Open Access. Powered by Scholars. Published by Universities.®

Other Engineering Science and Materials Commons™

Open Access. Powered by Scholars. Published by Universities.®

Theses/Dissertations

2016

Articles 1 - 6 of 6

Full-Text Articles in Other Engineering Science and Materials

Development Of Lignin Carbon Fiber And Reinforced Composites, Nathan Kieran Meek Dec 2016

Development Of Lignin Carbon Fiber And Reinforced Composites, Nathan Kieran Meek

Masters Theses

The aim of this work is to develop lignin carbon fiber for composite applications. This included mechanical testing of single lignin carbon fiber (LCF), interfacial shear strength determination for LCF-resin systems using single fiber fragmentation, x-ray diffraction for the evaluation of microstructural parameters, and finally composite manufacturing and testing. Through these focused areas of analysis, the carbon fiber is thoroughly characterized and composite performance is evaluated. This effort was a collaboration with the Center for Renewable Carbon (CRC) and the Civil and Environmental Engineering Department. LCF produced by the CRC resulted in fibers having tensile strength of 250-800 MPa and …

Go to article

Structure-Property Relationships Of Polyisobutylene-Block-Polyamide Thermoplastic Elastomers, Morgan Dunn Heskett Dec 2016

Structure-Property Relationships Of Polyisobutylene-Block-Polyamide Thermoplastic Elastomers, Morgan Dunn Heskett

Master's Theses

Thermoplastic elastomers (TPEs) are a class of polymer fit for a wide variety of applications due to their customizability. In the synthesis of these types of materials, an elastically-performing polymer, deemed the “soft block,” is combined with a stiffer “hard block” polymer, each of which can be selected based on their own specific properties in order to achieve desired material behavior in the final copolymer. Recently, the use of polyisobutylene as a soft block in combination with a polyamide hard block has been investigated for use in TPE synthesis. While the material showed some promising behavior, many properties were still …

Go to article

Direct Band Gap Gallium Antimonide Phosphide (Gasbxp1-X) For Solar Fuels., Harry Benjamin Russell May 2016

Direct Band Gap Gallium Antimonide Phosphide (Gasbxp1-X) For Solar Fuels., Harry Benjamin Russell

Electronic Theses and Dissertations

Photoelectrochemical water splitting has been identified as a promising route for achieving sustainable energy future. However, semiconductor materials with the appropriate optical, electrical and electrochemical properties have yet to be discovered. In search of an appropriate semiconductor to fill this gap, GaSbP, a semiconductor never tested for PEC performance is proposed here and investigated. Density functional theory (DFT+U) techniques were utilized to predict band gap and band edge energetics for GaSbP alloys with low amount of antimony. The overall objective of this dissertation is to understand the suitability of GaSbxP1-x alloys for photoelectrochemical water splitting application. Specifically, …

Go to article

First-Principles Studies Of Structure-Property Relationships: Enabling Design Of Functional Materials, Qunfei Zhou Jan 2016

First-Principles Studies Of Structure-Property Relationships: Enabling Design Of Functional Materials, Qunfei Zhou

Theses and Dissertations--Chemical and Materials Engineering

First-principles calculations based on quantum mechanics have been proved to be powerful for accurately regenerating experimental results, uncovering underlying myths of experimental phenomena, and accelerating the design of innovative materials. This work has been motivated by the demand to design next-generation thermionic emitting cathodes and techniques to allow for synthesis of photo-responsive polymers on complex surfaces with controlled thickness and patterns. For Os-coated tungsten thermionic dispenser cathodes, we used first-principles methods to explore the bulk and surface properties of W-Os alloys in order to explain the previously observed experimental phenomena that thermionic emission varies significantly with W-Os alloy composition. Meanwhile, …

Go to article

Multi-Use Fireline Handtool, Bruce W. Bernard Jr Jan 2016

Multi-Use Fireline Handtool, Bruce W. Bernard Jr

All Undergraduate Projects

A wildland firefighter is a valuable resource to protecting public lands and managing fuels. The many hand tools used by firefighters aid in their ability to complete any required tasks effectively. Several of the tools available are specially purposed for individually grubbing, scraping, or liming. A small squad of firefighters could become a more effective resource if the tools they carried could perform several of these purposes as one single tool. To improve the effectiveness of an individual on the fireline a multi-use hand tool was designed to include an axe for liming and a heavy duty scraper for grubbing …

Go to article

Galvanic Corrosion On Monel K-500 And 1018 Carbon Steel Couple, John K. Nnyanzi Jan 2016

Galvanic Corrosion On Monel K-500 And 1018 Carbon Steel Couple, John K. Nnyanzi

Williams Honors College, Honors Research Projects

The purpose of this research project was to evaluate galvanic damage on 1018 Carbon Steel coupled to Monel K-500 at varying rotation speeds on a rotating cylinder electrode in an aerated solution of ASTM artificial seawater. The work in this project is and attempt to study corrosion behavior for a Monel fastener coupled to a Carbon Steel plate. Polarization curves of each material at different rotation speeds were created to predict the corrosion behavior for a galvanic couple of Carbon Steel and Monel. The Potentiodynamic sweeps predict an increase in the corrosion current density for the galvanic couple when then …

Go to article