Engineering Science and Materials Commons^™

Determination Of Aromatic Amines By Diazonium Salt, Hong-Hue Hsu

Theses

There are many analytical methods used in the identification of aniline by the production of various colors upon treatment with certain reagents. In this work a new inexpensive, easy and sensitive methods to quantitate aniline is developed. The change of absorbance is large enough to measure with a difference of only 1 ppm in the aniline concentration.

In this method, the reagent (2,4-dinitrodiazonium sulphate) which reacts with aniline produces a yellow color. Formation of this color (which absorbs at 486 nm) indicates the presence of aniline. The amount of aniline can be determined by measuring the absorbance at 486 nm. …

Agitation Requirements For Complete Dispersion Of Emulsions, Dun-Huang Tsai

Theses

An investigation on the minimum agitation speed required to achieve complete dispersion in liquid-liquid systems has been carried out. A model based on the momentum balance for a droplet and on Kolmogoroff's theory of isotropic turbulence was used for the prediction of the role of the most important variables on the minimum agitation speed. The equation so derived can be expressed in terms of a number of non- dimensional groups (such as Re, Ar, and Su). For geometrically similar systems the equation contains only one adjustable parameter ( to be determined experimentally) in the form of the proportionality constant correlating …

The Design, Manufacture And Mechanical Analysis Of An L4-5 Spinal Disc Prosthesis, Bohdan A. Siryi

Theses

The purpose of this research was to develop an intervertebral disc prosthesis which can provide the biomechanical properties of the natural disc. The prosthesis will be used to replace the symptomatic degenerated disc and thereby limit backpain and subsequent spinal disease.

Four cadaveric L4-5 motion segments were mechanically tested under axial compression and combined compression/torsion, generating compressive moduli and torsional stiffness values. Following, prosthetic discs were fabricated and mechanically tested, with the fabrication technique directed towards the optimization of mechanical properties in compression, torsion and bending.

Thirty silicon rubber and forty five polyurethane disc prostheses were fabricated. Silicon rubber, dacron …

Approaches To The Synthesis Of Dentin Bonding Agents Containing Vinyl And Carbamate Functional Groups, Steven W. Amato

Theses

The synthesis of four new monomers containing vinyl and carbamate functional groups was attempted. The desired products were N-m-methacryloxyphenyl-O-phenyl carbamate, N-p-methacryloxy-O-phenyl carbamate, m-N-phenylcarbamato-2-methacryloxyethoxy benzoate, and p-N-phenylcarbamato-2-methacryloxyethoxy benzoate. The carbamate functional group was derived by the Lewis Acid catalyzed reaction of meta-aminophenol, para-aminophenol, meta-aminobenzoic acid, and para-aminobenzoic acid with diphenyl carbonate. The vinyl function was derived, in the case of the aminophenols, by reaction with methacrylyl chloride, and in the case of the aminobenzoic acids, with 2-hydroxyethyl methacrylate.

Partial products only were prepared, these being the two carbamate functional phenols, the two carbamate functional benzoic acids, the two methacryloxy functional derivatives …

Geometric And Enthalpic Calculational Study Of Monosubstituted Cyclobutanes ; Attempted Synthesis Of 1,3-Diphenyl-2,2,4,4-Tetrafluorobicyclo [1.1.0] Butane, Jose Luis Reyesgavilan

Theses

The work undertaken in this thesis is in two parts. In the first, the structure and heat of formation of substituted cyclobutanes were studied via the computer program MMII using an IBM PCXT personal computer with a math co-processor chip. Structurally, a trend was seen to be followed in which bulkier substituents were pushed away from any steric interaction with the ring. This was accomplished by having the latter alter its puckering angle, C2C1C4 angle, HCX angle, and to a smaller extent, the bond lengths immediately adjacent to the substituted carbon atom. This results demonstrated that the ring was very …

Trends In Metal (Pb, Zn, Ni, As And Se) Concentrations In The New Jersey Air Environment, Geoffrey Ike Ejiofor

Theses

The trend and atmospheric concentrations of five trace elements (Pb, Zn, Ni, As and Se) were studied at Newark (urban site) and Ringwood (rural site), New Jersey, during January - September 1985, whilst the Hackensack Meadowlands, New Jersey were monitored during October 1985-March 1986. The analytical procedure involved collection of the airborne particulates on a glass fiber filter using a non-dichotomous high volume sampler. The samples were digested and analyzed using the atomic absorption spectrophotometer. It was ascertained that Newark and Meadowlands exhibited higher average concentrations of Zinc and Lead than Ringwood. It was concluded all the metals originated mostly …

Physical And Mechanical Properties Of A New Type Of Polymer Concrete, Kyan Bin Khoo

Theses

A new type of Polymer concrete is an admixture of a special Latex, Portland cement and Sand. It has high bond strength, quick curing, durability and adequate strength. The Mechanical and Physical properties were investigated in this paper. Reinforcement with Glassfiber was done and its properties compared to those of control specimens. The heat generation in Polymer Concrete (PC) and its relationship with the properties of PC was also investigated.

A new type of Polymer concrete is an admixture of a special Latex, Portland cement and Sand. It has high bond strength, quick curing, durability and adequate strength. The Mechanical …

The Quantitative Analysis Of Airborne Particulates By X-Ray Flourescence, George C. Asteriou

Theses

Airborne particulate matter from the New Jersey State area collected on Quartz Microfiber filters was analyzed by X-Ray Fluorescence spectroscopy. The quantitative analysis of the samples against N. B. S. standards produced results which were compared with Atomic Absorption analysis

The results from the two methods were correlated by the introduction of empirical factors for each element.

However, a larger number of analyzed standards of varied composition, along with the creation of a spectral library, can minimize the need for empirical factors and yield accu¬rate results.

Synthesis Of Trimethylpropane-Tolylene-2,4-Diisocyanate Adduct And Its Blocked Monomers, Farhad Forohar

Theses

A trimethylolpropane adduct of tolylene-2,4-diisocyanate (TMP-TDI) was prepared by reaction in a heterogeneous solvent system. The isocyanate functional groups of the TMP-TDI adduct were blocked with the following blocking agents: p-cresol, eugenol, o-chlorophenol, and one to one mole ratio of mixtures of 2-hydroxyethyl methacrylate (HEMA) and each of the three preceding blocking agents. A sample of TMP-TDI adduct blocked with only HEMA was also prepared. The products were characterized by melting point, infrared spectroscopy, and elemental analysis. Monomers of TMP-TDI blocked with 50% HEMA and 50% blocking agents may be very useful as dental restorative materials.

Characterization Of Tdi-Hema Homopolymer Prepared Via An Immiscible Solvent System. Synthesis And Investigation Of Oligodichloroketene, Manuel Montero

Theses

The objective of this thesis has been divided in two parts.

The first part is subdivided into two areas. First a "Universal" calibration curve for gel permeation chromatography (GPC) was construc-ted using different molecular weight standards of PMMA and MMA-HEMA co-polymers. By measuring the viscosity of the different molecular weight solutions and calculating the Vr, (retention volume), from GPC data, plots of In [ η ] Mw against Vr and In Mw against Vr are obtained. These curves can be used to obtain the molecular weight of any linear (not crosslinked) copolymer by simple measurements of viscosity and GPC data. …

Three Studies On Airborne Polycyclic Aromatic Hydrocarbons, Carol Sophia Eveleens

Theses

Three studies have been conducted on polycyclic aromatic hydrocarbons found on airborne particulate matter. The first investigation involves the determination of fly ash "activity" in the reaction of two PAHs adsorbed on its surface. Mass spectrometry is used to monitor the exchange of hydrogen and deuterium atoms between anthracene and anthracene-d10. The results indicate that some fly ashes exhibit "activity" in the reactions of PAHs adsorbed on its surface. The second investigation involves the determination of cyclopenta[cd]pyrene (CcdP) and benzo[ghi]flouranthene (BghiF) on samples of airborne particulate material collected from two automobile traffic tunnels. Glass capillary gas chromatography with a precolumn …

Calibration Of Flame Ionization Detector For Chlorinated Hydrocarbons, Nahid Jabalameli

Theses

Relative Responses and Calibration Factors were developed for several volatile organic (mostly chlorinated) priority pollutant species in order to use one single stable compound (e.g.Benzene) for daily instrument calibration. This would replace the procedure of using a standard mixture of target compounds (25-35). This is of particular advantage because the standard mixture may not have all species stable or may show loss of some components relative to others due to wall adsorption in the standard (compressed gas) stainless steel cylinder.

The use of a single standard species was made possible by developing "accurate" relative response and calibration factors of all …

Preparation And Characterization Of Blocked Diisocyanate Monomers For Dental Applications, Stephen Richard Angeli

Theses

Six new monomers were prepared and characterized. The six monomers are blocked diisocyanate compounds. In the preparation 2,4-tolylene diisocyanate was first blocked with 2=hydroxyethyl methacrylate in the para NCO position. Six different blocking agents were then used to block the ortho NCO in the preparation of the monomers: (1) p-methoxyphenol, (2) m-methoxyphenol, (3) o-methoxyphenol, (4) p-chlorophenol, (5) m-chlorophenol, and (6) o-chlorophenol. The six monomers were characterized by mp, liquid chromatography, IR, NMR, and elemental analysis. All the characterizations show that the monomers are indeed the desired products.

Preparation And Characterization Of Blocked Isocyanate Monomer Polymer And Equilibrium Constant Of Deblocking, Kirti P. Kamdar

Theses

A 2-Hydroxyethyl methacrylate (HEMA) adduct of toluene 2-4 diisocyanate (TDI) was prepared in petroleum ether at 35-40°C under nitrogen. In order to prepare the monomer, equimolar amounts of TDI and HEMA were reacted with P-cresol which functions as a blocking agent.,Di-butyltin dilaurate was used as a catalyst and chloranil was used as an inhibitor. The solid monomer which was obtained was recrystallized, and polymerized in chloroform using azobis isobutyronitrile as initiator.

Monomer and polymer were characterized using infrared spectroscopy, melting point, liquid chromatography gel permeation chromatography. A vapor pressure osmometric study of the polymer in three different solvents at three …

The Quantitative Determination Of The Elemental Composition Of Coal Fly Ash Samples Using X-Ray Fluorescence, Joseph R. Cervassi

Theses

Bulk constituent elements contained in coal fly ash were measured by X-ray fluorescence spectroscopy in eight samples. Four samples were used as calibration standards for the spectrometer since their compositions were previously determined by atomic absorption spectrometry. Calibration coefficients of the standards were calculated with computer assisted regression analysis of the fluorescence spectra, and used to determine the composition of the remaining four samples. The compositions of the latter four samples, as predicted by X-ray fluorescence, were then compared to atomic absorption results. X-ray fluorescence and atomic absorption results agree best when the concentrations of elements in the standards are …

Preparation Of Aniline-Formaldehyde Ion-Exchanger Fiber : Part I : Polymer Synthesis And Fiber Curing, Ching-Hsin Chen

Theses

Aniline-Formaldehyde polymer was synthesized by a new procedure ( as opposed to the conventional approach ). With an equal molar ratio of aniline and formaldehyde and a small amount of oxalic acid, the resulted polymer is free from gels and is suitable for fiber transformation.

The polymer is a transparent yellowish resin, having a melting range between 100-115C, and an average molecular weight 1200. The polymer was intended to be the precursor material for ion-exchange fibers. However, due to the time limit, this thesis only covers the work of polymer synthesis, fiber spinning and the identification of an crosslinker.

Among …

A Purely Chemical Nitrogen Dioxide Laser, Conrado Mendoza Malalis

Theses

Purely chemical lasers promise to provide future high-power lasers for remote installations, airplanes, ships and in space without the necessity of external electric power, sources.

This study is about the design and construction of a new, gas phase purely chemical NO₂ laser, based on the reaction of NO + O₃ + NO≠₂ + O₂. The vibrationally excited NO≠₂ species at 1-40 mm Hg total pressure is the source of energy (photons) for the laser. A series of computer program calculations on the reaction kinetics and relaxational processes involved have also been made, …

Analysis Of Combustion Products Of Kynol And Nomex, Abdul Halim Hassan Housny

Theses

The gaseous products generated by flaming combustion of Kynol and Nomex fibers under the same conditions (temperature 300-700°C, natural air) were quantitatively analyzed by infrared spectrophotometry, gas chromatography, mass spectrometry and a colorimetric tube method. The four techniques were chosen to examine the wide range of volatile and condensable products expected due to their different capabilities and sensitivities.

The main gases generated were carbon monoxide, carbon dioxide, methane and benzene.

The mass spectrometer was used to identify the condensed vapors. These were mainly phenol, methyl phenol and dimethyl phenol from the Kynol fiber and benzene, aniline, diaminobenzene, benzoic acid, benzonitrile, …

Thermal Decomposition Products Of Kynol And Nomex With Reference To Structure And Toxicity, Shaker H. El-Sherbini

Theses

The purpose of this investigation was to study the combustion products of KYNOL and NOMEX as a fire retardant fibers. From the quantitative analysis data of the combustion products, the polymer structure is discussed and the property of thermal stability is explained.

From the analysis of the combustion products, the toxicity indices for the two fibers are determined. It is found to be 0.1 for KYNOL and 0.71 for NOMEX. This can be interpreted to mean that, if one gram of MIDI, is decomposed and the combustion products were diffused in one cubic meter of air, the probability of dying …

A Study Of The Vibrational Spectra Of Some Monosubstituted Benezene Derivatives Of Group Via Of The Periodic Table, Fawzi S. Rasheed

Theses

The vibrational frequencies for (C₆H₅)₂Se, (C₆H₅)₂Te, (C₆H₅)₂Se₂, (C₆H₅)₂Te₂, (C₆H₅)₂Hg, and (C6H5-Se)₂Hg are completely assigned and are consistent with the vibrational assignments for (C₆H₅)₂O, (C₆H₅)₂S, and (C₆H₅)₂S₂ previously reported. Further, whereas (C₆H₅)₂O and to a lesser extent (C₆H …

A Study Of The Vibrational Spectra Of Some Monosubstituted Pyridines, Hussein Ibrahim Abdel-Shafy

Theses

Infrared spectra in the range (4000-250 cm^-1) and Raman spectra in the range (4000-150 cm^-1) of pyridine, 2-, 3- and 4-chloro-, bromo-, and methylpyridines, 2-fluoro-, 2-amino and 4-ethylpyridines have been measured. The spectra, vibration and assignments of the observed frequencies of 2-amino-, and 4-ethylpyridines are presented for the first time. The infrared data for 2-fluoropyridine is combined with the previously reported Raman data of Stephenson and Voelz to allow complete vibrational assignments for this compound for the first time. Frequency assignments for the other molecules are re-examined and where necessary changes and/or additions in frequency assignments …

Rubbery Acrylic Polymer Adhesives, Steven Walter

Theses

This study shows how rubbery acrylic polymer adhesives can be used to adhere rubber substrates to each other. Two substrate rubber compounds were used. A styrene-butadiene copolymer and a styrene-acrylonitrile copolymer. The adhesives were homopolymers based on polybutyl acrylate and poly2-ethyl hexyl acrylate.

Two reference standards were used. The first was commercial rubber based, solvent cements. The second was commercial acrylic solution polymers. All experimental work was compared to these standards. An attempt was made to optimize the adhesive components, as well as the adhesive application procedures and curing conditions.

A primer coating consisting of polymer, monomer, and catalyst was …

Biocatalytic Oxidation Of Nitrilotriacetate, Saul Hammerman

Theses

The specific scope of this work is to study the biological and chemical effects of a single genetic strain of bacteria, Bacillus subtilis #9524, on the specific destruction to innocuous products of sodium nitrilotriacetate (NTA) and sodium tripolyphosphate (STPP). Insofar as the same strain of bacteria was used each time, under limited variability and sterile conditions, the side effects of multiple bacterial strains and their inter-relationships among themselves and the organic substrates are eliminated. This has allowed for excellent replication of results.

This is a generalized technique for the evaluation of the biodegradability of a compound. Whereas tests with activated …

An Analysis Of The Geneva Mechanism As A Timing Device, Hubert W. Meyer

Theses

A mathematical analysis of the Geneva mechanism was conducted to determine the potential of this device as a tinting mechanism, and the feasibility of replacing the widely used pallet and starwheel escapement with a Geneva mechanism.

The primary objective of the study was to determine if the Geneva mechanism will attain a terminal velocity, and if so, how much time is required to reach this velocity.

To accomplish this objective, the differential equation of motion for the system was derived using Lagrangian dynatos. The equation was programmed and solved on a digital computer.

The study indicated that the Geneva mechanism …

The Chemistry Of Azides, Edward D. Nelson

Theses

A review of the decomposition of alkyl and aryl azides by thermolysis and photolysis has been accomplished. Organic azides are a very distinct species that undergo its own unique reactions. Azides decompose to form an electron deficient nitrogen having a sextet of elcctrons. This is called a Nitrene. Nitrenes can exist in the singlet or triplet state. The triplet behaves like a diradical. General and specific reactions of nitrenes have been shown with detailed mechanisms accounting for the products. The main modes of nitrene stabilization are rearrangement, hydrogen abstraction and insertion. Insertion is characteristic of singlet species and abstraction characteristic …

Continuous Interfacial Polycondensation Of Nylon 6-10, Sumer Raj Hundia

Theses

Nylon 6-10 has been prepared by continuous interfacial polycondensation hexamethylenedlamine and sebacoyl chloride in a stirred system. The effect of monomer concentration and stirring on the intrinsic viscosity of the polyamide 6-10 solution in m-cresol was measured.

As stirring (RPM) and monomer increased the intrinsic and the polymer yield through a maximum. Diffusion coefficients (D_AB) for hexamethylenedlamine were for hexamethylenedlamine were and were used for the calculations of j_D factors and K/DAB ratios. A relationship and j_D factors was established by a correlation curve.