Materials Science and Engineering Commons^™

Application Of X-Ray Grating Interferometry To Polymer/Flame Retardant Blends In Additive Manufacturing, Omoefe Joy Kio

LSU Doctoral Dissertations

X-ray grating interferometry is a nondestructive tool for visualizing the internal structures of samples. Image contrast can be generated from the absorption of X-rays, the change in phase of the beam and small-angle X-ray scattering (dark-field). The attenuation and differential phase data obtained complement each other to give the internal composition of a material and large-scale structural information. The dark-field signal reveals sub-pixel structural detail usually invisible to the attenuation and phase probe, with the potential to highlight size distribution detail in a fashion faster than conventional small-angle scattering techniques. This work applies X-ray grating interferometry to the study of …

Exploring The Electrical Properties Of Twisted Bilayer Graphene, William Shannon

Senior Theses

Two-dimensional materials exhibit properties unlike anything else seen in conventional substances. Electrons in these materials are confined to move only in the plane. In order to explore the effects of these materials, we have built apparatus and refined procedures with which to create two-dimensional structures. Two-dimensional devices have been made using exfoliated graphene and placed on gold contacts. Their topography has been observed using Atomic Force Microscopy (AFM) confirming samples with monolayer, bilayer, and twisted bilayer structure. Relative work functions of each have been measured using Kelvin Probe Force Microscopy (KPFM) showing that twisted bilayer graphene has a surface potential …

Manufacturing And Testing The Permanent Magnet Linear Motor, Renjie Kang

Senior Theses

Controlled mechanical motion is vital in many useful applications in technology. Among them, linear motors have advantages over traditional rotating motors. In this work, we built a permanent magnet linear motor to test and measure its energy efficiency. A maximum 29% total energy efficiency, and 67% energy transfer rate, were detected. In addition, a C-shape support structure was added to the moving part in order to increase the moving accuracy. The tests show that, with the support structure, the fluctuation in the vertical direction decreases significantly, but the friction of the system slightly increases.

Plasmonic Properties Of Nanoparticle And Two Dimensional Material Integrated Structure, Desalegn Tadesse Debu

Graduate Theses and Dissertations

Recently, various groups have demonstrated nano-scale engineering of nanostructures for optical to infrared wavelength plasmonic applications. Most fabrication technique processes, especially those using noble metals, requires an adhesion layer. Previously proposed theoretical work to support experimental measurement often neglect the effect of the adhesion layers. The first finding of this work focuses on the impact of the adhesion layer on nanoparticle plasmonic properties. Gold nanodisks with a titanium adhesion layer are investigated by calculating the scattering, absorption, and extinction cross-section with numerical simulations using a finite difference time domain (FDTD) method. I demonstrate that a gold nanodisk with an adhesive …

Methods To Remotely Eliminate Biofilm From Medical Implants Using 2.4 Ghz Microwaves, Brett Glenn

Mechanical Engineering Undergraduate Honors Theses

Infections associated with biofilm growth are usually challenging to eradicate due to their high tolerance toward antibiotics [11, 12]. Biofilms often form on the inert surfaces of medically implanted devices [13]. No matter the sophistication, microbial infections can develop on all medical devices and tissue engineering constructs [12]. Related infections lead to 2 million cases annually in the U.S., costing the healthcare system over $5 billion in additional healthcare expenses [12].

Novel solutions to biofilm’s microbial colonization span the spectrum of engineering and science disciplines. Yet a practical solution still does not exist. The research presented here will explore a …

Equation Of State Of H2o Ice Using Melt-Recrystallization, Zachary Michael Grande

UNLV Theses, Dissertations, Professional Papers, and Capstones

The recent surge in exoplanet discoveries due to advancements in astrophysical technology and analysis has brought the reliability of early equation of state measurements into question as they are the limiting factor when modeling composition of these planets. H2O content is among the most important for the search of habitable planets as well as in understanding planetary dynamics and atmosphere formation. Over the last three decades the equation of state of H2O has been investigated with various techniques but, has suffered from anisotropic strain and poor powder statistics resulting in a large discrepancy in equation of state fits. At pressures …

Optical Enhancement In Periodic Plasmonic Gratings For Sers And Metal-Semiconductor-Metal Photodetectors (Msm-Pds) Applications, Ahmad Aziz Darweesh

Graduate Theses and Dissertations

This dissertation is aimed to numerically study the effect of plasmonic grating electrodes on the efficiency of metal-semiconductor-metal photodetectors (MSM PDs) and the sensitivity of Surface Enhanced Raman Spectroscopy (SERS). This research can benefit many areas of nanoscience and optics, including plasmonic applications, such as, super lenses, nano-scale optical circuits, optical filters, surface plasmon enhanced photo-detectors solar cells, imaging sensors, charge-coupled devices (CCD), and optical-fiber communication systems. Several parameters, wire widths and thickness, gap space, taper angle, and the incident wavelength and angle, were investigated. The goal of this research is to utilize the plasmonic phenomenon by using plasmonic gratings …

Phase Evolution And Dynamic Behavior In Materials With Noncollinear Spin Textures, Eleanor M. Clements

USF Tampa Graduate Theses and Dissertations

Noncentrosymmetric magnetic materials have gained special attention due to their ability to stabilize topologically nontrivial magnetic states via the competition between symmetric exchange and the antisymmetric Dzyaloshinskii-Moriya (DM) interaction. The spin struc- tures in these materials have become a center of interest for spintronics applications due to their stable, particle-like properties, and high degree of tunability via control of external parameters, such as magnetic and/or electric field and temperature. Understanding how these robust magnetic structures stabilize, evolve, dynamically respond, and adhere to existing models, all in the presence of external stimuli, are topics of fundamental interest. In this dissertation, the …

Influence Of Sonication Parameters On The Morphology Of Nanocellulose Aerogels, Dexter Cox, Tim Kidd

Research in the Capitol

Nanocellulose is a renewable and biocompatible material that has a tensile strength similar to aluminum, is stiffer than Kevlar, and has a strength to weight ratio eight times that of stainless steel. There has been a range of studies on nanocellulose materials for potential use as a low-calorie food substitute, biomedical wound dressings, and as a structural component for buildings. Throughout this research experiment, nanocellulose aerogels of different mass compositions were created through a mechanical process using an ultrasonic processor with a titanium probe attachment. The purpose of this study was to develop a method that reduces the amount titanium …

The Effects Of Organic And Inorganic Nanoparticles On Bacterial Deactivation, Lauren Cooper

Mahurin Honors College Capstone Experience/Thesis Projects

Antibacterial resistance is one of the greatest problems in modern medicine, as healthcare professionals are experiencing more and more difficulty in providing effective care. As such, alternative methods of treatment are needed in order to overcome this issue. One recently proposed method of alternative treatment is photodynamic therapy. Photodynamic therapy is a light-based method of treatment that utilizes (1) a photosensitizing agent, (2) light, (3) produced oxygen species. When the photosensitizing agent is injected into an infected region of interest and then irradiated with a certain wavelength of light, the agent is photoactivated and begins to produce harmful forms of …

Effect Of Alkali On The Efficiency And Reliability Of Cu(In,Ga)Se2 Solar Cells, Shankar Karki

Physics Theses & Dissertations

The incorporation of alkali metal has contributed tremendously in a bid to realize greater than 20% efficient Cu(In,Ga)Se₂(CIGS) solar cells. Achieving high efficiency is one key parameter for the success of a photovoltaic technology but so is its long-term stability. In this thesis, the relationship between the performance of alkali treated Cu(In,Ga)Se₂ solar cells and their physicochemical, electronic and structural properties are explored through a comparative study between standard devices and alkali (K, Rb) treated devices. The alkali treated devices tend to have a lower concentration of E_v+0.98 eV trap, higher majority carrier concentration and …

Scaling Film Cooling Adiabatic Effectiveness With Mass Transfer And Thermal Experimental Techniques, Luke J. Mcnamara

Theses and Dissertations

With increasing engine temperatures, it is becoming more important to design effective film cooling schemes. Low temperature, large scale tests are often implemented in the design process to reduce cost and complexity. A nondimensional adiabatic effectiveness can be used as an indication of the performance of a film cooling scheme. However, the coolant flow rate must be properly scaled between the low temperature tests and engine temperatures to accurately predict film cooling effectiveness. This process is complicated by gas property variation with temperature. Tests are commonly conducted using thermal measurement techniques with infrared thermography (IR), but the use of pressure …

Direct Numerical Simulation Of Roughness Induced Hypersonic Boundary Layer Transition On A 7° Half-Angle Cone, Tara E. Crouch

Theses and Dissertations

Direct numerical simulation (DNS) computational fluid dynamic (CFD) calculations were performed on a 30° slice of 7° half-angle cones with increasing nose radii bluntness at Mach 10 while simulating a distributed roughness pattern on the cone surface. These DNS computations were designed to determine if the non-modal transition behavior observed in testing performed at the Arnold Engineering Development Center (AEDC) Hypervelocity Wind Tunnel 9 was induced via distributed surface roughness. When boundary layer transition is dominated by second mode instabilities, an increase in nose radius delays the transition location downstream. However, blunt nose experiments indicated that as the nose radius …

Computational And Experimental Development Of 2d Anisotropic Photonic Crystal Metamaterials, James A. Ethridge

Theses and Dissertations

The future of optical devices involves manipulation of nanoscale structure in order to achieve full control over the properties of the device. In fields as diverse as directed energy, remote sensing, optical communications and optical computing, these devices promise to greatly improve performance and efficiency. To advance this further, novel samples that incorporate both photonic crystal (PhC) structure and metamaterial properties, known as PhC metamaterials, are proposed. These PhC metamaterials allow for complete control over the directionality of the light-matter interaction to serve in these new applications. To develop this technology, first, metamaterials with no PhC structure are fabricated using …

Proximitized Materials, Igor Žutić, Alex Matos-Abiague, Benedikt Scharf, Hanan Dery, Kirill Belashchenko

Kirill Belashchenko Publications

Advances in scaling down heterostructures and having an improved interface quality together with atomically thin two-dimensional materials suggest a novel approach to systematically design materials. A given material can be transformed through proximity effects whereby it acquires properties of its neighbors, for example, becoming superconducting, magnetic, topologically nontrivial, or with an enhanced spin–orbit coupling. Such proximity effects not only complement the conventional methods of designing materials by doping or functionalization but also can overcome their various limitations. In proximitized materials, it is possible to realize properties that are not present in any constituent region of the considered heterostructure. While the …

Coupling Of Light's Orbital Angular Momentum To A Quantum Dot Ensemble, Alaa A. Bahamran

Electronic Theses and Dissertations

We theoretically and experimentally investigate the transfer of orbital angular momentum from light to an ensemble of semiconductor-based nanostructures composed of lead sulfide quantum dots. Using an ensemble of quantum dots offers a higher cross-section and more absorption of twisted light fields compared to experimentally challenging single-nanostructure measurements. However, each quantum dot (except for on-center) sees a displaced light beam parallel to its own axis of symmetry. The transition matrix elements for the light-matter interaction are calculated by expressing the displaced light beam in terms of the appropriate light field centered on the nanoparticles. The resulting transition rate induced by …

Investigation Of Optical Second Harmonic Generation From Si (100) With Process Tailored Surface & Embedded Ag Nanostructures For Advanced Si Nonlinear Nanophotonics, Gourav Bhowmik

Legacy Theses & Dissertations (2009 - 2024)

The challenge of current microelectronic architecture in transmission bandwidth and power consumption can be potentially solved by using silicon photonics technologies that are compatible with modern CMOS fabrication. One of the critical active photonic devices for Si photonics is a Si based optical modulator. Most of the reported silicon modulators rely on the free carrier plasma dispersion effect. In those cases, a weak change of the refractive index obtained by carrier accumulation, injection or depletion is utilized in a Mach-Zehnder interferometer or a microring resonator to achieve intensity modulation, rendering them difficult for chip-level implementation due to a large footprint …

A Review: Thermal Stability Of Methylammonium Lead Halide Based Perovskite Solar Cells, Tanzila Tasnim Ava, Abdullah Al Mamun, Sylvain Marsillac, Gon Namkoong

Electrical & Computer Engineering Faculty Publications

Perovskite solar cells have achieved photo-conversion efficiencies greater than 20%, making them a promising candidate as an emerging solar cell technology. While perovskite solar cells are expected to eventually compete with existing silicon-based solar cells on the market, their long-term stability has become a major bottleneck. In particular, perovskite films are found to be very sensitive to external factors such as air, UV light, light soaking, thermal stress and others. Among these stressors, light, oxygen and moisture-induced degradation can be slowed by integrating barrier or interface layers within the device architecture. However, the most representative perovskite absorber material, CH_{3 …}

Ignition Of A Plasma Discharge Inside An Electrodeless Chamber: Methods And Characteristics, Mounir Laroussi

Electrical & Computer Engineering Faculty Publications

In this paper the generation and diagnostics of a reduced pressure (300 mTorr to 3 Torr) plasma generated inside an electrodeless containment vessel/chamber are presented. The plasma is ignited by a guided ionization wave emitted by a low temperature pulsed plasma jet. The diagnostics techniques include Intensified Charge Coupled Device (ICCD) imaging, emission spectroscopy, and Langmuir probe. The reduced-pressure discharge parameters measured are the magnitude of the electric field, the plasma electron number density and temperature, and discharge expansion speed.

Computational Studies On Perovskite-Metallofullerene Interface And Magnetic Properties Of Mn-Based Mixed Olivines, Bethuel Omutiti Khamala

Open Access Theses & Dissertations

Methyl ammonium lead halide (MAPbX3) perovskite based solar cells have recently emerged as promising class of materials for photovoltaic applications with efficiencies reaching over 22%. Designing interfaces with strong binding is vital to developing efficient, high-performing solar cells. Fullerene-based materials are widely employed as efficient electron acceptors and can serve as electron transporting layer in perovskite based solar cells. We have studied interfaces of methyl ammonium lead iodide MAPbI3 with Sc3N@C80 fullerene and Sc3N@C80PCBM fullerene derivate within the density functional formalism. Different surface terminations and orientations of the methyl ammonium are examined for binding of the fullerene layer. Our calculated …

Direct Polymer Grafting As A Method Of Maintaining The Mechanical Properties Of Cellulose Nanocrystals In The Presence Of Moisture, Mary Elizabeth Breen-Lyles

Graduate Research Theses & Dissertations

Cellulose nanocrystals (CNCs) are a distinctive nanomaterial derived from cellulose, the most abundant natural polymer on Earth, and the primary reinforcing structural component of cellulose fibrils found within the plant cell wall. These nanocrystals exhibit mechanical properties comparable to synthetic aramid fibers but are advantageous as they are biodegradable, renewable, and can be produced sustainably as they are predominantly extracted from naturally occurring cellulosic materials. These qualities make it a sustainable, highly renewable and environmentally friendly material to be used in place of synthetic materials in a variety of applications. With their high surface area to volume ratio, low level …

Magnetotransport In Zrte5 Crystals, Maksim Andreevich Sultanov

Graduate Research Theses & Dissertations

ZrTe5 is a topological material that is predicted to have a strain or temperature induced phase transition from a topological insulator state into a Weyl/Dirac semimetal state. In this study I find that there is insufficient evidence to support the claims for the existence of such a phase transition. I performed magnetoresistivity measurements using a Quantum Design Physical Properties Measurement System (PPMS) to measure the transverse and longitudinal resistivities at various temperatures and different strengths and orientations of the magnetic field. The measurement results were analyzed using OriginPro to determine the carrier mobility and density and to determine the temperature …

Scanning Probe Microscopy Measurements On 2d Materials And Iridates, Armin Ansary

Theses and Dissertations--Physics and Astronomy

In the past two decades, there has been a quest to understand and utilize novel materials such as iridates and two-dimensional (2D) materials. These classes of materials show a lot of interesting properties both in theoretical predictions as well as experimental results. Physical properties of some of these materials have been investigated using scanning probe measurements, along with other techniques.

One-dimensional (1D) catalytic etching was investigated in few-layer hexagonal boron nitride (hBN) films. Etching of hBN was shown to share several similarities with that of graphitic films. As in graphitic films, etch tracks in hBN commenced at film edges and …

Effects Of Substrate Radial-Position Relative To The Sputter-Gun Axis On The Electrical, Optical And Structural Properties Of Zno Thin Films Deposited By Reactive Direct Current Magnetron Sputtering, John Paul Eneku, Tom Otiti, Julius Mwakondo Mwabora, David Horwat

Tanzania Journal of Science

ZnO thin films were deposited using reactive direct current (dc) magnetron sputtering on glass substrates placed at seven variable radial positions (-1, 0, 1, 2, 3, 4 and 5 cm)  relative to the sputter-gun (target) axis. A pure zinc target was used and sputtering carried out in argon and oxygen atmosphere with flow rates of 50 sccm and 6 sccm, respectively. XRD characterization showed that, all films crystallized homogeneously in the wurtzite phase with a strong (002) and a weak (004) orientations. Film crystallinity was very low at substrate positions located less than or equal to 1 cm from the …

Optimization Of Zinc To Tin Ratio In A Sol Gel Precursor Solution On The Growth And Properties Of Annealed Czts Thin Films, Justine John Tibaijuka, Margaret E Samiji, Nuru R Mlyuka

Tanzania Journal of Science

CZTS thin films were deposited by sol–gel spin coating method using precursor solutions prepared by dissolving copper acetate dihydrate, zinc acetate dihydrate, tin chloride and thiourea in methanol and monoethylamine then annealed in RTP furnace at 500 °C. Sol–gel precursor solutions were prepared with different Zn/Sn in a precursor solution and were annealed at different time intervals; and their effects on the optical and electrical properties of CZTS (Cu2ZnSnS4) films were investigated. The optical band-gap values were estimated to be between 1.30 and 1.88 eV while the absorption coefficients were in the range of 104 cm–1 in the visible region. …

Compositional And Thickness Effects On The Optical Properties Of Zinc–Doped Selenium–Antimony Thin Films, Austine A Mulama, Julius M Mwabora, Andrew O Oduor, Cosmas M Muiva

Tanzania Journal of Science

Chalcogenide system of antimony (Sb)-selenium (Se)-zinc (Zn) system is a promising semiconductor for phase change memory devices due to its thermal stability and low power consumption. The study investigated the effect of film thickness and zinc content on the optical properties of thermally evaporated Sb10Se90-xZnx (x = 0, 5, 10 & 15 at. %) thin films. It was found that transmittance (T~ 85-40%) and optical band gap energy (Eopt ~ 1.60 eV – 1.22 eV) decreased but absorption coefficient (α~0.840–2.031 104 cm–1) increased with increase in zinc content. Furthermore, as the film thickness increased from 53 ± 5 nm to …

Effects Of Aluminium And Tungsten Co-Doping On The Optical Properties Of Vo2 Based Thin Films, Cephas J Lyobha, Nuru R Mlyuka, Margaret E Samiji

Tanzania Journal of Science

Aluminium and tungsten co-doped vanadium dioxide (VO2:W:Al) thin films were deposited by DC reactive magnetron sputtering technique. In this work we report on the effects of aluminium and tungsten co–doping on the optical properties of vanadium dioxide (VO2) based thin films with a view of combining both increased luminous transmittance (Tlum) and lowered transition temperature (τc). The effect of aluminium and tungsten co-doping on semiconductor-metal transition of vanadium dioxide films was investigated and compared with tungsten doped and undopedVO2films. Spectral transmittances of the films were obtained using Shimadzu SolidSpec-3700 DUV UV-VIS-NIR spectrophotometer. The results revealed that the transmittance of tungsten …

Hall Effect Parameters Of Aluminium And Tungsten Co-Doped Vo2 Thin Films, Mohamed Mussa, Nuru R Mlyuka, Margaret E Samiji

Tanzania Journal of Science

The Hall Effect parameters of Al and W co-doped VO2 thin films were studied in order to explain the effect of co-doping on the electrical properties of thermochromic VO2 films. The carrier concentrations and conductivity of the films were found to increase with increase in temperature while carrier mobility decreased reaching a minimum around the transition temperature then slightly rose and became stable at high temperatures. Tungsten doped films displayed higher carrier concentrations and conductivity on both sides of the metal insulator transition and lower mobility compared to undoped and Al and W co-doped VO2 thin films.

Transient Transmission Oscillations In Doped And Undoped Lithium Niobate Induced By Near-Infrared Femtosecond Pulses, Bryan J. Crossman, Gregory J. Taft

Physics Faculty Publications

Transient transmission oscillations in X-cut and Z-cut congruent, iron-doped, and magnesium-doped lithium niobate samples were measured using 50 fs, 800 nm, 0.5 nJ pulses from a self-mode-locked Ti:sapphire laser in an optical pump–probe system. Several Raman-active oscillation modes excited by these pulses were observed as changes in the transmitted probe intensity versus time delay between the pump and probe pulses. The samples were rotated to determine how the incident polarization of the pump pulses affects the mode excitations. The observed Raman-active oscillations correspond to previously reported symmetry modes measured with traditional, continuous-wave, Raman spectroscopy using the same scattering …

Optimization Of Useful Hard X-Ray Photochemistry, David Lewis Goldberger

UNLV Theses, Dissertations, Professional Papers, and Capstones

X-ray induced damage is generally considered a nuisance, but in the field of Useful Hard X-ray Photochemistry we harness the highly ionizing and penetrating properties of hard X-rays (> 7 keV) to initiate novel photochemical decomposition and synthesis at ambient and extreme conditions. Preliminary experiments suggest that the energy of irradiating photons and the sample pressure play roles in determining the nature of X-ray induced damage. Here, we present the X-ray energy dependence of damage induced in strontium oxalate, strontium nitrate, and barium nitrate, as well as the pressure dependence of X-ray induced damage of strontium oxalate. Our results indicate …