Materials Science and Engineering Commons^™

Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

Struvite, the stable hydration product and primary strength phase in magnesium ammonium phosphate cement (MAPC), derived from wastewater treatment, has recently been utilized as a sustainable additive to Portland cement (PC). However, its impacts on cement hydration kinetics, pore refinement, rheology, and the mechanisms underlying these processes have not been comprehensively studied. This study developed Portland cement-struvite (PCS) systems by replacing PC with 3–20 % struvite (ST wt.%: PCS3–PCS20) and evaluated these processes using isothermal calorimetry, 3D micro-computed tomography (μXCT), time-dependent rheometry, X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR), and the Krstulović-Dabić (K-D) model. The FTIR/XRD confirmed the coexistence …

Fly Ash Proppant Developed For Hydraulic Fracturing, Raz Rzgar Haydar

Theses and Dissertations

Proppants are critical components in hydraulic fracturing, used to maintain fracture conductivity and enhance reservoir stimulation. In high-pressure and harsh reservoir environments, the use of high-strength proppants is essential to ensure well performance. Conventional proppants, being sand, ceramic, and sintered bauxite can be expensive, and their use often requires costly fracture fluids. This study investigates the possibility of utalizing fly ash geopolymers as a sustainable alternative that is also cost-effective for proppants manufacturing. Fly ash, a by-product from the combustion of coal and other materials, was explored as a base material for proppants, utilizing an alkaline solution as an activator …

Data Set, R Scripts And Script Outputs For Manuscript: Manufacturing Systems: Characteristics And Dynamics, Alan J. Fitzmorris

Graduate Research Data

This file repository contains fifteen computer-generated datasets, two naturally occurring datasets, nineteen shipbuilding shop datasets, and sixty-one concrete plant datasets.  Each data set contains subdirectories associated with various aspects of the data analysis, including stationarity analysis, dynamic system analysis, and complexity analysis.  In each case, applicable R scripts are included.  The text file entitled “Directory_and_File_Names” depicts the directory structure and associated file names for a total of 225 directories encompassing 8008 files.

Direct Ink Writing Of Shear Exfoliated Two-Dimensional Nanomaterial- Elastomeric Multifunctional Nanocomposite, Md Abdur Rahman Bin Abdus Salam, Asif Hasan Ridoy, A K M Abirul Haque, Muhammad Shahbaz Rafique, Md Arafat Hossain, Md Shahriar Forhad, Matthew G. Boebinger, Farid Ahmed, Karen Lozano, Ali Ashraf

Manufacturing & Industrial Engineering Faculty Publications

Direct ink writing (DIW) of polymer nanocomposites with high loadings of two-dimensional (2D) nanofillers (graphene and hexagonal boron nitride (hBN)) is challenging because of potential clogging, use of hazardous solvents, and agglomeration. Here, in this work, a shear exfoliation and sieving method to prepare DIW ink with high loading of nanofillers produced from low-cost bulk layered materials such as graphite and bulk hBN powder for successful DIW printing without the use of any solvents, binders, or plasticizers. The single-step exfoliation technique resulted in a composite with substantial layer reduction along the c-axis, as confirmed by SEM, TEM, XRD, and Raman …

The Effects Of Mold Flux Contamination On Oxide Scale Formation And Hydro-Descaling Efficiency During Steel Processing, Tochukwu Princewill Ojiako, Richard Osei, Mario Buchely, Haiming Wen, Simon Lekakh, Ronald O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Oxide scale formation during thin-slab continuous casting has a complex structure, which is influenced by mold flux contamination, that modifies interfacial reactions during solidification, subsequent reheating, and descaling. While individual aspects of the oxidation behavior of carbon steel have been previously examined, the synergetic effects of mold flux contamination during continuous casting and subsequent reheating on scale modification and the efficiency of hydraulic descaling remain inadequately studied. This study quantitatively examines the effect of flux composition on oxide scale evolution, adhesion, and hydraulic removal in low-carbon steel under simulated industrial conditions. Slab samples with as-cast, cleaned, and flux-coated surfaces were …

Thermal Transformations And Mechanical Properties Of All-D-Metal Mn2fecu Heusler-Type Shape Memory Alloy, Choji J. Daches, Joseph W. Newkirk, Mario Buchely

Materials Science and Engineering Faculty Research & Creative Works

All-d-metal Heusler alloys are emerging functional materials in which magnetic ordering, lattice distortion, and mechanical behavior are strongly coupled through d–d electronic interactions. This study systematically investigates the structural, thermal, magnetic, and mechanical properties of Mn₂FeCu synthesized within a Heusler-type compositional framework. SEM/EDS revealed a dual-phase FCC-based microstructure consisting of Mn–Fe–rich and Mn–Cu–rich domains, while XRD confirmed FCC symmetry with compositional partitioning rather than full L2₁ ordering. Differential scanning calorimetry identified partial melting of the Cu-rich phase near ~ 900 °C. Dilatometry showed a thermoelastic FCC → FCT transformation at ~ 770–780 °C with a recoverable strain of ~ 0.067%. …

Co-Sputtered Cuni Heteroatomic Electrocatalyst For Enhanced 5-Hydroxymethylfurfural Selective Electrochemical Conversion, Moumita Dikshit, Baleeswaraiah Muchharla, Luz Vazquez Rivera, Kapil Kumar, Sunita Sanwaria, Kishor Kumar Sadasivuni, Abdennaceur Karoui, Sandeep Kumar, Adetayo Adedeji, Bijandra Kumar

Civil & Environmental Engineering Faculty Publications

The electrochemical conversion of biomass-derived 5-hydroxymethylfurfural (HMF) represents a promising, economically viable, and environmentally sustainable approach for producing value-added chemicals using renewable energy and in situ hydrogen generated through water electrolysis. However, the electrochemical hydrogenation (ECH) of HMF remains challenging due to the inherently low catalytic activity and selectivity of the electrodes, compounded by competition with the kinetically favored hydrogen evolution reaction (HER) in aqueous electrolytes. In this work, we demonstrate that Cu_xNi_100-x heteroatomic thin films, fabricated via direct current (DC) magnetron co-sputtering, achieve a more than one order of magnitude increase in the HMF to 2,5-Bis-hydroxymethylfuran …

Buckling Analysis Of Auxetic Composite Laminates And Optimal Design Using Lamination Parameters And Machine Learning, Hans Bendon Maria Tamil Selvan

Mechanical and Aerospace Engineering Theses

Composite materials are widely used as structural panels in aerospace, automotive, and civil engineering applications, where buckling is often a critical failure mode. This thesis focuses on the analysis and design of composite laminates that maximize buckling performance under prescribed stiffness and thickness constraints.

The first part of the study investigates the buckling behavior of auxetic laminates, which exhibit a negative Poisson's ratio. While previous studies suggest that auxetic laminates can achieve higher critical buckling loads than non-auxetic laminates under simply supported boundary conditions with lateral restraint, the influence of other boundary conditions and plate aspect ratios has not been …

Critical Parameters Controlling Oxide Scale Formation And Hydro-Descaling Efficiency During Steelmaking, Tochukwu Princewill Ojiako

Doctoral Dissertations

In modern steelmaking, cast slabs are exposed to high-temperature oxidizing environments during secondary cooling, reheating, and hot rolling, resulting in the formation of multilayer oxide scales on the steel surface. These scales interact with mold-flux residues originating from the casting process (CC). The morphology, chemistry, and adhesion of oxide scale strongly influence its removability during high-pressure hydraulic descaling and ultimately determine the surface quality of hot-rolled products. However, the mechanistic relationship between oxide scale evolution, scale-steel interfacial structure, and hydraulic descaling performance remains poorly understood.

This dissertation investigates oxide scale formation, modification, and removal in low-carbon thin-slab steels produced by …

Effect Of Local Steel Slag Incorporation On The Mechanical Properties Of Concrete, Ahmed Safaa Tariq Karmah, Wissam Khadum Alsaraj, Luma A. Zghair

Al-Esraa University College Journal for Engineering Sciences

The increasing interest in the production of concrete through the utilization of inexpensive materials has caused a rise in the number of studies concerning the use of materials with cementitious properties, such as Silica Fume, Slag, Fly Ash and other pozzolanic materials. Moreover, the increasing amounts of Steel Slag being produced from local factories that are being deposited without an available method of disposal provides an opportunity to harness the Slag in the production of an inexpensive, and possibly better concrete. Slag has been used as both an addition and substitution of the cement and fine aggregate. The mixtures included …

Decoding Climate Change: A Comprehensive Statistical Insight Into Temperature Anomalies In Iraq And Its Neighboring Countries, Jameel T. Al-Naffakha, Mohammed R. Al-Qassabanda, Israa Jafar

Al-Esraa University College Journal for Engineering Sciences

This study applies advanced statistical techniques, including the Mann-Kendall Trend Test and ARIMA forecasting, to validate and predict temperature anomalies across Iraq and its neighboring countries (2014–2024). Findings confirm a statistically significant warming trend (p < 0.00000005) across all nations, with Syria (1.02°C) and Turkey (0.97°C) experiencing the highest anomalies. GIS-based spatial analysis highlights regional disparities, identifying climate-vulnerable zones. The persistent rise in temperature anomalies correlates with worsening water scarcity, desertification, and extreme weather events, including prolonged droughts and heatwaves. Iraq’s peak anomaly (1.48°C) has exacerbated heat stress, agricultural decline, and reduced river inflows, while Kuwait and Saudi Arabia struggle to maintain critical infrastructure under record-breaking temperatures exceeding 50°C. These climate shifts pose severe risks to water availability, food security, and energy demand, necessitating urgent policy interventions. Key recommendations include enhanced water resource management, climate-adaptive agriculture, and renewable energy expansion. If left unaddressed, rising temperatures could destabilize the region, increasing socio-economic vulnerabilities and escalating resource conflicts. This study underscores the need for cross-border collaboration and sustainable adaptation policies to mitigate the long-term impacts of climate change in the Middle East.

Optimal Power Flow Control In The Iraqi Power Grid Using Artificial Intelligence Algorithms For Carbon Emission Reduction, Mohammed Shakir Juber

Al-Esraa University College Journal for Engineering Sciences

Iraq’s power sector remains in a protracted and severe crisis characterized by a significant mismatch between supply and demand, high levels of losses during transmission and distribution, as well as an increasing challenge to the resources base being largely unfavourably. These inefficiencies impose heavy costs on the national economy in excess of 40 billion annually and they also reinforce greenhouse gas emissions, and exacerbate environmental issues. To deal with these problems, we proposed in this paper that a new hybrid AI tool should be developed for the solution of multi-objective optimization problem based on purpose Genetic Algorithm (GA) merger with …

Applying Machine Learning Techniques For Early Detection Of Cyber Attacks On Iot Devices, Noor Adnan Allamy

Al-Esraa University College Journal for Engineering Sciences

This research designs, implements, and evaluates a machine learning-based framework for the early detection of cyber attacks targeting Internet of Things (IoT) devices, with a specific focus on the context and challenges present in Iraq. The study conducts a comparative analysis of three supervised learning algorithms—Support Vector Machine (SVM), Random Forest (RF), and Deep Neural Networks (DNN)—using a combination of benchmark datasets (NSL-KDD, CIC-IDS-2017, Bot-IoT) and a synthesized dataset adapted to simulate the Iraqi threat landscape. Key performance metrics, including accuracy, precision, recall, and F1-score, were used for evaluation. The proposed Random Forest model demonstrated superior performance, achieving an accuracy …

Ai-Enhanced Heat Transfer Optimization In Magnetic Bio-Nanofluids, Hasan Attyah Shaboot

Al-Esraa University College Journal for Engineering Sciences

This study presents a hybrid Artificial Intelligence–Computational Fluid Dynamics (AI-CFD) framework for optimizing heat transfer in magnetic bio-nanofluids subjected to external magnetic fields. Magnetic bio-nanofluids, composed of biocompatible base fluids containing superparamagnetic nanoparticles, exhibit tunable thermal and flow behavior, making them promising for biomedical and micro-cooling applications. Conventional optimization methods based on experiments or brute-force CFD are computationally expensive and limited in exploring the full design space. To overcome these challenges, an Artificial Neural Network (ANN) surrogate model was developed to predict two key performance indicators, the Nusselt number and the friction factor, with high accuracy (R² > 0.997). The surrogate …

Hybrid Experimental–Computational Study On The Energy Absorption Of Graphene Nanoplatelet-Reinforced Sandwich Structures, Hamdan Yousif Hamdan

Al-Esraa University College Journal for Engineering Sciences

Background: Sandwich composites are widely used in aerospace, automotive, and marine applications because of their lightweight, stiffness, and strength, but they remain prone to out-of-plane impacts and barely visible impact damage (BVID). Graphene Nanoplatelets (GNPs) have shown strong potential to improve fracture toughness and impact resistance. However, hybrid experimental–computational studies applying such reinforcement are still lacking in developing contexts like Iraq, where practical and accessible solutions are essential. Aims: The study investigates the effect of GNP reinforcement on the low-velocity impact behavior and energy absorption of glass fiber/epoxy sandwich panels with PVC foam and balsa wood cores. Objectives include fabricating …

Effect Of Thick Closed Walls Of West And South Elevations Of Iraqi Middle And South Territory Housing Building On Reducing Energy Use, Abeer Qasim Jbur, Shaimaa M. Hamza, Mayyadah Lutfi Abdulwahhab

Al-Esraa University College Journal for Engineering Sciences

Thermal insulation is one of the most important factors in achieving sustainability, increasing efficiency, and reducing energy consumption, but modern insulation materials are expensive, in addition to their availability. Therefore, through our research, we resorted to investigating the issue of reducing thermal load in buildings through the use of thick-walled facades in the southern and western facades, where we studied a building with two windows with windows on the southern and western facades and another without these windows and with thick walls, for two locations, the first in central Iraq, which is the city of Baghdad, and the second in …

The Impact Of Ethyl Levulinate Additive On Diesel Engine Performance And Emissions: An Experimental Study, Maha Ali Ghadbaan

Al-Esraa University College Journal for Engineering Sciences

This study explores the environmental and operational impact of adding Ethyl Levulinate—a biodegradable ester derived from biomass—to diesel fuel. A fuel blend known as B5El6 (comprising 5% biodiesel and 6% Ethyl Levulinate) was prepared and tested experimentally using a single-cylinder diesel engine operating at a constant speed of 1500 rpm under full load conditions. Performance metrics and emission data were recorded, and a Life Cycle Assessment (LCA) was conducted using the IMPACT2002+ methodology.

The results revealed that B5El6 significantly reduced greenhouse gas emissions (100 kg CO2 eq) and improved ecosystem quality. However, it presented challenges in terms of human health …

The Role Of The Scenario In Formulating The Contemporary Architectural Text, Rounaq Arif Mohsin, Abbas Ali Hamza, Bashar Shamil Alkhafaji

Al-Esraa University College Journal for Engineering Sciences

In order to create an integrated architectural text, which is a complicated art that blends beauty and practical elements, a rigorous design procedure is necessary. In this situation, the scenario’s role becomes crucial in developing the current architectural text and directing architectural approaches. In order to better understand how the scenario influences the design process and the interactions between various architectural aspects, this project intends to explore and analyze the impact of the scenario in developing and refining architectural text formulation approaches.

The study looks at the idea of a scenario and how it has been used in architecture, as …

Investigation Of Some Physical Properties Of Slurry Infiltrated Fibrous Concrete (Sifcon) Under Different Curing Times, Rand Kh. Mahmoud, Mohmmed Juad Khadhim, Fayq Hasan Jabbar

Al-Esraa University College Journal for Engineering Sciences

This research studied the effects of different types fibers (Basalt, Carbon and Basalt-Carbon hybrid mix) and curing ages (7, 14, 28 and 56 days) on some physical properties of - Slurry infiltrated fibrous concrete (SIFCON). Density, ultrasonic pulse velocity UPV, Poisson’s ratio and water absorption were measured for the experimental study with 30% cement replacement by Class F fly ash to increase sustainability. It was found that properties were significantly affected by the type and dosage of fiber admixture. The UPV was enhanced by basalt fibers and the absorption reduced up to an optimal range of 3–5% after which agglomeration …

Mechanical And Durability Properties Of Cement Panels Reinforced With Hybrid And Pva Fibers, Shukran H. Faraj, Mohammed J. Kadhim

Al-Esraa University College Journal for Engineering Sciences

This study examines the synergistic effects of hybrid fibers (HF) and polyvinyl alcohol (PVA) fibers on the structural and thermal properties of silica-fume cement panels. Scanning electron microscopy (SEM) was employed to examine mortar mixtures with varying fiber content to assess their enhancement of microstructure. We conducted several experiments on compressive, flexural, and splitting tensile strength, in addition to water absorption and thermal conductivity. The results indicate that 1% HF exhibits superior mechanical qualities, with a compressive strength of 46.89 MPa, a flexural strength of 8.56 MPa, and a reduced thermal conductivity of 0.83 W/m•K. PVA fibers at 2% enhance …

Experimental Analysis Of Droplet Deformation Dynamics In Combined Dc Electric And Shear Flow Fields Using Dpiv, Ayad Ibrahim Khlewee

Al-Esraa University College Journal for Engineering Sciences

This paper presented a systematic study of such droplet deformation at the intersection of uniform DC electric field and hydrodynamic shear flow, in which we focused on conductivity ratio (R) and permittivity ratio (S), describing their influence. The results demonstrate that droplet dynamics is extremely sensitive to the regime: under DC only, either elongation or compression depending on whether R > S or R S, similarly to classical EHD predictions. Under shear-only conditions, deformation was dictated by the balance of elongational stresses (EC) and rotational stresses (RC), with increasing capillary number (Ca) leading to progressive elongation and oscillatory orientation dynamics. When …

The Imaginary In Architecture: The Conceptual Structure Of The Imaginary And Its Manifestations In Architectural Text, Noora Ghadir Hlail, Abbas Ali Hamza Al Greiza

Al-Esraa University College Journal for Engineering Sciences

This study explores the concept of the imaginary as a collective cognitive and cultural structure that shapes symbolic reality through images, myths, and deeply rooted symbols in collective memory. The research applies this concept within the field of architecture, aiming to understand how the imaginary is embodied in architectural texts as symbolic carriers of identity and cultural meaning. Adopting a descriptive-analytical methodology, the study develops a theoretical framework comprising key components—preconditions, mechanisms, and traits of the imaginary—and applies it to two selected case studies: the General Secretariat of the Iraqi Council of Ministers and the Louvre Abu Dhabi Museum. The …

Generative Ai For Method Development In Analytical Chemistry: A New Paradigm In Experimental Design And Optimization, Yasir Fathi Mahmood

Al-Esraa University College Journal for Engineering Sciences

The fast development of artificial intelligence (AI), especially generative AI models, is changing the environment of analytical chemistry. As classical method generation in analytical methods relies on manual trial-and-error methodology as well as statistical methods, generative AI is a new paradigm with automated generation of experimental methodology and optimization. In this paper, the authors discuss the use of generative AI-based technologies, including large language models (LLMs) and neural network-based generators, to create new, efficient, and customized methods of analysis. The paper examines existing applications, technology frameworks, and issues and offers a roadmap with regards to the future incorporation of generative …

Numerical Modeling And Experimental Validation Of A High-Temperature Latent Heat Thermal Energy Storage System Using Metallic Phase Change Materials For Concentrated Solar Power Applications, Fouad Hashim Sharhan

Al-Esraa University College Journal for Engineering Sciences

To ensure reliable performance for the power-block of CSP plants, high power density and near-isothermal discharge must be achieved. A robust means of achieving this is through thermal energy storage (TES). High temperature latent heat storage (LHS) with phase change materials (PCMs) can serve these purposes, however the conventional salts used in PCMs typically suffer from low thermal conductivity that limits power density and increases energy storage charging/discharging times. This manuscript investigates ways to address these limitations using high temperature metallic phase change materials (MPCMs) while also developing a validated numerical framework to aid in their design. To this end, …

Thermal Performance Evaluation Of Solar Cooling Systems For Educational Facilities In Baghdad, Yasser Alawi Mohammed Attia Al-Jubouri

Al-Esraa University College Journal for Engineering Sciences

Schools in Baghdad also suffer from poor thermal comfort, which is a common problem in high-temperature and low-humidity arid climates such as that of the city, where using cooling devices leads to a large energy demand and overloads on the national power grid. Such study offers a thorough assessment of the thermal performance of solar-based cooling systems in an efficient manner to be suitable for educational buildings in Baghdad. The analysis is centred on a solar thermal cooling system with absorption as the heat interaction medium, and an experimental characterisation and mathematical simulation itself are performed. A pilot installation, consisting …

Curing Duration Optimization To Reduce Shrinkage Cracking In One-Part Alkali-Activated Slag Concrete, A. Sadrmomtazi, H. Zanganeh

Journal of Sustainable Construction Materials and Technologies

The consequences of inadequate curing on one-part alkali-activated slag concrete (O-AAS) performance relative to ordinary Portland cement concrete (OPCC) have been investigated in this research. Prior to exposure to unsaturated conditions, samples underwent initial moist curing for durations ranging from 24 hours to one year. The testing program included compressive strength evaluation, chloride ion transport analysis, and measurement of free and restrained shrinkage. In addition, cylindrical cores were extracted from concrete columns to assess internal strength and chloride penetration resistance. Under unsaturated exposure, O-AAS exhibited a strength-aging phenomenon, with up to a 37% decrease in compressive strength over 360 days, …

Laboratory Investigation And Numerical Modelling Effect Of Carbon Nanotubes On Hot Mix Asphalt Permanent Displacement, Sepehr Saedi, Auwal Usman Nadada

Journal of Sustainable Construction Materials and Technologies

One of the primary causes of asphalt pavement deterioration is rutting; in contrast, one of the most effective methods to address this type of damage is the use of additives and quality evaluation during the design stages. In this research, laboratory testing and modeling using Abaqus software were employed to validate the laboratory results and predict and assess the potential for rutting. Carbon nanotubes (CNTs) were selected as an additive due to their exceptional mechanical properties and molecular interactions with bitumen. These nanotubes were used to modify the bitumen for the preparation of laboratory samples. The laboratory results from the …

Influence Of Early Microwave Curing On Performance Of Slag-Based Geopolymer Mortars, Ahmet Taşdemı̇R, Abdulkadir Çevı̇K

Journal of Sustainable Construction Materials and Technologies

In this article, an experimental study was conducted to examine the effect of curing time and microwave power on the compressive strength of early microwave-cured slag based geopolymers. Geopolymers have the potential to serve as an environmentally friendly substitute for cement-based building materials, and the use of microwave curing to geopolymers holds the promise of substantial strength improvement. Different microwave curing energies (300 - 800 Watts) were utilized at varying durations (10 - 60 minutes) on demoulded mortar specimens after one day. After that, compressive strength tests were conducted on both the cured and uncured specimens at three different ages: …

Compression Forming Of Basic Oxygen Furnace Slag-Gypsum Blocks: Performance Enhancement And Environmental Assessment, Fengyi Zhang

Student Works (2020-2029)

The construction industry plays a crucial role in global development but faces significant environmental challenges, particularly CO2 emissions from cement production. Gypsum blocks provide a sustainable alternative to traditional cement concrete blocks. However, the low mechanical strength and water resistance of gypsum materials limit the widespread adoption of gypsum-based materials in the construction industry. This study initially produced gypsum-based blocks using compression forming, adding supplementary cementitious materials (SCMs), and subjecting accelerated carbonation curing (ACC). It was found that compression forming addressed the shortcomings of traditional block manufacturing (high energy consumption and long production time), and the addition of SCMs generated …

Shaking Table Test And Numerical Simulation Of Seismic Response Characteristics Of Rock Slope With Muddy Interlayer, Duan Chenggang, Fang Yanlin, Tian Yeqing, Zhou Zhijun

Journal of China & Foreign Highway

In order to study the seismic macroscopic failure process and dynamic response characteristics of rock slope with muddy interlayer and reveal the influence of muddy interlayer on slope stability,a similar slope model with concave and convex slope types was designed,and shaking table test was carried out;finite element analysis was used for numerical modeling analysis,and the results obtained by the two models were compared.The results show that:① The macroscopic deformation and failure process of the model slope is divided into three stages.Muddy interlayer dislocates,and cracks occur;mud interlayer slips,and cracks expand;slope collapses;② The seismic load has a decisive influence on the stability …