Engineering Science and Materials Commons^™

Corrosion Behavior Of The Welding Seam Of The Q235 Steel Jointed By J420 Electrode In Ammonium Sulfite Solution, A-Li Lei, Qiao-Qin Guo, La-Jun Feng

Journal of Electrochemistry

The corrosion behavior of welding seam of the Q235 steel jointed by J420 electrode in ammonium sulfite solution was researched.The results of electrochemical method of welding seam and metallurgical structure analysis showed that the poor corrosion resisting property was determined by its structure after the Q235 steel was jointed by J420 electrode.The sulfite corrosion rate was accelerated by increasing the temperature and concentration of ammorium.

Preparation Of Spherical Ni(Oh)2 Coated With Coooh And Its Fast Charge Performance, Min-Jie Yang, Jun-Min Nan, Jian-Jun Xue, Yan Cui, Ming Cui

Journal of Electrochemistry

Spherical Ni(OH)₂ was coated with CoOOH through chemical precipitation and electrolytic oxidation.The influences of CoOOH coating on fast charge performance ofMH/Ni battery were studied by preparing high capacity and fast charge AA size MH/Ni batteries.The sample coated with CoOOH was characterized by Infrared spectrum(IR) and scanning electron microscopy(SEM).The results showed that the internal resistance decreased 3.4 mΩ,the charge plateau lower and the cell temperrature was below 55 ℃ at the end of charging process when the cathode active material used Ni(OH)₂ coated with CoOOH as compared with that doped by CoO.In addition,an initial discharge efficiency of 90.6% and …

Effect Of Preparation Conditions On Electroluminescence Of Porous Silicon, Ya-Jun Yang, Qing-Shan Li, Xian-Yun Liu, Ning Zhang, Bo Zhao, Xue-Gang Zheng, Ming-Ji Shi, Da Chen, Jing-Jing Wang

Journal of Electrochemistry

Electrically induced visible light emitting porous silicon devices with the structure of ITO/PS/p-Si/Al were fabricated by evaporation-anodic oxidation method.The light emission last for a few hours under 7.5V forward bias conditions.It was shown that the electroluminescence(EL) peaks shifted to the blue with the increasing of current density,erosion time and solution concentration.In order to achieve samples with low driven voltage,long light emission time and high EL efficiency,porous silicon should be prepared under low current density and short erosion time.

Electrochemical Impedance Spectrum Of Ferrocene At A Rotating Disk Glassy Carbon Electrode And Its Interaction With Dna, Can-Hui Chen, Hong Li, Jian-Zhang Zhou, Zhong-Hua Lin, Wei Zhu, Quan-Xin Zhang

Journal of Electrochemistry

The electrochemical impedance spectrum(EIS) of ferrocene(Fc) at a rotating glassy carbon(GC) electrode and its interaction with calf thymus DNA in Tris-NaCl buffer solution(pH=7.2) have been investigated by using electrochemical techniques such as rotating disk electrode(RDE),EIS and its data fitting.A plateau of the limiting current for the voltammetric curve and two capacitance arches obtained at the rotating GC electrode are exhibited.The interaction of Fc with DNA is represented by the decrease of limiting diffusion current and the increase of electrochemical reaction resistances with the increase of DNA concentration,respectively.On the other hand,based on the theoretical analysis and data fitting of RDE and …

Structure And Properties Of Electrodeposited Sn-Co Alloy Electrodes As Anode Material For Lithium-Ion Secondary Batteries, Hong-Hong Jiang, Ling Huang, Shun-Wei Zhou, Fu-Sheng Ke, Fang-Zu Yang, Xiao-Yong Fan, Shi-Gang Sun

Journal of Electrochemistry

The Sn-Co alloy deposits were prepared by electroplating.The structure and electrochemical performance of the electroplated Sn-Co alloys have been investigated in detail. Experimental results show that the porous Sn-Co alloy film exhibits hexagonal solid solution,with Sn as the solvent, Co as the solute. The texture of the Sn-Co alloy coating exhibits(110) preferred orientation. Electrochemical tests show that the porous Sn-Co alloy coating electrodes can deliver a discharge capacity of 643mAh/g in the first cycle. At the 20^h cycle the charge was 461mAh/g. At initial charge curve the irreversible capacity is probably associated to a combination of processes, which may …

High Density Lifepo4/C Synthesized By Controlled Crystallization And Microwave Carbon Thermal Reduction, Chang-Ping Tang, Jie-Rong Ying, Min Lei, Wei Li, Chang-Yin Jiang, Chun-Rong Wan

Journal of Electrochemistry

The spherical FePO₄·xH₂O was prepared in the solution by controlled crystallization.The precursor FePO₄ was obtained in high temperatureceramic approach,then the high density LiFePO₄ /C was synthesized by microwave carbon thermal reduction.The structure and morphology of the materials were characterized by means of XRD and SEM techniques,and the electrochemical properties were studies by charge-discharge experiments.

Effect Of Cracks On Corrosion Of Rebar In Concrete Studied By Wire Beam Electrode, Guo-Xi Li, Xian-Lu Hou, Ri-Long Zhu, Jin-Feng Hu, Yan-Na Du

Journal of Electrochemistry

The effects of crack and ethanolamine on corrosion of rebar in concrete were studied by measuring the distribution of corrosion potential and polarization resistance of iron wires in 10% NaCl solution.The results showed that the diffusion of water,oxygen and chloric ion toward concrete was accelerated by the crack which intensified the nonuniform corrosion of iron wire with the regions near to crack as anode and the uncracked regions as cathode.Ethanolamine could diffuse into the body of concrete and absorb on the surface of iron wire,which reduced iron corrosion evidently and successfully inhibited the nonuniform corrosion caused by crack without changing …

Tyrosinase Immobilizarion On Boron-Doped Diamond Electrodes And The Determination Of Phenolic Compounds, Yan-Li Zhou, Jin-Fang Zhi

Journal of Electrochemistry

As-grown BDD surfaces were first functionalized by photochemically linking vinyl groups of allylamine,producing covalently linked amine-terminated active BDD surfaces.Then the tyrosinase was immobilized onto the BDD surface through peptide linking.Cyclic voltammograms of phenol,pcresol and hydroquinone were measured using the tyrosinase-modified BDD electrode and amperometric characteristics such as sensitivity,linear response range and stability were studied.

Electrochemical Studies On Electrocatalytic Activity Of AuCore PtShell Nanoparticles To Methanol Oxidation, Fang Bao, Jian-Lin Yao, Ren-Ao Gu

Journal of Electrochemistry

Au_corePt_shell nanoparticles with different thicknesses were prepared by using chemical reduction method,and characterized by ultraviolet-visible spectroscopy(UV-Vis),transmission electron microscopy(TEM) and cyclic voltammetry(CV).The electrocatalytic activity of Au_corePt_shell nanoparticles with the mean diameter of 70~80 nm to methanol oxidation was investigated by cyclic voltammetry in the acid solution.The results revealed that the prepared core-shell nanoparticles were covered by Pt shell and exhibited the similar optical property and electrocatalytic activity with the normal Pt surface.Moreover,the electrocatalytic activity increased with the electrochemical sweep in the certain potential range.It might be contributed by the special loose structure of Pt shell …

Electrochemical Preparation Of Gd-Ni Alloy Film In Acetamide-Urea-Nabr Melt, Bi-Qing Chen, Jian-Chao Wang, Chen-Yu Guo, Jin-Gui Wang, Qing Liu

Journal of Electrochemistry

Cyclic voltammetry was used to study the electroreduction of Ni²⁺ to Ni on Pt and Cu electrode in acetamide-urea-NaBr melt at 353K.It is irreversible in one step.At Pt and Cu eletrode the diffusion coefficient and electron transfer coefficient of Ni²⁺ in 0.063mol/dm³) NiCl₂-acetamide-urea-NaBr melt were determined.The transfer coefficient α=0.28 and diffusion coefficient D_(0)=4.63×10^-5 cm²·s^-1 of the Pt eletrode and transfer coefficient α=0.22 and diffusion coefficient D_(0)=6.05×10^-7 cm²·s^-1 of the Cu eletrode were measured.It was put emphasis on that Gd³⁺ is not reduced to Gd alone …

Study On Composite Organic Inhibitor Of Zinc Electrode In Alkaline Solutions, Xue-Tao Bu, Guang-Chuan Liang, Cui Li

Journal of Electrochemistry

The synergetic influence of sodium dodecyl benzene sulfonate(SDBS) with Tween-20(Tween) on zinc electrode was studied by polarization experiment,surface tension test,discharge test and SEM.It is found that the composite inhibitor ST has a much higher efficiency.The addition of Tween reduced the critical micell concentration of SDBS on zinc electrode remarkably and the distribution of adsorption became more homogeneous.ST inhibits corrosion of zinc electrode and improves discharge capacity of the whole battery.Through electrochemical morphological observation of anodic passivation behaviors of zinc electrode,the absorption of ST on electrode surface makes discharged production much smaller and keeps crude porous structure intact.Passivation of zinc electrode …

College Of Engineering Senior Design Competition Spring 2006, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Part of every UNLV engineering student’s academic experience, the senior design project stimulates engineering innovation and entrepreneurship. Each student in their senior year chooses, plans, designs and prototypes a product in this required element of the curriculum. A capstone to the student’s educational career, the senior design project encourages the student to use everything learned in the engineering program to create a practical, real world solution to an engineering challenge.

The senior design competition helps to focus the senior students in increasing the quality and potential for commercial application for their design projects. Judges from local industry evaluate the projects …

Modeling And Representation Of Geometric Tolerances Information In Integrated Measurement Processes, Xiaoping Zhao, T. M. Kethara Pasupathy, Robert G. Wilhelm

Department of Mechanical and Materials Engineering: Faculty Publications

Modeling and representation of geometric tolerances information across an enterprise is viable due to the advances in Internet technologies and increasing integration requirements from industry. In Integrated Measurement Processes (IMP), geometric tolerances data model must support different models from several well-defined standards: including ASME Y14.5M-1994, STEP, DMIS, and others. In this paper, we propose a layered conformance level geometric tolerances representation model. This model uses the widely applied ASME Y14.5M-1994 as its foundation layer by abstracting most information from this standard. The additional geometric tolerances information defined by DMIS and STEP is incorporated into this model to form corresponding conformance …

Experimental And Finite Element Analysis Of Preloaded Bolted Joints Under Impact Loading, Brendan O'Toole, Kumarswamy Karpanan, Masoud Feghhi

Mechanical Engineering Faculty Research

One of the primary parameters in analyzing bolted joints is preload in the bolt. We have considered several possible preload modeling techniques to analyze the effect of preload on the dynamic response of the bolted joints. Five different methods of applying preload in the nonlinear finite element analysis are evaluated. These methods are “force on bolt and nut”, “force on bolt shank”, “interference fit”, “thermal gradient” and “initial stress method”. Explicit and implicit analyses are used for transient response and preload generation in bolt respectively. Time history and shock response spectrum are used to compare experimental and simulation results. Simulation …

Energy Efficient Process Heating: Managing Air Flow, Kevin Carpenter, J. Kelly Kissock

Mechanical and Aerospace Engineering Faculty Publications

Much energy is lost through excess air flow in and out of process heating equipment. Energy saving opportunities from managing air flow include minimizing combustion air, preheating combustion air, minimizing ventilation air, and reconfiguring openings to reduce leakage.

This paper identifies these opportunities and presents methods to quantify potential energy savings from implementing these energy-savings measures. Case study examples are used to demonstrate the methods and the potential energy savings.The method for calculating savings from minimizing combustion air accounts for improvement in efficiency from increased combustion temperature and decreased combustion gas mass flow rate.

The method for calculating savings from …

Flexible Tools For Specifying Design Variation, Trichy Pasupathy, Xiaoping Zhao, Robert Wilhelm

Department of Mechanical and Materials Engineering: Faculty Publications

This paper describes flexible tools for specifying design variations that are based on nonuniform profile tolerance definitions. These tools specify bounds of design performance that can be used for negotiation among engineers in a collaborative design process. These specification methods allow for the capture of many different design functions that are not easily described with current tool designs. In addition, these specification methods lend themselves to efficient verification methods. Profile tolerance definitions provide the most general variation controls for complex mechanical surfaces. Common design practices and engineering standards for profile tolerances exhibit many weaknesses and limitations. We present a rationale …

Analysis And Simulation Of Hypervelocity Gouging Impacts, John D. Cinnamon

Theses and Dissertations

In this work, a summary of past and present research efforts, as well as the theoretical foundation, of hypervelocity gouging is presented. As the Holloman AFB High Speed Test Track (HHSTT) sled's speed has increased to Mach 8.5, material interactions develops which causes "gouging" - this can result in catastrophic failure. A characterization of gouging, including a thermodynamic history, is developed from an examination of a gouged rail. An extensive study is performed that determines the specific material flow models for VascoMax 300 and 1080 steel. The models are validated utilizing several experimental tests which are successfully simulated using CTH …

Application Of Spline Variational Analysis Method In The Modeling Of Composite Repairs, Brian M. Fredrickson

Theses and Dissertations

The purpose of this thesis is to apply a non-commercialized spline-based (BSpline Analysis Method or BSAM) computer program to model and predict strain fields in two composite repairs, a scarf joint and a stepped-lap joint, subjected to static tensile loading. Test specimens with scarf and stepped-lap joints are fabricated using quasiisotropic sixteen ply panels made from IM6/3501-6 prepreg with a [+45₂/0₂/-45₂/90₂]_s lay-up. The panels were bonded together with FM-300M (0.05psf), a 176°C cure film adhesive, under positive pressure. A total of five coupons of each joint type are made. Two of …

Characterization Of Compressive Creep Behavior Of Oxide/Oxide Composite With Monazite Coating At Elevated Temperature, Patrick R. Jackson

Theses and Dissertations

The compressive creep behavior of a N610/monazite/alumina composite was investigated in this work. The composite consists of a porous alumina matrix reinforced with NextelTM610 fibers coated with monazite in a symmetric cross-ply (0°/90°/0°/90°)s orientation. Compressive stress-strain behavior was investigated as well. The addition of monazite coating resulted in ~ 35% loss in compressive strength at 900°C and in ~45% loss in compressive strength at 1100°C. Compressive creep behavior was examined at 900 and 1100°C for creep stresses ranging from 50 to 95 MPa. Primary and secondary creep regimes were observed at both temperatures. Minimum creep rate was reached in all …

Evaluation Of Factors Contributing To Damping Of Coated And Uncoated Titanium Plates, Dustin W. Lee

Theses and Dissertations

High Cycle Fatigue (HCF) is the leading cause of component failure in gas turbine engines today, which poses great risk to aircraft, engines, and their crews. Mitigation of HCF effects has become a priority topic, and the damping benefits of hard coatings are being reevaluated for this purpose. Research was conducted to further understanding of damping measurements on these coatings. This study continues work to characterize the damping effects of a magnesium aluminate spinel (mag spinel) coating applied to a titanium plate via vibration testing. Two different plate sizes were evaluated in a clamped-free-free-free condition and a free-free-free-free condition, respectively. …

Fretting Fatigue Behavior Of Nickel Alloy In-100, Elhoucine Madhi

Theses and Dissertations

In this study, a systematic investigation of the fretting fatigue behavior of nickel alloy, IN-100 was carried out. The study includes both experimental work and the corresponding analysis of the contact conditions, and the latter is accomplished using the finite element method. Fretting fatigue tests were performed over a wide range of axial stresses to examine both low and high cycle fretting fatigue under constant contact load and the influence of different pad geometries was also explored. It was observed that fretting reduced the fatigue strength of IN- 100, and that increasing cylindrical pad radii does not have the same …

Validation Of A Scaled Plane Strain Hypervelocity Gouging Model, Ronald J. Pendleton

Theses and Dissertations

The phenomenon of high speed impact is of great interest to the Air Force of Scientific Research and the Air Force Research Laboratory's Holloman High Speed test track. Rocket sled tests at the facility frequently are limited to velocities lower than actually attainable due to damage to the rail in the form of gouges. Direct observation of the gouging phenomenon is not currently possible. This leaves computational modeling as the only means to study the phenomenon. A computer model has previously been used to model the development of gouging at the Holloman High Speed Test Track. However, this model has …

Effect Of Hold Times On Fatigue Behavior Of Nextel 720™/Alumina Ceramic Matrix Composite At 1200°C In Air And In Steam Environment, John M. Mehrman

Theses and Dissertations

The aerospace field requires structural materials that can maintain superior mechanical properties while subjected to high temperatures and oxidizing environments. This research investigated the effect of hold times at maximum load on fatigue performance of a Nextel 720/Alumina ceramic matrix composite at 1200 C, explored the influence of environment on material response to cyclic loading with hold times at maximum load, and assessed the effects of loading history on material behavior and environmental durability. The N720/A composite relies on an oxide/oxide composition for inherent oxidation resistance and a porous matrix with no interphase between the fiber and matrix for damage …

Structural Health Monitoring Considering Internal Beam Damage, Jessica B. Chronister

Theses and Dissertations

The present study establishes a nondestructive method of damage detection and assessment in cantilever beams. The specimens used are twelve-inch aluminum 2024-T3 beams with machined notches of varying lengths and locations. Laser Doppler vibrometry is used to obtain the frequency response of vibrating beams. Experimental methods are developed to detect the presence, location and extent of damage by direct observation of the eigenvector in the third through eighth modes. Models in MATLAB and ABAQUS are used to predict and validate the observed data. With this experimental method developed, the validity of the method is tested for specimens that have been …

Development Of In-Plane Surface Deformation Sensing For Thin Film Pvdf Actuated Membrane Mirrors, John J. Cornelius

Theses and Dissertations

This study investigated the feasibility of surface deformation sensing of a membrane mirror using only embedded PVDF sensors. Results were compared to measured deformations using a scanning laser vibrometer. The frequency response function (FRF) was measured based on recorded voltages of a single-layer 7-sensor mirror actuated externally from the embedded PVDF actuators. Additionally, a two-layer, 7-sensor, 7-actuator membrane mirror was constructed for use, with one layer acting as the sensing layer and the other acting as the actuation layer. The measured FRF for this mirror was compared to previous results. Finally a single-layer 61-sensor PVDF mirror was constructed to experimentally …

Creep-Rupture And Fatigue Behaviors Of Notched Oxide/Oxide Ceramic Matrix Composite At Elevated Temperature, Mark A. Sullivan

Theses and Dissertations

Oxide/oxide composites are being considered for use in high temperature aerospace applications where their inherent resistance to oxidation provides for better long life properties at high temperature than most other ceramic matrix composites (CMCs). One promising oxide/oxide CMC is Nextel 720/A (N720/A) which uses an 8-harness satin weave (8HSW) of Nextel 720 fibers embedded in a porous alumina matrix. Possible aerospace applications for N720/A will likely require inserting holes into the material for mounting and cooling purposes. The notch characteristics must be understood to ensure designs using the material are sufficient for the desired application. This research effort examined the …

Electroless Nickel Plating On Carbon Nanotube With Non-Palladium Activation Procedure, Guang-Hui Hu, Hui-Huang Wu, Fang-Zu Yang

Journal of Electrochemistry

A new procedure of surface activation without using palladium salt was proposed for electroless nickel plating on carbon nanotubes.In the procedure,carbon nanotubes were oxidized by nitric acid and then neutralized with NaOH to create carboxyl surface groups which were used to adsorb Ni²⁺ ions,thereafter the adsorbed Ni²⁺ ions were chemically reduced into Ni nano-particles as a catalytic center for electroless nickel deposition,all these were further confirmed by infrared absorption spectra and electron microscopic observations.The results indicate that the procedure is feasible to electroless nickel plating on carbon nanotubes.The different morphology of deposits obtained from electroless plating was also …

Anodic Behaviors Of Pb-Ca-Sn-Re Alloy And Tradditional Pb-Ca-Sn Alloy In Sulfuric Acid Solutions, Dang-Guo Li, Gen-Shu Zhou, Liang Yao, Guan-Fa Lin, Mao-Sheng Zheng

Journal of Electrochemistry

The anodic behaviors of Pb-Ca-Sn-Re and Pb-Ca-Sn alloys were investigated at 1.28 V(vsHg/(H₂SO₄)) in 4.5 mol/L sulfuric acid solution by means of ac voltammetry,ac impedance and cyclic voltammetry.The results showed that the corrosion-resistance property of Pb-Ca-Sn-Re alloy is better than that of tradditional Pb-Ca-Sn alloy,the growth of Pb(Ⅱ) compounds was inhibited in the film of Pb-Ca-Sn-Re alloy,and the film impedance of Pb-Ca-Sn-Re alloy was decreased,indicating that the conductivity of the film was(increased),which is helpful to enhance the deep recycling property for lead acid battery.

Mechanism Of Self Discharge Performance Improvement In The Ni-Mh Batteries With Naoh Electrolyte, Xiao-Feng Li, Tong-Chi Xia, Hui-Chao Dong, Yan-Wei Wei

Journal of Electrochemistry

The self-discharge performance and charge efficiency at 60 ℃ for Ni-MH battery can be markedly enhanced by using NaOH electrolyte instead of KOH electrolyte.Both the results of electrochemical impedance spectroscopy and cyclic voltammetry tests indicate that the separation of H₂ from the negative electrode may be partly blocked in the former because of the change of the adsorption/desorption behavior of H on the surface of the negative electrode,thus results in an improvement of self-discharge performance of the battery.

2006 National Conference On Corrosion Electrochemistry And Measuring Methods, Editorial Office Of J.Electrochem.

Journal of Electrochemistry

No abstract provided.