graphene at zero pressure and the condensation of carbon vapor is investigated by molecular dynamics (MD) simulations. The interatomic interactions are described by the Reactive Empirical Bond Order potential (REBO). It is found that graphene sublimates at a temperature of 5,200 K. At the onset of sublimation, defects that contain several pentagons and heptagons are formed, that are shown to evolve from double vacancies and stone wales defects. These defects consisting of pentagons and heptagons act as nucleation sites for the gaseous phase. The influence of the interatomic interactions on the sublimation process are …

Pulse Sharpening Effects Of Thin Film Ferroelectric Transmission Lines, Robert J. Sleezer

Graduate Theses and Dissertations

Advances in material science have resulted in the development of electrically nonlinear high dielectric thin film ferroelectrics, which have led to new opportunities for the creation of novel devices. This dissertation investigated one such device: a low voltage nonlinear transmission line (NLTL). A finite element simulation of ferroelectric transmission lines showed that NLTLs are capable of creating shockwaves. Additionally, if the losses are kept sufficiently low, it was shown that voltage gain should be possible. Furthermore, a method of accounting for material dispersion was developed. Results from simulations including material dispersion showed that temporal solitons might be possible from a …

P3ht:Pcpdtbt:Pcbm Multi- Polymer Single Layer Solar Cells, Ted Andreas

Physics

OPV efficiencies are limited by their narrow absorption; rather than using tandem architecture to overcome this obstacle, our group combined P3HT and PCPDTBT into a single layer BHJ solar cell that achieved 2.0% PCE. This is 33% higher than the pure P3HT control from this group, proving that multi-polymer solar cells have the potential to outperform their single-polymer components.

Study Of Morphological Changes In Mgh2 Destabilized Libh4 Systems Using Computed X-Ray Microtomography, Tabbetha A. Dobbins, Shathabish Narasegowda, Leslie G. Butler

College of Science & Mathematics Departmental Research

The objective of this study was to apply three-dimensional x-ray microtomographic imaging to understanding morphologies in the diphasic destabilized hydride system: MgH2 and LiBH4. Each of the single phase hydrides as well as two-phase mixtures at LiBH4:MgH2 ratios of 1:3, 1:1, and 2:1 were prepared by high energy ball milling for 5 minutes (with and without 4 mol % TiCl3 catalyst additions). Samples were imaged using computed microtomography in order to (i) establish measurement conditions leading to maximum absorption contrast between the two phases and (ii) determine interfacial volume. The optimal energy for measurement was determined to be 15 keV …

Commissioning Of The Asta Laser Lab With Uv Pulse Length Characterization, Daniel Kelley, Jeff Corbett

STAR Program Research Presentations

The Linac Coherent Light Source (LCLS) at SLAC depends on a photocathode electron gun to provide the linear accelerator with the raw material – electrons – used for making X-ray laser pulses. The photocathode used in the LCLS Injector is a clean copper plate in high vacuum. When the cathode is struck with high energy UV light, electrons are liberated from its surface and then accelerated down the linac with radio-frequency electric fields. These fast-moving bunches of electrons are directed through an undulator magnet to radiate X-ray light.

Although scientists have been using photocathode techniques at SLAC for 25 years, …

Dynamical Properties Of Ferroelectric Perovskites (Ba,Sr)Tio3 And Pb(Zr,Ti)O3 Systems From First Principles, Jeevaka Weerasinghe

Graduate Theses and Dissertations

A first-principles-based effective Hamiltonian scheme which incorporates coupling between ferroelectric (FE) and antiferrodistortive (AFD) motions is applied to Pb(Zr,Ti)O₃ alloys. It validates the existence of two modes of E symmetry (rather than the single E(1TO) soft mode) in the 50-75 cm^-1 range for temperatures smaller than 200 K and for compositions falling within the Rhombohedral R3c phase. Coupling between long-range-ordered FE and AFD motions is shown to be the cause of the additional mode and more insight into its nature is provided. This scheme is further used to reveal a field-induced anticrossing involving FE and AFD degrees of …

Probing And Controlling Fluid Rheology At Microscale With Magnetic Nanorods, Alexander Tokarev

All Dissertations

This Dissertation is focused on the development of new methods for characterization and control of fluid rheology using magnetic nanorods. This Dissertation consists of five chapters. In the first chapter, we review current microrheologial methods and develop a Magnetic Rotational Spectroscopy (MRS) model describing nanorod response to a rotating magnetic field. Using numerical modeling, we analyze the effects of materials parameters of nanorods and fluids on the MRS characteristic features. The model is designed for a specific experimental protocol. We introduce and examine physical parameters which can be measured experimentally. The model allows identification of MRS features enabling the calculation …

A Mean Curvature Model For Capillary Flows In Asymmetric Containers And Conduits, Yongkang Chen, Noël Tavan, Mark M. Weislogel

Mechanical and Materials Engineering Faculty Publications and Presentations

Capillarity-driven flows resulting from critical geometric wetting criterion are observed to yield significant shifts of the bulk fluid from one side of the container to the other during "zero gravity" experiments. For wetting fluids, such bulk shift flows consist of advancing and receding menisci sometimes separated by secondary capillary flows such as rivulet-like flows along gaps. Here we study the mean curvature of an advancing meniscus in hopes of approximating a critical boundary condition for fluid dynamics solutions. It is found that the bulk shift flows behave as if the bulk menisci are either “connected” or "disconnected." For the connected …

54th Rocky Mountain Conference On Analytical Chemistry

Rocky Mountain Conference on Magnetic Resonance

Final program, abstracts, and information about the 54th annual meeting of the Rocky Mountain Conference on Analytical Chemistry, co-endorsed by the Colorado Section of the American Chemical Society and the Society for Applied Spectroscopy. Held in Copper Mountain, Colorado, July 15-19, 2012.

Effect Of Disorder On Quantum Phase Transition In The Double Layered Ruthenates (Sr1−Xcax)3ru2o7effect Of Disorder On Quantum Phase Transition In The Double Layered Ruthenates (Sr1−Xcax)3ru2o7, Leonard Spinu, Zhe Qu, Jin Peng, Tijang Liu, David Forbes, Vkad Dobrosavljevic, Z Q. Mao

Physics Faculty Publications

(Sr_1−xCa_x)₃Ru₂O₇ is characterized by complex magnetic states, spanning from a long-range antiferromagnetically ordered state over an unusual heavy-mass nearly ferromagnetic (NFM) state to an itinerant metamagnetic (IMM) state. The NFM state, which occurs in the 0.4 > x > 0.08 composition range, freezes into a clusterspin glass (CSG) phase at low temperatures [Z. Qu et al., Phys. Rev. B 78, 180407(R) (2008)]. In this article, we present the scaling analyses of magnetization and the specific heat for (Sr_1−xCa_x)₃Ru₂O₇ in the 0.4 > x > 0.08 composition …

The Effect Of Polarization And Ingan Quantum Well Shape In Multiple Quantum Well Light Emitting Diode Heterostructures, Patrick M. Mcbride

Master's Theses

Previous research in InGaN/GaN light emitting diodes (LEDs) employing semi-classical drift-diffusion models has used reduced polarization constants without much physical explanantion. This paper investigates possible physical explanations for this effective polarization reduction in InGaN LEDs through the use of the simulation software SiLENSe. One major problem of current LED simulations is the assumption of perfectly discrete transitions between the quantum well (QW) and blocking layers when experiments have shown this to not be the case. The In concentration profile within InGaN multiple quantum well (MQW) devices shows much smoother and delayed transitions indicative of indium diffusion and drift during …

Multipolymer Interactions In Bulk Heterojunction Photovoltaic Devices, Grant Olson

Physics

Multipolymer photovoltaics, single layer devices made up of multiple photoactive polymers, can create organic photovoltaics (OPVs) with a wider spectral response than single polymer systems without the difficult fabrication of a tandem. Our group has successfully created multipolymer solar devices with 2% power conversion efficiency. We have analyzed the optical and electrical properties of these devices, and found that it may be possible for polymers to assist each other with charge extraction, though combining polymers disrupts single polymer crystallinity.

Real Time Shrinkage Studies In Photopolymer Films Using Holographic Interferometry, Mohesh Moothanchery, Izabela Naydenova, Viswanath Bavigadda, Suzanne Martin, Vincent Toal

Conference Papers

Polymerisation induced shrinkage is one of the main reasons why photopolymer materials are not more widely used for holographic applications. The aim of this study is to evaluate the shrinkage in an acrylamide photopolymer layer during holographic recording using holographic interferometry. Shrinkage in photopolymer layers can be measured by real time capture of holographic interferograms during holographic recording. Interferograms were captured using a CMOS camera at regular intervals. The optical path length change and hence the shrinkage were determined from the captured fringe patterns. It was observed that the photopolymer layer shrinkage is in the order of 3.5%.

Investigation Of Negative Differential Resistance Phenomena In Quantum Well Heterostructures, Nazariy Andrushchak

Graduate Theses and Dissertations

Increasing interest in entirely new possibilities for quantum mechanical description of carriers transport is becoming more evident with the developing advancements in epitaxial growth technique. Consequently, molecular beam epitaxy (MBE) technique is considered to be the most precise technique that allows the growth of ultra-thin layers of different compositions.

Those structures can be designed to investigate the wave-nature of carriers, which broadens the possibilities in device design and fabrication for a specific area. In this thesis the fundamental study of the real space charge transfer (RST) mechanism that took place in quantum well heterostructures and led to the negative differential …

Mott Transition And Electronic Structure In Complex Oxide Heterostructures, Jian Liu

Graduate Theses and Dissertations

Strongly correlated electron systems, particularly transition metal oxides, have been a focus of condensed matter physics for more than two decades since the discovery of high-temperature superconducting cuprates. Diverse competing phases emerge, spanning from exotic magnetism to unconventional superconductivity, in proximity to the localized-itinerant transition of Mott insulators. While studies were concentrated on bulk crystals, the recent rapid advance in synthesis has enabled fabrication of high-quality oxide heterostructures, offering a new route to create novel artificial quantum materials.

This dissertation details the investigation on ultrathin films and heterostructures of 3d⁷(t_2g⁶e_g¹) systems with …

Functional Magnetic Nanoparticles, James Gass

USF Tampa Graduate Theses and Dissertations

Nanoparticle system research and characterization is the focal point of this research and dissertation. In the research presented here, magnetite, cobalt, and ferrite nanoparticle systems have been explored in regard to their magnetocaloric effect (MCE) properties, as well as for use in polymer composites. Both areas of study have potential applications across a wide variety of interdisciplinary fields.

Magnetite nanoparticles have been successfully dispersed in a polymer. The surface chemistry of the magnetic nanoparticle proves critical to obtaining a homogenous and well separated high density dispersion in PMMA. Theoretical studies found in the literature have indicated that surface interface energy …

Section Abstracts: Astronomy, Mathematics And Physics With Materials Science

Virginia Journal of Science

Abstracts of the Astronomy, Mathematics, and Physics with Material Science Section for the 90th Annual Meeting of the Virginia Academy of Science, May 23-25, 2012, Norfolk State University, Norfolk, Virginia

Laser Processing Of Metals And Polymers, Senthilraja Singaravelu

Physics Theses & Dissertations

A laser offers a unique set of opportunities for precise delivery of high quality coherent energy. This energy can be tailored to alter the properties of material allowing a very flexible adjustment of the interaction that can lead to melting, vaporization, or just surface modification. Nowadays laser systems can be found in nearly all branches of research and industry for numerous applications. Sufficient evidence exists in the literature to suggest that further advancements in the field of laser material processing will rely significantly on the development of new process schemes. As a result they can be applied in various applications …

Controlling Nanoparticles Formation In Molten Metallic Bilayers By Pulsed-Laser Interference Heating, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mathematics Faculty Publications

The impacts of the two-beam interference heating on the number of core-shell and embedded nanoparticles and on nanostructure coarsening are studied numerically based on the non-linear dynamical model for dewetting of the pulsed-laser irradiated, thin (< 20 nm) metallic bilayers. The model incorporates thermocapillary forces and disjoining pressures, and assumes dewetting from the optically transparent substrate atop of the reflective support layer, which results in the complicated dependence of light reflectivity and absorption on the thicknesses of the layers. Stabilizing thermocapillary effect is due to the local thickness-dependent, steady- state temperature profile in the liquid, which is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Linear stability analysis of the model equations set for Ag/Co bilayer predicts the dewetting length scales in the qualitative agreement with experiment.

Measurement Of Semiconductor Surface Potential Using The Scanning Electron Microscope, Jennifer T. Heath, Chun-Sheng Jiang, Mowafak M. Al-Jassim

Faculty Publications

We calibrate the secondary electron signal from a standard scanning electron microscope to voltage, yielding an image of the surface or near-surface potential. Data on both atomically abrupt heterojunction GaInP/GaAs and diffused homojunction Si solar cell devices clearly show the expected variation in potential with position and applied bias, giving depletion widths and locating metallurgical junctions to an accuracy better than 10 nm. In some images, distortion near the p-n junction is observed, seemingly consistent with the effects of lateral electric fields (patch fields). Reducing the tube bias removes this distortion. This approach results in rapid and straightforward collection of …

Fundamental Properties Of Functional Zinc Oxide Nanowires Obtained By Electrochemical Method And Their Device Applications, Athavan Nadarajah

Dissertations and Theses

We report on the fundamental properties and device applications of semiconductor nanoparticles. ZnO nanowires and CdSe quantum dots were used, prepared, characterized, and assembled into novel light-emitting diodes and solar cells. ZnO nanowire films were grown electrochemically using aqueous soluble chloride-based electrolytes as precursors at temperatures below 90° C. Dopants were added to the electrolyte in the form of chloride compounds, which are AlCl₃, CoCl₂, CuCl₂, and MnCl₂. The optical, magnetic, and structural properties of undoped and transition-metal-ion doped ZnO nanowires were explored. Our results indicate that the as-grown nanowire structures have …

Effects Of Transition Metal Doping On Multiferroic Ordering In Ni3v2o8 And Fevo4, Akila Deeghayu Kumarasiri

Wayne State University Dissertations

We have studied the effects of doping both non-magnetic and magnetic ions on the phase transitions and multiferroic ordering in two multiferroic oxides; Ni3V2O8 and FeVO4. Magnetic, dielectric, specific heat, polarization and AC susceptibility measurements were used to track changes in phase transition temperatures. We found that the two higher temperature magnetic transitions in Ni3V2O8; TH = 9.1 K and TL = 6.3 K are suppressed to lower temperatures with all transition metal dopants. For Zn doping, the rates of the suppression of both TH and TL with dopant fraction are consistent with simple site dilution for two-dimensional spin systems, …

Experimental And Theoretical Analysis Of Strain Engineered Aluminium Nitride On Silicon For High Quality Aluminium(X)Indium(Y)Gallium(1-X-Y)Nitride Epitaxy, Mihir Hemant Tungare

Legacy Theses & Dissertations (2009 - 2024)

III-Nitrides on Si are of great technological importance due to the availability of large area, epi ready Si substrates and the ability to heterointegrate with mature silicon micro and nanoelectronics. The major roadblock with realizing this is the large difference in thermal expansion coefficients and lattice constants between the two material systems. A novel technique developed in our research lab shows the potential of simultaneous and substantial reduction in dislocation and crack density in GaN on Si (111). Research undertaken in the current doctoral dissertation, validates the superior GaN quality on Si obtained using our technique and determines the factors …

Growth Analysis Of (Ag,Cu)Inse2 Thin Films Via Real Time Spectroscopic Ellipsometry, S. A. Little, V. Ranjan, R. W. Collins, S. Marsillac

Electrical & Computer Engineering Faculty Publications

In situ and ex situ characterization methods have been applied to investigate the properties of (Ag,Cu)InSe₂ (ACIS) thin films. Data acquired from real time spectroscopic ellipsometry (RTSE) experiments were analyzed to extract the evolution of the nucleating, bulk, and surface roughness layer thicknesses. The evolution of these layer thicknesses suggests a transition from Volmer-Weber to Stranski-Krastanov type behavior when Cu is replaced by Ag. The complex dielectric functions of ACIS at both deposition and room temperature as a function of film composition were also extracted from the RTSE data, enabling parameterization of the alloy optical properties.

Electric-Field-Induced Interfacial Instabilities Of A Soft Elastic Membrane Confined Between Viscous Layers, Mohar Dey, Dipankar Bandyopadhyay, Ashutosh Sharma, Shizhi Qian, Sang Woo Joo

Mechanical & Aerospace Engineering Faculty Publications

We explore the electric-field-induced interfacial instabilities of a trilayer composed of a thin elastic film confined between two viscous layers. A linear stability analysis (LSA) is performed to uncover the growth rate and length scale of the different unstable modes. Application of a normal external electric field on such a configuration can deform the two coupled elastic-viscous interfaces either by an in-phase bending or an antiphase squeezing mode. The bending mode has a long-wave nature, and is present even at a vanishingly small destabilizing field. In contrast, the squeezing mode has finite wave-number characteristics and originates only beyond a threshold …

Multi-Wavelength Laser Sensor For Intruder Detection And Discrimination, Kavitha Venkataraayan, Sreten Askraba, Kamal E. Alameh, Clifton L. Smith

Research outputs 2011

An intruder detection and discrimination sensor with improved optical design is developed using lasers of different wavelengths to demonstrate the concept of discrimination over a distance of 6 m. A distinctive feature of optics is used to provide additional transverse laser beam scanning. The sample objects used to demonstrate the concept of discrimination over a distance of 6 m are leaf, bark, black fabric, PVC, wood and camouflage material. A camouflage material is chosen to illustrate the discrimination capability of the sensor. The sensor utilizes a five-wavelength laser combination module, which sequentially emits identically-polarized laser light beams along one optical …