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Articles 61 - 90 of 176
Full-Text Articles in Engineering Science and Materials
Tungstate/Pertungstate System Cathodic Indirect Oxidation To Synthesis Hydrophobic Monascus Yellow Colorant, Wen-Jian Chen, Xue-Hong Huang, Zhen Chen, Sheng-Bo Ke, You-Zhen Lin
Tungstate/Pertungstate System Cathodic Indirect Oxidation To Synthesis Hydrophobic Monascus Yellow Colorant, Wen-Jian Chen, Xue-Hong Huang, Zhen Chen, Sheng-Bo Ke, You-Zhen Lin
Journal of Electrochemistry
Using SBS-g-(AA/StSO3Na)/SBS-g-DMAEMA Bipolar Membrane as a separator between the cathode and anode chambers in the electrolysis cell,the optimum conditions of deoxidization of oxygen in cathode were obtained through orthogonal experiment. Then using tungstate/pertungstate as media to indirect electrooxidate hydrophobic monascus red colorant to prepare hydrophobic monascus yellow colorant in cathode. The experiment results show the average current efficiency of cathode was up to 72.39% under the following conditions:that graphite as electrode,10% sulfuric acid as anode electrolyte,0.5 g·L-1 hydrophobic monascus red colorant solution as cathode electrolyte,tungstate concentration:15 mmol/L,pH=3,flow rate of oxygen:65 cm3/min,electrolyze 2 h under the …
Electrocatalytic Oxidation Of Glucose On Cnt/Nanocrystlline Tio2-Pt Complex Film Electrode In Ionic Liquids, Dao-Bao Chu, Long-Wu Zha, Shu-Xi Wang, Jian Wang, Ying Xiao, Yuan-Yuan Hou, Jian-Guo He, Xue-Jiao Zhang
Electrocatalytic Oxidation Of Glucose On Cnt/Nanocrystlline Tio2-Pt Complex Film Electrode In Ionic Liquids, Dao-Bao Chu, Long-Wu Zha, Shu-Xi Wang, Jian Wang, Ying Xiao, Yuan-Yuan Hou, Jian-Guo He, Xue-Jiao Zhang
Journal of Electrochemistry
Using ionic liquid [EMI]BF4 as the electrolyte,the electrocatalytic oxidation of glucose on carbon nanotubes/nanocrystlline TiO2 film loaded on Pt (CNT/nanoTiO2-Pt) complex film electrode was investigated by cyclic voltammetry. The results found that the CNT/nanoTiO2-Pt complex electrode had high catalytic activity to the electrochemical oxidation of glucose in ionic liquids and the oxidation potential was -0.46 V. The best effect of glucose oxidation was obtained with the volume ratio of ionic liquid to water being 3:1. The process of electrodic reaction process was concentration polarization controlled.
Electrochemical Properties Of Ru-P/Mwcnts-Dhp/Gc Electrode, Miao-Jing Chen, Bao-Yi Lu, Wen-Jie Mei, Hong Li
Electrochemical Properties Of Ru-P/Mwcnts-Dhp/Gc Electrode, Miao-Jing Chen, Bao-Yi Lu, Wen-Jie Mei, Hong Li
Journal of Electrochemistry
Electrochemical properties of a novel monoruthenated porphyrin [Ru(phen)2(MPyTMPP)Cl]+ (where phen =1,10-phenanthroline,MPyTMPP =5-(3-pyridyl)-10,15,20-tris-(4-methylphenyl) porphyrin) on a multi-walled carbon nanotubes (MWCNTs) modified glassy carbon (GC) electrode with the participation of dihexadecyl phosphate (DHP) have been investigated by using cyclic voltammetry,differential pulse voltammetry,UV-Visible spectroscopy and fluorescence spectroscopy. It is found that [Ru(phen)2(MPyTMPP)Cl]+ has the ability to adsorb strongly onto the MWCNTs-DHP modified GC electrode and exhibits a pair of redox waves controlled by surface electrochemical process. DHP dispersed on the MWCNTs/GC electrode can facilitate the ruthenium complex to adsorb onto the MWCNTs-DHP surface. A new complex is generated by the …
Ellipsometric Study On Colored Electroplating Of Cuprous Oxide On Ni Substrate, Xue-Song Feng, Jing-Lei Lei, Ai-Xiang Chen, Wan-Shan Yin, Ling-Jie Li, Sha Zheng, Hui Zhao, Shao-Yan Pan
Ellipsometric Study On Colored Electroplating Of Cuprous Oxide On Ni Substrate, Xue-Song Feng, Jing-Lei Lei, Ai-Xiang Chen, Wan-Shan Yin, Ling-Jie Li, Sha Zheng, Hui Zhao, Shao-Yan Pan
Journal of Electrochemistry
The colored Cu2O coating was electroplated on Ni substrate to meet the decorative requirements. Results of X-ray photoelectron spectroscopy (XPS) indicate the coating consisting of Cu2O. Images of scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) show that the Cu2O coating is smooth and uniform,and covers the Ni substrate wholly. Ellipsomtric measurements for Cu2O coatings with various electroplating time were carried out. Using a 4-layer model of "Air-Cu2O layer-interphase-Ni" ,the interphase was modeled with the graded effective medium approximation (EMA),the ellipsomtric data were deconvoluted and the Cu2O …
Doppler Broadening Analysis Of Steel Specimens Using Accelerator Based In Situ Pair Production, V. Makarashvili, Douglas P. Wells, Ajit K. Roy
Doppler Broadening Analysis Of Steel Specimens Using Accelerator Based In Situ Pair Production, V. Makarashvili, Douglas P. Wells, Ajit K. Roy
Mechanical Engineering Faculty Research
Positron Annihilation Spectroscopy (PAS) techniques can be utilized as a sensitive probe of defects in materials. Studying these microscopic defects is very important for a number of industries in order to predict material failure or structural integrity. We have been developing gamma‐induced pair‐production techniques to produce positrons in thick samples ( ∼4–40 g/cm2, or ∼0.5–5 cm in steel). These techniques are called ‘Accelerator‐based Gamma‐induced Positron Annihilation Spectroscopy’ (AG‐PAS). We have begun testing the capabilities of this technique for imaging of defect densities in thick structural materials. As a first step, a linear accelerator (LINAC) was employed to produce photon beams …
Characterization And Enhancement Of Sensing Properties Of Piezoelectric Materials With Applications To Vibration Suppression, Siddharth Aphale
Characterization And Enhancement Of Sensing Properties Of Piezoelectric Materials With Applications To Vibration Suppression, Siddharth Aphale
All Theses
This thesis undertakes the study of piezoelectric properties of polymer-based fabric and film sensors. An enhancement in piezoelectric properties of such sensors, as noted through earlier work, is observed with increasing weight ratios of nanomaterials dispersed in the polymer matrix. A comprehensive mathematical model using cantilever beams is developed to analyze this enhancement both qualitatively and quantitatively. An experimental setup is also developed to implement the proposed real time signal processing necessary to collect required data towards the characterization. In order to distinguish piezoelectric materials from other materials, study of the frequency response of developed fabric sensors to periodic chirp …
On The Modeling Of Energy Harvesters And Analysis Of Their Response Under Time-Varying Frequency Excitations, Thiago Seuaciuc-Osorio
On The Modeling Of Energy Harvesters And Analysis Of Their Response Under Time-Varying Frequency Excitations, Thiago Seuaciuc-Osorio
All Theses
Energy harvesting is a process by which otherwise wasted ambient energy can be captured and transformed into a useful form. Historical examples of this concept include windmills, sailing ships, and waterwheels. Modern technologies and current energy needs have brought this same concept to a smaller scale wherein small wireless devices with minute energy consumption can be operated autonomously. Today, many critical electronic devices, such as health-monitoring sensors, pace makers, spinal stimulators, electric pain relievers, etc. require minimal amounts of power to function, which permits utilizing energy from their environment to power them. By exploiting the ability of active materials and …
Development Of A Rigid Ring Tire Model And Comparison Among Various Tire Models For Ride Comfort Simulations, Norm Frey
All Theses
One vehicle subassembly that is of great importance to automobile manufacturers for tuning final vehicle performance is the pneumatic tire. Pneumatic tires present themselves as unique tuning tools as they 1) are the sole link between the roadway surface and the integrated vehicle suspension, chassis and steering systems, and 2) provide a wide range of tunability over many vehicle performances, including handling (steering feel as well as chassis dynamics), traction (braking, driving, and cornering), and ride comfort (roadway isolation). Therefore the vehicle manufacturing industry continues to research and refine various aspects of tire modeling to improve up-front integrated tire/vehicle CAE/CAD …
Use Of Orthogonal Arrays For Efficient Evaluation Of Geometric Designs For Reducing Vibration Of A Non-Pneumatic Wheel During High-Speed Rolling, William Rutherford
Use Of Orthogonal Arrays For Efficient Evaluation Of Geometric Designs For Reducing Vibration Of A Non-Pneumatic Wheel During High-Speed Rolling, William Rutherford
All Theses
During high speed rolling of a non-pneumatic wheel, vibration may be produced by the interaction of collapsible spokes with a shear deformable ring as they enter the contact region, buckle and then snap back into a state of tension. In the present work, a 2D planar finite element model with geometric nonlinearity and explicit time-stepping is used to simulate rolling of the non-pneumatic wheel. Vibration characteristics are measured from the FFT frequency spectrum of the time-signals of perpendicular distance of marker nodes from the virtual plane of the spoke, thickness change in the ring between spokes, and ground reaction forces. …
Survey Of Concurrent Engineering Environments And The Application Of Best Practices Towards The Development Of A Multiple Industry, Multiple Domain Environment, Jonathan Osborn
All Theses
This thesis investigates the best practices of fifteen existing Concurrent Engineering Environments (CEE). A CEE is defined as any environment, from physical to virtual, designed to facilitate concurrent engineering with multiple domain experts real time. All existing environments surveyed have been focused on the aerospace industry showing significant reductions in design time and cost. I have identified hardware, software, and peopleware as three major classifications as well as sixteen subcategories with which to compare the different CEEs. The success in reducing time and cost of designs seen in the aerospace industry with the introduction of CEEs can and should be …
Dynamic Finite Element Simulation Of Ultrasonic Consolidation, Daniel Mccullough
Dynamic Finite Element Simulation Of Ultrasonic Consolidation, Daniel Mccullough
All Theses
Ultrasonic Consolidation (UC) is a promising solid state rapid manufacturing process that provides the ability to create functional, multilayered, and often geometrically complex parts. This thesis seeks to address one of the primary obstacles faced when using the process, namely the apparent build height limit encountered when using UC to construct high aspect ratio specimens. A fully transient, three dimensional Finite Element model is created to study the dynamic behavior of an ultrasonically consolidated part during the UC process. The model is used to find the cause of bond failure at the build height limit and a potential way to …
Predictive Energy Management In Smart Vehicles: Exploiting Traffic And Traffic Signal Preview For Fuel Saving, Behrang Asadi
Predictive Energy Management In Smart Vehicles: Exploiting Traffic And Traffic Signal Preview For Fuel Saving, Behrang Asadi
All Theses
This master thesis proposes methods for improving fuel economy and emissions of vehicles via use of future information of state of traffic lights, traffic flow, and deterministic traffic flow models.
The first part of this thesis proposes use of upcoming traffic signal information
within the vehicle's adaptive cruise control system to reduce idle time at stop lights and lower fuel use. To achieve this goal an optimization-based control algorithm is formulated for each equipped vehicle that uses short range radar and traffic signal information predictively to schedule an optimum velocity trajectory for the vehicle. The objectives are timely arrival at …
Development And Integration Of Geometric And Optimization Algorithms For Packing And Layout Design, Santosh Tiwari
Development And Integration Of Geometric And Optimization Algorithms For Packing And Layout Design, Santosh Tiwari
All Dissertations
The research work presented in this dissertation focuses on the development and application of optimization and geometric algorithms to packing and layout optimization problems. As part of this research work, a compact packing algorithm, a physically-based shape morphing algorithm, and a general purpose constrained multi-objective optimization algorithm are proposed. The compact packing algorithm is designed to pack three-dimensional free-form objects with full rotational freedom inside an arbitrary enclosure such that the packing efficiency is maximized. The proposed compact packing algorithm can handle objects with holes or cavities and its performance does not degrade significantly with the increase in the complexity …
The Effects Of Combined Compression And Aging On The Properties Of Glassy Polycarbonate, Kyle W. Strabala
The Effects Of Combined Compression And Aging On The Properties Of Glassy Polycarbonate, Kyle W. Strabala
Department of Engineering Mechanics: Dissertations, Theses, and Student Research
Physical aging and plastic flow are known to cause changes in the properties of glassy polycarbonate (PC). Although the individual effects of physical aging and plastic flow have been studied, the combined mechanical and thermal effects have yet to be evaluated for PC at large plastic strains. This work is the first characterization of the combined effects in PC of large plastic flow followed by thermal (physical) aging. To conduct this study, samples were prepared with different extents of plastic compressive strain, up to approximately 50% engineering strain, followed by thermal aging up to 135 °C, with various …
Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira
Multiscale Modeling Of Glass Fiber Reinforced Viscoelastic Polymers Subjected To Impact Loads, Victor Ferreira Teixeira
Department of Engineering Mechanics: Dissertations, Theses, and Student Research
New applications for polymer composite materials are occurring at a rapid pace today. These include structural components in the energy, transportation, and biomedical fields. Many if not all of these new applications will require that part performance is insured with some degree of sustainable damage. With the growth in the use of composite structures comes the necessity of improved methodologies that can predict more accurately the life and serviceability conditions of composite parts. Damage mechanics in two-phase composite materials is a very complex problem that has challenged researchers for many years. However, most of the available models perform only a …
Flexible Electronics Using Ion Implantation To Adhere Polymer Substrate To Single Crystal Silicon Substrate, Terry L. Alford, Douglas C. Thompson Jr., Hyunchul Kim, Michael A. Nastasi, James W. Mayer, Daniel Adams
Flexible Electronics Using Ion Implantation To Adhere Polymer Substrate To Single Crystal Silicon Substrate, Terry L. Alford, Douglas C. Thompson Jr., Hyunchul Kim, Michael A. Nastasi, James W. Mayer, Daniel Adams
Department of Mechanical and Materials Engineering: Faculty Publications
An electronic apparatus uses a single crystalline silicon Substrate disposed adjacent to a flexible substrate. The electronic apparatus may be a flexible flat panel display, or a flexible printed circuit board. The flexible substrate can be made from polymer, plastic, paper, flexible glass, and stainless steel. The flexible substrate is bonded to the single crystalline substrate using an ion implantation process. The ion implantation process involves the use of a noble gas Such as hydrogen, helium, Xenon, and krypton. A plurality of semiconductor devices are formed on the single crystalline silicon Substrate. The semi conductor devices may be thin film …
Me-Em Enewsbrief, June 2009, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University
Me-Em Enewsbrief, June 2009, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University
Department of Mechanical and Aerospace Engineering eNewsBrief
No abstract provided.
Effect Of Liquid Dispersion On Corrosion Behavior Of Metals In Gas/Liquid/Solid Multiphase Corrosion Systems, Jing Jiang, Jia Wang
Effect Of Liquid Dispersion On Corrosion Behavior Of Metals In Gas/Liquid/Solid Multiphase Corrosion Systems, Jing Jiang, Jia Wang
Journal of Electrochemistry
Liquid dispersion,described by the parameters of gas/liquid/solid three-phase boundary(TPB) zone of dispersed liquid on a metal surface,is an important property of liquid state influencing corrosion behavior of metals in gas/liquid/solid multiphase corrosion systems.In our paper,the characterisation of cathodic oxygen reduction process in TPB zone was discussed,and a model describing the cathodic process of TPB zone was developed.On this basis,the relationship between the cathodic limiting current and the TPB parameters was studied,and the simulation results were in good agreement with the experimental data.The role of liquid dispersion in atmospheric and sandy soil corrosion systems was also simulated.
Electrodeposition Of Al On Magnesium Alloy In Ionic Liquid, Wen-Ta Tsai, Shu-You Chen, Mu-Huan Zhuang, Jeng-Kuei Chang, Yi-Wen Sun
Electrodeposition Of Al On Magnesium Alloy In Ionic Liquid, Wen-Ta Tsai, Shu-You Chen, Mu-Huan Zhuang, Jeng-Kuei Chang, Yi-Wen Sun
Journal of Electrochemistry
Electrodeposition of a metallic aluminum on a magnesium alloy in acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride ionic liquids(AlCl3-EMIC) was investigated.The effects of current density and AlCl3 content in the ionic liquid on the electrodeposition behavior were studied.The results showed that aluminum could be successfully electrodeposited on the AZ91D substrate.At-0.2 V,the ionic liquid containing 60 m/o AlCl3 was optimum for Al electrodeposition.The current efficiency was higher if electrodeposition was performed at a lower applied current density.The existence of Al coating could caused a substantial increase in open circuit potential,reducing the susceptibility of Mg alloy to corrosion.The results of electrochemical …
Electrochemical Characteristics Of Vitaminb6 At Polybromocresol Green Modified Electrode, Jun Yao, Jiang-Yuan Li, Yang Luo
Electrochemical Characteristics Of Vitaminb6 At Polybromocresol Green Modified Electrode, Jun Yao, Jiang-Yuan Li, Yang Luo
Journal of Electrochemistry
Electrochemical characteristics of VB6 were investigated at PBG modified electrode by Cyclic voltammetry and linear sweep voltammetry.The VB6 produced an irreversible oxidation peak at 0.978 V(Vs.SCE) in HAc-NaAc(pH=4.0) buffer solution over the potential range of 0.7 to 1.2 V.The electron number,the proton number,the transfer coefficient were determined to be 1,1 and 0.37,respectively.The oxidation peak currents of VB6 versus its concentration showed a linear relationship in the concentration range of 1×10-3~2×10-5mol/L with the correlation coefficient of 0.9967 and the detection limit of 2×10-6mol/L.The recovery was 100.06%.
Corrosion Performance Of Epoxy Coatings By Chemical Modification With Silanes, Liang Liu, Wei-Gang Ji, Ji-Ming Hu, Jian-Qing Zhang, Chu-Nan Cao
Corrosion Performance Of Epoxy Coatings By Chemical Modification With Silanes, Liang Liu, Wei-Gang Ji, Ji-Ming Hu, Jian-Qing Zhang, Chu-Nan Cao
Journal of Electrochemistry
The improvement of corrosion performance of epoxy coatings by modification with "active" and "non-active" silanes is presented."Active" silanes are defined as ones having functional groups that can react with the epoxy groups in the epoxy resin,usually amino-silanes."Non-active" silanes are defined as ones not reacting with the epoxy groups,but can react with the hydroxyl groups in the epoxy backbone by the condensation reactions under the catalysis of organic tin compounds.The FTIR results showed that both the "active" and "non-active" silanes had been successfully grafted onto the epoxy resin.Electrochemical impedance spectroscopy(EIS) and accelerated corrosion test(Machu test) showed that the corrosion performance of …
Electrode Of Metallic Oxides Coated Titanium With Interlayer, Yi Tang, Li-Kun Xu, Yong-Lei Xin, Jun-Tao Wang, Ping Long
Electrode Of Metallic Oxides Coated Titanium With Interlayer, Yi Tang, Li-Kun Xu, Yong-Lei Xin, Jun-Tao Wang, Ping Long
Journal of Electrochemistry
Various Ti/IrRuSn,Ti/IrTa/IrRuSn and Ti/IrTaSn/IrRuSn oxide electrodes were prepared by sol-gel method.The surface morphology and microstructure were analysed with FESEM and XRD.The electrochemical activity and stability were investigated using electrochemical technologies including chlorine and oxygen evolving potential measurements,cyclic voltammetry,accelerated life test,and alternative electrolysis.The results indicate that the electrodes with interlayers present more cracks on the surface and a little bigger average grain size,with particles of different shapes precipitated in the cracks.The electroactive sites are increased and the selectivity for the chlorine evolving reaction is enhanced,but the current efficiency for the chlorine production is somewhat lowered by the addition of different interlayers.The …
The Accelerated Test Of Simulated Atmospheric Corrosion And The Rust Evolution Of Low Carbon Steel, Jun-Hua Dong, Wei Ke
The Accelerated Test Of Simulated Atmospheric Corrosion And The Rust Evolution Of Low Carbon Steel, Jun-Hua Dong, Wei Ke
Journal of Electrochemistry
It has been set up an accelerated method of simulating to atmospheric corrosion by using wet/dry alternate test.The rust evolution rule of mass change vs time(in logarithmic coordinate) of low carbon steel under this test shows two linear sections with different slopes,in which the rust evolution transition in weight change corresponds to the compactness transition and crystallization transition during the rust layer growth.It has found that the rust evolution rule of low carbon steel in Wanning exposure site correlates to the rust evolution rule obtained by simulating the coastal atmospheric corrosion test,and the rust evolution rule of low carbon steel …
Investigation Of Electrochemical Noise In The Crevice Corrosion Of Q235 Carbon Cteel, Qian Hu, Yu-Bing Qiu, Xing-Peng Guo
Investigation Of Electrochemical Noise In The Crevice Corrosion Of Q235 Carbon Cteel, Qian Hu, Yu-Bing Qiu, Xing-Peng Guo
Journal of Electrochemistry
The crevice corrosion behavior of Q235 carbon steels in a NaHCO3+NaCl solution was investigated by electrochemical noise(EN) and electrochemical impedance spectroscopy(EIS).Three stages of crevice corrosion including the induction,the rapid transform and the stable development could be clearly distinguished.The characteristics of the electrochemical noise and the noise resistance Rn showed remarkable differences at each stage.The electrode area ratio(r) of outside to inside the crevice had a significant influence in the development of crevice corrosion.The time of the induction stage increased with increasing r.However,under the stable development stage of the crevice corrosion,the surface outside the crevice was at an active …
Effect Of Naphthalene Water Reducer On Corrosion Behavior Of Reinforcing Steel In Concrete, Yu-Ming Tang, Jie Zhang, Yu Zuo
Effect Of Naphthalene Water Reducer On Corrosion Behavior Of Reinforcing Steel In Concrete, Yu-Ming Tang, Jie Zhang, Yu Zuo
Journal of Electrochemistry
The influence of naphthalene water reducer on corrosion behavior of reinforcing steel in concrete was studied by the methods of corrosion potential measurement,linear polarization and EIS test.The values of concrete resistance(Rc) and polarization resistance(Rp) of the samples with naphthalene water reducer were higher than those without naphthalene water reducer,especially in the concrete with 0.2 percent naphthalene water reducer.A suitable amount of water reducer can improve the pore structures of concrete,increase the concrete compactness and impermeability,and decrease corrosion rate of rebars in concrete.
Effect Of Electrochemical Property Of Uns J91450 Stainless Steel On Stress Corrosion Cracking In Hydrogen Sulfide Solutions, Zhi-Yong Liu, Chao-Fang Dong, Xiao-Gang Li, Li-Xian Wang
Effect Of Electrochemical Property Of Uns J91450 Stainless Steel On Stress Corrosion Cracking In Hydrogen Sulfide Solutions, Zhi-Yong Liu, Chao-Fang Dong, Xiao-Gang Li, Li-Xian Wang
Journal of Electrochemistry
Effect of electrochemical behaviours on stress corrosion cracking(SCC) of UNS J91450 stainless steel in hydrogen sulfide environment was investigated using slow-strain-rate test(SSRT) and electchemial techniques.Results show that UNS J91540 stainless steel was susceptible to SCC in varying H2S solutions,and the SCC susceptibility reduced with the increase of pH value.The electrochemical property plays an important role in the SCC occurrence,as a combined effect of hydrogen embritlement and anodic dissolution at SCC cracktip at open circuit potential.In the solution with a lower pH the hydrogen revolution was intensive and the cracktip anodic dissolution was weaker,however,in the higher pH solution the …
Developments Of Scanning Electrochemical Probes And Their Applications In Studying Of Localized Corrosions, Chang-Jian Lin, Yan Li, Bin Lin, Rong-Gang Hu, Min Zhang, Xiang-Dong Zhuo, Rong-Gui Du
Developments Of Scanning Electrochemical Probes And Their Applications In Studying Of Localized Corrosions, Chang-Jian Lin, Yan Li, Bin Lin, Rong-Gang Hu, Min Zhang, Xiang-Dong Zhuo, Rong-Gui Du
Journal of Electrochemistry
The electrochemical inhomogeneities always exist at the interface of metal/solution,and play an important and often controlling role in localized corrosion of metals in a given environment.It is necessary to develop in situ imaging techniques for further studying the electrochemical and environmental inhomogeneities at the interface of metal/solution for the localized corrosion system.In this paper,various techniques with spatial resolution,such as scanning micro reference electrode(SMET),scanning electrochemical microscope(SECM),atomic force microscope(AFM),and scanning Kelvin probe(SKP),and their applications in corrosion studies were briefly reviewed.The chemical probes and array electrode have been developed.It was concentrated to describe our newly developed techniques of the scanning electrochemical probes,including SMET …
Preparation And Electrochemical Properties Of Layered Manganese Oxide(Li-Birnessite Type), Xing-Kang Huang, Hai-Tao Chang, Jian-Long Gan, Qing-Shun Zhang, Hong-Jun Yue, Dong-Ping Lv, Yong Yang
Preparation And Electrochemical Properties Of Layered Manganese Oxide(Li-Birnessite Type), Xing-Kang Huang, Hai-Tao Chang, Jian-Long Gan, Qing-Shun Zhang, Hong-Jun Yue, Dong-Ping Lv, Yong Yang
Journal of Electrochemistry
Layered Li-birnessite was prepared by means of oxidizing Mn2+ with O2 gas in alkaline media.The as-prepared sample was characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), BET and thermogravimetric/diffenential thermal analysis(TG/DTA) techniques. The electrochemical properties of the material were also investigated. The results show that such a Li-birnessite consists of well-crystallized spherical particles with an interlayer distance of 0.70 nm. The Li-birnessite delivered a high discharge capacity of 203 mAh/g at a rate of 0.2 C(40 mA/g), and had good rate capability as well.
Electrochemical Behavior Of Mg-Li Electrodes In Nacl Solution, Lin Wu, Yan-Zhuo Lv, Xue Cao, Gui-Ling Wang, Dian-Xue Cao
Electrochemical Behavior Of Mg-Li Electrodes In Nacl Solution, Lin Wu, Yan-Zhuo Lv, Xue Cao, Gui-Ling Wang, Dian-Xue Cao
Journal of Electrochemistry
The Mg-Li electrodes containing 8.5% and 14% Li were prepared using an induction melting method. Their electrochemical behavior in NaCl solution was investigated by means of potentiodynamic polarization, potentiostatic oxidation,electrochemical impedance technique and mass-loss measurements. The morphology of the electrodes after discharge was examined using scanning electron microscopy. The Mg-14Li electrode showed more negative open circuit potential and higher discharge current density than Mg-8.5Li electrode. The oxidation products of Mg-14Li loosely attached on the electrode surface and peeled off easily. The Mg-8.5Li exhibited higher utilization efficiency. Both electrodes gave higher utilization efficiencies when discharged at lower anodic potential.
Electrochemical Performance Of The Exfoliated Graphite Containing Sulfur Cathode Material For Lithium Sulfur Battery, Ke-Guo Yuan, Wei-Kun Wang, Zhong-Bao Yu, An-Bang Wang
Electrochemical Performance Of The Exfoliated Graphite Containing Sulfur Cathode Material For Lithium Sulfur Battery, Ke-Guo Yuan, Wei-Kun Wang, Zhong-Bao Yu, An-Bang Wang
Journal of Electrochemistry
The exfoliated graphite containing sulfur cathode material was prepared by the high temperature sulfur gas diffusion adsorption method.This cathode material could obtain an initial discharge specific capacity 972 mAh·g-1,capacity retention ratio 78% and cycling efficiency above 80%,respectively.The exfoliated graphite containing sulfur cathode could decrease the reaction interphase charge transfer impedance,and restrain the sulfur or polysulfide shuttle phenomenon during the charge-discharge process through improving the diffusion impedance.