Materials Science and Engineering Commons^™

First Announcement Of 76th Annual Meeting Of The International Society Of Electrochemistry, International Society Of Electrochemistry (Ise)

Journal of Electrochemistry

No abstract provided.

Data-Driven Viewpoint For Developing Next-Generation Mg-Ion Solid-State Electrolytes, Fang-Ling Yang, Ryuhei Sato, Eric Jian-Feng Cheng, Kazuaki Kisu, Qian Wang, Xue Jia, Shin-Ichi Orimo, Hao Li

Journal of Electrochemistry

Magnesium (Mg) is a promising alternative to lithium (Li) in solid-state batteries due to its abundance and high theoretical volumetric capacity. However, the sluggish Mg-ion conduction in the lattice of solid-state electrolytes (SSEs) is one of the key challenges that hamper the development of Mg-ion solid-state batteries. Though various Mg-ion SSEs have been reported in recent years, key insights are hard to be derived from a single literature report. Besides, the structure-performance relationships of Mg-ion SSEs need to be further unraveled to provide a more precise design guideline for SSEs. In this Viewpoints article, we analyze the structural characteristics of …

Professor Yong Yang, The Editorial Board Member Of Journal Of Electrochemistry, Is Elected As A Fellow Of The Electrochemical Society, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.

Tribocorrosion And Metal Release From Austenitic Stainless Steels 304 And 201 In Simulated Cassava Food Contact, Robert Addai, Temitope E. Olowoyo, Thalia E. Standish, Jeffrey Daniel Henderson, Ubong Eduok, Yolanda Hedberg

Chemistry Publications

Cassava is the third most significant calorie source in the tropics. Its processing has changed from traditional methods to stainless steel processing machines. This study investigated the influence of cassava on metal release from two common stainless steels, ASTM 304 and 201, with and without friction, and on tribocorrosion (multianalytically) of 304. Cassava was relatively corrosive and hindered repassivation of the surface oxide of stainless steel, but it also acted as a lubricant against mechanical friction. The combined action of friction and cassava caused a significant increase in iron, chromium, nickel, and manganese release from the stainless steels (30–35- fold …

Laser 3d Printing Of Diamond-Based Composite Materials For Thermal Management Applications, Nada Kraiem

Dissertations and Doctoral Documents, University of Nebraska-Lincoln, 2023–

With the trend towards miniaturization of electrical equipment and the constant increase in power density in semiconductor devices, efficient heat management has become a major concern for researchers. Indeed, this technological evolution imposes increasingly strict constraints in terms of thermal dissipation, necessitating innovative solutions to ensure better durability and reliability of components. In this context, the use of composite materials offering high thermal conductivity (TC) and low coefficient of thermal expansion (CTE) compared to pure metals has become essential to address overheating issues in electronic components.

The utilization of advanced materials such as diamond (D), with exceptional TC and hardness …

Dual Light Emission Of Cssni3-Based Powders Synthesized Via A Mechanochemical Process, Xuan Huang, Xiaobing Tang, Xiyu Wen, Yuebin Charles Lu, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

Lead toxicity has hindered the wide applications of lead halide perovskites in optoelec- tronics and bioimaging. A significant amount of effort has been made to synthesize lead-free halide perovskites as alternatives to lead halide perovskites. In this work, we demonstrate the feasibility of synthesizing CsSnI3-based powders mechanochemically with dual light emissions under ambi- ent conditions from CsI and SnI2 powders. The formed CsSnI3-based powders are divided into CsSnI3-dominated powders and CsSnI3-contained powders. Under the excitation of ultraviolet light of 365 nm in wavelength, the CsSnI3-dominated powders emit green light with a wavelength centered at 540 nm, and the CsSnI3-contained powders …

Poly(Thioether) Thermosets With Gated Photodegradation, Surabhi Jha

Dissertations

Photodegradable polymer networks are attractive due to the precise spatiotemporal control and large-area applicability of light. Chemical linkages that enable these polymer networks to be photo-responsive, also hinder their applicability in ambient light. Photostable and photodegradable networks have recently been reported to overcome this challenge by combining other stimuli with light for degradation. We report the design of a network that responds to a simultaneous, dual stimulus for photodegradation. We design poly(thioether acetal) networks with benzylidene acetal moieties that are known to undergo β-scission in the presence of free thiols. By blocking these free thiols with a thermally labile protecting …

Understanding And Tuning Magnetism In Layered Ising-Type Antiferromagnet Fepse3 For Potential 2d Magnet, Rabindra Basnet, Taksh Patel, Jian Wang, Dinesh Upreti, Santosh Karki Chhetri, Gokul Acharya, Md Rafique Un Nabi, Joshua Sakon, Jin Hu

Chemistry & Biochemistry Faculty Publications and Presentations

Recent developments in 2D magnetic materials have motivated the search for new van der Waals magnetic materials, especially Ising-type magnets with strong magnetic anisotropy. Fe-based MPX₃ (M = transition metal, X = chalcogen) compounds such as FePS₃ and FePSe₃ both exhibit an Ising-type magnetic order, but FePSe₃ receives much less attention compared to FePS₃. This work focuses on establishing the strategy to engineer magnetic anisotropy and exchange interactions in this less-explored compound. Through chalcogen and metal substitutions, the magnetic anisotropy is found to be immune against S substitution for Se whereas …

Mesostructure Reconstruction Of Prepreg Platelet Molded Composite With Artificial Intelligence, Richard Larson

Mechanical & Aerospace Engineering Theses & Dissertations

Prepreg platelet molded composites (PPMC) are long, discontinuous fiber reinforced polymer materials. PPMC are an important subcategory of composite materials as they are processible into geometrically complex structures and can be produced via high-throughput manufacturing processes, however they have higher stiffness and strength as compared to traditional discontinuous fiber reinforced polymers. However, there is inherent randomness in the structure of PPMCs and as such, PPMC parts frequently require per part testing that is cost prohibitive.

Herein, a method using artificial intelligence is proposed as a more cost-effective method of inspecting PPMC parts. Different artificial intelligence (AI) architectures are explored to …

Carbon-Based Nanocomposite Membranes For Membrane Distillation: Progress, Problems And Future Prospects, Chhabilal Regmi, Yuwaraj K. Kshetri, S. Ranil Wickramasinghe

Chemical Engineering Faculty Publications and Presentations

The development of an ideal membrane for membrane distillation (MD) is of the utmost importance. Enhancing the efficiency of MD by adding nanoparticles to or onto a membrane’s surface has drawn considerable attention from the scientific community. It is crucial to thoroughly examine state-of-the-art nanomaterials-enabled MD membranes with desirable properties, as they greatly enhance the efficiency and reliability of the MD process. This, in turn, opens up opportunities for achieving a sustainable water–energy–environment nexus. By introducing carbon-based nanomaterials into the membrane’s structure, the membrane gains excellent separation abilities, resistance to various feed waters, and a longer lifespan. Additionally, the use …

Molybdenum Disulfide And Carbon Nanotubes Composite Electrode For Electrochemical Conversion Of Salinity Gradient Energy, Jia-Jun Li, Wei-Bin Zhang, Xin-Yu Liu, Jing-Lei Yang, Yi Yin, Ze-Qin Yang, Xue-Jing Ma

Journal of Electrochemistry

The ocean accounts for 97% of the total water resources on earth, covering over 70% of the map's surface area. With the continuous consumption of non-renewable energy sources such as fossil fuels and the rapid development of renewable energy, humans are increasingly paying attention to the utilization of ocean resources. Ocean energy includes tidal energy, wave energy, temperature difference energy, and salinity gradient energy. Salinity gradient energy is the energy generated by the interaction of seawater and fresh water, which is the ocean energy existing in the form of chemical energy. This energy is mostly generated in estuaries. The osmotic …

Surface Structures And Properties Of High-Voltage Licoo2: Reviews And Prospects, Jian-Jun Fang, Yu-Hao Du, Zi-Jian Li, Wen-Guang Fan, Heng-Yu Ren, Hao-Cong Yi, Qing-He Zhao, Feng Pan

Journal of Electrochemistry

Nowadays, the development of high-voltage LiCoO₂ (lithium cobalt oxide, LCO) cathodes has attracted the widespread attention from both the academic and industry fields. Among the multiple concerns, researches on the surface issues would provide the most effective performance optimization pathway for the synthesis of high-voltage LCO. In this work, the issues of high-voltage LCO, including the phase transitions and crack formation, the oxygen redox related issues and side reactions, as well as the surface structure degradation, have been systematically reviewed. Then, we further clarify the surface modulations, and the interplay between the surface modulation and electrolyte tuning. Finally, we …

In Situ Diffuse Reflectance Spectroelectrochemistry Of Cathode Materials In Lithium-Ion Batteries, Lu-Lu Chen, Hao-Ran Li, Wei-Yi Liu, Wei Wang

Journal of Electrochemistry

Developing in situ spectroelectrochemistry methods, which can provide detailed information about species transformation during electrochemical reactions, is very important for studying electrode reaction mechanisms and improving battery performance. Studying real-time changes in the surface of electrode materials during normal operation can be an effective way to assess and optimize the practical performance of electrode materials, thus, in situ and in operando characterization techniques are particularly important. However, batteries are hard to be studied by in situ characterization measurements due to their hermetically sealed shells, and there is still much room for battery characterizations. In this work, a specially designed battery …

Pollution Characteristics Of Heavy Metals In Solid Waste Subgrade Filling Materials, Du Qianhui, Fu Wei, Zhang Junhui, Tang Qiang, Gu Fan

Journal of China & Foreign Highway

Using solid waste in the road engineering field for subgrade filling is an important approach for building green and low-carbon emission roads.However,most solid waste contains heavy metal pollutants to varying degrees,and heavy metals will be released under complex environments including rainfall infiltration and groundwater immersion,thereby causing pollution to the surrounding soil and groundwater if not handled properly.This paper reviewed the current status of research on four aspects,including the comprehensive use of solid waste materials in subgrade engineering,the leaching and migration behaviors of heavy metals in solid waste,and the prevention and control treatment of heavy metals in solid waste.It is found …

Experimental Study On Influence Of Adsorbed Bound Water On Strength And Permeability Characteristics Of High Liquid Limit Soil, Fu Ceyuan, Zhou Shijie

Journal of China & Foreign Highway

In order to reveal the influence of adsorbed bound water on the strength and permeability characteristics of high liquid limit soil,the initial adsorbed bound water content of the high liquid limit soil specimens from Hunan and Hainan was controlled by different concentrations of sodium chloride solution,and thermogravimetric analysis method was used to determine the content.The direct shear test,unconfined compressive strength test,and permeability test were carried out.The results show that the adsorbed bound water content decreases with the increase in salt solution concentration,while the strong bound water content is basically unchanged.The adsorbed bound water has a high viscosity,low activity,and certain solid-like …

Analysis Of Asphalt Pavement Structure Based On Master Curve Parameters Of Dynamic Modulus Of Asphalt Mixture, Liu Zhaohui, Yang Xin, Huang You, Liu Li

Journal of China & Foreign Highway

In order to study the effect of the change in the master curve parameters of the dynamic modulus of asphalt mixture and the interaction on the structural response of asphalt pavement,a three-dimensional model of the asphalt pavement structure was established using the finite element method,and the structural calculations of asphalt pavement with semi-rigid base and flexible base were carried out.The master curve parameters of the dynamic modulus δ,α,β,and γ were taken as the influencing factors,and the maximum tensile strain at the bottom of the asphalt layer and the vertical compressive strain at the top of the subgrade were set as …

Mechanism Of Water‑Damaged Landslides Of Embankments And Comparison Of Reinforcement Measures, Hu Minghua, Zhang Baiyong, Xu Kui

Journal of China & Foreign Highway

Water damage to embankments serious ly affects the normal operation of highways,so it is extremely important to ensure the stability of the embankment.In addition,it is necessary to analyze the mechanism and study the safety control measures for water-damaged landslides of the embankment.A highway subgrade embankment was studied,and the causes and formation mechanism of the landslide were qualitatively analyzed based on the on-site deformation monitoring and stability calculation.Then,the stability coefficients of different reinforcement schemes were calculated.An appropriate reinforcement scheme was recommended by considering the project cost,construction technology,and construction period.The results indicate that uneven settlement of the embankment stratum is the fundamental …

Effect Of Cellulose Fiber On Humidity Control And Properties Of Cement Mortar, Liang Jinguo, Ma Baofu

Journal of China & Foreign Highway

To explore the effect of flax cell ulose fiber on the humidity and basic properties of cement mortar,this paper adopted flax cellulose fibers with different lengths (0.5 and 5 mm ) and mixing amounts (mass fraction of 0.5%,1%,1.5%,and 2% of cement ).Tests were conducted on rheological properties,mechanical properties,autogenous shrinkage properties,and internal relative humidity development of cement mortar.Setting time,compressive strength,shrinkage rate,and relative humidity were used to evaluate the performance improvement effect of cellulose fiber on cement mortar.The results show that the absorbance rate of flax fiber per unit mass of 0.5 mm is 3.45 times its weight,while the absorbance rate of …

Micro Mechanical Analysis And Experiment On Fatigue Damage Of Rubber Powder Asphalt Mixture Of Expressway, Li Nanpeng, Wang Guoqing, Wang Zhibin, Zhang Xia3, Si Chundi

Journal of China & Foreign Highway

To explore the fatigue damage mechanism and micro-mechanical behavior of the pavement of rubber powder asphalt mixture (ARHM- 20) of expressway influenced by heavy vehicles,a three-dimensional microstructural model of the mixture was built based on the discrete element method,and research on the damage mechanism from aggregate motion to macroscopic permanent deformation were conducted.The Burger's constitutive model was used to characterize the viscoelastic properties of asphalt mortar.The macro mechanical parameters of Burger ’s model at different temperatures were obtained through asphalt creep tests,and the micro modeling parameters were obtained based on the macro and micro conversion formulas.The irregular coarse aggregate was …

Meso-Mechanical Properties Of Bearing Ratio Of Waste Lime‑Fly Ash Macadam And Soil Mixture Based On Discrete Element, Zhang Xiaofei, Chen Yuru, Zhang Song, Gao Lei, Tian Angran, Tang Qiang

Journal of China & Foreign Highway

In the process of applying construction waste to subgrade,the bearing capacity of the material has an important impact on the service performance of roads.In order to evaluate the meso-mechanical properties of construction waste used as subgrade filler,the bearing ratio test of waste lime-fly ash macadam and soil mixture with different stone contents was carried out by using discrete element software.The strength formation mechanism was revealed by using the discrete element method.The results show that the bearing ratio of the mixture increases with the increase in the stone content and reaches the maximum value when the stone content is 80%.In the …

Effect Of Hydrothermal Coupling Aging On Performance Of Rubber Modified Asphalt, Chen Zhenwei, Wu Xuewen, Xiao Xuan, Li Ping, Liu Shende

Journal of China & Foreign Highway

To study the effect of hydrothermal coupling aging on the performance of rubber modified asphalt,this article simulated thermal aging and hydrothermal coupling aging tests and investigated the effect of different aging environments on the high-temperature and low-temperature performance of asphalt from macroscopic and microscopic levels through conventional index tests,dynamic shear rheology tests,and gel chromatography tests,as well as the effect of different aging environments on the interfacial properties through low-temperature adhesion tests of asphalt and aggregates.The results show that the effects of hydrothermal coupling aging on the ductility and softening point of rubber modified asphalt are more significant than those of …

Fatigue Performance Of Qingchuan Rock Modified Asphalt Mixture Under Accelerated Loading Test, Li Zhi, Hao Yan, Yuan Xiaoman, Zhuang Chuanyi

Journal of China & Foreign Highway

To evaluate the fatigue performance of Qingchuan rock modified asphalt mixture,a dynamic wheel-load three-point bending loading fatigue test device based on an accelerated loading test system of 1∶3 scale pavement was designed.The three-point bending repeated loading fatigue test of a composite rutting specimen of double-layer asphalt mixture under tire rolling was carried out.Through the MTS bending fatigue test of a small beam specimen of asphalt mixture,the improvement effects of Qingchuan rock modified asphalt and composite modified asphalt on the fatigue performance of the asphalt mixture were evaluated.The results show that Qingchuan rock modified asphalt can improve the ability of asphalt …

Review On Lcca And Lca Methods For Pavement Based On Bim, You Shengjie, Hu Yonggang, Liu Xinsuo, Zheng Xiaoyan

Journal of China & Foreign Highway

Currently,life cycle cost analysis (LCCA ) and life cycle assessment (LCA ) methods are commonly used to assess the economic and environmental impacts of pavement during the whole life cycle.However,there are drawbacks in the application of LCCA and LCA methods,such as a large amount of data and multiple data categories,which lead to a tedious evaluation process.In view of this,some scholars have tried to combine building information modeling (BIM ) with LCCA and LCA methods to optimize the evaluation process.In the pavement field,the combination of LCCA and LCA with BIM is still in its infancy,lacking a summary of relevant research results.Therefore,this …

Anti‑Freezing Performance Of Cement-Stabilized Mixture For Recycled Aggregate From Solid Construction Waste, Zheng Jiajia, Zhang Laijun, Wang Xihui, Xie Jianwei, Chen Zhiyong

Journal of China & Foreign Highway

This paper investigated the effects of particle size and content of recycled aggregate on the anti-freezing performance of cement-stabilized recycled aggregate mixture,so as to provide a reference for the fine utilization of recycled aggregate with different particle sizes.The basic performance indexes of recycled aggregates with different particle sizes were tested,and the optimum moisture content and maximum dry density were determined by compaction test.The specimens were prepared with 4% cement content,and the anti-freezing performance of the mixture was evaluated by testing the unconfined compressive strength loss of the mixture after the freeze-thaw cycle.The results show that the optimum moisture content increases,and …

Analytical Method For Deformation And Internal Force Of Suspension Bridge Under Concentrated Live Load, Zhao Haixia, Wang Tao

Journal of China & Foreign Highway

As a flexible structure,the response of suspension bridges under live load has been the focus of research for a long time.This paper presented an analytical calculation method for structural deformation and internal force of suspension bridges under concentrated live load.Based on the known bridge state parameters and live load parameters,the deformation of the main cable,the deformation of the main beam,the relationship between the main cable and the main beam,and the deformation of the bridge tower were analyzed successively.Then,four kinds of governing equations were established,involving the conserved unstrained length of each main cable,the coordinated force and deformation of each suspender,the closed …

Influence Of Crosswind On Traffic Operation Safety Of Long‑Span Bridges, Shen Quanjun, Wang Zijian, Xing Xiaoliang, Zhang Yu, Gao Lixiao, Chen Liang

Journal of China & Foreign Highway

Crosswind has a great influen ce on the operation safety of vehicles on long-span bridges.To explore the relationship between the characteristic parameters of the crosswind and the traffic operation safety of the long-span bridge,the Yellow River Bridge with frequent crosswinds was taken as the experimental section,and the relationship between traffic accidents and the distribution of crosswinds on the bridge was analyzed.A fitting relationship model of traffic operation coordination of the long-span bridge under the action of the crosswind was established.The study shows that the occurrence of crosswinds in each season is highly discrete.The crosswind is the main cause of vehicle …

Experimental Study On Road Performance Of Resin Elastomer For Seamless Expansion Joints Of Bridges, Zhou Wei, Sheng Liang, Gao Qin, Zhang Hui, Zhao Menglong

Journal of China & Foreign Highway

Seamless expansion joint is a new type of bridge expansion joint.In order to study the road performance of resin elastomer for seamless expansion joints,the feasibility of applying resin elastomer to small and medium displacement expansion joints of bridges was explored.Through the rutting test at 60 ℃, low-temperature beam bending test at −10 ℃,dynamic modulus test,Poisson's ratio test,and overlay test (OT),the high and low temperature stability,deformation performance,and fatigue crack resistance of the resin elastomer were compared.The test results show that the dynamic stability of the resin elastomer at 60 ℃ is more than 31 000 times/mm,and the bending strain at low …

Experimental Study On Adhesive Pe Rformance Of Second-Order Thermosetting Epoxy Asphalt In Bridge Deck Pavement, Zhou Changdong, Dai Mingjing, Zhao Mingyu, Li Zhiqiang, Lei Yuxiang, Ding Qingjun

Journal of China & Foreign Highway

Based on the Wujiagang Yangtze River bridge project in Yichang,the interfacial shear strength and pull-out strength of the second-order thermosetting epoxy asphalt material between RA asphalt concrete and high viscoelastic SMA asphalt concrete in pavement structure were studied under different spraying amount,different first-stage curing time,different curing time,and different service temperatures.In addition,the influence of spraying amount on shear fatigue resistance was studied.The results show that with the increase in the spraying amount of the second-order thermosetting epoxy asphalt,the adhesive performance and shear strength are improved,and the shear fatigue resistance of the structure is enhanced.At a construction ambient temperature of 25‒35 ℃,the …

Design And Key Technologies Of Bridges With Long‑Cantilever Closed Steel Box Composite Girder, Ji Jiandong, Wang Bin

Journal of China & Foreign Highway

In order to meet the span requirements of bridges over the Yellow River and reduce the interference of temporary construction facilities on flood discharge from the Yellow River,the Linyi Yellow River Bridge was studied.The main bridge adopted a continuous long-cantilever closed steel box composite girder of (112 + 28 × 128 + 120) m and was divided into two parts,with the maximum length of the parts being 1 912 m.The steel box composite girder was constructed by incremental launching method without temporary piers,and the bridge deck was installed after the closed steel box girder was in place.The installation sequence of …

Supporting Capacity Anal Ysis And Construction Scheme Optimization Of Support System For Cast‑In‑Situ Box Girders In High‑Pier Wading Bridges, Guo Tao, Yao Yuchen, Ma Hongze, Huang Xiaomin, Zhang Yongchun

Journal of China & Foreign Highway

Although a concrete bridge su pport system is a temporary structure,it still has a supporting capacity.With the development of bridge engineering,concrete bridges with high piers and long spans are gradually applied in deep reservoir areas,and the forces on scaffolding are more and more complex.Traditional manual calculations in structural mechanics can no longer completely reflect the stress-strain states of scaffolding with irregular configurations,special parts,and uncommon conditions.Thus,it is necessary to use a numerical method to calculate the supporting capacity of scaffolding and design construction schemes.This paper took a concrete wading bridge with high piers as an example.An evaluation method based on the …