Engineering Science and Materials Commons^™

Preparation And Characterization Of Self-Supporting Flexible Nitrogen-Doped Carbon Fabric Electrodes, Bo Yang, Zhi-Hang Jin, Ya-Ping Zhao, Zai-Sheng Cai

Journal of Electrochemistry

With the wide applications of intelligent wearable devices in various fields, developing a new generation of flexible energy storage devices has become a major challenge for the current technology. As a wide application of wearable flexible substrate, cotton fabric has the advantages over low price, non-toxic and environmental friendly, but the poor conductivity becomes a major problem limiting its development. As a nitrogen-containing conducting polymer, polypyrrole is traditionally used as electrode materials, but poor mechanical performance and cycle stability severely limit its application in electrode materials. In this article, a self-supporting flexible nitrogen-doped carbon fabric electrode was prepared by in …

Hybrid Battery-Capacitor System Based On Liti5O12 Anode And Ptpan Cathode, Xiu-Li Su, Xiao-Li Dong, Yao Liu, Yong-Gang Wang, Ai-Shui Yu

Journal of Electrochemistry

Owing to its high safe, high rate and long life characteristics, lithium titanate (Li₄Ti₅O₁₂) anode material has attracted extensive attention in recent years, and many efforts are being made to develop the Li₄Ti₅O₁₂ based high performance hybrid supercapacitors and Li-ion batteries. Herein, we prepared the organic cathode material polytriphenylamine (PTPAn) through chemical oxidation and polymerization of triphenylamine (TPAn), and investigated its charge storage mechanism and electrode kinetics withthe typical electrochemical methods in an organic electrolyte. It was demonstrated that the PTPAn exhibited the reversible capacity of 85 mA·g^{-1 …}

Electrochemical Performances Of Neodymium Doped Lead Dioxide Composite Anode, Hong-Hui Wang, Ming-Jie Ma, Jie Feng, Huang-Ya Kang, Wen-Jie Huang

Journal of Electrochemistry

Neodymium (Nd) doped titanium (Ti)-based lead dioxide (PbO₂) composite anode was prepared by electrodeposition. The surface morphologies and crystal structures of the as-prepared anodes were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) technique, respectively. The electrochemical performances of PbO₂-Nd anode were studied by electrochemical impedance spectroscopy, linear sweep voltammetry and cyclic voltammetry. Additionally, the electrocatalytic activity and durability of PbO₂-Nd anode were investigated through the degradation of simulative refractory organic wastewater of phenol. The results showed that Nd doping made the PbO₂ anode surface structure dense and uniform with smaller …

Assemblies And Properties Of Asymmetric Supercapacitors Based On Wo3/Carbon Cloth, Wen-Ke Shao, Lei Zhao, Chao Liu, Yan-Ying Dong, Yuan-Jie Zhu, Qiu-Fan Wang

Journal of Electrochemistry

The demand for a new generation of flexible, portable, and high-capacity power sources increases rapidly with the development of advanced wearable electronic devices. One dimensional (1D) nanowires structures have been demonstrated as one of the most ideal electrode materials in energy storage systems due to their advantages in both micorstructures and their high surface areas. Here we report a simple process for large-scale fabrication of self-standing composite film electrodes composed of WO₃ nanorods on carbon cloth. In order to improve the energy density of supercapacitor, we assembled an asymmetric supercapacitor using WO₃ nanorods and activated carbon cloth as …

Preparations Of Nano-Manganite Loaded Titanium Electocatalytic Membrane Electrode For Phenolic Wastewater Treatment, Le Li, Hong Wang, Rong-Hua Ma, Hong-Sen Hui, Xiao-Ping Liang, Jian-Xin Li

Journal of Electrochemistry

Nano-manganese oxide loaded on titanium electrocatalytic membrane electrodes (nano-MnO_x/Ti) were synthesized bysol-gel method using porous Ti membrane as a substrate and the manganese acetate as a raw material without releasing NO_x. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Field-emission scanning electron microscopy (FESEM) were employed to characterize crystal form, valence state and surface morphology of nano-MnO_x, respectively. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronoamperometry (CA) were used to investigate the electrochemical properties of nano-MnO_x electrode. The results indicated that the MnO_x catalysts consisted of γ-MnO₂ and Mn_{2 …}

Electrochemical Preparation And Photo-Electro Catalytic Properties Of Flexible Znni/Al-Ldhs/Carbon Fibers Composite, Jing-Jing Tian, Tao Chen, Xing-Chen Bao, Meng-Xu Gao, Ye-Xiao Yu, Si-Yao Peng, Guan-Ping Jin

Journal of Electrochemistry

In this work, a promising flexible composite consisting of zinc (Zn), nickel (Ni) and aluminum (Al) layered double hydroxide coated carbon fibers (ZnNi/Al-LDHs/CFs) was prepared by electrochemical method with convenient recovery and separation. The structures, morphologies, and photo-electro catalytic properties of ZnNi/Al-LDHs/CFs were characterized by X-ray diffraction, infrared spectroscopy, field emission scanning electron microscopy, inductively coupled plasma atomic emission spectrometry and electrochemical impedance spectroscopy techniques. The excellent photo-electro bifunctional catalytic properties were obtained with the ZnNi/Al-LDHs/CFs composite as compared to that of Zn/Al-LDHs/CFs (photo catalyst) or Ni/Al-LDHs/CFs (electrocatalyst) alone, which could be used in the electro-catalytic oxidations of methanol and …

An Aqueous All-Metal Oxide Asymmetric Supercapacitor With High Gravimetric And Volumetric Energy Densities, Xin Jing, Xu Zhang, Wei Wang, Jun-Wei Lang

Journal of Electrochemistry

Only with both high gravimetric and high volumetric energy densities, can supercapacitors find more extensive applications.In this paper, by making good use of the interesting nanostructures and the high packing densities of RuO₂ (nanoshpheres,1.69 g·cm^-3) and Co-Ni oxide (nanoflakes, 2.14 g·cm^-3), the RuO₂//KOH//Co-Ni oxide all-metal oxide asymmetric supercapacitors with high performance were successfully fabricated, which led to the maximum specific capacitance of 217.5 F·g^-1 (412.3 F·cm^-3) and specific energy density of 61.8 Wh·kg^-1 (121 Wh·L^-1) in a cell voltage between 0 and 1.5 V in KOH electrolyte. …

Highly Crystalline Nickel Borate Nanorods As Oxygen Evolution Reaction Electrocatalysts, Xi Xu, Juan Liu, Hua-Zong Wu, Wen-Jie Jiang

Journal of Electrochemistry

Hydrogen energy, a kind of clean and renewable energy, is considered to be the solution to the problems of energy crisis and environmental deterioration. Electrochemical water splitting is an efficient and promising technology for the production of high-purity hydrogen. However, oxygen evolution reaction (OER) at the anode of water electrolyzer limits the efficiency of water splitting due to the high overpotential. Therefore, the challenges still remain for the exploration of highly active, stable and low-cost catalysts with superior activity for OER. Herein, nickel borate nanorods with high crystallinity were prepared via high-temperature calcination. The as-obtained nickel borate nanorods with 2 …

Influences Of Na-Mn Ratio On Electrochemical Performances And Intercalation-Deintercalation Processes Of Sodium Ion In NaXMno2, Yong-Chun Xie, Cheng Wang, Fang Jiang, Yang Yang, Jing Su, Yun-Fei Long, Yan-Xuan Wen

Journal of Electrochemistry

In this work, Na_xMnO₂ was synthesized by a solid-state reaction. The influences of Na:Mn ratio on the structure, morphology and electrochemical performance, and sodium ion intercalation/deintercalation processes were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge-discharge test. The prepared Na_xMnO₂ was mainly composed of Na_0.7MnO₂ and Na_0.91MnO₂, and the content of Na_0.91MnO₂ increased with the increase of Na:Mn ratio. However, the activation energy values of surface membrane diffusion, interfacial electrochemical reaction and …

Development Of Self-Healing Mechanisms For Asphalt Pavements, Max Abelardo Aguirre Deras

LSU Doctoral Dissertations

Self-healing mechanisms, such as microcapsules or hollow-fibers, filled with an asphalt rejuvenator present an emerging technology that would enhance an asphalt mixture’s resistance to cracking damage caused by vehicular and environmental loading. The objectives of this study were to: (a) Evaluate the effects of asphalt rejuvenators on hot-mix asphalt mixtures in order to test its effects on the fundamental engineering properties of the mixtures at high and intermediate temperatures; (b) Develop a synthesis procedure for production of microcapsules and hollow-fibers containing an asphalt rejuvenator; (c) Evaluate the self-healing efficiency of double-walled microcapsules and hollow-fibers filled with an asphalt rejuvenator, through …

Synthesis Of Crumpled Graphene And Titanium Dioxide Based–Nanomaterials And The Application To Carbon Dioxide Photoreduction, Yao Nie

McKelvey School of Engineering Graduate Student Theses & Dissertations

With the rapid development of the economy, increasing combustion of fossils fuels has caused an increase in the atmospheric carbon dioxide (CO2) level, and has led to global climate change. As a mitigation approach, CO2 capture and conversion (CCC) can not only capture CO2, but also convert it to useable products, such as hydrocarbon fuels. Photocatalytic reduction is an attractive CCC option that directly harnesses inexpensive and abundant solar energy. Titanium dioxide (TiO2) is a widely used semiconductor for photocatalysis, and graphene nanosheets are a promising material for use in fabricating graphene-TiO2 hybridized photocatalysts. To realize the application of these …

Developing Strategies To Toughen Bio-Inspired Adhesives, Narelli P. Narciso, Samuel Lee Huntington, Jonathan J. Wilker

The Summer Undergraduate Research Fellowship (SURF) Symposium

Mussels and other marine creatures adhere very well in underwater environments, having the ability to withstand the force of the sea. These animals have inspired synthetic biomimetic adhesives for wet systems, presenting potential for biomedical applications. However, most current commercial adhesives tend to be brittle, not resisting repetitive movements. This study assesses toughening strategies to improve the mussel-inspired adhesives’ ductility while maintaining its strength. The strategies included altering the polymer’s chemical structure by changing the percentage of polyethylene glycol (PEG) in the molecule and by adding fillers, such as calcium carbonate, silica and nacre - a calcium carbonate compound found …

Ice Adhesion Analysis Of Severely Aged Pdms Rubbers, Theodore R. Woll

Electronic Theses and Dissertations

The goal of this study was to evaluate and optimize the ice adhesion test initially developed by the University of Denver and to examine Polydimethylsiloxane (PDMS) based silicone rubbers for their ice-phobicity as a function of their physical and chemistry properties, and under severe oxidative aging. The test is based on an ice block bonded to a silicone rubber substrate and subjected to shear. In its original state, the test had severe limitations that caused the ice to be dislodged through a mixture of shear and peeling. Several steps were taken in this research to improve the test, and the …

Measuring Solid–Liquid Interfacial Energy Fields: Diffusion-Limited Patterns, Martin E. Glicksman

Mechanical and Civil Engineering Faculty Publications

The Leibniz–Reynolds transport theorem yields an omnimetric interface energy balance, i.e., one valid over all continuum length scales. The transport theorem, moreover, indicates that solid–liquid interfaces support capillary-mediated redistributions of energy capable of modulating an interface’s motion—a thermodynamic phenomenon not captured by Stefan balances that exclude capillarity. Capillary energy fields affect interfacial dynamics on scales from about 10 nm to several mm. These mesoscopic fields were studied using entropy density multiphase-field simulations. Energy rate distributions were exposed and measured by simulating equilibrated solid–liquid interfaces configured as stationary grain boundary grooves (GBGs). Negative rates of energy distributed over GBGs were measured …

Modeling And Validations Of Control Parameters For Material Extrusion-Based Additive Manufacturing Of Thixotropic Aluminum Alloys., Lars Herhold

Electronic Theses and Dissertations

Additive Manufacturing (AM) with metals has been accomplished mainly through powder bed fusion processes. Initial experiments and simulations using Material Extrusion Additive Manufacturing (MEAM) have been performed by various researchers especially using low melting alloys. Recently Stratasys Inc. submitted a patent application for the use of their Material Extrusion technology also called Fused Deposition Modeling (FDM) where they describe the process using thixotropic semi-solid alloys. Currently this process using semi-solid, engineering type alloys such as A356 or THIXALLOY 540 aluminum have not been researched to evaluate the control parameters. This research combines the in-depth knowledge of applying thixotropic semi-solid aluminum …

Pnnl Dark Matter Bubble Chamber, Ryan Robinson

STAR Program Research Presentations

The Pacific Northwest National Laboratory (PNNL) prototype bubble chamber is intended to address issues encountered with the current PICO dark matter search detectors and improve the functionality of future experimental designs. The PNNL bubble chamber accomplishes this with a simplified interface between the hydraulic pressure controls and the target vessel and altering the standard chamber design such that it can be easily exchanged and replaced with vessels of various sizes and materials for testing purposes. The chamber itself is a glass vessel which houses perfluorobutane and holds the target fluid above room temperature and atmospheric pressure. The target fluid becomes …

The Effect Of Rotational Speed, Friction Duration, And Pressure On Tensile Strength Of Aisi 6061 Welding Joints, Dewi Puspitasari, Poppy Puspitasari, M. Rizka Gita Firmansyah, Solichin Solichin

Journal of Mechanical Engineering Science and Technology (JMEST)

Electric arc welding with covered electrodes is ideally suited for flat plates. If this technique is employed for welding rigid bodies, the results would be of poor quality. One viable solution to weld rigid bodies is through friction welding. The study aimed to investigate the tensile strength of specimens subjected to friction welding with variations in rotational speed, friction time, and pressure and to examine the microstructure of friction welding joints. This research used the one-shot case study design and involved descriptive analysis. The descriptive analysis described the results of tensile testing and microstructure of welding joints. Results showed that …

Pine Flower Waste Innovation As A Plant Based Program Augmented Reality, Ayik Bela Saputra, Imam Muhtarom, Ni’Matul Rochmaniyah, Ardhana Iswari Citra Padmi, Ika Rahmawati

Journal of Mechanical Engineering Science and Technology (JMEST)

Indonesia one of the tropical countries in the world can not be separated from environment problems like other developing countries. One of the causes of declining environment quality is the decline of forests in Indonesia. In 2009, Indonesia’s forest area was by more than half, to about 88 million hectares. By the year 2013 the number is about 82 million hectares. One of the efforts to promote environment education is to familiarize planting plants to children from an early age from the school environment to the family environment. Therefore it is necessary an alternative in the form of planting media …

Effect Of Mnfe2o4 Nanoparticles To Reduce Co And Hc Levels On Vehicle Exhaust Gas Emissions, Poppy Puspitasari, Sukarni Sukarni, Amir Hamzah

Journal of Mechanical Engineering Science and Technology (JMEST)

The air pollution particle emitted from transportation in Indonesia Bay 2015 consist of 70.50% CO; 18.34% HC; 8.89% NOx; 0.88% SOx; 1.33%. These gases are very harmful to humans. To reduce the toxic gas effect, special treatment is needed, one of them is by applying catalyst on exhaust system. MnFe2O4 has the potential to bind the CO and HC elements contained in the exhaust gas. This study aims to investigate the effect of MnFe2O4 addition on catalityc converter towards CO gas and HC emissions of motor vehicles. Therefore, the percentage of exhaust reduction with and without applying MnFe2O4 on varied …

Damage Simulation Of Pre-Forming V-Neck Plates With Variations In Material Type, Time And Temperature Using The Taguchi Method, Avita Ayu Permanasari, Rr. Poppy Puspitasari, Kevin Valiant Cahya, Mahfud Ihsan

Journal of Mechanical Engineering Science and Technology (JMEST)

In metal forming, damage can be caused by several factors: load on the workpiece, initial heating temperature, and temperature due to the friction between the die and the material for pre-forming. The metal forming process can be executed in 2 ways, namely by hot working and cold working. During these two types of mechanical working process, the metal undergoes plastic deformation. In hot working, the required deformation force is relatively low, and changes in mechanical properties are also insignificant. In cold working, a higher force is required, but the strength of the metal will increase significantly. The use of simulation …

Mechanical Properties And Permeability Of Sand Casting Moulds With Eggshells Binder, Maryam Sharifi Jebeli Sharifi Jebeli, Wahyu Kurnianto, Wahono Wahono

Journal of Mechanical Engineering Science and Technology (JMEST)

This research aimed to analyse whether or not eggshell could be a potential addition to sand mould composition as a binding material together with bentonite. Different amounts of eggshell material, i.e. 4%, 7%, 10% and 3%, were added to each sample. This study was a type of pre-experimental design called the one-shot case study. Among all sand moulds under study, sample 3 10% ES in dry conditions had the highest tensile, compressive and shear strengths of 0.09 Kg/cm2, 3.11 Kg/cm2 and 1.13 Kg/cm2, respectively. The results of the permeability test with heat treatment at 110˚C for 60 minutes showed that …

Properties Of Cassava Starch Based Bioplastic Reinforced By Nanoclay, Nanang Eko Wahyuningtiyas, Heru Suryanto

Journal of Mechanical Engineering Science and Technology (JMEST)

Synthetic Synthetic plastic is chemical materials which cause severe environmental problems. Incinerating plastic waste leads to release of hazardous gases, which is not good for humans. Bioplastic can help reduce the dependence on fossil fuels and petroleum, that bioplastic can solve the problem of synthetic plastic use. This research aims to define the properties of the cassava starch-based bioplastic reinforced by nanoclay. Methods were experimental with bioplastic component of cassava starch, glycerol as plasticizer and nanoclay as reinforcement. The bioplastic was analyzed using XRD, tensile test, moisture absorption, biodegradability, and compared with another bioplastic. The results show that the addition …

Full Field Computing For Elastic Pulse Dispersion In Inhomogeneous Bars, A. Berezovski, R. Kolman, M. Berezovski, D. Gabriel, V. Adamek

Publications

In the paper, the finite element method and the finite volume method are used in parallel for the simulation of a pulse propagation in periodically layered composites beyond the validity of homogenization methods. The direct numerical integration of a pulse propagation demonstrates dispersion effects and dynamic stress redistribution in physical space on example of a one-dimensional layered bar. Results of numerical simulations are compared with analytical solution constructed specifically for the considered problem. Analytical solution as well as numerical computations show the strong influence of the composition of constituents on the dispersion of a pulse in a heterogeneous bar and …

Tunable Plasmonic Resonances In Highly Porous Nano-Bamboo Si-Au Superlattice-Type Thin Films, Ufuk Kılıç, Alyssa Mock, René Feder, Derek Sekora, Matthew J. Hilfiker, Rafal Korlacki, Eva Schubert, Christos Argyropoulos, Mathias Schubert

Department of Electrical and Computer Engineering: Faculty Publications

We report on fabrication of spatially-coherent columnar plasmonic nanostructure superlattice-type thin films with high porosity and strong optical anisotropy using glancing angle deposition. Subsequent and repeated depositions of silicon and gold lead to nanometer-dimension subcolumns with controlled lengths. The superlattice-type columns resemble bamboo structures where smaller column sections of gold form junctions sandwiched between larger silicon column sections (“nano-bamboo”). We perform generalized spectroscopic ellipsometry measurements and finite element method computations to elucidate the strongly anisotropic optical properties of the highly-porous nano-bamboo structures. The occurrence of a strongly localized plasmonic mode with displacement pattern reminiscent of a dark quadrupole mode is …

Near-Field Heat Transfer Enabled Nanothermomechanical Memory And Logic Devices, Sidy Ndao, Mahmoud Elzouka

Department of Mechanical and Materials Engineering: Faculty Publications

A thermomechanical memory / logic device is disclosed . In embodiments , the thermomechanical device includes a first thermally controlled terminal ( e . g . , hot terminal ) ; a second thermally controlled terminal ( e . g . , cool terminal / base ) ; a stem or other structure that can be thermally expanded connected to the cool terminal ; and a thermal conductive head coupled to the stem . The head can exchange heat with the hot terminal . The stem and head are between the first thermally controlled terminal and the second thermally controlled …

Artificial Neural Network And Finite Element Modeling Of Nanoindentation Tests On Silica, Kianoosh Koocheki

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Two major forms of Silica include the crystalline form named Quartz which consist of the sand grains in nature, and amorphous form named Silica Glass or Fused Silica which is commonly known as glass. Fused Silica is an amorphous crystal that can show plastic behavior at micro-scale despite its brittle behavior in large scales. Due to the amorphous and ductile nature of Fused Silica, this behavior may not be explained well using the traditional dislocation-based mechanism of plasticity for crystalline solids. The crystal plasticity happens due to shear stress and stored energy in the material as dislocations which does not …

Properties Of Matter, Mike Jackson, Holly Haney

High School Lesson Plans

Students will investigate the relationship(s) between thermal and electrical properties of matter. First, students will use a multimeter and temperature probe to investigate the relationship between electrical resistance and temperature of an electrical resistor composed of metals. They will then graph collected data to analyze the relationship and draw a conclusion as to their relationship. They will then perform the same investigation on a thermal resistor made of a semiconducting substance and analyze that collected data. Finally, using ClaimEvidence-Reasoning (CER) structure, students will use their experimental evidence to state the similarities and differences between the electro-thermal properties of metals and …

Prevascularization Of 3d Printed Bone Scaffolds By Bioactive Hydrogels And Cell Co-Culture, Mitchell Kuss, Shaohua Wu, Ying Wang, Jason B. Untrauer, Wenlong Li, Jung Yul Lim, Bin Duan

Department of Mechanical and Materials Engineering: Faculty Publications

Vascularization is a fundamental prerequisite for large bone construct development and remains one of the main challenges of bone tissue engineering. Our current study presents the combination of 3D printing technique with a hydrogel-based prevascularization strategy to generate prevascularized bone constructs. Human adipose derived mesenchymal stem cells (ADMSC) and human umbilical vein endothelial cells (HUVEC) were encapsulated within our bioactive hydrogels, and the effects of culture conditions on in vitro vascularization were determined. We further generated composite constructs by forming 3D printed polycaprolactone/hydroxyapatite scaffolds coated with cell-laden hydrogels and determined how the co-culture affected vascularization and osteogenesis. It was demonstrated …

Continuous Flow Process For Recovery Of Metal Contaminants From Industrial Wastewaters With Magnetic Nanocomposites, David Hutchins

Graduate Theses & Non-Theses

Remediation of metal-containing industrial effluents presents both a technical challenge and an economic opportunity. Many industrial waste streams contain low levels of metal ions requiring treatment prior to discharge. Existing treatment technologies are frustrated by disparate compositions and low metal concentrations. Chemical precipitation is effective; however, it requires excessive reagents and discourages selective recovery. Ion-exchange enables recovery, but requires a batch process with extensive operational and maintenance demands, and is rarely implemented in large-scale applications. A continuous flow process capable of selective recovery would present many advantages over existing technologies.

This research examines and develops a continuous flow process for …

Smart Bandage For Monitoring And Treatment Of Chronic Wounds, Pooria Mostafalu, Ali Tamayol, Rahim Rahimi, Manuel Ochoa, Akbar Khalilpour, Gita Kiaee, Iman K. Yazdi, Sara Bagherifard, Mehmet R. Dokmeci, Babak Ziaie, Sameer R. Sonkusale, Ali Khademhosseini

Department of Mechanical and Materials Engineering: Faculty Publications

Chronic wounds are a major health concern and they affect the lives of more than 25 million people in the United States. They are susceptible to infection and are the leading cause of nontraumatic limb amputations worldwide. The wound environment is dynamic, but their healing rate can be enhanced by administration of therapies at the right time. This approach requires real-time monitoring of the wound environment with on-demand drug delivery in a closed-loop manner. In this paper, a smart and automated flexible wound dressing with temperature and pH sensors integrated onto flexible bandages that monitor wound status in real-time to …