Open Access. Powered by Scholars. Published by Universities.®

Engineering Science and Materials Commons™

Open Access. Powered by Scholars. Published by Universities.®

2003

Discipline
Institution
Keyword
Publication
Publication Type

Articles 61 - 84 of 84

Full-Text Articles in Engineering Science and Materials

Electroreduction Of Cd(Ⅱ) In Dmso And Complexation Of Cd(Ⅱ) With Coumarin Derivates, Ji-Guo Song, Hua-Can Song, Qi-Qin Yang, Yi-Wen Chen, Zun-Le Xu Feb 2003

Electroreduction Of Cd(Ⅱ) In Dmso And Complexation Of Cd(Ⅱ) With Coumarin Derivates, Ji-Guo Song, Hua-Can Song, Qi-Qin Yang, Yi-Wen Chen, Zun-Le Xu

Journal of Electrochemistry

Cadmium p-toluenesulfonate was synthesized and tested electrochemically for the first time. This salt can lose all the hydrated water easily and the dehydrated salt do not deliquesce in the air.Hence,the cadmium p-toluenesulfonate is suitable for the electrochemical studies in organic solvents.When the Cd(Ⅱ) reduced on Pt electrode in Cd(p-CH3C6H4SO3)2+TBAP+DMSO, underpotential deposition of cadmium occurred at first, and then cadmium deposited. 4-Methyl-7-hydroxylcoumarin and 3-aminocoumarin coordinate with Cd(Ⅱ) respectively, as a result the reductive potentials of Cd(Ⅱ) moved to the negative direction.

Go to article

Magnetic Resonance Studies On Lithium Intercalation Into Carbons, Xiao-Rong Zhou, Zhen-Ming Du, Lin Zhuang, Jun-Tao Lu Feb 2003

Magnetic Resonance Studies On Lithium Intercalation Into Carbons, Xiao-Rong Zhou, Zhen-Ming Du, Lin Zhuang, Jun-Tao Lu

Journal of Electrochemistry

The electron spin resonance(ESR) and 7Li-NMR magnetic resonance (7Li-NMR) studies on lithium intercalation into carbons were reviewed based on recently published papers, including those by the authors of this review. Two kinds of electronic spins were found in ESR studies. One corresponds to the charge carrier electrons and is called the Pauli spin. From the ESR intensity of Pauli spins, the curve of the density of electronic states can be deduced for the carbon material studied and, in turn, the contribution of the band model mechanism to the lithium intercalation can be calculated for the given carbon sample. The other …

Go to article

Study Of Electrochemical Lithium Intercalation Performance Of Ni0.67Mg0.33O, Zhen-Cai Huang, Mao-Hui Chen, Guo-Tao Wu, Jin-Kua You, Zu-Geng Lin Feb 2003

Study Of Electrochemical Lithium Intercalation Performance Of Ni0.67Mg0.33O, Zhen-Cai Huang, Mao-Hui Chen, Guo-Tao Wu, Jin-Kua You, Zu-Geng Lin

Journal of Electrochemistry

In the present work, Ni0.67Mg0.33O and NiO were produced by sol-gel method, and characterized by XRD, a rietveld refinement and the discharge/charge test.It was found that the magnesium-doping restrained the reduction of Ni and decreased the reversible capacity for the sample of Ni0.67Mg0.33O. But the formation of the solid solution after the magnesium-doping facilitated the high dispersion of NiO, and accordingly improved the electrochemical performance.

Go to article

Application Of Biphenyl Electroploymerization For Overcharge Protection In Li-Ion Batteries, Li-Fen Xiao, Xin-Ping Ai, Yu-Liang Cao, Han-Xi Yang Feb 2003

Application Of Biphenyl Electroploymerization For Overcharge Protection In Li-Ion Batteries, Li-Fen Xiao, Xin-Ping Ai, Yu-Liang Cao, Han-Xi Yang

Journal of Electrochemistry

The electropolymerization of biphenyl at overcharged positive electrode was investigated for overcharge protection of Li-ion batteries. Biphenyl in electrolyte as an additive can electrochemically polymerize at 4.5～4.75 V(vs. Li/Li+) to form a layer of conductive film on cathode surface. The surface film increases the internal resistance and the gases released during the electropolymerization also increases the internal pressure of the batteries, which therefore enhance the sensitivities of the electrical disconnecting devices. During prolonged overcharge, the growth of the conductive polymer film can create short circuit between the positive and negative electrodes and cause self-discharge of the batteries to …

Go to article

The Preparation And Characterization Of Zno-Pani Composite Film, Yan-Yan Xi, Huai-Guo Huang, Zhi-Xin Zheng, Ping Dong, Jian-Zhang Zhou, Ling-Ling Wu, Zhong-Hua Lin Feb 2003

The Preparation And Characterization Of Zno-Pani Composite Film, Yan-Yan Xi, Huai-Guo Huang, Zhi-Xin Zheng, Ping Dong, Jian-Zhang Zhou, Ling-Ling Wu, Zhong-Hua Lin

Journal of Electrochemistry

ZnO nanoparticle films were prepared on the Au film, PANI film and ITO by sol-gel method, and their morphological optical and photoelectrochemical properties were also studied. The results showed that the porous structure of PANI can suppress the aggregation of ZnO particles, resulting in the blue shift of on-set in the UV-Vis spectra and fluorescence spectra of ZnO-PANI composite film compared with that of ZnO-Au film. It was suggested that the ZnO-PANI composite film can be used in photoelectric coversion.

Go to article

The Electrochemical Behavior Of Amorphous Ni-P And Ni-B Alloys In 0.5 Mol/L H2So4, Xu-Cheng Wang, Wei-Jiang Wang, Hou-Tian Liu, Zu-Zhan Yu Feb 2003

The Electrochemical Behavior Of Amorphous Ni-P And Ni-B Alloys In 0.5 Mol/L H2So4, Xu-Cheng Wang, Wei-Jiang Wang, Hou-Tian Liu, Zu-Zhan Yu

Journal of Electrochemistry

Polarization curves and impedance spectra were used to investigate the electrochemical behavior of amorphous Ni-P and Ni-B alloys in 0.5 mol/L H2SO4 solutions. The possible reason about the remarkable difference in the electrochemical behavior between amorphous Ni-P and Ni-B alloys was discussed.

Go to article

Behaviors Of Fe-Cr Alloys During Cavitation Damage, Xia Bai, Dong-Bai Sun, Hong-Ying Yu, Hui-Ming Meng, Hui-Qin Li, Zi-Shuang Fan Feb 2003

Behaviors Of Fe-Cr Alloys During Cavitation Damage, Xia Bai, Dong-Bai Sun, Hong-Ying Yu, Hui-Ming Meng, Hui-Qin Li, Zi-Shuang Fan

Journal of Electrochemistry

The influence of the surface galvanic effect on the behaviors of three Fe-Cr alloys during cavitation damage in NaCl solutions have been investigated. The results showed that the galvanic effect caused by the inhomogeneity between the undamaged surface of the alloy and the damaged one will be enhanced by the area ratio of the undamaged and the damaged. The behaviors of alloys during cavitation are closely related to both their mechanical performance and anti-corrosion capabilities.

Go to article

Study On The Corrosion & Electrochemical Properties Of Alloy Aa5083 And The Effect Of Active Chlorine In Seawater, Hong-Ren Wang, Jian-Hua Wu, Jun-Tao Wang, Hong-Bin Wang, Zhi-Gang Fang Feb 2003

Study On The Corrosion & Electrochemical Properties Of Alloy Aa5083 And The Effect Of Active Chlorine In Seawater, Hong-Ren Wang, Jian-Hua Wu, Jun-Tao Wang, Hong-Bin Wang, Zhi-Gang Fang

Journal of Electrochemistry

In this paper potentiodynamic technique, cyclic polarization technique and immersion corrosion method were used to study the corrosion and electrochemical properties of AA5083 alloy in quiescent seawater, the effect of active chlorine on its properties was also studied. The results obtained indicate that the active chlorine has no remarkable impact on the corrosion and electrochemical properties of AA5083 alloy in area of design concentration which range from 0.2 to 0.5 mg/L, and it has favorable influence on the improvement of pitting corrosion resistance. While the pH value of seawater has evident influence on the corrosion resistance of AA5083 alloy.

Go to article

Study For The Cathodic Behavior Of Active Chlorine On 316l Ss Electrode Surface, Hui Yu, Ming-Xian Sun, Yan Ma, Xiao-Bin Wang Feb 2003

Study For The Cathodic Behavior Of Active Chlorine On 316l Ss Electrode Surface, Hui Yu, Ming-Xian Sun, Yan Ma, Xiao-Bin Wang

Journal of Electrochemistry

The cathodic reducing reactions of active chlorine on 316 L SS electrode surface have been investigated by electrochemical techniques. The open circuit potential shifted positively and the limited diffusion current density increased significantly with the increasing content of active chlorine in the 3.5% sodium chloride solution. The two cathodic reduction processes of HClO and ClO- exhibited on the surface of electrode with the active chlorine added to the 3.5%sodium chloride solution and the corresponding potentials of the two reducing reactions were confirmed. The linear relationship of the mass transport-limited Faradaic current, Id vs. the square root of the angular …

Go to article

Development And Study Of The (Ag)-Ni/Cr Composite Plating With Antibacterial Properties And Corrosion Resistance, Ya-Ping Zhao, Jin-Hua Wang, Ren-He Yin, Jin Zheng, Le-Shu Yu Feb 2003

Development And Study Of The (Ag)-Ni/Cr Composite Plating With Antibacterial Properties And Corrosion Resistance, Ya-Ping Zhao, Jin-Hua Wang, Ren-He Yin, Jin Zheng, Le-Shu Yu

Journal of Electrochemistry

The 3-factor and 3-level orthogonal experiment was designed and through the comparison of the different films' antibacterial properties measured by bacterial colony counting and the corrosion resistance studied with the AC impedance method. The optimal plating conditions of the (Ag)-Ni/Cr composite plating, a novel functional plating, were determined. The results have indicated that the (Ag)-Ni/Cr composite plating is characterized by both antibacterial and corrosion resisting properties and has its wide applied prospect.

Go to article

Synthesis By Complexation Processes And Characterization Of Lini0.8Co0.2O2 Cathode Materials, Jing Liu, Zhao-Yin Wen, Zhong-Hua Gu, Xiu-Jian Zhu, Zu-Xiang Lin Feb 2003

Synthesis By Complexation Processes And Characterization Of Lini0.8Co0.2O2 Cathode Materials, Jing Liu, Zhao-Yin Wen, Zhong-Hua Gu, Xiu-Jian Zhu, Zu-Xiang Lin

Journal of Electrochemistry

The layered LiNi0.8Co0.2O2 compound, which has been of great interest for lithium ion batteries, was prepared at low temperatures by calcining a complex precursor at different temperatures. The physical properties of the synthesized cathode materials were discussed in the light of structural (XRD). The charge and discharge cycling of the cells containing the synthesized oxide as the positive electrode in conjunction with lithium metals and employing a non-aqueous electrolyte showed that LiNi0.8Co0.2O2 treated at 900 ℃ exhibited excellent performances. The first discharge capacity of LLiNi0.8Co0.2O2 …

Go to article

Rotary Kiln Incineration Of Hazardous Wastes: Pilot-Scale Studies At Louisiana State University, John Sutherland Earle Jan 2003

Rotary Kiln Incineration Of Hazardous Wastes: Pilot-Scale Studies At Louisiana State University, John Sutherland Earle

LSU Doctoral Dissertations

Studies of incineration of surrogates for hazardous wastes are conducted in the pilot-scale rotary kiln incinerator (RKI) at Louisiana State University (LSU) in Baton Rouge, Louisiana. The purpose of the research is to investigate methods of treating and destroying hazardous wastes in a cost-effective and environmentally sound way. The objective is to provide process data that will contribute to increased knowledge for RKI design and operation. The LSU facility is a College of Engineering Combustion Laboratory that is unique in its large size as a university laboratory. It is equipped with individual instruments for analysis of O2, CO, …

Go to article

Optimization And Automation Of A Thermal Oyster Shucking Process, Daniel Edgar Martin Jan 2003

Optimization And Automation Of A Thermal Oyster Shucking Process, Daniel Edgar Martin

LSU Doctoral Dissertations

Louisiana Gulf Coast oysters (Crassostrea virginica) were subjected to thermal shucking treatments to effect adductor muscle release from both left and right valves. The oysters were instrumented with thermocouples to monitor and record process temperatures in the oysters and on the shell. Following treatment, the oysters were evaluated for relaxation and release of the adductor muscle, meat quality and texture, and for the effect of the treatments on the storage life of the oysters as measured by total microbial plate counts. The treatments of many oysters resulted in a complete release of the adductor muscle from the shell while maintaining …

Go to article

Finite-Horizon Operations Planning For A Lean Supply Chain System, Ahmad Diponegoro Jan 2003

Finite-Horizon Operations Planning For A Lean Supply Chain System, Ahmad Diponegoro

LSU Doctoral Dissertations

This dissertation studies an operational policy for a lean supply chain system consisting of a manufacturer, multiple suppliers and multiple buyers. The manufacturer procures raw materials from the suppliers and converts them into finished products, which are then shipped in batches to the buyers at certain intervals of times. Three distinct but inseparable problems are addressed: single supplier and single buyer with fixed delivery size (FD), multiple suppliers and multiple buyers with individual delivery schedule (MD), and time dependent delivery quantity with trend demand (TD). The mathematical formulations of these supply systems are categorized as mixed-integer, nonlinear programming problems (MINLAP) …

Go to article

Progressive Fatigue Effects On Manual Lifting Factors, Anthony D'Wayne Banks Jan 2003

Progressive Fatigue Effects On Manual Lifting Factors, Anthony D'Wayne Banks

LSU Doctoral Dissertations

Much evidence suggests that the cause of lower back pain (LBP) and injury is frequently related to the posture of lifting, the load, muscle fatigue, and other factors. The purpose of this study was to evaluate the effect of progressive fatigue on factors that have previously been associated with increased risk of LBP in various occupational settings, during a repetitive lifting task where freestyle lifting technique was utilized. A laboratory experiment was conducted to evaluate several fatigue analysis, electromyography amplitude, kinematic, and kinetic parameters of repetitive freestyle lifting during a 2-hour lifting period. Each of ten (10) young adult male …

Go to article

Developing A Methodology To Detect Partial Failures For Dynamic Systems, Anwar A. Al-Jowder Jan 2003

Developing A Methodology To Detect Partial Failures For Dynamic Systems, Anwar A. Al-Jowder

Engineering Management & Systems Engineering Theses & Dissertations

The purpose of this research is to develop a decision support system that can assist in detecting partial failures in dynamic systems such as Fire Control System Tracking Radar (TR) onboard Naval Ships. Partial failures do not necessarily shut down the system immediately but cause degradation of operational performance. Previous work has shown that experts in the field of failure detection, test point insertion and Built-In-Test Equipment (BITE) can provide useful input in detecting partial failures. Partial failures affect operational system performance and support costs, which can be significant. Often, however, partial failure detection consists of the estimations and opinions …

Go to article

Freeway Accident Analysis Using Second Order Statistics, Khasim Khasimul Shaik Jan 2003

Freeway Accident Analysis Using Second Order Statistics, Khasim Khasimul Shaik

LSU Master's Theses

This research focuses on the use of historical freeway traffic data for comparison of the precursory traffic conditions to that accident occurrence by using 15-minute traffic speed contour maps. The second order statistics measures, namely angular second moment (ASM), contrast and entropy were used as the traffic performance measures in order to compare the two situations. The data used is from I-4 freeway traffic condition database, stored in a SQL server and 1999 year accident database for the same I-4 freeway. The study section is located in Orlando, Florida. The approach shows an approach to understand the performance of the …

Go to article

Synthesis, Structure And Properties Of Nanolayered Dlc/Dlc Films, Pankaj Gupta Jan 2003

Synthesis, Structure And Properties Of Nanolayered Dlc/Dlc Films, Pankaj Gupta

LSU Master's Theses

Diamondlike carbon (DLC) films have been explored extensively in the past due to their highly attractive properties. However, the high level of internal stress developed during growth prevents deposition of thick films. Synthesis of DLC/DLC multilayers (DDM) presents a venue to overcome this drawback. In the present study, DLC films and DDM were deposited on Si substrate using dc plasma of CH4 and Ar gas mixture. FTIR was used to analyze the structure of the DLC films. Mechanical properties of the films were characterized by microhardness testing and nanoindentation. The tribological properties were studied by conducting pin-on-disc experiments in …

Go to article

High Strain Rate Properties Of Polymer Matrix Composites, Amol Jadhav Jan 2003

High Strain Rate Properties Of Polymer Matrix Composites, Amol Jadhav

LSU Master's Theses

The vast differences in strength, ultimate strain and modulus during high strain rate (HSR) deformation of materials have been a very long-standing subject of engineering interest. This thesis deals with characterization of mechanical properties of two composite materials, balanced angle-ply graphite epoxy laminates (fibrous composite) and syntactic foams (particulate composite). The focus of this study is to compare the mechanical properties of these composite materials at high strain rates and quasi-static conditions and to find out the effects of failure modes on HSR mechanical properties of these materials. Split Hopkinson Pressure Bar (SHPB) apparatus is used for the HSR testing …

Go to article

Tensile Strength And Bonding Characteristics Of Self-Compacting Concrete, Cristian Druta Jan 2003

Tensile Strength And Bonding Characteristics Of Self-Compacting Concrete, Cristian Druta

LSU Master's Theses

Self-compacting concrete, also referred to as self-consolidating concrete, is able to flow and consolidate under its own weight and is deaerated almost completely while flowing in the formwork. It is cohesive enough to fill the spaces of almost any size and shape without segregation or bleeding. This makes SCC particularly useful wherever placing is difficult, such as in heavily-reinforced concrete members or in complicated workforms. The objectives of this research were to compare the Splitting Tensile Strength and Compressive Strength values of self-compacting and normal concrete specimens and to examine the bonding between the coarse aggregate and the cement paste …

Go to article

Alloy States In Dilute Gaas1-XNX Alloys (X<1%), X. D. Luo, Jinsong Huang, Z. Y. Xu, C. L. Yang, J. Liu, W. K. Ge, Y. Zhang, A. Mascarenhas, H. P. Xin, C. W. Tu Jan 2003

Alloy States In Dilute Gaas1-XNX Alloys (X<1%), X. D. Luo, Jinsong Huang, Z. Y. Xu, C. L. Yang, J. Liu, W. K. Ge, Y. Zhang, A. Mascarenhas, H. P. Xin, C. W. Tu

Department of Mechanical and Materials Engineering: Faculty Publications

A set of GaAs1-xNx samples with small nitrogen composition (x<1%) were investigated by continuous-wave photoluminescence (PL), pulse-wave excitation PL, and time-resolved PL. In the PL spectra, an extra transition located at the higher-energy side of the commonly reported N-related emissions was observed. By measuring the PL dependence on temperature and excitation power, the PL peak was identified as a transition of alloy band edge-related recombination in GaAsN. The PL dynamics further confirms its intrinsic nature as being associated with the band edge rather than N-related bound states.

Go to article

Characterization Of Syntactic Foams And Their Sandwich Composites: Modeling And Experimental Approaches, Nikhil Gupta Jan 2003

Characterization Of Syntactic Foams And Their Sandwich Composites: Modeling And Experimental Approaches, Nikhil Gupta

LSU Doctoral Dissertations

Hollow particle filled polymers known as syntactic foams are lightweight and highly damage tolerant. Syntactic foams are used as core materials in sandwich composites. The use of such materials in aeronautical and space structures make it necessary to understand their characteristics for various environmental and loading conditions. The first part of the present work takes modeling and finite element analysis approach to understand and predict the deformation behavior of syntactic foams. Contact analysis is performed on single particle models by the finite element analysis approach. In the second part extensive experiments are carried out to characterize syntactic foams for hygrothermal …

Go to article

Block-Level Discrete Cosine Transform Coefficients For Autonomic Face Recognition, Willie L. Scott, Ii Jan 2003

Block-Level Discrete Cosine Transform Coefficients For Autonomic Face Recognition, Willie L. Scott, Ii

LSU Doctoral Dissertations

This dissertation presents a novel method of autonomic face recognition based on the recently proposed biologically plausible network of networks (NoN) model of information processing. The NoN model is based on locally parallel and globally coordinated transformations. In the NoN architecture, the neurons or computational units form distributed networks, which themselves link to form larger networks. In the general case, an n-level hierarchy of nested distributed networks is constructed. This models the structures in the cerebral cortex described by Mountcastle and the architecture based on that proposed for information processing by Sutton. In the implementation proposed in the dissertation, the …

Go to article

Study Of A Growth Instability Of Γ-In[Sub 2]Se[Sub 3], C. Amory, J. C. Bernede, S. Marsillac Jan 2003

Study Of A Growth Instability Of Γ-In[Sub 2]Se[Sub 3], C. Amory, J. C. Bernede, S. Marsillac

Electrical & Computer Engineering Faculty Publications

γ-In[sub 2]Se[sub 3] thin film are deposited for various substrate temperatures in the range of 523–673 K. This study shows that at 573 and 673 K the thin films are well crystallized with grains aligned along the c axis. Between these temperatures, a domain of instability appears where the γ-In[sub 2]Se[sub 3] thin films have a randomly orientation and the c-lattice parameter increases. The presence of the metastable phase κ-In[sub 2]Se[sub 3], during the growth, can explain the existence of this domain of instability. The insertion of Zn during the preparation process allows us to stabilize the phase κ at …

Go to article

First Prev