Other Engineering Science and Materials Commons^™

Method For Single Crystal Growth Of Photovoltaic Perovskite Material And Devices, Jinsong Huang, Qingfeng Dong

Department of Mechanical and Materials Engineering: Faculty Publications

Systems and methods for perovskite single crystal growth include using a low temperature solution process that employs a temperature gradient in a perovskite solution in a container , also including at least one small perovskite single crystal , and a substrate in the solution upon which substrate a perovskite crystal nucleates and grows , in part due to the temperature gradient in the solution and in part due to a temperature gradient in the substrate . For example , a top portion of the substrate external to the solution may be cooled .

Oct-Based Three Dimensional Modeling Of Stent Deployment, Pengfei Dong, David Prabhu, David L. Wilson, Hiram G. Bezerra, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Stent deployment has been widely used to treat narrowed coronary artery. Its acute outcome in terms of stent under expansion and malapposition depends on the extent and shape of calcifications. However, no clear understanding as to how to quantify or categorize the impact of calcification. We have conducted ex vivo stenting characterized by the optical coherence tomography (OCT). The goal of this work is to capture the ex vivo stent deployment and quantify the effect of calcium morphology on the stenting. A three dimensional model of calcified plaque was reconstructed from ex vivo OCT images. The crimping, balloon expansion and …

Floating-Gate Transistor Photodetector, Jinsong Huang, Yongbo Yuan

Department of Mechanical and Materials Engineering: Faculty Publications

A field effect transistor photodetector that can operate in room temperature includes a source electrode , a drain electrode , a channel to allow an electric current to flow between the drain and source electrodes , and a gate electrode to receive a bias voltage for controlling the current in the channel . The photodetector includes a light - absorbing mate rial that absorbs light and traps electric charges . The light absorbing material is configured to generate one or more charges upon absorbing light having a wavelength within a specified range and to hold the one or more charges …

3d Printing Of 316l Stainless Steel And Its Effect On Microstructure And Mechanical Properties, Rawn Penn

Graduate Theses & Non-Theses

Laser powder bed fusion or 3D printing is a potential candidate for net shape forming and manufacturing complex shapes. Understanding of how various parameters affect build quality is necessary. Specimens were made from 316L stainless steel at 0°, 30°, 60°, and 90° angles measured from the build plate. Three tensile and four fatigue specimens at each angle were produced. Fracture morphology investigation was performed to determine the fracture mode of specimens at each build angle. Microstructural analysis was performed on one of each orientation. The average grain size of the samples was marginally influenced by the build angle orientation. Tensile …

Software For Extracting Deformation Gradient And Stress From Md Simulations: Simulations Using The Charmm Force Field, Mehrdad Negahban, Lili Zhang, Zesheng Zhang, John Jasa, Antoine Jérusalem

Department of Mechanical and Materials Engineering: Faculty Publications

Software was developed, and is provided under a general use license, to calculate continuum level deformation gradient and stress for any group of atoms in an MD simulation that uses the Charmm force fields. This software can also calculate the interaction stress applied by one group of atoms on any other group. To obtain deformation gradient and stress, the user needs to provide the selected group(s) of atoms in an atom group identification file, and provide the associated LAMMPS format files and force field parameter file. An example is included to demonstrate the use of the software.

Energy Absorbing Guardrail System, John R. Rohde, John D. Reid, King K. Mak, Dean L. Sicking

Department of Mechanical and Materials Engineering: Faculty Publications

A highway crash attenuation system having W - beam rail elements attached to a plurality of vertical posts . An impact terminal with a feeder chute guides one or more of the W - beam rail elements through the impact terminal . The feeder chute has an impact shield extending along a traffic facing side of the chute from an upstream - most end to a downstream - most end of the chute closing the traffic - facing side of the chute . The system also has an anchor cable release mechanism for releasing the cable downstream of the first …

Shape-Adaptive Mechanism For Robotic Grasping, Carl A. Nelson

Department of Mechanical and Materials Engineering: Faculty Publications

A grapser can include a first pantograph cell and a second pantograph cell coupled with the first pantogrpah cell. The first and second pantograph cells can be coupled together at a first pivot and a second pivot. The grasper can also include a finger extendable in a direction extending between the first pivot and the second pivot. The grasper can include a support base, where one or more links of the first pantograph cell can be slidably coupled with the support base for extending the grasper. In some embodiment, the grasper can be configured to extend along a curved path. …

Simulating Dynamic Failure Of Polymer-Bonded Explosives Under Periodic Excitation, Rachel Kohler, Camilo Duarte Cordon, Marisol Koslowski

The Summer Undergraduate Research Fellowship (SURF) Symposium

Accidental mishandling of explosive materials leads to thousands of injuries in the US every year. Understanding the mechanisms behind the detonation process is crucial to prevent such accidents. In polymer-bonded explosives (PBX), high-frequency mechanical excitation generates thermal energy and can lead to an increase in temperature and vapor pressure, and potentially the initiation of the detonation process. However, the mechanisms behind this energy release, such as the effects of dynamic fracture and friction, are not well understood. Experimental data is difficult to collect due to the different time scales of reactions and vibrations, so research is aided by running simulations …

Meniscus-Assisted Solution Printing Of Largegrained Perovskite Films For High-Efficiency Solar Cells, Ming He, Bo Li, Xun Cui, Beibei Jiang, Yanjie He, Yihuang Chen, Daniel O'Neil, Paul Szymanski, Mostafa A. El-Sayed, Jinsong Huang, Zhiqun Lin

Department of Mechanical and Materials Engineering: Faculty Publications

Control over morphology and crystallinity of metal halide perovskite films is of key importance to enable high-performance optoelectronics. However, this remains particularly challenging for solution-printed devices due to the complex crystallization kinetics of semiconductor materials within dynamic flow of inks. Here we report a simple yet effective meniscus-assisted solution printing (MASP) strategy to yield large-grained dense perovskite film with good crystallization and preferred orientation. Intriguingly, the outward convective flow triggered by fast solvent evaporation at the edge of the meniscus ink imparts the transport of perovskite solutes, thus facilitating the growth of micrometre-scale perovskite grains. The growth kinetics of perovskite …

Dissipative Elastic Metamaterial With A Lowfrequency Passband, Yongquan Liu, Jianlin Yi, Zheng Li, Xianyue Su, Wenlong Li, Mehrdad Negahban

Department of Mechanical and Materials Engineering: Faculty Publications

We design and experimentally demonstrate a dissipative elastic metamaterial structure that functions as a bandpass filter with a low-frequency passband. The mechanism of dissipation in this structure is well described by a mass-spring-damper model that reveals that the imaginary part of the wavenumber is non-zero, even in the passband of dissipative metamaterials. This indicates that transmittance in this range can be low. A prototype for this viscoelastic metamaterial model is fabricated by 3D printing techniques using soft and hard acrylics as constituent materials. The transmittance of the printed metamaterial is measured and shows good agreement with theoretical predictions, demonstrating its …

Multiple Scattering Theory For Heterogeneous Elastic Continua With Strong Property Fluctuation: Theoretical Fundamentals And Applications, Huijing He

Department of Mechanical and Materials Engineering: Faculty Publications

Scattering of elastic waves in heterogeneous media has become one of the most important problems in the field of wave propagation due to its broad applications in seismology, natural resource exploration, ultrasonic nondestructive evaluation and biomedical ultrasound. Nevertheless, it is one of the most challenging problems because of the complicated medium inhomogeneity and the complexity of the elastodynamic equations. A widely accepted model for the propagation and scattering of elastic waves, which properly incorporates the multiple scattering phenomenon and the statistical information of the inhomogeneities is still missing. In this work, the author developed a multiple scattering model for heterogeneous …

A Strategy To Optimize Recovery In Orthopedic Sports Injuries, Michael P. Sealy, Ziye Liu, Chao Li, Yuebin Guo, Ben White, Mark Barkey, Brian Jordon J, Luke N. Brewer, Dale Feldman

Department of Mechanical and Materials Engineering: Faculty Publications

An important goal for treatment of sports injuries is to have as short a recovery time as possible. The critical problem with current orthopedic implants is that they are designed to be permanent and have a high complication rate (15%) that often requires removal and replacement with a second surgery; and subsequently a second rehabilitation cycle. This study was designed to test the feasibility of having a device that could provide the needed mechanical properties, while promoting healing, for a specified amount of time and then degrade away, to shorten the recovery time. The specific strategy was to create a …

Bear Minimum: Ultralight Composite Bear Canister, Rama B. Adajian, Adam C. Eisenbarth

Mechanical Engineering

The ultralight backpacking community needs a strong, easy to use, safe bear canister that is lighter than current market products for trekking in the backcountry. A full design of the lid for the bear canister is to be completed. This includes the locking mechanism to ensure it is bear proof, the interface between the lid and the canister, and the structure of the lid so it passes the strength and weight specifications. The lid, along with the already designed canister body, is to be manufactured with formal documentation. The lid will initially be tested separately and then with the canister …

Data Driven Discovery Of Materials Properties., Fadoua Khmaissia

Electronic Theses and Dissertations

The high pace of nowadays industrial evolution is creating an urgent need to design new cost efficient materials that can satisfy both current and future demands. However, with the increase of structural and functional complexity of materials, the ability to rationally design new materials with a precise set of properties has become increasingly challenging. This basic observation has triggered the idea of applying machine learning techniques in the field, which was further encouraged by the launch of the Materials Genome Initiative (MGI) by the US government since 2011. In this work, we present a novel approach to apply machine learning …

The Development Of A Vacuum Forming System For Kydex® And Other Thermoplastic Sheet, Andrew G. Smith

Electronic Theses and Dissertations

Vacuum forming is a popular, cost effective method amongst large and small scale applications. The method is used to mold a material to the surface of a mold/pattern in order to create a negative copy for reproduction or an object in positive form. The prototype vacuum forming system developed and documented herein is of a membrane-seal type that consists of three (3) principle parts: radial platen, Hinged Frame and Platen Support Assembly, and a PVC surge tank. Each part is described in detail through design, manufacturing, and testing processes. The design supports functional versatility, small scale molding, and uses readily …

Developments And Properties Of Plastic Mimicking Biopolymers For Food Packaging Application, Daniel I. Hefft

Journal of Applied Packaging Research

Sustainability takes an ever increasing importance in the food industry. Here not only the selection of raw materials plays a role, but also packaging materials. Nowadays there is an increasing number of biodegradable and bio-compostable packaging materials available.

However, these materials are still not able to replace mineral oil based packaging materials completely, nevertheless they are becoming increasingly important, since there must be solutions to problems such as pollution of the oceans by plastic waste, growing piles of rubbish from growing population, etc.

The following literature review shows briefly recent developments on plastic mimicking biopolymers, as these materials guarantee great …

Adsorption Of Salicylhydroxamic Acid On Selected Rare Earth Oxides And Carbonates, Greer Galt

Graduate Theses & Non-Theses

Adsorption behavior of the anionic collector salicylhydroxamic acid (SHA) on a selected group of rare earth oxides (REOs) and carbonates (RECs) was studied via experimental methods and modelling software. Synthetic oxide and carbonate powders of the rare earth elements cerium (Ce), praseodymium (Pr), europium (Eu), and terbium (Tb) were tested for this research. Studies were conducted at different pH levels to analyze the kinetics of collector adsorption onto the oxide and carbonate surfaces in attempts to optimize recovery parameters for commercial flotation processes using SHA. In addition, thermodynamic software StabCal was implemented to compare theoretical adsorption behavior of collectors SHA …

Primary Blast Waves Induced Brain Dynamics Influenced By Head Orientations, Yi Hua, Yugang Wang, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

There is controversy regarding the directional dependence of head responses subjected to blast loading. The goal of this work is to characterize the role of head orientation in the mechanics of blast wave-head interactions as well as the load transmitting to the brain. A three-dimensional human head model with anatomical details was reconstructed from computed tomography images. Three different head orientations with respect to the oncoming blast wave, i.e., front-on with head facing blast, back-on with head facing away from blast, and side-on with right side exposed to blast, were considered. The reflected pressure at the blast wave-head interface positively …

The Effect Of Creasing Lines On The Compression Strength Of Adjustable Height Corrugated Boxes, Péter Csavajda, Péter Böröcz, Ákos Mojzes, Bence Molnár

Journal of Applied Packaging Research

Due to its high strength and low density, the corrugated fibreboard (CFB) box is one of the most popular types of packaging all over the world. This packaging device is able to fulfil a huge number of requirements of the logistic process, during the phases of handling, shipping and storage. In addition to this, corrugated packaging is easily machinable, so it is also suitable for special supply chains and products. These special needs include the requirement to fit to the inner measurements of the shipping device, e.g. the shipping container. This is particularly expected in case of less than container-load …

Dirichlet Process Gaussian Mixture Models For Real-Time Monitoring And Their Application To Chemical Mechanical Planarization, Jia (Peter) Liu, Omer F. Beyca, Prahalad K. Rao, Zhenyu (James) Kong, Satish T. S. Bukkapatnam

Department of Mechanical and Materials Engineering: Faculty Publications

The goal of this work is to use sensor data for online detection and identification of process anomalies (faults). In pursuit of this goal, we propose Dirichlet process Gaussian mixture (DPGM) models. The proposed DPGM models have two novel outcomes: 1) DP-based statistical process control (SPC) chart for anomaly detection and 2) unsupervised recurrent hierarchical DP clustering model for identification of specific process anomalies. The presented DPGM models are validated using numerical simulation studies as well as wireless vibration signals acquired from an experimental semiconductor chemical mechanical planarization (CMP) test bed. Through these numerically simulated and experimental sensor data, we …

Strained Hybrid Perovskite Thin Films And Their Impact On The Intrinsic Stability Of Perovskite Solar Cells, Jingjing Zhao, Yehao Deng, Haotong Wei, Xiaopeng Zheng, Zhenhua Yu, Yuchuan Shao, Jeffrey E. Shield, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Organic-inorganic hybrid perovskite (OIHP) solar cells have achieved comparable efficiencies to those of commercial solar cells, although their instability hinders their commercialization. Although encapsulation techniques have been developed to protect OIHP solar cells from external stimuli such as moisture, oxygen, and ultraviolet light, understanding of the origin of the intrinsic instability of perovskite films is needed to improve their stability. We show that the OIHP films fabricated by existing methods are strained and that strain is caused by mismatched thermal expansion of perovskite films and substrates during the thermal annealing process. The polycrystalline films have compressive strain in the out-of-plane …

The Effect Of Number Of Corrugation On Crashworthiness Of Aluminum Corrugated Tube Under Lateral Loading, Hozhabr Mozafari, Arameh Eyvazian, Abdel Magid Hamouda

Department of Mechanical and Materials Engineering: Faculty Publications

Thin-walled tubes have been developed and are growing in use as new energy absorber structures. The objective of this study is to investigate the energy absorption and crushing characteristics of corrugated tubes with different number of corrugation in a specific length exposed to lateral loading. At the first step, experimental tests were carried out on a corrugated tube with three con'ugations (two inner and one outer) and a tube without corrugation. After that, a finite element model was developed by means of ABAQUS software in order to study the effect of corrugation number on crushing properties of thin-walled tubes. The …

Methods, Systems, And Devices For Surgical Visualization And Device Manipulation, Shane M. Farritor, Mark Rentschler, Amy Lehman, Nathan A. Wood, Adam Bock, Reed Prior

Department of Mechanical and Materials Engineering: Faculty Publications

A surgical device includes a console having a visual display and a manipulator arm, a robotic device having a camera and a connection component. The robotic device is configured to be positioned completely within a body cavity. The camera is configured to transmit visual images to the visual display. The connection component operably couples the console and the robotic device. The manipulator arm is positioned relative to the visual display so as to appear to be penetrating the visual display.

Local And Segmental Motions Of The Mobile Amorphous Fraction In Semi-Crystalline Polylactide Crystallized Under Quiescent And Flow-Induced Conditions, Xavier Monnier, Laurence Chevalier, Antonello Esposito, Lucia Fernandez-Ballester, Allisson Saiter, Eric Dargent

Department of Mechanical and Materials Engineering: Faculty Publications

The molecular dynamics of the constrained and unconstrained mobile amorphous fractions in semicrystalline polylactide (PLA) was investigated in the presence of both flow-induced crystalline structures and spherulites by fast scanning calorimetry (FSC) through cooperativity and physical aging concepts. First, the shear rate conditions leading to flow-induced crystallization were characterized by examining the relaxation of shear-induced precursors. At a temperature of 150 °C, the critical relaxation time is so long that cooling down the sheared melt to the crystallization temperature does not affect significantly the precursors. Therefore, highly oriented structures develop. The arrangement of the crystalline fraction, either in flow-induced crystalline …

Experimental Study Of Corrugated Metal-Composite Tubes Under Axial Loading, Arameh Eyvazian, Hozhabr Mozafari, Abdel Magid Hamouda

Department of Mechanical and Materials Engineering: Faculty Publications

In this study, crushing behavior of corrugated metal-composite tube was examined experimentally under axial loading condition. Six types of specimens, classified into two groups of metal and metal-composite, were tested under quasi static axial loading. The failure mechanism and failure history of the specimens were presented and discussed. The experimental result showed that corrugated metal composite tubes demonstrate perfect energy absorption characteristics in terms of uniformity of load-displacement diagram, reduction of initial peak load and controlling failure mechanism. Moreover, it was also found that adding filament wound layer of composite on the surface of metallic corrugated tube compensated weakness of …

Disturbed Cyclical Stretch Of Endothelial Cells Promotes Nuclear Expression Of The Pro-Atherogenic Transcription Factor Nf-Kb, Ryan M. Pedrigi, Konstantinos I. Papadimitriou, Avinash Kondiboyina, Sukhjinder Sidhu, James Chau, Miten B. Patel, Daniel C. Baeriswyl, Emmanuel M. Drakakis, Rob Krams

Department of Mechanical and Materials Engineering: Faculty Publications

Exposure of endothelial cells to low and multidirectional blood flow is known to promote a pro-atherogenic phenotype. The mechanics of the vessel wall is another important mechano-stimulus within the endothelial cell environment, but no study has examined whether changes in the magnitude and direction of cell stretch can be pro-atherogenic. Herein, we developed a custom cell stretching device to replicate the in vivo stretch environment of the endothelial cell and examined whether low and multidirectional stretch promote nuclear translocation of NF-kB. A fluid–structure interaction model of the device demonstrated a nearly uniform strain within the region of cell attachment and …

Quantification Of Re-Absorption And Re-Emission Processes To Determine Photon Recycling Efficiency In Perovskite Single Crystals, Yanjun Fang, Haotong Wei, Qingfeng Dong, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Photon recycling, that is, iterative self-absorption and re-emission by the photoactive layer itself, has been speculated to contribute to the high open-circuit voltage in several types of high efficiency solar cells. For organic–inorganic halide perovskites that have yielded highly efficient photovoltaic devices, however, it remains unclear whether the photon recycling effect is significant enough to improve solar cell efficiency. Here we quantitatively evaluate the re-absorption and re-emission processes to determine photon recycling efficiency in hybrid perovskite with its single crystals by measuring the ratio of the re-emitted photons to the initially excited photons, which is realized by modulating their polarization …

Target Lesion Calcium Arc Influence The Performance Of Stenting, Pengfei Dong, Shengmao Lin, David L. Wilson, Hiram G. Bezerra, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

Percutaneous coronary intervention (PCI) is the most common revascularization procedure, in which, fibrocalcific plaques are found in 17–35% of patients undergoing PCI [1]. Numbers will rise with population aging and prolonged statin treatment. Calcifications often lead to stent under expansion and strut malapposition, with increased risk of thrombosis and in-stent restenosis [2]. Presence of calcium strongly inhibits stent performance, a well-documented metric for outcome [3]. The goal of this work is to develop the finite element models for inspecting the influence of the calcium arc extent on the stenting outcomes, such as the stress and strain distribution within the plaque, …

Growth Mechanisms Of Multiscale, Mound-Like Surface Structures On Titanium By Femtosecond Laser Processing, Edwin Peng, Ryan Bell, Craig A. Zuhlke, Meiyu Wang, Dennis R. Alexander, George Gogos, Jeffrey E. Shield

Department of Mechanical and Materials Engineering: Faculty Publications

Femtosecond laser surface processing (FLSP) can be used to functionalize many surfaces, imparting specialized properties such as increased broadband optical absorption or superhydrophobicity/- hydrophilicity. In this study, the subsurface microstructure of a series of mound-like FLSP structures formed on commercially pure titanium using five combinations of laser fluence and cumulative pulse counts was studied. Using a dual beam Scanning Electron Microscope with a Focused Ion Beam, the subsurface microstructure for each FLSP structure type was revealed by cross-sectioning. The microstructure of the mounds formed using the lowest fluence value consists of the original Ti grains. This is evidence that preferential …

Dissipative Elastic Metamaterial With A Lowfrequency Passband, Yongquan Liu, Jianlin Yi, Zheng Li, Xianyue Su, Wenlong Li, Mehrdad Negahban

Department of Mechanical and Materials Engineering: Faculty Publications

We design and experimentally demonstrate a dissipative elastic metamaterial structure that functions as a bandpass filter with a low-frequency passband. The mechanism of dissipation in this structure is well described by a mass-spring-damper model that reveals that the imaginary part of the wavenumber is non-zero, even in the passband of dissipative metamaterials. This indicates that transmittance in this range can be low. A prototype for this viscoelastic metamaterial model is fabricated by 3D printing techniques using soft and hard acrylics as constituent materials. The transmittance of the printed metamaterial is measured and shows good agreement with theoretical predictions, demonstrating its …