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Gradient In Microstructure And Mechanical Property Of Selective Laser Melted Alsi10mg, Yujing Liu, Zeng Qian Liu, Y Jiang, G.W Wang, Yang Yang, Laichang Zhang

Research outputs 2014 to 2021

It is known that metal parts can be made stronger, tougher and better wear resistance by introducing gradient microstructure. This work reports the cooling rate of melt pool induced discrepancy in microstructural gradient and element distribution during selective laser melting (SLM), thereby resulting in decrease in microhardness and wear resistance from surface to inside with a range of ∼100 μm of SLM- manufactured AlSi10Mg alloy. The cooling rate in the top surface of melt pool reaches ∼ 1.44 × 10⁶ K/s, which is much higher than that at the bottom ( ≤ 1 × 10³ K/s). Such a …

การจำลองแบบทางพลศาสตร์ของไหลเชิงคำนวณของของเหลวที่ไม่ละลายเข้าหากันในเครื่องปฏิกรณ์แบบจุลภาคที่ขยายขนาด, คณิน มงคล

Chulalongkorn University Theses and Dissertations (Chula ETD)

สำหรับการสกัดด้วยตัวละลายในเครื่องปฏิกรณ์ขนาดจุลภาคนั้น ของเหลวในกระบวนการจะมีคุณสมบัติที่ไม่ละลายเข้าหากันซึ่งจะทำให้เกิดรูปแบบของการไหลที่แตกต่างกันออกไป โดยการไหลแบบ slug นั้นเป็นรูปแบบการไหลที่มักจะพบได้เมื่อเป็นการไหลที่ความเร็วต่ำ ซึ่งการไหลดังกล่าวสามารถรักษารูปแบบการไหลให้คงที่ตลอดความยาวท่อโดยที่มีประสิทธิภาพในการสกัดที่สูงกว่ารูปแบบการไหลแบบอื่นๆ ซึ่งเป็นผลจากการหมุนวนภายในเนื่องจากการเคลื่อนที่ของของเหลวภายใน slug การศึกษาการสกัดด้วยตัวทำละลายด้วยวิธีการดังกล่าวได้รับการยอมรับว่ามีประสิทธิภาพที่สูงเมื่อเปรียบเทียบกับวิธีการอื่นที่มีการใช้งานอยู่ในปัจจุบัน แต่ที่ผ่านมามักเป็นการศึกษาในระดับจุลภาคซึ่งมีผลผลิตโดยรวมน้อย ในงานวิจัยนี้ได้มุ่งไปที่การศึกษาผลเนื่องจากการเพิ่มขนาดเส้นผ่านศูนย์กลางของท่อในระดับมิลลิเมตร ที่มีต่อการเปลี่ยนแปลงรูปแบบการหมุนวนภายใน และความดันตกคร่อมภายใน slug โดยทำการศึกษาด้วยการจำลองแบบทางพลศาสตร์ของไหลเชิงคำนวณแบบ 2 มิติ ของการไหลผ่านท่อที่มีพื้นที่หน้าตัดเป็นรูปสี่เหลี่ยมที่มีขนาดแตกต่างกันออกไปตั้งแต่ 1-10 มิลลิเมตร ของเหลว 2 ชนิดที่มีคุณสมบัติการไม่ละลายเข้าหากันประกอบด้วยน้ำและเคโรซีนจะถูกป้อนเข้าสู่ท่อที่อยู่ตรงข้ามกันและเกิดการผสมกันที่บริเวณข้อต่อรูปตัว T โดยเปลี่ยนแปลงค่า Weber number ในช่วง 0.002-0.02 ผลการศึกษาแสดงให้เห็นว่าการเพิ่มขึ้นของขนาดเส้นผ่านศูนย์กลางท่อทำให้เวลาการหมุนวนลดลง 1.39% และความดันตกคร่อม slug ลดลง 85.12% โดยที่มีอัตราการไหลเชิงปริมาตรเพิ่มมากขึ้น อย่างไรก็ตามพบว่ารูปแบบการไหลแบบ slug จะไม่สามารถพบได้อีกต่อไปเมื่อเป็นการไหลในท่อที่มีขนาดเส้นผ่านศูนย์กลางมากกว่า 6 มิลลิเมตร

การออกแบบและผลิตเท้าเทียมแบบไดนามิคสำหรับผู้พิการขาขาดในระดับกิจกรรมปานกลาง, ดนุพงษ์ บุตรทองคำ

Chulalongkorn University Theses and Dissertations (Chula ETD)

ในปัจจุบัน ประเทศไทยมีผู้พิการขาขาดจำนวนมากและมีแนวโน้มที่จะเพิ่มจำนวนขึ้นอย่างต่อเนื่องในทุกๆ ปี หากแบ่งตามช่วงอายุของผู้พิการจะพบว่ามีผู้พิการขาขาดในกลุ่มวัยรุ่นถึงวัยกลางคนในช่วงอายุ 15 ถึง 44 ปี ประมาณร้อยละ 39 ของผู้พิการขาขาดทั้งหมด ซึ่งมีจำนวนมากกว่าช่วงอายุอื่นๆ ผู้พิการในกลุ่มนี้จะถูกจัดอยู่ในระดับกิจกรรมปานกลางหรือ K2-K3 ซึ่งเท้าข้างที่ยังเหลืออยู่ของผู้พิการในกลุ่มนี้สามารถปลดปล่อยพลังงานในการดีดตัวไปข้างหน้าที่เพียงพอต่อการเดินด้วยความเร็วเท่ากับคนปกติ อีกทั้งยังสามารถเคลื่อนไหวได้ดีทั้งในระนาบด้านหน้าและด้านข้าง จึงสามารถเดินบนพื้นที่มีความขรุขระหรือต่างระดับได้เป็นอย่างดี แต่ทว่าผู้พิการในกลุ่มนี้ยังคงใช้เท้าเทียมที่มีบริจาคในประเทศซึ่งมีข้อเท้าแข็งเกร็ง ไม่สามารถงอและปลดปล่อยพลังงานในการดีดตัวได้เหมือนเท้าคนปกติ งานวิจัยนี้จึงมีเป้าหมายที่จะออกแบบและผลิตเท้าเทียมแบบไดนามิคสำหรับผู้พิการขาขาดในระดับกิจกรรมปานกลาง ซึ่งสามารถเก็บสะสมพลังงานในจังหวะดีดตัวได้อย่างเหมาะสม และเคลื่อนไหวได้ทั้งในระนาบด้านข้างและด้านหน้า โครงสร้างเท้าเทียมถูกออกแบบโดยใช้วิธีการไฟไนต์เอลิเมนต์เพื่อวิเคราะห์การเก็บสะสมพลังงานและการเคลื่อนไหวให้เหมาะสมกับการใช้งานของผู้พิการในระดับกิจกรรมปานกลางและวิเคราะห์ความแข็งแรงตามแนวทางมาตรสากล ISO10328 โดยจะออกแบบให้มีพลังงานที่เก็บสะสมมากกว่าเท้าเทียมในท้องตลาดเล็กน้อยเพื่อให้พลังงานที่ปลดปล่อยสูงกว่าและใกล้เคียงกับคนปกติ ใช้แนวคิดการออกแบบแบบผ่าครึ่งซีกที่ส้นเท้าและเซาะร่องที่ปลายเท้าช่วยให้เคลื่อนไหวได้ในระนาบด้านหน้า โครงสร้างหลักของเท้าเทียมทำจากวัสดุผสมคาร์บอนไฟเบอร์มีความแข็งแรงสูงและน้ำหนักเบา ซึ่งผลิตโดยใช้วิธีการอบขึ้นรูปแบบสุญญากาศที่ควบคุมความดันและอุณหภูมิ เท้าเทียมต้นแบบได้รับการทดสอบการทำงานและทดสอบการเก็บสะสมและปลดปล่อยพลังงานของเท้าเทียมด้วยวิธีการทดสอบทางกล พบว่าสามารถเก็บพลังงานปลดปลอดพลังงานได้ 0.167 และ 0.137 J/kg ตามลำดับและมีมุมงอเท้าในทิศงอลง, งอขึ้น และพลิกด้านข้างของส้นและปลายเท้าเป็นมุม 8.96 องศา,16.98 องศา, 5.72 องศา และ 7.1 องศา ตามลำดับ ซึ่งเหมาะสมกับการใช้งานของผู้พิการขาขาดในระดับกิจกรรมปานกลาง อีกทั้งยังผ่านการทดสอบความแข็งแรงตามแนวทางมาตรฐานสากล ISO 10328:2006

Processing Of Ultra-Thin Film Of Un Modified C60 Fullerene Using The Langmuir-Blodgett Technique. Effect Of Structure On Stiffness And Optoelectric Properties, Hasanain Basim Altalebi

Browse all Theses and Dissertations

Monolayer films of C60 fullerene were for the first time produced successfully by using the Langmuir-Blodgett technique. The processing parameters were optimized and the structure of these films has been investigated using Scanning Tunneling Microscopy (STM) and Atomic Force Microscopy (AFM). Film stiffness was measured to be in the range of 15 MPa to 32 MPa depending on the nature of the solvent used to process the films. Optical transparency and electrical performance have been measured and correlated to the film structure. While 100% transparent, the film measured conductivity was in the range of 1013 S/m, that is orders of …

An Experimental Investigation Of Residual Stress Development During Selective Laser Melting Of Ti-6al-4v, Nathan Charles Levkulich

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Selective laser melting (SLM) is an additive manufacturing (AM) process that gives rise to large thermal gradients and rapid cooling rates that lead to the development of undesirable residual stress and distortion. In this work, a number of different techniques (i.e., x-ray-diffraction, hole-drilling, layer-removal, and contour) were utilized to establish the effect of process parameters on residual stress development during SLM of Ti-6Al-4V. The measurements indicated that higher laser power, slower scan speed, smaller stripe width, reduced substrate overhang, and reduced build plan area each reduce the level of residual stress. In addition, the correlation between microstructure, crystallographic texture, and …

The Impact Of Active Aerodynamics On Motorcycles Using Computational Fluid Dynamics Simulations, Aditya Sripathi

All Graduate Theses, Dissertations, and Other Capstone Projects

Motorcycles are mostly utilized by commuters whose requirements are cheap and affordable transportation from point A to point B. Motorcycles also provide means to tour various places and have a leisure time for the majority of motorcyclists. Unfortunately, with pros also come cons such as accidents which are disabling or life-taking. According to motorcycle crash statistics produced every year, the majority of motorcycle crashes are caused due to facing unexpected obstacles in the path causing collisions due to insufficient braking time. Thus, this thesis serves as a mean to overcome this issue and provide a technological solution to the world …

Process-Structure-Property Relationship In Magnesium-Based Biodegradable Alloy For Biomedical Applications, Pramanshu Trivedi

Open Access Theses & Dissertations

Magnesium alloys are considered to be the next generation of biomaterials because of their ability to degrade in the physiological environment. We elucidate here the impact of multiaxial forging of Mg-2Zn-2Gd alloy on grain refinement to sub-micron regime and relate the structure to mechanical properties and biological functionality. As-cast and annealed samples were multiaxial forged (MAF) for a total number of two passes with a true strain of ~2/pass. Considering that the microstructure governs the biological response of materials, we studied the constituents of the microstructure in conjunction with the mechanical behavior. The antimicrobial behavior in a Mg-2Zn-2Gd alloy with …

Electronic Structure Studies On Transition Metal Containing Endohedral Fullerenes, Carbon Onions And Zinc Sulfide Cages, Shusil Bhusal

Open Access Theses & Dissertations

We present the most stable structures for VXSc3-XN@C2n (where X=1-3 and 2n=70, 76, 78 and 80) using a systematic procedure that involves all possible isomers of the host fullerene cages. Subsequently, a detailed investigation of structural and electronic properties of the lowest energy isomers is performed using density functional theory in combination with large polarized Gaussian basis sets. The search procedure developed involved structural optimizations of thousands of fullerenes and correctly identifies the experimentally observed VSc2N@C80 and V2ScN@C80 isomer as the most stable structures. The structural analysis shows that a few V-doped endohedral fullerenes do not follow the isolated pentagon …

Organic-Inorganic Graphite And Transition Metal Dichalcogenide Based Composites For 3d Printing, Jorge Alfredo Catalan Gonzalez

Open Access Theses & Dissertations

This project was multipronged to help fuse together topics of additive manufacturing and two-dimensional (2D) layered materials, and studying the mechanical and electrical properties of the composites produced. The composites are made from the thermoplastic polymer acting as a matrix and the graphite and 2D transition metal dichalcogenides (TMDs) serving as the filler or reinforcement. Different concentrations of TMD's were added to the matrix to study the effect of composition on the mechanical and electrical properties. To shed insights into the mechanical properties, test coupons were produced as "dog bone" structures for tensile testing using the ASTM D638 type 5 …

Mechanically Activated Magnesiothermic Combustion Synthesis Of Zirconium And Hafnium Diborides, Sergio Cordova

Open Access Theses & Dissertations

Magnetohydrodynamic (MHD) generation of electric power has the potential to increase the thermal efficiency of fossil-fuel burning power plants. Electrode materials in MHD generators must possess a high melting point, high electrical and thermal conductivities, chemical stability, and resistance to thermal shock, oxidation, and plasma sparks/arcs. Ultra-high temperature ceramics based on diborides of zirconium and hafnium (ZrB2 and HfB2) are promising materials for this application. Self-propagating high-temperature synThesis (SHS) is an attractive method for their large-scale fabrication, but SHS of ZrB2 and HfB2 from elemental Zr, Hf, and B is not economically viable because of the high cost of the …

Methods For Producing Graphene From Petroleum By-Products, Eva M. Deemer

Open Access Theses & Dissertations

N/A

Test Methods For The Fracture And Fatigue Crack Growth Behavior Of Hot Mix Asphalts, Eduardo Garcia

Open Access Theses & Dissertations

The service life and mechanical properties of bituminous mixtures are greatly affected by distress problems such as fracture, thermal cracking, and fatigue cracking of the asphalt layers. The fracture and fatigue crack growth (FCG) behavior of bituminous mixtures are difficult to quantify due to material-, test-, and equipment-related uncertainties. The goal of this study is to introduce a systematic fracture and fatigue crack growth testing approach for hot mix asphalts (HMAs). The objective is to experimentally evaluate the fracture resistance and fracture toughness behavior of a dense-graded HMA material at different temperatures and varying thicknesses. The effect of thickness on …

On Demand 3d Printed Hybrid Scaffolds For Tissue Engineering Applications, Ivan D. Hernandez

Open Access Theses & Dissertations

A composite 3D printed polymer scaffold with inbuilt porosity and filled with a hydrogel can provide an ideal support system for cell growth, proliferation, and vascularization. Therefore, a hybrid system of 3D printed polycaprolactone (PCL) scaffold and a hydroxyapatite-based hydrogel was developed for application in the reconstruction of bone defects, which are inherently difficult to repair without any guided therapies. In the present study, a 3D printed gyroid structure of PCL allowed the loading of a higher amount of hydrogel as compared to conventionally used 3D printed mesh structure of the same volume and strut thickness. The hydrogel was composed …

Ac Susceptibility And Epr Investigations Of Superspin Dynamics In Manganese Oxide Nanoparticles, Mahesh Koirala

Open Access Theses & Dissertations

We have investigated the superspin dynamics of 5 nm and 10 nm mixed state Mn3O4 nanoparticles utilizing ac-susceptibility and electron paramagnetic resonance measurements. The out of phase component of the ac-susceptibility measurements show a magnetic anomaly below (T

Protonic Conductors For Intermediate Temperature Fuel Cell Electrolytes: Superprotonic Csh2po4 Stabilization And In-Doped Snp2o7 Structure Study, Heber Jair Martinez Salinas

Open Access Theses & Dissertations

Proton conductor solid electrolytes CsH2PO4 and In-doped tin pyrophosphate have been investigated as candidates to fill a gap of suitable electrolytes for fuel cells at the intermediate temperature range due their unusually high conductivities between 200 and 300 °C. Unfortunately, in the case of CsH2PO4, complicated experimental conditions, like a humidified environment, or high pressure, are needed to preserve the sought high conducting phase.

In the first stage of this work, X-ray diffraction on CsH2PO 4 samples performed in air, and under normal conditions of humidity and pressure, evidence of the cubic phase of CsH2PO4 was observed during short intervals …

Structural And Mechanical Characterization Of Nanocrystalline Tungsten And Tungsten-Based Alloy Thin Films For Extreme Environment Applications, Gustavo Martinez

Open Access Theses & Dissertations

Extreme environments associated with nuclear applications often results in degradation of the physical, mechanical and thermo-mechanical properties of the materials. Tungsten (W) exhibits unique physical and mechanical properties, which makes tungsten a good candidate for nuclear applications; however, intrinsic W exhibits low fracture toughness at all temperatures in addition to a high ductile to brittle transition. In the present work, nanocrystalline W, W-Y and W-Mo alloys were nanoengineered for nuclear applications. Nanocrystalline tungsten coatings with a thickness of ~1 µm were deposited onto Silicon (100) and Sapphire (C-plane) using RF and DC sputtering techniques under various growth conditions. Yttrium content …

Raman Microscopic Analysis Of Internal Stress In Boron-Doped Diamond Thin Films, Emma M.A. Sundin

Open Access Theses & Dissertations

The correlations between induced stress on undoped and boron-doped diamond (BDD) thin films, sample chemical composition, and fabrication substrate are investigated in this study via confocal Raman microspectroscopic analysis. Stability of BDD films is relevant to fast-scan cyclic voltammetry, as film delamination and dislocation of BDD-coated electrodes that can occur during neurosurgical electrode implantation can negatively impact the biosensing reliability of this technique. Electrodes were fabricated by coating cylindrical tungsten rods using a custom-built chemical vapor deposition reactor. The results of the analysis reveal a direct correlation between regions of pure diamond and enhanced material stress, as well as preferential …

Structural And Electrical Characterization Of Tin Oxide Resistive Switching, Arka Talukdar

Open Access Theses & Dissertations

Resistive switching in metal oxide is a phenomenon in which the metal oxide changes its resistance upon application of electric field and thus giving two states; high resistance state (HRS) and low resistance state (LRS). Many metal oxides have been investigated however very little is known about unipolar resistive switching in SnO2 though it has shown excellent resistive switching characteristics. Defects in the material play a vital role in resistive switching of the metal oxides. In this work, the role of defects in resistive switching of SnO2 are investigated in Ti/SnO2/Au structures. Two methods were used to control the concentration …

Comprehensive Finite Element Modeling Of Ti-6al-4v Cellular Solids Fabricated By Electron Beam Melting, Edel Arrieta

Open Access Theses & Dissertations

Additive manufacturing permits the fabrication of cellular metals which are materials that can be highly customizable and possess multiple and extraordinary properties such as damage tolerance, metamorphic and auxetic behaviors, and high specific stiffness. This makes them the subject of interest for innovative applications. With interest in these materials for energy absorption applications, this work presents the development of nonlinear finite element models in commercial software platforms (MSC Patran/Nastran) that permit the analysis of the deformation mechanisms of these materials under compressive loads. In the development of these models, a detailed multiscale study on the different factors affecting the response …

Characterization & Extraction Of Extracellular Matrix From Porcine Adipose Tissue, Rahulkumar Kantibhia Bhoi

Open Access Theses & Dissertations

Tissue in particular extracellular matrix(ECM) plays a vital role in the growth and the function of each cell types and promote tissue regeneration and repair an impair organs. Many techniques have been developed so far to decellularized porcine tissue for the purpose to use as regenerative medicine and in tissue engineering. We aimed to optimized a method to decellularized porcine tissue while effectively eliminating xenogeneic epitopes, lipids and to retain necessary component of it intact without disrupting ECM. We have developed 2-week protocol to optimize well preserved ECM component that may keep xenogeneic biomaterial for tissue engineering and regenerative medicine. …

Studies Of Ionic Liquid Hybrids: Characteristics And Their Potential Application To Li-Ion Batteries And Li-Ion Capacitors, Mengxin Liu

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Ionic liquids (ILs) have attracted much attention in electrochemical energy storage systems for their advantageous properties over traditional lithium salt/carbonate solvent electrolyte in terms of higher electrochemical potential windows, comparable ionic conductivity, negative vapor pressure and non-flammability. Ionic liquids can be used as the solvent-free electrolyte in electrochemical double layer capacitors (EDLCs) or can act as the important additives to the carbonate electrolyte in lithium ion batteries (LIBs). Recently, lithium ion capacitors (LICs) have emerge as a novel energy storage system to satisfy the demands for higher energy density and higher power density in portable and transportation systems. This Master …

Synthesis And Characterizations Of Lithium Aluminum Titanium Phosphate (Li1+Xalxti2-X(Po4)3) Solid Electrolytes For All-Solid-State Li-Ion Batteries, Jianping Yang

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New-generation low-emission transportation systems demand high-performance lithium ion (Li-ion) batteries with high safety insurance at broad operable temperatures. Highly conductive solid electrolyte is one of the key components for such applications. The objective of this thesis is to synthesize and characterize aluminum doped lithium titanium phosphate, i.e. Li1+xAlxTi2-x(PO4)3 (LATP), one of the solid-state electrolytes for potential applications to all solid-state lithium-ion batteries. In this research, sol-gel method and one step solid-state reaction approaches were explored and critical processes were optimized towards maximizing lithium ion conductivities at room temperature. The impacts of the processing conditions on the structures, morphologies, compositions of …

Investigation Of Residual Stresses In Melt Infiltrated Sic/Sic Ceramic Matrix Composites Using Raman Spectroscopy, Kaitlin Noelle Kollins

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Ceramic matric composites (CMCs) are being developed for use in extreme operating conditions. Specifically, there is interest to replace superalloys with Silicon Carbide/Silicon Carbide (SiC/SiC) CMCs in the hot section of gas turbine engines because of their lower densities, high temperature performance, and oxidation resistance. Residual stresses in SiC/SiC CMCs are a direct result of the high temperature processing conditions, a mismatch in the coefficients of thermal expansion between composite constituents, and silicon crystallization expansion upon cooldown. Understanding the residual stress state and magnitudes of these stresses will enable better prediction of behavior and life performance in application environments. This …

Low-Drag Events In Transitional Wall-Bounded Turbulence, Richard D. Whalley, Jae Sung Park, Anubhav Kushwaha, David J.C. Dennis, Michael D. Graham, Robert J. Poole

Department of Mechanical and Materials Engineering: Faculty Publications

Intermittency of low-drag pointwise wall shear stress measurements within Newtonian turbulent channel flow at transitional Reynolds numbers (friction Reynolds numbers 70 – 130) is characterized using experiments and simulations. Conditional mean velocity profiles during low-drag events closely approach that of a recently discovered nonlinear traveling wave solution; both profiles are near the so-called maximum drag reduction profile, a general feature of turbulent flow of liquids containing polymer additives (despite the fact that all results presented are for Newtonian fluids only). Similarities between temporal intermittency in small domains and spatiotemporal intermittency in large domains is thereby found.

Flowtaxis Of Osteoblast Migration Under Fluid Shear And The Effect Of Rhoa Kinase Silencing, Brandon D. Riehl, Jeong Soon Lee, Ligyeom Ha, Il Keun Kwon, Jung Yul Lim

Department of Mechanical and Materials Engineering: Faculty Publications

Despite the important role of mechanical signals in bone remodeling, relatively little is known about how fluid shear affects osteoblastic cell migration behavior. Here we demonstrated that MC3T3-E1 osteoblast migration could be activated by physiologically-relevant levels of fluid shear in a shear stress-dependent manner. Interestingly, shear-sensitive osteoblast migration behavior was prominent only during the initial period after the onset of the steady flow (for about 30 min), exhibiting shear stress-dependent migration speed, displacement, arrest coefficient, and motility coefficient. For example, cell speed at 1 min was 0.28, 0.47, 0.51, and 0.84 μm min^-1 for static, 2, 15, and 25 …

Fluid-Structure Interaction In Abdominal Aortic Aneurysm: Effect Of Modeling Techniques, Shengmao Lin, Xinwei Han, Yonghua Bi, Siyeong Ju, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, the impact of modeling techniques on predicting the mechanical behaviors of abdominal aortic aneurysm (AAA) is systematically investigated. The fluid-structure interaction (FSI) model for simultaneously capturing the transient interaction between blood flow dynamics and wall mechanics was compared with its simplified techniques, that is, computational fluid dynamics (CFD) or computational solid stress (CSS) model. Results demonstrated that CFD exhibited relatively smaller vortexes and tends to overestimate the fluid wall shear stress, compared to FSI. On the contrary, the minimal differences in wall stresses and deformation were observed between FSI and CSS models. Furthermore, it was found that …

High Temperature Near-Field Nanothermomechanical Rectification, Mahmoud Elzouka, Sidy Ndao

Department of Mechanical and Materials Engineering: Faculty Publications

Limited performance and reliability of electronic devices at extreme temperatures, intensive electromagnetic fields, and radiation found in space exploration missions (i.e., Venus & Jupiter planetary exploration, and heliophysics missions) and earth-based applications requires the development of alternative computing technologies. In the pursuit of alternative technologies, research efforts have looked into developing thermal memory and logic devices that use heat instead of electricity to perform computations. However, most of the proposed technologies operate at room or cryogenic temperatures, due to their dependence on material’s temperature-dependent properties. Here in this research, we show experimentally—for the first time—the use of near-field thermal radiation …

Surface Charge Switchable And Ph-Responsive Chitosan/Polymer Core-Shell Composite Nanoparticles For Drug Delivery Application, W. F. Huang, C. P. Tsui, M. Yang, Linxia Gu

Department of Mechanical and Materials Engineering: Faculty Publications

The mutually conflicting surface charge requirements for nanoparticles to have long circulation and good cell affinity have made the development of polymer nanoparticles for controlled drug delivery fall into a dilemma. In order to solve this problem, the first attempt has been made in this work to develop vancomycin loaded composite nanoparticles with a novel chitosan core and poly (lactide-co-glycolide) (PLGA) shell structure and with both pH-responsive and surface charge switchable properties. Spherical composite nanoparticles have been successfully fabricated through a modified emulsion-gelation method with a controllable size (316–573 nm), surface charge (–27.6–31.75 mV) and encapsulation efficiency up to 70.8%. …

Molecular Dynamics Simulations Of Heterogeneous Cell Membranes In Response To Uniaxial Membrane Stretches At High Loading Rates, Lili Zhang, Zesheng Zhang, John Jasa, Dongli Li, Robin O. Cleveland, Mehrdad Negahban, Antoine Jérusalem

Department of Mechanical and Materials Engineering: Faculty Publications

The chemobiomechanical signatures of diseased cells are often distinctively different from that of healthy cells. This mainly arises from cellular structural/compositional alterations induced by disease development or therapeutic molecules. Therapeutic shock waves have the potential to mechanically destroy diseased cells and/or increase cell membrane permeability for drug delivery. However, the biomolecular mechanisms by which shock waves interact with diseased and healthy cellular components remain largely unknown. By integrating atomistic simulations with a novel multiscale numerical framework, this work provides new biomolecular mechanistic perspectives through which many mechanosensitive cellular processes could be quantitatively characterised. Here we examine the biomechanical responses of …

High-Velocity Projectile Impact Induced 9r Phase In Ultrafine-Grained Aluminium, Sichuang Xue, Zhe Fan, Olawale B. Lawal, Ramathasan Thevamaran, Qiang Li, Yue Liu, K. Y. Yu, Jian Wang, Edwin L. Thomas, Haiyan Wang, Xinghang Zhang

Department of Mechanical and Materials Engineering: Faculty Publications

Aluminium typically deforms via full dislocations due to its high stacking fault energy. Twinning in aluminium, although difficult, may occur at low temperature and high strain rate. However, the 9R phase rarely occurs in aluminium simply because of its giant stacking fault energy. Here, by using a laser-induced projectile impact testing technique, we discover a deformation-induced 9R phase with tens of nm in width in ultrafine-grained aluminium with an average grain size of 140 nm, as confirmed by extensive post-impact microscopy analyses. The stability of the 9R phase is related to the existence of sessile Frank loops. Molecular dynamics simulations …